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Date submitted2024-04-16
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Date accepted2024-09-24
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Date published2024-11-12
Deep-buried Lower Paleozoic oil and gas systems in eastern Siberian Platform: geological and geophysical characteristics, estimation of hydrocarbon resources
The study of deep-buried oil and gas systems is a promising trend in the preparation of hydrocarbon resources. The study of the factors determining oil and gas potential is extremely important. The Lena-Vilyui sedimentary basin in the eastern Siberian Platform has a potential for the discovery of large oil and gas fields in deep-buried Cambrian deposits. The use of original methodological approaches to the analysis of black shale and overlying deposits, generalization of the results of lithological, biostratigraphic and geochemical studies of Cambrian deposits in territories adjoining the study area, modern interpretation of geophysical data showed that siliceous, carbonate, mixed rocks (kerogen-mixtite) of the Kuonamka complex and clastic clinoform-built Mayan deposits are most interesting in terms of oil and gas potential. Oil and gas producing rocks of the Lower and Middle Cambrian Kuonamka complex subsided to the depths of 14 km. The interpretation of modern seismic surveying data confirms the hypothesis of a limited occurrence of the Upper Devonian Vilyui rift system. Based on generalization of geological, geophysical and geochemical archival and new materials on the Lower Paleozoic deposits of the eastern Siberian Platform, a probabilistic estimation of geological hydrocarbon resources of the Cambrian and younger Paleozoic complexes in the Lena-Vilyui sedimentary basin was performed. Based on basin modelling results it was concluded that the resources were mainly represented by gas. It is presumed that oil resources can be discovered in traps of the barrier reef system as well as on the Anabar and Aldan slopes of the Vilyui Hemisyneclise. With a confidence probability of 0.9, it can be stated that total initial resources of oil and gas (within the boundaries of the Vilyui Hemisyneclise) exceed 5 billion t of conventional hydrocarbons. The recommended extremely cautious estimate of resources of the pre-Permian complexes is 2.2 billion t of conventional hydrocarbons. In the study area, it is necessary to implement a program of deep and super-deep parametric drilling without which it is impossible to determine the oil and gas potential of the Lower Paleozoic.
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Date submitted2024-04-25
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Date accepted2024-09-24
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Date published2024-11-12
Specific features of kinetics of thermal transformation of organic matter in Bazhenov and Domanik source rocks based on results of pyrolysis gas chromatography
Pyrolysis of organic matter with subsequent analysis of hydrocarbon composition of the resulting products allows obtaining multicomponent distribution spectra of the generation potential by the activation energies of reactions of kerogen transformation into hydrocarbons. Configuration of the spectra depends on the structure of kerogen and is individual for each type of organic matter. Studies of kerogen kinetics showed that the distribution of activation energies is unique for each oil source rocks. The kinetic model of thermal decomposition of kerogen of the same type, for example, marine planktonic (type II), can differ significantly in different sedimentary basins due to the multivariate relationship of chemical bonds and their reaction energy threshold. The developed method for calculating multicomponent kinetic spectra (four-component models are used) based on results of pyrolysis gas chromatography allows obtaining one of the most important elements of modelling the history of oil and gas generation in geological basins. Kinetic parameters of organic matter of oil and gas source rocks influence the onset time of generation and directly reflect differences in the composition and structure of different types of kerogens. The results of determining the kinetic parameters of two high-carbon source rocks occurring across the territory of three oil and gas basins are shown. Generation and updating of the data of kinetic models of certain oil and gas source rocks will increase the reliability of forecasting oil and gas potential using the basin modelling method.
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Date submitted2024-05-03
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Date accepted2024-09-05
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Date published2024-11-12
Platinum group elements as geochemical indicators in the study of oil polygenesis
This study examines elements of the platinum group (PGE), primarily platinum and palladium, as geochemical indicators in the investigation of oil polygenesis. It has been found that, like other trace elements such as nickel, vanadium, and cobalt, platinum group elements and gold can occur in oil fields at both background levels and in elevated or even anomalously high concentrations. The objective of this research is to analyze PGE and trace elements as geochemical markers to identify the geological factors, including endogenous processes, responsible for these unusually high concentrations in oil. A comprehensive review of the literature on this subject was conducted, along with new data on the presence of precious metals in oils from Russia and globally. The study explores the geological mechanisms behind elevated PGE concentrations in oils, utilizing atomic absorption spectroscopy with atomization in the HGA-500 graphite furnace to measure PGE content. Previously, the tellurium co-deposition method (ISO 10478:1994) was used to isolate noble metals from associated elements. Possible geological origins of abnormally high concentrations of platinum metals in oils have been identified. These include endogenous factors such as the spatial proximity of oil fields to ultrabasic rock massifs, the effects of contact-metasomatic processes, and influences from mantle dynamics. Moreover, data concerning mantle elements can serve as indicators of the depth origins of certain hydrocarbon fluids, thus contributing to the study of oil polygenesis.
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Date submitted2022-03-01
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Date accepted2024-06-03
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Date published2024-12-25
Study of the possibility of using high mineralization water for hydraulic fracturing
The results of laboratory studies aimed at developing hydraulic fracturing fluid based on alternative sources of high mineralization water are presented. It is shown that Cenomanian sources have the most stable mineralization parameters, while bottom water and mixed waters collected from pressure maintenance systems differ significantly in their properties, with iron content varying several times, and hardness and mineralization undergoing substantial changes. The quality of the examined hydraulic fracturing fluids based on alternative water sources is confirmed by their impact on residual permeability, as well as residual proppant pack conductivity and permeability. The experimental results show similar values for these parameters. The comprehensive laboratory studies confirm the potential for industrial use of high mineralization water in hydraulic fracturing operations.
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Date submitted2024-10-29
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Date accepted2024-10-29
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Date published2024-11-12
Study of thermodynamic processes of the Earth from the position of the genesis of hydrocarbons at great depths
In the context of significant depletion of traditional proven oil reserves in the Russian Federation and the inevitability of searching for new directions of study and expansion of the raw material base of hydrocarbon raw materials in hard-to-reach regions and on the Arctic shelf, a scientific search is underway for accumulations in complex geological conditions and in manifestations that differ significantly from traditional ones, which include the processes of oil and gas formation and preservation of oil and gas in low-permeability “shale” strata and in heterogeneous reservoirs at great and super-great depths. Within the oil and gas provinces of the world, drilling of a number of deep and super-deep wells has revealed deposits at great depths, established connections between hydrocarbon deposits and “traces” of hydrocarbon migration left in the core of deep wells, which has made it possible to significantly re-evaluate theoretical ideas on the issue of oil and gas formation conditions and the search for technologies aimed at solving applied problems. Modern geochemical, chromatographic, bituminological, coal petrographic and pyrolytic methods of studying oil and bitumoids extracted from the host rocks of deep well cores give a hope for identifying correlations in the oil-source system, revealing processes that determine the possibility of hydrocarbon formation and accumulation, and defining predictive criteria for oil and gas potential at great depths.
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Date submitted2023-11-15
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Date accepted2024-09-24
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Date published2024-12-25
Development and validation of an approach to the environmental and economic assessment of decarbonization projects in the oil and gas sector
- Authors:
- Nadezhda A. Sheveleva
This article addresses the problem of selecting a priority decarbonization project for an oil and gas company aiming to reduce greenhouse gas emissions. The wide range of decarbonization options and assessment methods prompted the development of a comprehensive ranking system for project selection. This system incorporates both internal and external factors of project implementation, a two-stage algorithm that filters out unsuitable projects taking into account sustainable development goals, and a quantitative evaluation approach using absolute and relative indicators. The proposed system evaluates decarbonization projects by considering not only the reduction of emissions in both absolute and relative terms, but also the broader environmental, social, and economic aspects relevant to the oil and gas company and the national economy. It includes a ranking mechanism for identifying priority projects and integrates carbon regulation incentives and green taxonomy tools into the economic assessment for more precise comparative analysis. The quantitative assessment in absolute terms involves a specialized net present value calculation, which accounts for revenue from both carbon credit sales and the potential sale of new low-carbon products, if applicable. The proposed assessment provides for targeted analysis of specific performance indicators, such as the cost per unit of emissions reduced, tax and social security contributions per unit of emissions reduced, energy efficiency improvements, and other indicators used for additional assessments of projects under otherwise equal conditions.
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Date submitted2022-10-04
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Date accepted2024-03-05
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Date published2024-08-26
Localization and involvement in development of residual recoverable reserves of a multilayer oil field
During waterflooding of a multilayer oil field there is a constant deterioration of the structure and composition of residual reserves due to geological and technological reasons. The largest share of residual reserves is localized in pillars, which arise from uneven development of the production facility and are undrained or poorly drained zones. The results of a quantitative assessment of the distribution of residual oil reserves in the Middle and Upper Devonian deposits of the Romashkinskoe oil field of the Republic of Tatarstan are presented. A retrospective method is proposed to identify reserves by analyzing and summarizing historical exploration data and the long history of reservoir development, and a calculation algorithm is proposed to quantify them. It has been established that residual oil reserves are localized in rows of dividing and injection wells, as well as in the central rows of producing wells in a three-line drive, in abandoned and piezometric wells, in the areas adjacent to the zones of reservoir confluence, pinch-out, oil-bearing contours, distribution of reservoirs with deteriorated porosity and permeability properties. Depending on geological conditions, algorithms for selecting geological and technical measures to include localized reserves in development and forecasting production profiles were proposed. According to the proposed method, residual recoverable reserves were identified and a number of wells were recommended for experimental works on their additional recovery: in well 16 (hereinafter in the text, conventional well numbers are used) after isolation of overlying high-water-cut formations, the additional perforation was carried out and oil flow was obtained. Additional perforation in well 6 resulted in oil recovery during development as well. Thus, the developed approaches to identifying residual recoverable reserves and patterns of their spatial distribution can be recommended in other multilayer oil fields with a long history of development.
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Date submitted2023-09-29
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Date accepted2023-10-25
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Date published2024-08-26
Laboratory studies of transformation of porosity and permeability and chemical composition of terrigenous reservoir rocks at exposure to hydrogen (using the example of the Bobrikovskii formations in the oil field in the northeast Volga-Ural oil and gas province)
The article describes the methodology for laboratory studies of reservoir rock exposure to hydrogen. The stages of sample research and the instruments used in the experiments are considered. A comparative analysis of the results of studies on porosity and permeability of core samples was performed. It was shown that after exposure to hydrogen, the porosity decreased by 4.6 %, and the permeability by 7.9 %. The analysis of correlation dependencies demonstrated a typical change in the relationship of these characteristics: after the samples exposure to hydrogen the scatter of the values increased and the correlation coefficient decreased, which indicates a change in the structure of the void space. Based on the research results, it was concluded that the decrease in porosity and permeability of the core samples occurred due to their minor compaction under the action of effective stresses. The chemical analysis of the rock showed no major difference in the composition of the basic oxides before and after exposure to hydrogen, which points to the chemical resistance of the studied formation to hydrogen. The experimental results showed that the horizon under consideration can be a storage of the hydrogen-methane mixture.
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Date submitted2022-11-21
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Date accepted2024-05-02
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Date published2024-08-26
M1 formation tectono-structural features and gas-oil potential within Archinskaya area Paleozoic basement (Western Siberia)
- Authors:
- Vladimir B. Belozerov
- Mikhail O. Korovin
Western Siberian Plate basement oil and gas potential evaluation largely depends on structural and stratigraphic complex architecture representation. New modern procedures for seismic data processing, detailed Paleozoic deposits stratigraphic studies and expanded geophysical well logging significantly change the representation of the basement rocks fold-block structure and previously developed hydrocarbon reservoirs models. Detailed studies conducted within the Archinskii uplift showed that Paleozoic sediments form a contrasting folded structure complicated by block tectonics. The significant block displacements amplitude determines the lithological and stratigraphic basement rocks erosional-tectonic surface, while the identified stratigraphic blocks control the oil productivity distribution within the Archinskaya area. The filtration-capacity heterogeneity folded structure of the Paleozoic sediments is reflected in the distribution of hydrocarbon saturation in the well section, forming independent gas, oil, and oil-water zones for the development process. The relationship between anticlinal structural forms of basement rocks to lowered, and synclinal to elevated blocks, determines the necessity to conduct exploration prospecting within younger stratigraphic blocks when assessing the deep Paleozoic oil and gas potential.
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Date submitted2024-06-12
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Date accepted2024-07-18
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Date published2024-07-26
Development of parameters for an industry-specific methodology for calculating the electric energy storage system for gas industry facilities
- Authors:
- Ivan S. Tokarev
The issue of determining the main parameters of electric energy storage systems – power and energy intensity – is being considered, the determination of which is a fundamentally important task when introducing such devices into the power supply systems of enterprises for both technical (technological) and economic reasons. The work analyzes problems that can be solved by installing electricity storage systems at gas industry facilities. An industry-wide methodology has been developed for calculating the parameters of an electricity storage system based on traditional methods and methods aimed at minimizing the standardized cost of electricity with adaptation to the conditions of the gas industry. A distinctive feature of the presented methodology is the ability to determine the power and energy intensity of electricity storage systems when performing several functions. The methodology was tested at a typical gas industry facility – the Yarynskaya compressor station of OOO Gazprom Transgaz Ukhta, a characteristic feature of which is an autonomous power supply system. An example is given of calculating the electricity storage normalized cost using an improved LCOS indicator, which takes into account the effect of changing the fill factor of the electrical load schedule on the amount of gas consumption by a power plant for its own needs. To confirm the economic efficiency of introducing electricity storage systems calculated using the above methodology, calculations of the integral effect, net present value and efficiency index are presented.
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Date submitted2024-03-30
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Date accepted2024-06-03
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Date published2024-07-04
Preparation and use of complex titanium-containing coagulant from quartz-leucoxene concentrate
- Authors:
- Evgenii N. Kuzin
The search for the new high-efficiency reagents for wastewater treatment is a challenging and urgent task. Titanium-containing coagulants represent a new trend in water treatment and have a much higher efficiency that the traditional aluminium and iron-containing coagulants. The high cost of reagents significantly hinders their implementation. Complex titanium-containing reagents are coagulants prepared by modifying the traditional coagulants by adding 2.5-10.0 wt.% titanium compounds. In this work, titanium tetrachloride prepared from quartz-leucoxene concentrate was prehydrolyzed with subsequent double decomposition with sulfuric acid. The resulting mixture of hydrochloric and sulfuric acids was neutralized with aluminium hydroxide/oxide to form a self-hardening mixture (chemical dehydration). The sample of a complex sulfate-chloride titanium-containing coagulant was a mixture of AlCl3·6H2O – 5-20 wt.%, Al2(SO4)3·18H2O – 70-90 wt.% and TiOSO4 – 2.5-10.0 wt.%. It was proved that by changing the ratio of aluminium oxide/hydroxide and titanium tetrachloride at the stage of prehydrolysis and double decomposition, it is possible to obtain samples of a complex coagulant with different contents of the modifying additive of titanium compounds. An assessment of the coagulation properties of the complex reagent demonstrated its higher efficiency in cold water compared to aluminium sulfate. Studies on the use of the complex titanium-containing coagulant in the process of wastewater treatment from phosphate anions and suspended matter demonstrated its higher efficiency as compared to that of traditional reagents. The advantages of the prepared reagent are a reduction in the effective dose of the reagent, minimization of residual concentrations of pollutants in purified water, intensification of the processes of sedimentation and filtration of coagulation sludge. Purified water can be reused in the recycling water supply system. The use of quartz-leucoxene concentrate and titanium tetrachloride obtained from it as the source material would not only minimize the cost of the resulting complex coagulant, but also take a step towards the implementation of the Zero Waste concept.
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Date submitted2024-01-31
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Date accepted2024-06-03
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Date published2024-07-04
Rationale for a possibility of using humic preparations production waste for wastewater purification from metals (Cd2+, Zn2+, Mg2+, Cu2+) aimed at developing efficient measures on environmental rehabilitation
Results of studying optimal conditions and parameters for afterpurification of underspoil waters from metal ions using humic acids production waste are presented with a view to develop the efficient measures on environmental rehabilitation of ecosystems disturbed by the development of copper pyrite deposits. The influence of contact time and waste dosage on the purification process was analysed, changes in the pH of wastewater and its impact on the growth and development of plants were studied. The key factors were identified allowing to achieve the efficiency of the purification process – the optimal contact time in the range from 120 to 180 min and waste dosage of 10 g/l. The study showed that the use of waste resulted in a neutral pH value of 7.03 compared to the initial pH value of 5.95. It was ascertained that the use of iron-magnesium production waste in combination with waste from humic preparations production made it possible to achieve the MPC of commercial fishing importance (with the exception of magnesium). Wastewater after the afterpurification process with high magnesium concentrations did not have a stimulating effect on the growth and development of Lepidium sativum L. plants. From biotesting results it can also be stated that there is no negative impact on the growth and development of Lepidium sativum L. The results obtained indicate a potentiality of using afterpurified wastewater for watering plants in the process of initiating the environmental rehabilitation of the disturbed ecosystems.
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Date submitted2024-05-02
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Date accepted2024-06-03
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Date published2024-07-04
Iron ore tailings as a raw material for Fe-Al coagulant production
The paper presents the results of experimental research into the recovery of Fe-Al coagulant from iron ore tailings (IOTs). The variables investigated in the laboratory tests included sulphuric acid concentration, temperature, leaching time, solid/liquid phase ratio (S:L) and the presence of stirring. The experiment determined the composition of the coagulant and the solid residue after leaching. The maximum iron content in the solution after leaching was obtained using 40 % H2SO4 at a temperature of 100 °C (or with stirring at 75 °C) and a contact time of 60 minutes. In this case, the iron yield was at the level of 25 % of the total content in the iron ore tailings. Chemical analysis of the solution obtained after leaching showed Fe and Al sulphate contents of 11 and 2 % respectively. In the next step, the efficiency of the coagulant was evaluated on model solutions of colour. The experimental results showed that the coagulant obtained from the iron ore tailings can be used for wastewater treatment in a wide pH range from 4 to 12 pH units. The solid residue after leaching is a fine-grained powder rich in silica, which can potentially be used as an artificial raw material in the construction industry. The research carried out in this thesis has shown that the extraction of coagulants from iron ore tailings can be considered as a way to extend the production chain of iron ore mining and to minimise the amount of tailings to be stored in tailing ponds. The technical solution presented in this work allows to comprehensively solve the problem of environmental protection by creating new target products for wastewater treatment from IOTs.
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Date submitted2024-07-04
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Date accepted2024-07-04
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Date published2024-07-04
Environmental safety and sustainable development: new approaches to wastewater treatment
In 2015, the UN member states adopted the 2030 Agenda for Sustainable Development. Despite significant progress, billions of people – one in three people – do not have access to safe, clean drinking water. Modern wastewater treatment methods include a wide range of biological, chemical and physical processes, each having its own advantages and applications. This thematic volume considers the latest achievements in wastewater treatment technologies, wastewater purification and treatment as well as their potential applications at the local level. The problem of surface water pollution is relevant for all regions of the world. One of the largest sources of pollutants is mining and processing industry. The first stage in the development of wastewater treatment technologies is monitoring of anthropogenically modified water bodies.
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Date submitted2024-03-07
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Date accepted2024-06-14
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Date published2024-07-04
Anomaly detection in wastewater treatment process for cyber resilience risks evaluation
Timely detection and prevention of violations in the technological process of wastewater treatment caused by threats of different nature is a highly relevant research problem. Modern systems are equipped with a large number of technological sensors. Data from these sensors can be used to detect anomalies in the technological process. Their timely detection, prediction and processing ensures the continuity and fault tolerance of the technological process. The aim of the research is to improve the accuracy of detection of such anomalies. We propose a methodology for the identification and subsequent assessment of cyber resilience risks of the wastewater treatment process, which includes the distinctive procedure of training dataset generation and the anomaly detection based on deep learning methods. The availability of training datasets is a necessary condition for the efficient application of the proposed technology. A distinctive feature of the anomaly detection approach is a new method of processing input sensor data, which allows the use of computationally efficient analytical models with high accuracy of anomaly detection, and outperforms the efficiency of previously published methods.
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Date submitted2024-03-29
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Date accepted2024-06-03
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Date published2024-07-04
Potential use of water treatment sludge for the reclamation of small-capacity sludge collectors
- Authors:
- Olga M. Guman
- Irina A. Antonova
In small settlements, collectors for the sludge produced during water treatment processes are small-sized and located in the vicinity of drinking water storage reservoirs or in coastal areas. Sludge removal is not economical. Besides, the relief depressions formed after sludge disposal are required to be reclaimed. In ore mining regions, where the main settlements of the Urals are located, sludge produced in water treatment has high contents of heavy metals typical of ore mining provinces. Consequently, places of sludge accumulation are potential sources of water pollution. The article discusses the possibility to mix sludge with slaked lime and local overburden with the help of special equipment. So far water treatment sludge in the region has been used to reclaim the surface of solid waste landfills by creating anaerobic conditions for waste decomposition. When placed inside the embankment dams as an independent object, sludge needs to be improved for the increase of its bearing capacity and the ability to bind heavy metals. The article aims at the substantiation of the composition and properties of the reclamation material made of the water treatment sludge mixed with local overburden and slaked lime (technosoil). For this reason the paper describes the composition of the sludge in a sludge collector, the composition and properties of the overburden rocks as a component of the mixtures with water treatment sludge, the composition and properties of the mixtures of water treatment sludge with overburden rocks and Ca(OH)2 as a component dewatering sludge and neutralizing toxicants. Furthermore, the research work provides the technology created for the optimal processing of the water treatment sludge in the process of the reclamation of a sludge collector. The research results and the experience obtained in reclamation of disturbed lands in the region have confirmed the possible use of technosoil for the reclamation of small-capacity sludge collectors. The analysis of the chemical composition and physical and mechanical properties of the mixtures under study has shown that the most economical and environmentally sound reclamation material is a mixture of water treatment sludge, loose overburden dump soils and Ca(OH)2 in a ratio of 60 : 30 : 10 %.
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Date submitted2024-04-09
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Date accepted2024-06-03
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Date published2024-07-04
Analysis of the geochemical barriers effectiveness as the basis for the use of nature-like water purification technologies
Nature-like technologies are being introduced into many human activities including mining wastewater treatment. This work is based on long-term studies of the Sibay copper-zinc-pyrite deposit development. It is dedicated to assessment of geochemical barriers effectiveness in Cu, Zn, Cd removal from water of the Karagayly River (receiving quarry and dump drainage water). The research is based on the elements’ content and forms in water and bottom sediments, pH values etc. Four types of hydrogeochemical environment (formed due to changes in the water use over the past 20 years) were distinguished using discriminant analysis. The mechanisms of barriers formation and destruction were described. Statistical modeling of the metals’ precipitation was performed by multivariate regression analysis. Cu is adsorbed by recently formed Fe hydroxides, and, to a lesser extent, precipitates with sulfates as water pH increases. Antagonism to Mn hydroxides has been demonstrated, due to different physicochemical conditions for their precipitation. Zn enters solid phase mainly with sulfates, this element also forms its own mineral phases. The second mechanism is adsorption by recently formed Mn hydroxides, which corresponds to the idea of similar conditions for the precipitation of metal hydroxides. Cd behavior reflects conditions intermediate between these of Cu and Zn. Contribution of both mechanisms (related to Fe hydroxides and aqueous sulfates) is equal. Antagonism to Mn is absent. According to the assessment results using of nature-like technologies in situ in watercourses, canals and other water drainage systems is promising. Developed statistical models can be used for needs of experimental studies and artificial geochemical barriers engineering.
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Date submitted2024-04-22
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Date accepted2024-06-13
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Date published2024-07-04
Comprehensive utilization of urban wastewater sludge with production of technogenic soil
The article presents the analysis of the existing approach to wastewater sludge treatment and justifies the selection of the most promising management technology that allows maximum use of wastewater sludge resource po-tential. To obtain a useful product (biocompost) suitable for use as part of technogenic soil, experimental studies of aerobic stabilization of organic matter of dehydrated urban wastewater sludge with the addition of other waste by using passive composting technology were carried out. The technology is included in the list of best available technologies (BAT). The selection of the most optimal components for the mixture was based on the results of determining the C and N content, humidity and pH of the components used that ensured the composting of organic waste. The results of laboratory studies of the obtained biocompost according to the main agrochemical and sanitary-epidemiological indicators are presented. Testing was carried out according to the criterion of toxicity of the biocompost’s aqueous extract. The assessment of the technogenic soil was performed when using biocompost in its composition for compliance with existing hygienic requirements for soil quality in the Russian Federation. Based on the results of the vegetation experiment, optimal formulations of the technogenic soil were determined, i.e., the ratio of biocompost and sand, under which the most favorable conditions for plant growth are observed according to a combination of factors such as the number of germinated seeds, the maximum height of plants and the amount of biomass. The conducted research makes it possible to increase the proportion of recycled urban wastewater sludge in the future to obtain soils characterized by a high degree of nutrient availability for plants and potentially suitable for use in landscaping, the biological stage of reclamation of technogenically disturbed lands, as well as for growing herbaceous plants in open and protected soil.
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Date submitted2024-04-25
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Date accepted2024-06-13
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Date published2024-07-11
Evaluation of the effectiveness of neutralization and purification of acidic waters from metals with ash when using alternative fuels from municipal waste
- Authors:
- Polina A. Kharko
- Aleksandr S. Danilov
The problem of pollution of natural water objects with heavy metals is extremely relevant for the areas where industrial enterprises are located. Unauthorized discharge of contaminated wastewater, inefficient operation of sewage treatment plants, as well as leakage of drainage waters from man-made massifs lead to changes in the hydrological system affecting living objects. The article studies the composition of ash from the combustion of alternative fuels from municipal waste, and also considers the possibility of using it to neutralize sulfuric acid drainage waters and extract metal ions (Cu, Cd, Fe, Mn, Zn) from them. It has been established that the efficiency of water purification from metals depends on the pH value achieved during the purification process. The pH value is regulated by the dose of the introduced ash, the contact time and depends on the initial concentration of metal ions and sulfates in the solution. Studies on the neutralization and purification of a model solution of sulfuric acid drainage waters of a tailings farm of known composition have shown that in order to achieve a pH of 8-9, optimal for precipitation of metal hydroxides Cu, Cd, Fe, Mn, Zn and Al washed out of ash, and water purification with an efficiency of 96.60 to 99.99 %, it is necessary to add 15 g/l of ash and stir the suspension continuously for 35 minutes. It was revealed that exposure to ash with sulfuric acid waters leads to the transition of water-soluble forms of metals into insoluble ones and their “cementation” with calcium sulfate. The amount of Zn and Fe ions washed out of the ash decreases by 82 and 77 %, Al, Cd, Cu, Mn – by 25 %. This reduces the toxicity of ash, which is proved by a decrease in the toxic multiplicity of dilution of the water extract by 14 times.
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Date submitted2023-05-21
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Date accepted2024-05-02
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Date published2024-08-26
Assessment of the influence of lithofacies conditions on the distribution of organic carbon in the Upper Devonian “Domanik” deposits of the Timan-Pechora Province
The study of high-carbon formations was instigated both by the decreasing raw material base of oil as a result of its extraction, and by the progress in development of low-permeability shale strata, primarily in the USA, Australia, and China. The most valuable formations occur in traditional hydrocarbon production areas – the West Siberian, Volga-Ural and Timan-Pechora, North Pre-Caucasian and Lena-Tunguska oil and gas provinces. Specific features of the Late Devonian-Early Carboniferous high-carbon formation occurring in the eastern marginal part of the East European Platform are: heterogeneous section due to intense progradation of the carbonate platform from west to east; succession of lithofacies environments that determined the unevenness of the primary accumulation and secondary distribution of organic matter (OM); possible migration or preservation in the source strata during the subsidence stages of the moving parts of bitumides, which determined the prospects for oil and gas potential. The distribution pattern of the present OM content was investigated depending on lithofacies conditions and lithological composition of rocks in the “Domanik type” Upper Devonian-Tournaisian deposits in the Timan-Pechora Province (TPP), its transformation degree to bring it to the initial content of organic carbon and further estimation of the share of stored “mobile oil” in oil and gas source formation. The study was based on the analysis of the data set on organic carbon content in core samples and natural exposures in the Ukhta Region in the Domanik-Tournaisian part of the section including more than 5,000 determinations presented in reports and publications of VNIGRI and VNIGNI and supplemented by pyrolytic and bituminological analyses associated with the results of microtomographic, macro- and lithological studies and descriptions of thin sections made at the Saint Petersburg Mining University. For each tectonic zone of the TPP within the investigated high-carbon intervals, the content of total volumes of organic carbon was determined. The data obtained allow estimating the residual mass of mobile bitumoids in a low-permeability matrix of the high-carbon formation.
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Date submitted2024-01-31
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Date accepted2024-05-02
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Date published2024-12-25
Evaluation of the effectiveness of water dust-suppressing emulsions based on acrylic and alkyd polymers
Currently, the use of special dust-suppressing reagents is promising to reduce the level of dust in the vicinity and on the territories of pits, mining and processing plants and other facilities with a high content of fine dust. The analysis of ways to reduce the dust-forming ability of inorganic dispersions with a high degree of dusting is carried out. Due to the lack of regulatory and technical documentation devoted to the standardization of quality control methods for dust-suppressing compounds, it becomes necessary to analyze existing parameters and methods for their determination in order to develop mandatory methods for controlling the properties of dust-suppressing compounds, films formed by them and consolidated systems. The study is devoted to substantiating the necessary methods for assessing the dust-forming ability of inorganic dispersions after treatment with various dust suppressants and evaluating their effectiveness. The parameters are considered and methods for quantifying the determination of the quality of the consolidated layer of dust samples using different dust-suppressing compositions are described. As a result of the analysis of the set of parameter values, it was found that the most resistant to the effects of negative factors due to the formation of a denser and more durable polymer matrix mesh are dusting surface samples treated with an emulsion of alkyd glypthalic resin on a water basis with a high agglomerating effect on particles of inorganic dispersion and the formation of a consolidated layer with a wetting angle of 92.5° and a compressive strength 0.56 MPa.
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Date submitted2024-02-01
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Date accepted2024-05-02
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Date published2024-06-18
Methodology for managing energy development of production facilities in the gas industry
- Authors:
- Anatolii A. Shapovalo
The current stage of Russia's development is characterized by dynamic changes in the operating conditions of gas industry enterprises, which leads, among other things, to significant adjustments in approaches to the development of energy production facilities. The article examines on the system level the ways to improve energy supply, taking into account the goals and objectives of the development of production facilities from the conditions of solving a single technological problem of the gas industry – high-quality gas supply to consumers. The optimal functioning of energy supply systems, taking into account the peculiarities of technological processes at production facilities, presupposes the development models coordination of production facilities energy complexes with the gas industry enterprises parameters based on an integrated unified information space at all stages of their life cycle. The structure of production facility energy complex and the connections of its elements with related systems are justified taking into account the purposes of their creation and the requirements for production facilities. Problem solving for each system element as well as the exchange of information between equivalent systems is done on the basis of a developed hierarchy of optimization problems adjusted depending on the type of tasks of energy supply improvement of a production facility. Determining the values of parameters and indicators of energy complexes, as well as optimizing the lists and content of work to improve the energy supply of production facilities, is planned to be carried out in accordance with the methodology under consideration using a set of mathematical models.
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Date submitted2024-01-18
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Date accepted2024-05-02
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Date published2024-12-25
Industrial clusters as an organizational model for the development of Russia petrochemical industry
The article explores the challenges facing Russia petrochemical industry over the past decade and examines the reasons behind its significant lag compared to other industrialized nations. It presents a review of academic research on clusters accompanied by a comparative analysis, generalization, and consolidation of factors influencing the development of the petrochemical industry in Russia. It is argued that advancing the petrochemical industry from production plants to integrated production complexes necessitates a shift towards clustering, which will improve resource utilization efficiency, bolster product competitiveness, and reduce production costs. The article examines and consolidates key cluster concepts, encompassing definitions, characteristics, composition, and constituent elements. It also examines strategic documents guiding the development of the petrochemical sector, assesses the progress made in forming petrochemical clusters in Russia, and draws upon European and Asian experiences and government support tools in the domain of petrochemical clusters. The successful development of petrochemical clusters in Russia is argued to be strongly dependent on state initiatives and support for infrastructure development. Additionally, the presence of research organizations within clusters is crucial for fostering high-tech product innovation and forming an efficient value chain that integrates research and development with specific assets. When establishing petrochemical clusters in Russia, it is essential to consider the unique characteristics of each cluster, including the types of raw materials and resources used, the necessary infrastructure, and the specific support measures and incentives provided by the state.
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Date submitted2023-07-07
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Date accepted2023-12-27
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Date published2024-12-25
A new insight into recording the mineral composition of carbonate reservoirs at well killing: experimental studies
Well killing operation remains an important technological stage before well workover or servicing, during which filtrate penetrates the bottomhole area of the formation. The impact of process fluids and their filtrate on rock has a significant influence on permeability and porosity of carbonate reservoirs, which decrease due to fines migration. There are few known scientific studies of the interaction of killing fluid filtrate with carbonate rock and fines migration. In our experiments, an aqueous phase was used which is the basis for well killing in pure form, for the preparation of blocking agents and is used in reservoir pressure maintenance system. Core samples taken from the pay of the reservoir were used to simulate the well killing process with generation of reservoir thermobaric conditions. Killing fluid filtrate was kept for seven days, which characterizes the average workover time at flowing wells in the fields of the Perm Territory. Using micro-X-ray tomography and scanning electron microscope, images were obtained before and after the experiment, which allowed confirming a decrease in total number of voids due to fines migration and, as a consequence, a decreasing permeability of samples. Measurement of pH and fines concentration in the aqueous phase was performed before and after the experiment and pointed to mineral reactions occurring as a result of rock dissolution. The results of experiments made it possible to record a decrease in permeability of carbonate samples by an average of 50 % due to clogging of void space and migration of fines (clayey and non-clayey).
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Date submitted2023-08-14
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Date accepted2023-12-27
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Date published2024-12-25
Modelling of compositional gradient for reservoir fluid in a gas condensate deposit with account for scattered liquid hydrocarbons
In oil and gas reservoirs with significant hydrocarbon columns the dependency of the initial hydrocarbon composition on depth – the compositional gradient – is an important factor in assessing the initial amounts of components in place, the position of the gas-oil contact, and variations of fluid properties throughout the reservoir volume. Known models of the compositional gradient are based on thermodynamic relations assuming a quasi-equilibrium state of a multi-component hydrodynamically connected hydrocarbon system in the gravity field, taking into account the influence of the natural geothermal gradient. The corresponding algorithms allow for calculation of changes in pressure and hydrocarbon fluid composition with depth, including determination of the gas-oil contact (GOC) position. Above and below the GOC, the fluid state is considered single-phase. Many oil-gas-condensate reservoirs typically have a small initial fraction of the liquid hydrocarbon phase (LHC) – scattered oil – within the gas-saturated part of the reservoir. To account for this phenomenon, a special modification of the thermodynamic model has been proposed, and an algorithm for calculating the compositional gradient in a gas condensate reservoir with the presence of LHC has been implemented. Simulation cases modelling the characteristic compositions and conditions of three real oil-gas-condensate fields are considered. The results of the calculations using the proposed algorithm show peculiarities of variations of the LHC content and its impact on the distribution of gas condensate mixture composition with depth. The presence of LHC leads to an increase in the level and possible change in the type of the fluid contact. The character of the LHC fraction dependency on depth can be different and is governed by the dissolution of light components in the saturated liquid phase. The composition of the LHC in the gas condensate part of the reservoir changes with depth differently than in the oil zone, where the liquid phase is undersaturated with light hydrocarbons. The results of the study are significant for assessing initial amounts of hydrocarbon components and potential efficiency of their recovery in gas condensate and oil-gas-condensate reservoirs with large hydrocarbon columns.