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Pashkevich Mariya A., Bykova Marina V. Methodology for Thermal Desorption Treatment of Local Soil Pollution by Oil Products at the Facilities of the Mineral Resource Industry. Journal of Mining Institute. 2022. DOI: 10.31897/PMI.2022.6
Gorlanov E.S., Leontev L.I. Directions in the technological development of aluminium pots // Journal of Mining Institute. 2023. EDN PYSEVM
Пашкевич М.А., Быкова М.В. Методология термодесорбционной очистки локальных загрязнений почв от нефтепродуктов на объектах минерально-сырьевого комплекса. Записки Горного института. 2022. DOI: 10.31897/PMI.2022.6
The use of stage-wise schemes in the development of deep quarries is one of the ways to increase the economic efficiency of mining a deposit and determining the optimal stage parameters remains an urgent task. Such parameters are stage depth, bench height, block length, etc. However, there is a wide range of values for these parameters. Therefore, to select the optimal values and evaluate the effectiveness of design solutions, it is advisable to use the net present value, which is an international notion. As a result of the analysis of data on deposits, a large number of variable indicators can be identified that presumably affect the efficiency of mining. The article proposes to divide all parameters of the quarry mining into two types: mine engineering and economic. The importance of each of them is determined by the measure of influence on the net present value. Thus, to assess the measure of influence of mining indicators, the average values of each of them are taken, and as a result of the alternating change of one parameter under study, the measure of its influence on the discounted income received is estimated. The results of the analysis of relevant factors, their evaluation and comparative analysis are important indicators that significantly affect the design decisions made and the effectiveness of the investment project.
This study focuses on the features of hydraulic fracture propagation in intersecting boreholes in polymethyl methacrylate blocks in a non-uniform stress field. Glycerol aqueous solution and plasticine were used as the working fluids. According to linear fracture mechanics, a stress concentrator at the borehole intersection contributes to the beginning of crack formation, with further crack propagation occurring in the plane containing their axes. The relevance of this study is due to the search for innovative approaches and the development of technological solutions to address the issue of effective longitudinal crack formation and its further propagation in a rock mass under unfavourable stress field conditions. This paper provides a scheme of laboratory stand operation and a general view of the sealing packers used to isolate a specified interval when performing tests. The graphs of glycerol pressure versus injection time are presented, and the breakdown pressure in the blocks is specified. The shape of fractures formed during the indentation of plasticine into the borehole system was investigated. The findings of physical modelling indicate that longitudinal cracks are predominantly formed in the boreholes. The deviation of the crack trajectory from the vertical plane containing the borehole axes is primarily affected by the magnitude of the horizontal compressive stress field rather than the increase in the angle between them. In addition, the angles of inclination of the longitudinal crack plane measured at its intersection with the side face of the block are specified.
One of the priority areas of scientific research in Antarctica is the study of its deep structure. Most of the continent is covered with a thick ice sheet, so the main geoscientific data are acquired using geophysical methods, among which magnetotelluric (MT) ones have the greatest penetration depth and insignificant environmental impact. The possibility of acquiring high-quality MT data in the conditions of the sixth continent has long been questioned. The work is aimed at studying the specifics of magnetotelluric survey in Antarctica. The following tasks were set: to summarize the world experience of studying Antarctica using MT sounding methods; to identify factors that negatively affect the high-quality data acquisition; to determine methods for minimizing the influence of these factors. The article analyses geophysical studies conducted by the magnetotelluric sounding method in the Antarctic region from 1964 to the present. The application of the method is complicated by the following: extremely low temperature affects the drop in the batteries capacity, freezing of the non-polarizing electrodes solution, and changes in the strength properties of materials. Electromagnetic noise occurs during strong winds; proximity to the magnetotelluric field source can violate the plane wave principle on which the method is based. The ice sheet covering most of Antarctica does not allow acquiring optimal values of the contact resistance of the electrode grounding; the extended coastline distorts the acquired data. Studies of the influence of factors complicating the MT sounding method in the coastal and central parts of Antarctica made it possible to formulate recommendations for preparing equipment and adapting the work procedure, modifying the processing flow and a set of measures to ensure safety, the implementation of which will both allow safe performance of geophysical investigations and high-quality data acquisition.
Artisanal small-scale gold mining is the largest artificial source of mercury pollution and has been a very common problem recently. This study examined the contribution of Hg release due to artisanal small-scale gold mining in contaminating the sediment of the watershed in Indonesia. Different from other methods, we measured Hg pollution using the stable isotopes of carbon and nitrogen. This report is the first time analytical reports in Indonesia since most papers focus primarily on only detecting heavy metals in river water and sediments, neglecting deep research on Hg pollution and resources. The findings of this study indicate that artisanal and small-scale gold mining activities, located in the upstream areas of the tributaries that act as point sources, are the primary source of mercury in the sediment of the Ciujung watershed. The isotopes δ13C and δ15N successfully trace the Hg-contaminated sediment in the Ciujung watershed derived from the Cisimeut and Ciberang Rivers based on soil organic matter. The biological effect showed the Hg concentration in most of the sampling sites exceeded the Effects-range medium and Probable effect limit values. The Risk quotient values of Hg indicated the Hg pollution had a possibility effect on the benthic organism. Several limitations have also been added in this study and needs for further investigation.
The Saltakh Massif is located in the northern Anabar Shield, in the Saltakh shear-zone. It consists of two-pyroxene schists and plagiogneisses metamorphosed under granulite-facies conditions. Their chemical composition is consistent with that of a differentiated series of rocks ranging from gabbro to tonalites with abundant alaskitic gneissose granite veins and bodies. The rocks are mainly high-potassium (K2O/Na2O > 0.50), high-magnesium (mg# 50-70), low-titanium (TiO2 0.35-1.31 wt.%) with low TiO2 concentration in clino- and orthopyroxene. Normative olivine makes up 6-9 % of metagabbroic rocks. The rocks display well-defined negative Ti, Nb, Ta, and P anomalies typical of subduction magmatism. The two-pyroxene gneisses show high Sr/Y ratios of 67.6-88 and (La/Yb)N of 24.8-25.6. Saltakh rocks are part of a shoshonite series, as indicated by Nb/La, La/Yb, Th/Nb and Ce/Yb ratios. All the rocks display positive εNd(T) values of 1.9-4.1 and εSr(T) of 0.77-17.8 indicative of a mantle source of magma and T(Nd)DM of 2,20-2,26 Ga. U-Pb zircon dating (SHRIMP II) has shown that the protoliths of Saltakh melanocratic rocks were dated at 2100-2086 Ma, and those of two-pyroxene plagiogneisses of tonalite composition were dated at 2025±7 Ma. Alaskitic gneissose granites were dated at 1969±7 Ma. The study of the trace element composition of zircon has revealed general enrichment in LREE. High LREE concentrations are due to secondary zircon alterations and the shoshonitic pattern of the melt, the high-temperature conditions of crystallization, and an anomalous fluid regime. The geodynamic setting in which the Saltakh Massif was formed was consistent with a pericontinental magmatic arc. The formation of alaskitic gneissose granites was due to anatexis provoked by later collision processes. Saltakh magmatic rocks were formed simultaneously with magmatic rocks from the Khapchan prospect which occur farther south, and were studied earlier (2095±10 Ma tholeiitic metadiorites and 2030±17 Ma calc-alkaline metatonalites). We interpret them as part of a metamorphosed juvenile Paleoproterozoic suprasubduction complex.
Due to the insufficient accuracy of existing studies of frozen sedimentary rock cutting process for practical calculations, the article solves the problem of determining the tangential component cutting resistance for blocked, deep blocked and cell cutting, which are currently the most commonly used methods in earthmoving equipment. The cutting tool and rock mass force interaction is considered from the point of view of the emerging stresses, which act on the separated chip element. The analytical dependences for determining the tangential component of cutting resistance were obtained. The numerical explanation of the choice of cell cutting in relation to blocked and deeply blocked cutting is given. For all three methods of cutting, under equal geometrical parameters of the cutting tool and the physical and mechanical properties of the frozen rock, the numerical value of the tangential component of cutting resistance is obtained. The comparison of the cutting resistance estimated values has shown that cell cutting requires relatively less energy and is preferred during the process of frozen sedimentary rock excavation. During field and laboratory investigations with the use of a multi-purpose cutting stand, a sufficient convergence of the analytical statements with the physics of frozen sedimentary rock cutting process was established. The results of the research allow a more reasonable approach to the adjustment of existing methods for determining the required tractive force and power for the drive of an excavation machine, and, therefore, to the actual efficiency and profitability of work.
The current stage of Russia's development is characterized by dynamic changes in the operating conditions of gas industry enterprises, which leads, among other things, to significant adjustments in approaches to the development of energy production facilities. The article examines on the system level the ways to improve energy supply, taking into account the goals and objectives of the development of production facilities from the conditions of solving a single technological problem of the gas industry – high-quality gas supply to consumers. The optimal functioning of energy supply systems, taking into account the peculiarities of technological processes at production facilities, presupposes the development models coordination of production facilities energy complexes with the gas industry enterprises parameters based on an integrated unified information space at all stages of their life cycle. The structure of production facility energy complex and the connections of its elements with related systems are justified taking into account the purposes of their creation and the requirements for production facilities. Problem solving for each system element as well as the exchange of information between equivalent systems is done on the basis of a developed hierarchy of optimization problems adjusted depending on the type of tasks of energy supply improvement of a production facility. Determining the values of parameters and indicators of energy complexes, as well as optimizing the lists and content of work to improve the energy supply of production facilities, is planned to be carried out in accordance with the methodology under consideration using a set of mathematical models.
Numerous local varieties of weathering crusts are known in the South Timan. They differ in their position in the section, type of weathering products, substrates, and occurrence. The aim of the research is to identify patterns in the distribution of rock-forming, rare and rare earth elements and the composition of clay minerals in clay formations of the weathering crusts. The main task is to describe the occurrence and geochemical features that enable determining the genetic type and formation conditions of weathering crusts. The paper presents the results of a study of the distribution of petrogenic, rare earth, rare elements, and clay minerals in weathering crust of different ages, genetic types and occurrence conditions on the Dzhezhimparma Ridge and the Nemskaya Upland in the South Timan. We found that hydromica-kaolinite-type weathering crust is developed after the Late Riphean Dzhezhim Fm. rocks in the basement-cover contact zone on the Dzhezhimparma Upland, and the layer of fine-grained rock at the base of the Devonian section previously considered a weathering crust was formed as a result of mechanical destruction of the Devonian sandstones during movement in the thrust zone. In the Vadyavozh quarry located on the Nemskaya Upland, we studied and described the formations of Mesozoic-Cenozoic areal and linear weathering crusts after the Late Riphean Dzhezhim Fm. rocks. We found that micaceous siltstones in the siltstone-sandstone strata of the Dzhezhim Fm. are associated with the Riphean stage of crust formation and are composed of weathering crust material redeposited in the epicontinental basin.
First quantitative estimates are presented for nitrogen isotopic fractionation during diamond crystallization with respect to nitrogen-bearing fluid components using quantum-mechanical (DFT) calculations on the defect (with the substitutional nitrogen) diamond lattice. Provided equilibrium isotopic fractionation, 15N/14N ratio decreases within the sequence of compounds NH4+ > N2 > (diamond, NH3) > CH3N > CN− > NH2. At temperatures of 1,100 to 1,200 °C fractionation among diamond and fluid N-compounds are estimated at –2.23, –0.77, 0.01, 0.44, 1.31 and 2.85 ‰ and substantially (over 1 ‰) exceed the already available estimates based on the modeling diamond C-N bonds by analogy with HCN or CN – molecules. Depending on the dominant nitrogen and carbon substance in the mineral-forming fluid, diamond formation can be accompanied by different isotope compositional trends, as expressed either by zoned patterns within individual diamond grains or by isotopic δ15N vs δ13C covariations during successive crystallization. Provided the dominance of NH3 component (the reduced conditions, high pressures and the cold geotherm) nitrogen isotope fractionation between diamond and fluid does not exceed 0.1-0.2 ‰ and the isotope shifts at temperature ca. 1100 °C Δ15N << Δ13C. In nitrogen depleted reduced mantle fluids possible existence of compounds with low heavy isotope affinity at temperature of diamond formation (especially NH2) implies high isotope fractionation between diamond and the fluid and hence, evolved Δ15N/Δ13C ratios. Oxidized fluids dominated by CO2 or CO3 coupled with N2 component are characterized by close to zero Δ15N/Δ13C ratios as inferred by prevailing carbon isotope fractionation with respect to nitrogen isotopes, the latter change considerably with nitrogen distribution coefficient among diamond and the growth media.
A comparative financial and economic analysis is conducted of different public-private partnership (PPP) models for industrial infrastructure construction projects in an underdeveloped resource-rich region. The Stackelberg game theory-based model is used to build a parametrized family of bilevel mathematical programming models that describe an entire spectrum of partnership schemes. This approach enables a comparison of different strategies for the distribution of infrastructure investments between the government and the subsoil user and hence a scenario of transformation of Russia’s current PPP scheme into the classical partnership model, which is practiced in developed economies. To this end, a database is created on fifty polymetallic deposits in Transbaikalia, and a comparative analysis is conducted of Stackelberg-equilibrium development programs that implement different PPP models. The numerical experiment results show the classical PPP model to be most effective in the case of a budget deficit. The analysis helps assess the economic consequences of a gradual transformation of the partnership institution in industrial infrastructure construction from investor support in the Russian model to government support in the classical scheme. Intermediate partnership models, which act as a transitional institution, help reduce the budget burden. These models can be implemented by clustering the deposits, developing subsoil user consortia, and practicing shared construction of necessary transport and energy infrastructure. The intensification of horizontal connections between subsoil users creates favorable conditions for additional effects from the consolidation of resources and can serve as a foundation for a practical partnership scheme within the framework of the classical model.
The article presents an overview of the assessment and modelling of the stress state of rocks in the near-wellbore zone of horizontal wells during acid stimulation of the formation for improving the efficiency of oil and gas field development. A numerical finite element model of near-wellbore zone of the reservoir drilled by a horizontal section was compiled using one of oil fields in the Perm Territory as an example. The distribution of physical and mechanical properties of the terrigenous reservoir near the well was determined considering transformation under the action of mud acid for different time periods of its injection. Multivariate numerical simulation was performed and the distribution of horizontal and vertical stresses in near-wellbore zone was determined with regard for different values of pressure drawdown and changes in stress-strain properties depending on the area of mud acid infiltration. It was found that a change in elastic modulus and Poisson's ratio under the influence of acid led to a decrease in stresses in near-wellbore zone. Analysis of the stress distribution field based on the Coulomb – Mohr criterion showed that the minimum safety factor of rock even after the effect of mud acid was 1.5; thus, under the considered conditions of horizontal well modelling, the reservoir rock remained stable, and no zones of rock destruction appeared.
The development of new fields with low-permeability reservoirs required the introduction of new production technologies, of which the most significant for well killing and underground repair were multi-ton hydraulic fracturing, the simultaneous operation of two or three development sites by one well grid, and an increase in the rate of fluid extraction. These global decisions in field development have led to the need to search for new effective materials and technologies for well killing. The article is devoted to the analysis of problems associated with the process of killing production wells in fields characterized by increased fracturing, both natural and artificial (due to hydraulic fracturing), with reduced reservoir pressure and a high gas factor. The relevance of the analysis is due to the increase in the number of development sites where complications arise when wells are killed. Particular attention is paid to technical solutions aimed at preserving the filtration and capacity properties of the bottomhole formation zone, preventing the absorption of process fluid, and blocking the manifestation of gas. The classification of block-packs used in killing is given, based on the nature of the process fluid. Suspension thickened water-salt solutions are considered, forming a waterproof crust on the surface of the rock, which prevents the penetration of water and aqueous solutions into the formation. This approach ensures the safety and efficiency of killing operations, especially when working with formations in which maintaining water saturation and preventing the ingress of the water phase are of critical importance. Modern trends in the development of technology are revealed, and promising areas for further improvement of well killing with absorption control are outlined.
Possessing high strength, low density and significant chemical resistance, titanium has found wide application in various fields of the national economy – the chemical industry, aviation and rocket technology, mechanical engineering, medicine, etc. The production of titanium products is hampered by a fairly strong oxide film covering its surface. Removal of the oxide film from the surface of titanium workpieces is carried out by etching in solutions of mineral acids of various compositions. A spent acid etching solution (SAES) is formed, containing titanium salt and the remainder of unreacted acids. Almost all etching solutions contain HF and one of the strong acids. This is H2SO4, HCl or HNO3. Thus, the SAES includes ions of titanium, fluorine or chlorine, orsulfate, or nitrate. SAES is quite toxic and must be diluted or cleaned several times before being discharged into a reservoir. Most of the methods used to extract impurities contained in SAES lead to a decrease in their content. As a result of such purification, there is a loss of substances contained in SAES in significant quantities and of interest for further use. The work presents experimental results obtained from the combined processing of SAES containing titanium fluoride, hydrofluoric and hydrochloric acids. At the first stage, SAES is treated with sodium hydroxide. The resulting titanium hydroxide precipitate is filtered off. At the second stage, the filtrate containing sodium fluoride and chloride is processed in a membrane electrolyzer. In this case, not only the extraction of sodium salts from the filtrate occurs, but also the production of sodium hydroxide and a mixture of hydrofluoric and hydrochloric acids. Sodium hydroxide can be used for processing SAES, and a mixture of acids for etching titanium workpieces.
The article is devoted to solving the problem of voltage fluctuations in the power supply systems of ore mining enterprises. The connection of high-power consumers with abruptly variable operating mode (for example, high-voltage mining excavators) causes voltage fluctuations and sags, disabling electrical equipment, communication, and automation devices in the 6-10 kV distribution network, which disrupts technological processes, etc. The use of existing solutions and methods to reduce voltage variations caused by dynamic loads is not effective. To solve the problem, booster transformers with high-speed thyristor switches can be used to work out switching the control steps towards increasing or decreasing the voltage. The authors offer a new circuitry solution for a thyristor booster device (TBD) with a pulse-phase control method. The purpose of the research is to determine the control laws of TBD, which enable to effectively reduce voltage fluctuations from dynamic load in the power supply systems of mining enterprises. The article provides a schematic diagram of the TBD and describes the principle of operation of the device. Some modes of increasing and decreasing the output voltage of the TBD, as well as the basic mode (without voltage addition) are provided. Mathematical modeling of TBD control processes was carried out and adjustment characteristics were set taking into account the load power factor. On a simulation computer model of a 6 kV electric network with a dynamic load, the verification of the adjustment characteristics of TBD obtained during mathematical modeling was carried out. Based on the research results, the laws for regulating the output voltage of TBD were established. The TBD effective control range with normal permissible limits of odd harmonics have been determined. The conducted research will make it possible to implement the device control system.
The problem of pollution of natural water objects with heavy metals is extremely relevant for the areas where industrial enterprises are located. Unauthorized discharge of contaminated wastewater, inefficient operation of sewage treatment plants, as well as leakage of drainage waters from man-made massifs lead to changes in the hydrological system affecting living objects. The article studies the composition of ash from the combustion of alternative fuels from municipal waste, and also considers the possibility of using it to neutralize sulfuric acid drainage waters and extract metal ions (Cu, Cd, Fe, Mn, Zn) from them. It has been established that the efficiency of water purification from metals depends on the pH value achieved during the purification process. The pH value is regulated by the dose of the introduced ash, the contact time and depends on the initial concentration of metal ions and sulfates in the solution. Studies on the neutralization and purification of a model solution of sulfuric acid drainage waters of a tailings farm of known composition have shown that in order to achieve a pH of 8-9, optimal for precipitation of metal hydroxides Cu, Cd, Fe, Mn, Zn and Al washed out of ash, and water purification with an efficiency of 96.60 to 99.99 %, it is necessary to add 15 g/l of ash and stir the suspension continuously for 35 minutes. It was revealed that exposure to ash with sulfuric acid waters leads to the transition of water-soluble forms of metals into insoluble ones and their “cementation” with calcium sulfate. The amount of Zn and Fe ions washed out of the ash decreases by 82 and 77 %, Al, Cd, Cu, Mn – by 25 %. This reduces the toxicity of ash, which is proved by a decrease in the toxic multiplicity of dilution of the water extract by 14 times.
The article presents the findings from research conducted at Vostok Station during the 69th Russian Antarctic expedition. The primary goal of the research is to perform a thorough investigation of the snow-firn layer using both direct (drilling and core analysis) and indirect (georadiolocation and seismic exploration) methods. As part of the research, fundamental tasks related to the study of the structure and dynamics of the upper part of the ice sheet were addressed, as well as applied tasks aimed at justifying the depth of explosive charge placement for seismic work with the goal of conducting a detailed study of Lake Vostok and selecting the point for drilling access to the lake. Data on the microstructure and physical properties of the snow-firn layer were collected. The findings will allow for future improvements to the firn densification model, which is required to understand the evolution of ice grains during the early stages of metamorphism. The study's findings aided in the understanding of the structural features of the ice sheet's surface layer, allowing for more precise determination of the structural and physical characteristics of the snow-firn layer and ice, potentially leading to a better understanding of climatic and geological processes in Antarctica.
For more than 50 years, most rare earth elements were extracted from carbonatite deposits, which can contain different rare earth phases, but the main extracted minerals are bastnaesite, monazite and xenotime. Many studies focused on the improvement and development of dressing circuits for ores of these minerals. However, in some carbonatite complexes, rare earth deposits are composed partly or mainly of ancylite ores. This type of rare earth ores was very poorly studied in terms of dressability – previous experiments with ancylite ores are rare and not productive enough. Ancylite is the main concentrator of rare earth elements in most carbonatite complexes of the Devonian Kola Alkaline Province (northwest Russia). Dressability of ancylite ore from the Petyayan-Vara carbonatite field in the Vuorijärvi alkaline-ultramafic complex was assessed using the flotation method. The complex is one of the most potential rare earth deposits associated with carbonatites in the Kola Region. Petrographic and mineralogical studies demonstrated the occurrence of abundant iron and barite oxide inclusions in ancylite, which imposes restrictions on physical separation of these three minerals. The study of petrogeochemical and mineralogical composition of fractions formed during mechanical grinding of ores to a size less than 2.0 mm showed that even at this stage of sample preparation, the finest-grained fractions (less than 0.071 mm) were enriched in ancylite (to 19 vol.% or more with a content of 15 vol.% in ore). Three classes of reagents were considered as collectors in flotation experiments: fatty acids, alkyl hydroxamic acids, and amino acid derivatives. The reagent from the amino acid derivative class was highly efficient. The use of such a collector in combination with sodium hexametaphosphate depressant made it possible to obtain a flotation concentrate in an open circuit with total rare earth oxides content 33.4 wt.% at 64.7 % extraction.
Solving the problems of modern building materials science is reduced to obtaining high-quality materials, expanding and searching for a rational raw material base, which can be carried out through the use of various industrial wastes. In this paper, the possibility of using waste from the mining industry – saponite-containing material (SCM) obtained during the enrichment of kimberlite ores from the Lomonosov diamond deposit, as an active mineral additive for cement binders and concretes is considered. The influence of mechanical and thermal treatment on a number of properties of the material selected from the tailings dump and in its initial state was studied. The study of the surface activity of SCM samples consisted in determining the sorption capacity, acid-base centers and their distribution. An increase in the activity of the surface of the material particles as a result of mechanical activation and its decrease during temperature treatment were determined. These effects are associated with phase rearrangements and structural changes in the sandy-clay rock, which was confirmed during thermal analysis. The temperature effect has no pronounced effect on the microstructure, the “smoothness” of the particles and the formation of a consolidated surface of the structural elements of the saponite-containing material are noted.
Construction of a new wintering complex at the Antarctic Vostok Station required prompt delivery of builders and mechanics to Progress Station to move them further to the work area. To solve this major logistical issue, a new landing site, later named Zenit, certified for accommodating heavy wheeled aircraft, was prepared in the Progress Station area from March to August 2022. Its snow pavement slab with a total area of 350 thousand m2 is from 100 to 120 cm high. It was made by applying snow layers with their subsequent compaction by a specially designed compaction platform for snow airfields suitable for heavy wheeled aircraft. As a result, the pavement has a surface hardness of at least 1 MPa. The layer from 30 to 60 cm has a hardness of at least 0.8 MPa, and the bottom layer at least 0.6 MPa. The first Il-76TD-90VD aircraft of the Russian company Volga-Dnepr was accommodated to the new runway on 7 November 2022. The aircraft landed in normal mode. The depth of the chassis wheels track after landing did not exceed 3 cm. The research provided in-depth understanding of the mechanisms for forming the supporting base of the runway from snow and ice in Antarctica. The experience gained can be used to solve similar issues in the Far North.
The mineral composition of metacarbonate rocks (silicate marbles and carbonate-silicate rocks) of the Khapchan series (southeastern part of the Anabar Shield) was studied, and the PT (pressure and temperature)-parameters of their formation were established. Silicate marbles contain calcite, dolomite, forsterite, clinohumite, spinel, enstatite, diopside, pargasite, meionite, phlogopite, and feldspars. Carbonate-silicate rocks are composed of calcite, quartz, feldspars, diopside, grossular, marialite, and vesuvianite. Carbonate-silicate rocks are significantly enriched in SiO2, Al2O3, FeO, Na2O, K2O, TiO2 and contain less MgO, CaO than silicate marbles. A difference was revealed in PT-parameters determined for silicate marbles (temperatures 700-900 °C and pressure no more than 8 kbar) and for carbonate-silicate rocks (temperatures 680-820 °C, pressures 8-15 kbar). Silicate marbles have a primary sedimentary nature, as evidenced by their rare-element composition and the presence of fragments of host terrigenous rocks. There is no doubt about the primary sedimentary nature of carbonate-silicate rocks, which are very similar in REE distribution spectra and in rare-element composition to silicate marbles. A number of features indicate that metacarbonate rocks have undergone metasomatic alteration. Thus, in silicate marbles, reaction rims are observed around orthopyroxene, forsterite, potassium feldspar, as well as quartz veins bordered by accumulations of phlogopite, feldspars, and diopside. In carbonate-silicate rocks, the development of secondary marialite on potassium feldspar has been established; the rare-element composition of garnet may indicate its metasomatic origin.
The deeper the mineral deposits developments are, the worse the mining and geological conditions become. Significant growth of stress level in the rock mass contributes to possible manifestation of rock pressure in dynamic form. The resulting task of assessment of rock impact hazard is closely related to the task of obtaining more accurate results of compression tests of samples in rigid or servohydraulic test presses using graphs of their full deformation. This approach requires special expensive equipment, considerable time resources, and sufficient core material. Therefore, it is important to have an approach that allows to assess the propensity of rocks to brittle fracture with research methods simple enough not to result in the loss of quality and reliability of the obtained results. This paper presents the results of laboratory tests of rocks from the Norilsk Industrial Region to determine their tensile and compressive strengths. Test methods involved both domestic and foreign standards for determining the value of the brittleness coefficient. The impact hazard potential of rocks was determined using the Kaiser criterion. It is found that the tested lithological types (rich sulfide ores, hornblende, disseminated ores, and gabbro-dolerite rocks), with the exception of anhydrite, have a low impact hazard potential.
The paper presents an analysis of the advantages and limitations of additional measures to intensify the transportation of the backfill hydraulic mixture flow. The results of the analysis of the conditions for using pumping equipment to move flows with different rheological properties are shown. Generalizations of the methods for influencing the internal resistance of backfill hydraulic mixtures by means of mechanical activation, as well as increasing fluidity due to the use of chemical additives are given. The article presents the results of studies confirming the feasibility of using pipes with polymer lining, which has proven its efficiency in pumping flows of hydraulic mixtures with different filler concentrations. An analytical model of hydraulic mixture movement in the pipeline of the stowage complex has been developed. The trends in pressure change required to ensure the movement of hydraulic mixture in pipelines of different diameters are exponential, provided that the flow properties are constant. The effect of particle size on the motion mode of the formed heterogeneous flow, as well as on the distribution of flow density over the cross-section, characterizing the stratification and change in the rheological properties of the backfill hydraulic mixture, is assessed. An analytical model of centralized migration of the dispersed phase of the hydraulic mixture flow is formulated, describing the effect of turbulent mixing of the flow on the behavior of solid particles. An assessment of the secondary dispersion of the solid fraction of the hydraulic mixture, which causes a change in the consistency of the flow, was performed. The studies of the influence of the coefficient of consistency of the flow revealed that overgrinding of the fractions of the filler of the hydraulic mixture contributes to an increase in the required pressure in the pipeline system.
The demand for feldspar as a raw material in the ceramic industry is continuously increasing. Feldspar is abundant in the Earth's crust and typically found alongside other silicate minerals, as well as titanium and iron oxides. This study aims to reduce the iron oxide content in feldspar ore from the Wadi Zirib region and achieve an optimal grade of feldspar concentrate for various industrial uses. The research involved dry and wet magnetic separation techniques followed by leaching with oxalic and citric acids to minimize iron impurities and enhance optical properties. The factors affecting the dry magnetic separation, for feldspar size of –250+45 µm, were optimized using the Box – Behnken factorial design and a non-magnetic concentrate with 0.29 % Fe2O3 and an 92.19 % feldspar yield was obtained. The wet magnetic separation for feldspar fines of size –45 µm was optimized and a concentrate with 0.27 % Fe2O3 was achieved. The acid leaching was conducted on the non-magnetic feldspar concentrates using oxalic and citric acid. Oxalic acid was more successful in reducing iron oxide of dry (to 0.19 %) and wet (to 0.12 %) non-magnetic feldspar concentrates. The optical properties of the leached concentrates were improved compared to the original sample, as the whiteness improved up to 90 %.
The issue of determining the main parameters of electric energy storage systems – power and energy intensity – is being considered, the determination of which is a fundamentally important task when introducing such devices into the power supply systems of enterprises for both technical (technological) and economic reasons. The work analyzes problems that can be solved by installing electricity storage systems at gas industry facilities. An industry-wide methodology has been developed for calculating the parameters of an electricity storage system based on traditional methods and methods aimed at minimizing the standardized cost of electricity with adaptation to the conditions of the gas industry. A distinctive feature of the presented methodology is the ability to determine the power and energy intensity of electricity storage systems when performing several functions. The methodology was tested at a typical gas industry facility – the Yarynskaya compressor station of OOO Gazprom Transgaz Ukhta, a characteristic feature of which is an autonomous power supply system. An example is given of calculating the electricity storage normalized cost using an improved LCOS indicator, which takes into account the effect of changing the fill factor of the electrical load schedule on the amount of gas consumption by a power plant for its own needs. To confirm the economic efficiency of introducing electricity storage systems calculated using the above methodology, calculations of the integral effect, net present value and efficiency index are presented.
The annual increase of coal production and its demand lead to the necessity in temporary storage places (warehouses) organization to accommodate raw coal materials before the shipment. It is noted that at the open method of coal storing the dust emission from loading/unloading operations and from the pile surface effects negatively the health of the warehouse workers and adjacent territories. An alternative solution is closed-type warehouses. One of the main hazards of such coal storage can be the release of residual methane from coal segregates into the air after degassing processes during mining and extraction to the surface, as well as transportation to the place of temporary storage. The study carries the analysis of methane content change in coal during the processes of extraction, transportation and storage. Physical and chemical bases of mass transfer during the interaction between gas-saturated coal mass and air are studied. It is determined that the intensity of methane emission depends on: the coal seam natural gas content, parameters of mass transfer between coal, and air and the ambient temperature. The dynamics of coal mass gas exchange with atmospheric air is evaluated by approximate approach, which is based on two interrelated iterations. The first one considers the formation of methane concentration fields in the air space of the bulk volume and the second accounts the methane emission from the pile surface to the outside air. It is determined that safety of closed coal warehouses exploitation by gas factor can be ensured by means of artificial ventilation providing volumetric methane concentration in the air less than 1 %. The flow rate sufficient to achieve this methane concentration was obtained as a result of computer modeling of methane concentration fields formation in the air medium at theoretically calculated methane emission from the pile surface.
Achieving technological sovereignty implies accelerating innovation and reducing import dependence. An effective tool for addressing these challenges is local content policy (LCP). The purpose of this study is to assess the impact of LCP on innovation activity in oil and gas companies and to provide recommendations for enhancing the effectiveness of this policy in Russia. The paper analyzes the influence of LCP on innovation levels in the oil and gas sector, drawing on examples from 10 countries. A positive short-term impact of LCP on innovation was identified in Brazil, Malaysia, and Saudi Arabia, with long-term effects observed in China and South Africa. Recommendations for improving the effectiveness of LCP in Russia are supplemented with a methodology for calculating the level of technological sovereignty. A refinement of the method for solving the «responsiveness» problem, incorporating the level of localization, has been proposed.
The paper focuses on the technique and results of an aeromagnetic survey conducted using a fixed-wing unmanned aerial system (UAS) in East Antarctica at the Bunger Hills and Highjump Archipelago (Wilkes Land) during the 69th Russian Antarctic Expedition. The above survey was carried out at a 250-meter distance between flight lines (scale 1:25,000) over the area of 600 km2 to increase the geological knowledge of the area. The magnetic anomaly map obtained after data processing is more detailed than any of known published geological maps of the area. The size of anomalies detected varies from dozens of meters up to large, kilometer-scale structures traced within the entire area under survey. The data analysis shows that the surveyed region is characterized by morphological heterogeneity and amplitude variability of anomalous magnetic field. Along with relatively calm zones one can observe strong gradient ones. Even the fluent analysis of aeromagnetic survey results proves their high information content. The UAS-based survey results demonstrate that the technique implemented is an important tool of applied geophysics and can effectively solve tasks of geological mapping in harsh weather conditions of Antarctica. It can adequately replace conventional aeromagnetic surveys that are now done using manned aircraft.