-
Date submitted2024-06-04
-
Date accepted2025-01-28
-
Date published2025-04-04
Impact of dry and wet magnetic separator process parameters on iron oxide removal from Egyptian feldspar ore
The demand for feldspar as a raw material in the ceramic industry is continuously increasing. Feldspar is abundant in the Earth's crust and typically found alongside other silicate minerals, as well as titanium and iron oxides. This study aims to reduce the iron oxide content in feldspar ore from the Wadi Zirib region and achieve an optimal grade of feldspar concentrate for various industrial uses. The research involved dry and wet magnetic separation techniques followed by leaching with oxalic and citric acids to minimize iron impurities and enhance optical properties. The factors affecting the dry magnetic separation, for feldspar size of –250+45 µm, were optimized using the Box – Behnken factorial design and a non-magnetic concentrate with 0.29 % Fe2O3 and an 92.19 % feldspar yield was obtained. The wet magnetic separation for feldspar fines of size –45 µm was optimized and a concentrate with 0.27 % Fe2O3 was achieved. The acid leaching was conducted on the non-magnetic feldspar concentrates using oxalic and citric acid. Oxalic acid was more successful in reducing iron oxide of dry (to 0.19 %) and wet (to 0.12 %) non-magnetic feldspar concentrates. The optical properties of the leached concentrates were improved compared to the original sample, as the whiteness improved up to 90 %.
-
Date submitted2024-03-11
-
Date accepted2024-11-07
-
Date published2025-03-06
Geochemical characteristics of weathering crusts on the Dzhezhimparma Ridge and the Nemskaya Upland (South Timan)
Numerous local varieties of weathering crusts are known in the South Timan. They differ in their position in the section, type of weathering products, substrates, and occurrence. The aim of the research is to identify patterns in the distribution of rock-forming, rare and rare earth elements and the composition of clay minerals in clay formations of the weathering crusts. The main task is to describe the occurrence and geochemical features that enable determining the genetic type and formation conditions of weathering crusts. The paper presents the results of a study of the distribution of petrogenic, rare earth, rare elements, and clay minerals in weathering crust of different ages, genetic types and occurrence conditions on the Dzhezhimparma Ridge and the Nemskaya Upland in the South Timan. We found that hydromica-kaolinite-type weathering crust is developed after the Late Riphean Dzhezhim Fm. rocks in the basement-cover contact zone on the Dzhezhimparma Upland, and the layer of fine-grained rock at the base of the Devonian section previously considered a weathering crust was formed as a result of mechanical destruction of the Devonian sandstones during movement in the thrust zone. In the Vadyavozh quarry located on the Nemskaya Upland, we studied and described the formations of Mesozoic-Cenozoic areal and linear weathering crusts after the Late Riphean Dzhezhim Fm. rocks. We found that micaceous siltstones in the siltstone-sandstone strata of the Dzhezhim Fm. are associated with the Riphean stage of crust formation and are composed of weathering crust material redeposited in the epicontinental basin.
-
Date submitted2024-03-20
-
Date accepted2024-11-07
-
Date published2025-02-27
Analysis of the stress state of rocks transformation near a horizontal well during acid treatment based on numerical simulation
The article presents an overview of the assessment and modelling of the stress state of rocks in the near-wellbore zone of horizontal wells during acid stimulation of the formation for improving the efficiency of oil and gas field development. A numerical finite element model of near-wellbore zone of the reservoir drilled by a horizontal section was compiled using one of oil fields in the Perm Territory as an example. The distribution of physical and mechanical properties of the terrigenous reservoir near the well was determined considering transformation under the action of mud acid for different time periods of its injection. Multivariate numerical simulation was performed and the distribution of horizontal and vertical stresses in near-wellbore zone was determined with regard for different values of pressure drawdown and changes in stress-strain properties depending on the area of mud acid infiltration. It was found that a change in elastic modulus and Poisson's ratio under the influence of acid led to a decrease in stresses in near-wellbore zone. Analysis of the stress distribution field based on the Coulomb – Mohr criterion showed that the minimum safety factor of rock even after the effect of mud acid was 1.5; thus, under the considered conditions of horizontal well modelling, the reservoir rock remained stable, and no zones of rock destruction appeared.
-
Date submitted2023-06-25
-
Date accepted2024-11-07
-
Date published2025-02-25
Study of wormhole channel formation resulting from hydrochloric acid treatment in complex-type reservoirs using filtration and X-ray computed tomography methods
- Authors:
- Andrei A. Аbrosimov
The primary function of hydrochloric acid treatment (HAT) is to create the maximum number of high-conductivity channels in the near-wellbore zone of the reservoir to restore its permeability and enhance hydraulic connectivity between the undisturbed part of the formation and the well. The objective of this study is to physically model HAT on core samples from the Orenburg oil and gas condensate field and to research the impact of such treatment on the structure of the pore space of rocks related to complex-type reservoirs. The complexity of the rock's pore space and the low permeability of the formations are distinguishing features of the study object. For this reason, HAT is a widely applied method for production intensification, necessitating the verification of acid injection rates, where the success criterion is the formation of high-conductivity filtration channels (wormholes) in the near-wellbore zone. These channels significantly expand the drainage area of wells, thereby bringing additional reservoir sections into development. The study examined the characteristics of filtration channel development resulting from acid treatment. Their structure was characterized and analyzed using X-ray computed tomography. The complex study confirmed the accuracy of the selected injection rate and provided practical recommendations for enhancing the efficiency of HAT.
-
Date submitted2022-09-30
-
Date accepted2024-11-07
-
Date published2025-02-25
Carbon dioxide corrosion inhibitors: current state of research and development
Among the methods of corrosion control in the oil and gas production industry the leading place belongs to inhibitor protection, since there is no need for technological and technical changes in the existing equipment. The combination of high variability of inhibitor composition with changing conditions of its application and low capital investments makes it an indispensable reagent at oil and gas fields. The main classes of compounds used as active bases of carbonic acid corrosion inhibitors for the protection of oil and gas equipment are described. Classical organic active bases containing heteroatoms (oxygen, sulfur, nitrogen) are examined. Special attention was paid to alkylimidazolines and other nitrogen-containing compounds as the most frequently used as active bases of carbonic acid corrosion inhibitors in Russia and abroad. A wide range of possibilities to achieve the desired properties of corrosion inhibitors by varying the substitutes has been demonstrated. Nowadays, in addition to the traditional requirements for corrosion inhibitors, their safety for the environment is equally important. The information on prospective research and development aimed at improving the environmental characteristics of the reagents used is given. Plant extracts, synthetic and biological polymers involved in traditional corrosion inhibitors or used as new independent compounds are considered. It is shown that the effectiveness of corrosion inhibitors significantly depends on the pH of the medium, temperature, partial pressure of СО2, flow rate, and other factors.
-
Date submitted2024-04-24
-
Date accepted2024-09-24
-
Date published2024-11-12
Study and justification of the combination of beneficiation processes for obtaining flake graphite from technogenic carbon-containing dusts
The most important task of modern production development is to provide the mineral and raw materials sector of the economy with resources included in the list of strategic raw materials, including flake graphite. In addition to natural raw materials, the source of its obtaining can be metallurgical production wastes not involved in processing. Development of metallurgical dust beneficiation technology will solve the problem of obtaining high-purity flake graphite with a crystal structure close to ideal and in demand in the production of high-tech materials. It will allow creating a renewable raw material base of graphite and utilising metallurgical production wastes. The research included the study of dust beneficiation by coarseness, magnetic and flotation methods, the influence of dust disintegration processes on beneficiation indicators. Based on the established technological properties of the components of dusts, magnetic, flotation and gravity beneficiation methods can be applied for their separation in different sequence. It is shown that dusts from different sites have different enrichability by these methods, and it should be taken into account when developing a complex technology of their processing. The degree of beneficiation increases in a row of dusts from the blast furnace shop (BF) – electric steel smelting shop (ESS) – oxygen-converter shop (OCS). The method of grinding has a significant influence on the separation indicators – at dry grinding in a centrifugal-impact mill with subsequent pneumatic classification the quality of graphite concentrates increases by 22.7 % of carbon for BF dust and by 13.48 % of carbon for ESS dust. OCS dust beneficiation indicators are high at coarse grinding with steel medium – mass fraction of carbon 96.1 %.
-
Date submitted2023-06-21
-
Date accepted2023-10-25
-
Date published2024-08-26
Specific action of collector from phosphoric acid alkyl esters class in flotation of apatite-nepheline ores
Increasing amount of apatite-nepheline ores with complex mineral composition involved in processing, growing content of the associated minerals in ore which are similar in their floatability to apatite lead to the necessity of using highly selective collectors. Non-frothing flotation method gave a comparative assessment of floatability of pure minerals and demonstrated a high selectivity of the action of phosphoric acid esters in relation to apatite. The effect of four reagent modes differing in the number of selective synthetic collectors was studied using the example of flotation of an apatite-nepheline ore sample containing 17.27 % apatite and 40.18 % nepheline. Mineralogical analysis of crushed ore showed that it contained two apatite varieties – coarse-grained free and finer poikilitic as inclusions in rock-forming minerals. Free apatite opens and occurs as open grains even in coarse-grained (+0.16 mm) grades. Poikilitic apatite occurs as intergrowths with different minerals, mainly with nepheline and its alteration products (natrolite, spreustein, sodalite, etc.), and pyroxene. Optical microscopy demonstrated that a growing share of reagent from the phosphoric acid oxyethylated esters class in the composition of the collector mixture allows improving the quality of the produced apatite concentrates by reducing the number of apatite intergrowths with nepheline and pyroxenes in the concentrates. In the concentrate obtained in the most selective reagent mode, the intergrowths are characterized by a 50/50 and higher ratio in favour of apatite. Concentrates of lower quality comprised intergrowths with lower apatite content, to 20/80 or less.
-
Date submitted2023-09-29
-
Date accepted2023-10-25
-
Date published2024-08-26
Laboratory studies of transformation of porosity and permeability and chemical composition of terrigenous reservoir rocks at exposure to hydrogen (using the example of the Bobrikovskii formations in the oil field in the northeast Volga-Ural oil and gas province)
The article describes the methodology for laboratory studies of reservoir rock exposure to hydrogen. The stages of sample research and the instruments used in the experiments are considered. A comparative analysis of the results of studies on porosity and permeability of core samples was performed. It was shown that after exposure to hydrogen, the porosity decreased by 4.6 %, and the permeability by 7.9 %. The analysis of correlation dependencies demonstrated a typical change in the relationship of these characteristics: after the samples exposure to hydrogen the scatter of the values increased and the correlation coefficient decreased, which indicates a change in the structure of the void space. Based on the research results, it was concluded that the decrease in porosity and permeability of the core samples occurred due to their minor compaction under the action of effective stresses. The chemical analysis of the rock showed no major difference in the composition of the basic oxides before and after exposure to hydrogen, which points to the chemical resistance of the studied formation to hydrogen. The experimental results showed that the horizon under consideration can be a storage of the hydrogen-methane mixture.
-
Date submitted2024-04-10
-
Date accepted2024-06-03
-
Date published2024-07-19
Combined method for processing spent acid etching solution obtained during manufacturing of titanium products
Possessing high strength, low density and significant chemical resistance, titanium has found wide application in various fields of the national economy – the chemical industry, aviation and rocket technology, mechanical engineering, medicine, etc. The production of titanium products is hampered by a fairly strong oxide film covering its surface. Removal of the oxide film from the surface of titanium workpieces is carried out by etching in solutions of mineral acids of various compositions. A spent acid etching solution (SAES) is formed, containing titanium salt and the remainder of unreacted acids. Almost all etching solutions contain HF and one of the strong acids. This is H2SO4, HCl or HNO3. Thus, the SAES includes ions of titanium, fluorine or chlorine, orsulfate, or nitrate. SAES is quite toxic and must be diluted or cleaned several times before being discharged into a reservoir. Most of the methods used to extract impurities contained in SAES lead to a decrease in their content. As a result of such purification, there is a loss of substances contained in SAES in significant quantities and of interest for further use. The work presents experimental results obtained from the combined processing of SAES containing titanium fluoride, hydrofluoric and hydrochloric acids. At the first stage, SAES is treated with sodium hydroxide. The resulting titanium hydroxide precipitate is filtered off. At the second stage, the filtrate containing sodium fluoride and chloride is processed in a membrane electrolyzer. In this case, not only the extraction of sodium salts from the filtrate occurs, but also the production of sodium hydroxide and a mixture of hydrofluoric and hydrochloric acids. Sodium hydroxide can be used for processing SAES, and a mixture of acids for etching titanium workpieces.
-
Date submitted2024-04-11
-
Date accepted2024-06-03
-
Date published2024-07-04
Assessment of the efficiency of acid mine drainage purification (using the example of copper-pyrite mines in the Middle Urals)
According to the results of the anti-rating of regions with extreme pollution of watercourses in the Sverdlovsk region, the largest number of polluted rivers has been recorded in recent years – more than a quarter of all high and extremely high pollution. One of the sources of pollution of natural water bodies in the Middle Urals are closed and flooded copper-pyrite mines, where acidic mine drainage continue to form and unload to the surface. Several of them have organized collection and a two-stage acidic drainage purification system, including neutralization with lime milk and settling in a clarifier pond. Despite the identical schemes, different indicators of pollutants are recorded during discharge into water bodies. The aim of the work is to evaluate the effectiveness of the applied acid mine drainage purification system and identify the parameters affecting the quality of treated mine water. Laboratory studies were performed using methods of flame emission spectrometry, flame atomic absorption, atomic absorption spectrometry, mass spectrometry with ionization in inductively coupled plasma, potentiometric, etc. It has been established that the existing mine drainage purification system at the Degtyarskii mine makes it possible to significantly reduce the concentrations of most toxic components of mine waters to almost standard values. At the Levikhinskii mine, the multiplicity of exceeding the maximum permissible concentrations reaches hundreds and thousands of times. To achieve a higher degree of purification, it is necessary that the duration of passive purification is sufficient for the reactant to interact with acidic waters. However, to ensure this possibility, it will require the creation of a cascade of ponds with an area of several thousand hectares. If the current two-stage system is quite effective for the Degtyarskii mine, then for Levikhinskii it is necessary to switch to the use of more modern systems, including three stages of purification.
-
Date submitted2024-05-06
-
Date accepted2024-06-14
-
Date published2024-07-04
Natural carbon matrices based on brown coal, humic acids and humine extracted from it for purification of aqueous solutions from low molecular weight organic impurities
Heterogeneous systems including natural carbon matrices in the solid phase and aqueous solutions of low molecular weight organic compounds with positive and negative variations from ideality in the liquid phase are considered. The technical characterization of the considered supramolecular ensembles on the basis of brown coal of the Kara-Keche deposit (Kyrgyzstan), humic acids and humine extracted from it is given. Functional analysis of the samples was carried out using FTIR spectroscopy. The morphology of the surface of the considered carbon matrices has been investigated, in different points of which the local microelement composition has been established. An X-ray phase analysis of Kara-Keche brown coal and humic acids and humine extracted from it was carried out. The isothermal adsorption of bipolar molecules of glycine and urea, neutral D-glucose from aqueous solutions on solid carbon sorbents has been studied. An assumption has been made about the adsorption of low molecular weight organic compounds from aqueous solutions on humine and Kara-Keche coal in irregularities and pores of the carbon matrix of sorbents, for humic acids – on surface reaction centers. Due to its developed pore structure and resistance to acids and alkalis, humine from Kara-Keche coal is recommended for the purification of industrial wastewater from low molecular weight organic ecotoxicants.
-
Date submitted2024-05-02
-
Date accepted2024-06-03
-
Date published2024-07-04
Iron ore tailings as a raw material for Fe-Al coagulant production
The paper presents the results of experimental research into the recovery of Fe-Al coagulant from iron ore tailings (IOTs). The variables investigated in the laboratory tests included sulphuric acid concentration, temperature, leaching time, solid/liquid phase ratio (S:L) and the presence of stirring. The experiment determined the composition of the coagulant and the solid residue after leaching. The maximum iron content in the solution after leaching was obtained using 40 % H2SO4 at a temperature of 100 °C (or with stirring at 75 °C) and a contact time of 60 minutes. In this case, the iron yield was at the level of 25 % of the total content in the iron ore tailings. Chemical analysis of the solution obtained after leaching showed Fe and Al sulphate contents of 11 and 2 % respectively. In the next step, the efficiency of the coagulant was evaluated on model solutions of colour. The experimental results showed that the coagulant obtained from the iron ore tailings can be used for wastewater treatment in a wide pH range from 4 to 12 pH units. The solid residue after leaching is a fine-grained powder rich in silica, which can potentially be used as an artificial raw material in the construction industry. The research carried out in this thesis has shown that the extraction of coagulants from iron ore tailings can be considered as a way to extend the production chain of iron ore mining and to minimise the amount of tailings to be stored in tailing ponds. The technical solution presented in this work allows to comprehensively solve the problem of environmental protection by creating new target products for wastewater treatment from IOTs.
-
Date submitted2024-04-25
-
Date accepted2024-06-13
-
Date published2024-07-11
Evaluation of the effectiveness of neutralization and purification of acidic waters from metals with ash when using alternative fuels from municipal waste
- Authors:
- Polina A. Kharko
- Aleksandr S. Danilov
The problem of pollution of natural water objects with heavy metals is extremely relevant for the areas where industrial enterprises are located. Unauthorized discharge of contaminated wastewater, inefficient operation of sewage treatment plants, as well as leakage of drainage waters from man-made massifs lead to changes in the hydrological system affecting living objects. The article studies the composition of ash from the combustion of alternative fuels from municipal waste, and also considers the possibility of using it to neutralize sulfuric acid drainage waters and extract metal ions (Cu, Cd, Fe, Mn, Zn) from them. It has been established that the efficiency of water purification from metals depends on the pH value achieved during the purification process. The pH value is regulated by the dose of the introduced ash, the contact time and depends on the initial concentration of metal ions and sulfates in the solution. Studies on the neutralization and purification of a model solution of sulfuric acid drainage waters of a tailings farm of known composition have shown that in order to achieve a pH of 8-9, optimal for precipitation of metal hydroxides Cu, Cd, Fe, Mn, Zn and Al washed out of ash, and water purification with an efficiency of 96.60 to 99.99 %, it is necessary to add 15 g/l of ash and stir the suspension continuously for 35 minutes. It was revealed that exposure to ash with sulfuric acid waters leads to the transition of water-soluble forms of metals into insoluble ones and their “cementation” with calcium sulfate. The amount of Zn and Fe ions washed out of the ash decreases by 82 and 77 %, Al, Cd, Cu, Mn – by 25 %. This reduces the toxicity of ash, which is proved by a decrease in the toxic multiplicity of dilution of the water extract by 14 times.
-
Date submitted2023-08-14
-
Date accepted2023-12-27
-
Date published2024-12-25
Modelling of compositional gradient for reservoir fluid in a gas condensate deposit with account for scattered liquid hydrocarbons
In oil and gas reservoirs with significant hydrocarbon columns the dependency of the initial hydrocarbon composition on depth – the compositional gradient – is an important factor in assessing the initial amounts of components in place, the position of the gas-oil contact, and variations of fluid properties throughout the reservoir volume. Known models of the compositional gradient are based on thermodynamic relations assuming a quasi-equilibrium state of a multi-component hydrodynamically connected hydrocarbon system in the gravity field, taking into account the influence of the natural geothermal gradient. The corresponding algorithms allow for calculation of changes in pressure and hydrocarbon fluid composition with depth, including determination of the gas-oil contact (GOC) position. Above and below the GOC, the fluid state is considered single-phase. Many oil-gas-condensate reservoirs typically have a small initial fraction of the liquid hydrocarbon phase (LHC) – scattered oil – within the gas-saturated part of the reservoir. To account for this phenomenon, a special modification of the thermodynamic model has been proposed, and an algorithm for calculating the compositional gradient in a gas condensate reservoir with the presence of LHC has been implemented. Simulation cases modelling the characteristic compositions and conditions of three real oil-gas-condensate fields are considered. The results of the calculations using the proposed algorithm show peculiarities of variations of the LHC content and its impact on the distribution of gas condensate mixture composition with depth. The presence of LHC leads to an increase in the level and possible change in the type of the fluid contact. The character of the LHC fraction dependency on depth can be different and is governed by the dissolution of light components in the saturated liquid phase. The composition of the LHC in the gas condensate part of the reservoir changes with depth differently than in the oil zone, where the liquid phase is undersaturated with light hydrocarbons. The results of the study are significant for assessing initial amounts of hydrocarbon components and potential efficiency of their recovery in gas condensate and oil-gas-condensate reservoirs with large hydrocarbon columns.
-
Date submitted2023-04-11
-
Date accepted2023-10-25
-
Date published2024-07-04
Acid mine water treatment using neutralizer with adsorbent material
One of the biggest issues in the mining sector is due to acid mine drainage, especially in those abandoned mining operations and active ones that fail to adequately control the quality of their water discharge. The removal degree of copper, iron, lead, and zinc dissolved metals in acid mine drainage was investigated by applying different proportions of mixtures based on neutralizing reagent hydrated lime at 67 % calcium oxide (CaO), with adsorbent material – natural sodium bentonite, compared to the application of neutralizing reagent without mixing, commonly used in the neutralization of acid mining drainage. The obtained results show that the removal degree of dissolved metals in acid mine drainage when treated with a mixture of neutralizing reagent and adsorbent material in a certain proportion, reaches discharge quality, complying with the environmental standard (Maximum Permissible Limit), at a lower pH than when neutralizing material is applied without mixing, registering a net decrease in the consumption unit of neutralizing agent express on 1 kg/m3 of acid mine drainage. Furthermore, the sludge produced in the treatment with a mixture of the neutralizing reagent with adsorbent material has better characteristics than common sludge without bentonite, since it is more suitable for use as cover material, reducing the surface infiltration degree of water into the applied deposit.
-
Date submitted2022-09-26
-
Date accepted2023-09-20
-
Date published2024-04-25
Technology of absorption elimination with cross-linking plugging material based on cement and cross-linked polymer
The peculiarity of the geological structure of carbonate reservoirs is their complex permeability and porosity characteristics, reflecting the simultaneous presence of cavities variety (fractures, caverns, pores). Loss of circulation during penetration of fractured rock intervals significantly increases well construction time due to lack of efficient plugging isolation compositions. The main disadvantages of traditional compositions are high sensitivity to dilution in the process of their injection into the absorption zone, as well as insufficient structural strength to prevent the isolation composition from spreading during the induction period. For efficient isolation of catastrophic absorption zones in conditions of high opening of absorption channels a new cross-linking plugging isolation composition has been developed, which allows to exclude disadvantages of traditional isolation compositions. Application of the composition will allow to reduce the injection volume of the isolation composition and the time of isolation works due to its resistance to dilution and movement of formation water in the absorption interval.
-
Date submitted2022-12-01
-
Date accepted2023-01-19
-
Date published2023-12-25
Inclusions of diamond crystals in the tourmaline of the schorl-uvite series: problems of genesis
The mineralogical and geochemical features of diamond-bearing tourmaline crystals (schorl-uvite series) from garnet-clinopyroxene rocks of the Kumdy-Kol deposit (Northern Kazakhstan) have been studied in detail. The formation of the main rock-forming minerals (garnet + K-bearing clinopyroxene) occurred in the diamond stability field at 4-6 GPa and 950-1000 °C. Crystallization of K-bearing clinopyroxene at these parameters is possible in the presence of an ultra-potassic fluid or melt formed because of crustal material melting in subduction zones. Tourmaline crystals (up to 1 cm) containing diamond inclusions perform veins crosscutting high-pressure associations. The composition of individual zones varies from schorl to uvite within both a single grain and the sample as a whole. The potassium content in this tourmaline does not exceed 0.1 wt.% K2O, and the isotopic composition of boron δ11B varies from –10 to –15.5 ‰, which significantly differs from the previously established isotopic composition of boron in maruyamaite crystals (δ11B 7.7 ‰ in the core and –1.2 ‰ in the rim) of the same deposit. Analysis of the obtained data on δ11B in the tourmalines from the diamond-grade metamorphic rocks within the Kumdy-Kol deposit suggests the existence of two boron sources that resulted in crystallization of K-bearing tourmaline crystals (maruyamaite-dravite series) and potassium-free tourmalines of the schorl-uvite series.
-
Date submitted2022-10-23
-
Date accepted2023-02-13
-
Date published2023-12-25
Sorption purification of acid storage facility water from iron and titanium on organic polymeric materials
Obtaining and production of metals from natural raw materials causes a large amount of liquid, solid, and gaseous wastes of various hazard classes that have a negative impact on the environment. In the production of titanium dioxide from ilmenite concentrate, hydrolytic sulphuric acid is formed, which includes various metal cations, their main part is iron (III) and titanium (IV) cations. Hydrolytic acid waste is sent to acid storage facilities, which have a high environmental load. The article describes the technology of ion exchange wastewater treatment of acid storage facility from iron (III) and titanium (IV) cations, which form compounds with sulphate ions and components of organic waste in acidic environments. These compounds are subjected to dispersion and dust loss during the evaporation of a water technogenic facility, especially in summer season. Sorption of complex iron (III) cations [FeSO4]+ and titanyl cations TiO2+ from sulphuric acid solutions on cation exchange resins KU-2-8, Puromet MTS9580, and Puromet MTS9560 was studied. Sorption isotherms were obtained both for individual [FeSO4]+ and TiO2+ cations and in the joint presence. The values of the equilibrium constants at a temperature of 298 K and the changes in the Gibbs energy are estimated. The capacitive characteristics of the sorbent were determined for individual cations and in the joint presence.
-
Date submitted2022-11-04
-
Date accepted2023-03-03
-
Date published2023-04-25
Efficiency of acid sulphate soils reclamation in coal mining areas
During the development of coal deposits, acid mine waters flowing to the surface cause the formation of acid sulphate soils. We study the effectiveness of soil reclamation by agrochemical and geochemical methods at the site of acid mine water discharge in the Kizel Coal Basin, carried out in 2005 using alkaline waste from soda production and activated sludge. A technosol with a stable phytocenosis was detected on the reclaimed site, and soddy-podzolic soil buried under the technogenic soil layer with no vegetation on the non-reclaimed site. The buried soddy-podzolic soil retains a strong acid рН concentration Н 2 О = 3. A high content of organic matter (8-1.5 %) is caused by carbonaceous particles; the presence of sulphide minerals reaches a depth of 40 cm. Technosol has a slightly acid pH reaction H 2 O = 5.5, the content of organic matter due to the use of activated sludge is 19-65 %, the presence of sulphide minerals reaches a depth of 20-40 cm. The total iron content in the upper layers of the technosol did not change (190-200 g/kg), the excess over the background reaches 15 times. There is no contamination with heavy metals and trace elements, single elevated concentrations of Li, Se, B and V are found.
-
Date submitted2022-10-19
-
Date accepted2023-02-14
-
Date published2023-04-25
Electric steelmaking dust as a raw material for coagulant production
The paper describes the issues associated with waste generated during steel production and processing, in particular the dust from electric arc furnaces (EAF). An effective solution for the disposal of such waste is its involvement in processing to obtain valuable products. This paper studies the physical and chemical properties of EAF dust produced during the smelting of metallized pellets and captured by the dust and gas cleaning system of the steel-smelting shop at the Oskol Electrometallurgical Combine, Belgorod Region. The results obtained in the study of the chemical and disperse compositions of dust, the microstructure of the surface made it possible to propose the use of dust as a raw material for coagulant production. The conditions of acid-thermal treatment of dust are determined, contributing to the partial dissolution of iron (II), (III), and aluminium compounds, which ensure the coagulation processes during wastewater treatment. Model solutions show high efficiency (> 95 %) of water treatment from heavy metal ions by modified EAF dust.
-
Date submitted2022-05-10
-
Date accepted2022-09-06
-
Date published2022-11-03
Flotation separation of titanite concentrate from apatite-nepheline-titanite ores of anomalous zones of the Khibiny deposits
Titanium raw materials are widely used for the synthesis of various functional materials – sorbents of radionuclides and rare earth elements, various additives, filler pigments, etc. Since most of titanium concentrates are imported, in line with the import substitution program, production of titanite concentrate from apatite-nepheline ores of the Khibiny deposits is a promising trend for supplying national industry with titanium raw materials. The article presents the results of laboratory studies of flotation separation of titanite concentrate from apatite-nepheline-titanite ores extracted from the upper ore horizon of the Koashvinskoye deposit, where titanite-enriched ores are concentrated. Recovery of titanite concentrate was accomplished using two reagent modes – a mixture of alkyl hydroxamic and carboxylic acids with the addition of distilled tall oil and a mixture of tall oils with the addition of polyalkyl benzene sulfonic acids. The results of the research showed that the first flotation mode, which allows a selective recovery of titanite into the concentrate (titanite content in the concentrate was 93.5 %) is the most efficient. It was shown that flotation separation of titanite concentrate is preferable compared to the chemical method based on sulfuric acid leaching.
-
Date submitted2022-02-22
-
Date accepted2022-05-11
-
Date published2022-11-03
Scientific substantiation and development of innovative processes for the extraction of zirconium and rare earth elements in the deep and comprehensive treatment of eudialyte concentrate
- Authors:
- Valentin A. Chanturiya
Based on a package of modern analysis methods, the influence of various acids and energy effects on the morphology, elemental composition, structural and chemical transformations of the mineral surface, and the efficiency of eudialyte concentrate leaching was studied. The mechanism and the optimal conditions and specific features of the destruction of eudialyte and rock minerals and the extraction of zirconium and REE under the influence of various acids, powerful nanosecond pulses, dielectric barrier discharge, electrochemical processing, mechanochemical activation and ultrasound were revealed. The mechanism of formation and the optimal conditions for the dispersion of silica gel, depending on the methods and parameters of energy effects, was theoretically and experimentally substantiated. A combined three-stage circuit of nitric acid leaching of eudialyte concentrate with ultrasonic treatment of the suspension, providing 97.1 % extraction of zirconium and 94.5 % REE, were scientifically substantiated and tested. The conditions for the selective deposition of zirconium and REE were theoretically and experimentally substantiated.
-
Date submitted2021-02-12
-
Date accepted2022-07-26
-
Date published2022-11-10
Manifestation of incompatibility of marine residual fuels: a method for determining compatibility, studying composition of fuels and sediment
- Authors:
- Radel R. Sultanbekov
- Andrey M. Schipachev
The results of studying the problem of active sediment formation when mixing residual fuels, caused by manifestation of incompatibility, are presented. A laboratory method has been developed for determining the compatibility and stability of fuels allowing identification of a quantitative characteristic of sediment formation activity. Laboratory studies were performed, and incompatible fuel components were identified. Tests were made to determine the quality indicators of samples and group individual composition of fuels. Results on the content of total and inorganic carbon in the obtained sediments were determined using Shimadzu TOC-V SSM 5000A. Chemical composition was determined and calculated on LECO CHN-628 analyser. Group composition of hydrocarbon fuels contained in the sediment was studied by gas chromato-mass spectrometry on GCMS-QP2010 Ultra Shimadzu. To obtain additional information on the structural group composition of fuel sediment, IR spectrometry was performed on IR-Fourier spectrometer IRAffinity-1. X-ray diffraction analysis of sediment samples was made using X-ray diffractometer XRD-7000 Shimadzu; interplanar distances d002 and d100 as well as Lс and Lа crystallite sizes served as the evaluation criteria. Microstructural analysis of total sediment was performed by scanning electron microscopy. The results of the research confirmed that the content of normal alkanes in the fuel mixture mainly affects sediment formation. Recommendations were drawn on preserving the quality of fuels and reducing sediment formation during storage and transportation.
-
Date submitted2021-09-17
-
Date accepted2022-04-07
-
Date published2022-12-29
Technique for calculating technological parameters of non-Newtonian liquids injection into oil well during workover
Technique for automated calculation of technological parameters for non-Newtonian liquids injection into a well during workover is presented. At the first stage the algorithm processes initial flow or viscosity curve in order to determine rheological parameters and coefficients included in equations of rheological models of non-Newtonian fluids. At the second stage, based on data from the previous stage, the program calculates well design and pump operation modes, permissible values of liquid flow rate and viscosity, to prevent possible hydraulic fracturing. Based on the results of calculations and dependencies, a decision is made on the necessity of changing the technological parameters of non-Newtonian liquid injection and/or its composition (components content, chemical base) in order to prevent the violation of the technological operation, such as unintentional formation of fractures due to hydraulic fracturing. Fracturing can lead to catastrophic absorptions and, consequently, to increased consumption of technological liquids pumped into the well during workover. Furthermore, there is an increased risk of uncontrolled gas breakthrough through highly conductive channels.
-
Date submitted2021-08-05
-
Date accepted2021-11-30
-
Date published2021-12-27
Morozkinskoye gold deposit (southern Yakutia): age and ore sources
The paper presents the results of the comprehensive isotope geochemical (Re-Os, Pb and δ 34 S) study of sulfide mineralization of the Morozkinskoye deposit. The ore zones of the deposit are localized in the syenite massif of Mount Rudnaya, which is located within the Central Aldan ore region (southern Yakutia). Gold mineralization is represented by vein-disseminated or vein type mineralization and is manifested in acidic low-temperature metasomatites – beresites (Qz-Ser-Ank-Py). For the first time we obtained an age estimate of the gold mineralization ~ 129 ± 3 Ma, which the synchronism of the hydrothermal ore process in the beresites, which formed the Morozkinskoye deposit, and magmatic crystallization of the syenites of Mount Rudnaya (~130 Ma). The osmium initial isotopic composition of the studied sulfides indicates a mixed mantle-crustal source of sulfide mineralization. New lead isotopic data of syenites indicate the predominance of mantle lead and an insignificant role of the lower – crust lead, while the isotopic composition of pyrite denotes the presence of the upper crustal material in the ore genesis. The sulfide δ 34 S values vary from –2.3 to +0.6 ‰ and indicate a predominantly magmatic source of sulfur in the ores.