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Date submitted2024-05-08
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Date accepted2024-11-07
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Date published2025-04-25
The effect of mechanical and thermal treatment on the characteristics of saponite-containing material
Solving the problems of modern building materials science is reduced to obtaining high-quality materials, expanding and searching for a rational raw material base, which can be carried out through the use of various industrial wastes. In this paper, the possibility of using waste from the mining industry – saponite-containing material (SCM) obtained during the enrichment of kimberlite ores from the Lomonosov diamond deposit, as an active mineral additive for cement binders and concretes is considered. The influence of mechanical and thermal treatment on a number of properties of the material selected from the tailings dump and in its initial state was studied. The study of the surface activity of SCM samples consisted in determining the sorption capacity, acid-base centers and their distribution. An increase in the activity of the surface of the material particles as a result of mechanical activation and its decrease during temperature treatment were determined. These effects are associated with phase rearrangements and structural changes in the sandy-clay rock, which was confirmed during thermal analysis. The temperature effect has no pronounced effect on the microstructure, the “smoothness” of the particles and the formation of a consolidated surface of the structural elements of the saponite-containing material are noted.
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Date submitted2024-05-03
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Date accepted2024-11-07
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Date published2025-04-02
Assessment of ancylite ore dressability by flotation method
For more than 50 years, most rare earth elements were extracted from carbonatite deposits, which can contain different rare earth phases, but the main extracted minerals are bastnaesite, monazite and xenotime. Many studies focused on the improvement and development of dressing circuits for ores of these minerals. However, in some carbonatite complexes, rare earth deposits are composed partly or mainly of ancylite ores. This type of rare earth ores was very poorly studied in terms of dressability – previous experiments with ancylite ores are rare and not productive enough. Ancylite is the main concentrator of rare earth elements in most carbonatite complexes of the Devonian Kola Alkaline Province (northwest Russia). Dressability of ancylite ore from the Petyayan-Vara carbonatite field in the Vuorijärvi alkaline-ultramafic complex was assessed using the flotation method. The complex is one of the most potential rare earth deposits associated with carbonatites in the Kola Region. Petrographic and mineralogical studies demonstrated the occurrence of abundant iron and barite oxide inclusions in ancylite, which imposes restrictions on physical separation of these three minerals. The study of petrogeochemical and mineralogical composition of fractions formed during mechanical grinding of ores to a size less than 2.0 mm showed that even at this stage of sample preparation, the finest-grained fractions (less than 0.071 mm) were enriched in ancylite (to 19 vol.% or more with a content of 15 vol.% in ore). Three classes of reagents were considered as collectors in flotation experiments: fatty acids, alkyl hydroxamic acids, and amino acid derivatives. The reagent from the amino acid derivative class was highly efficient. The use of such a collector in combination with sodium hexametaphosphate depressant made it possible to obtain a flotation concentrate in an open circuit with total rare earth oxides content 33.4 wt.% at 64.7 % extraction.
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Date submitted2024-03-22
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Date accepted2024-09-24
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Date published2025-02-25
Behaviour of cerium (III) phosphate in a carbonate-alkaline medium
- Authors:
- Tatyana E. Litvinova
- Stepan A. Gerasev
The article investigates the behaviour of rare earth metals in carbonate-alkaline systems. The results of experimental studies on rare earth element extraction from phosphogypsum, a large-tonnage industrial waste forming in production of phosphoric acid are presented. Using the liquid phase leaching method, it was possible to extract more than 53 % of rare earth elements from old phosphogypsum and more than 69 % from fresh phosphogypsum due to solid phase treatment with a 4 mol/l potassium carbonate solution at temperature 90 °C. The behaviour of model cerium (III) phosphate in a carbonate-alkaline medium is characterized: a solubility isotherm is obtained as well as the dependences of the degree of cerium extraction into solution on temperature, carbonate ion concentration, interphase ratio, stirring intensity, and pH. The ability of soluble rare earth element complexes to precipitate over time was established, which was confirmed using cerium and neodymium as an example. Within 240 h after the end of the experiment, approximately 25 % of cerium and 17 % of neodymium were precipitated from the liquid phase. A similar property was recorded in representatives of the light group and was not noted in elements of the heavy group. The ability to self-precipitate in future can serve as a basis for developing an alternative approach to separating rare earth metals into groups after extraction in a carbonate ion medium. Also, based on the analysis of experimental data, the mechanism of cerium (III) phosphate dissolution in a carbonate-alkaline medium was characterized. An assumption was made that rare earth metal phosphates dissolve sequentially passing into an insoluble carbonate and then into a soluble carbonate complex.
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Date submitted2024-07-04
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Date accepted2024-07-04
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Date published2024-07-04
Environmental safety and sustainable development: new approaches to wastewater treatment
In 2015, the UN member states adopted the 2030 Agenda for Sustainable Development. Despite significant progress, billions of people – one in three people – do not have access to safe, clean drinking water. Modern wastewater treatment methods include a wide range of biological, chemical and physical processes, each having its own advantages and applications. This thematic volume considers the latest achievements in wastewater treatment technologies, wastewater purification and treatment as well as their potential applications at the local level. The problem of surface water pollution is relevant for all regions of the world. One of the largest sources of pollutants is mining and processing industry. The first stage in the development of wastewater treatment technologies is monitoring of anthropogenically modified water bodies.
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Date submitted2023-11-02
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Date accepted2024-03-05
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Date published2024-08-26
The polyphase Belokurikhinsky granite massif, Gorny Altai: isotope-geochemical study of zircon
Based on the isotopic-geochemical analyses of zircons from granites of the Belokurikhinsky massif in the Gorny Altai using the U-Pb method, the ages of three intrusion phases have been determined for the first time: the age of the first phase refers to the time interval of 255-250 Ma, the second and the third phases have similar ages of about 250 Ma. The formation time of the Belokurikhinsky massif is estimated as not exceeding 5-8 Ma. The δ18O values for zircons from granites of the second and the third intrusion phases average around 11.5-12.0 ‰, indicating a significant contribution of a crustal component in the formation of the parent melts for granites of these phases. The crystallization temperature values of the zircons by the Ti-in-zircon thermometer for three phases range from 820 to 800 °C. The P-T crystallization parameters of titanite from the first phase, determined using a titanite thermobarometer, average around 770 °C and 2.7 kbar. The zircons from the first phase mostly exhibits geochemical characteristics of typical magmatic zircons. The zircons from the second and the third intrusion phases either may be unaltered magmatic zircons or enriched in incompatible elements (LREE, Th, U, Ti, Ca, etc.) due to fluid influence, resembling hydrothermal-metasomatic type zircons in terms of their geochemical characteristics. A number of zircon grains from the second and the third phases of granites demonstrate anomalous geochemical characteristics – the REE distribution spectra atypical for zircons (including “bird's wing” type spectra with oppositely tilted of light and heavy REE distribution profiles), as well as significantly higher contents of certain trace elements compared to other varieties. Such an enriched zircon composition and wide variations in the incompatible element content are due to non-equilibrium conditions of zircon crystallization and evolution of the fluid-saturated melt composition during the final stages of the massif formation.
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Date submitted2023-04-13
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Date accepted2023-10-25
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Date published2025-02-25
Assessment of the ecological state of aquatic ecosystems by studying lake bottom sediments
- Authors:
- Mariya A. Chukaeva
- Tatyana V. Sapelko
The article presents the results of coupled palynological and geochemical studies of five various genesis lakes, located along the route of the expedition “In the footsteps of Alexander von Humboldt in Siberia, Altai and Eastern Kazakhstan”, dedicated to the double anniversary: the 190th anniversary of the expedition across Russia of the famous scientist and his 250th birthday. A geochemical analysis of water and bottom sediments of Ik Lake (Siberia), Lakes Kolyvanskoe and Beloe (Altai), Lake Bezymyannoe (Kazakhstan) and Nagornyi Pond (Altai) was carried out. Based on their results an assessment of studied lakes ecological state was given through single and integral criteria. A high level of pollution was noted for Nagornyi Pond and Lake Bezymyannoe, which is caused by a significant technogenic load from nearby mines. This is consistent with the data of palynological research. The aquatic ecosystems of Lakes Kolyvanskoe and Beloe are characterized by a satisfactory ecological situation, but they experience an increased recreational load. The results of spore-pollen analysis and analysis of non-pollen palynomorphs showed the low ability of these lakes to self-healing. The most favorable ecological state and high self-cleaning capacity were noted for Lake Ik, which is consistent with the data of palynological studies. It is being confirmed with the results of palynological studies. It was therefore concluded about the ability to make a quick assessment of the aquatic ecosystems’ ecological state by studying lakes using coupled palynological and geochemical analysis.
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Date submitted2023-07-20
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Date accepted2023-10-25
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Date published2024-04-25
Directions in the technological development of aluminium pots
- Authors:
- Еvgenii S. Gorlanov
- Leopold I. Leontev
Directions for the technical and technological development of aluminium industry, existing and promising projects to reduce the energy consumption and the environmental impact are analyzed. The active participation of the state in the organization of financial instruments for the ecological reconstruction of obsolete production facilities is discussed. In spite of the fact that the technology of aluminium pots is developed towards the increase of a single capacity, but with limited potential of reducing energy consumption and greenhouse gases emission, the possibilities for the increase of specific output are practically non-existent. Therefore, such projects like pots, equipped with inert anodes and drained cathodes arise and are under development, the successful completion of which is unlikely after multi-year researches and pilot tests. To continue the works related to inert anodes the decisive answer about the industrial safety of local sources of the massive oxygen emissions to atmosphere is required from competent entities. The drained cathode project, after discussing the existing problems, seems unfeasible. As opposed to the existing technology the development of the pots with vertical electrodes offers great opportunities to the designs of inert anodes and drained cathodes. Positive results of using shaped electrodes, homogenizing their surface and developing the methods for the synthesis of composite cathodes directly during the electrolytic process were obtained in laboratory conditions. It is expected that the combination of these trends and the successive dimensional scaling shall allow using the vertical electrodes at the next level for the fold increase of specific pot capacity and for the decrease of energy consumption and greenhouse gas emissions.
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Date submitted2022-06-25
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Date accepted2023-06-20
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Date published2024-02-29
Determination of the accuracy of leveling route based on GNSS/leveling and Earth gravitational model data SGG-UGM-2 at some typical regions in Vietnam
- Authors:
- Bui Thi Hong Tham
- Phi Truong Thanh
This paper presents the accuracy of leveling routes determined by using GNSS/leveling at three grades and Earth gravitational model data SGG-UGM-2 in four regions of Vietnam by calculating the difference between the measured height anomalies and the model of pairs of points. The calculation is made based on the total points of three grades for four regions (99 in the Northwest, 34 in the Red River Delta, 130 in the Central Highlands, and 96 in the Mekong River Delta) with the leveling routes, connected between pair of points in each region are 189, 92, 294, and 203. The calculated results of the percentage of accuracy of the leveling routes of the four regions have shown that most of the leveling routes are satisfactory (grades I-IV, and technical leveling). The determination of the accuracy of the leveling route is completely applicable to other areas when the points have simultaneous ellipsoid and leveling heights and it also helps managers and surveyors to predict the accuracy of the height points when the above-mentioned leveling routes are connected and to take reasonable measures when implementing the project.
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Date submitted2022-05-17
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Date accepted2023-04-03
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Date published2024-02-29
Improvement of concentrate quality in flotation of low-rank coal
- Authors:
- Sergei A. Kondratev
- Tatyana A. Khamzina
Percentage of high-rank coal with low content of ash, moisture, and sulfur in total coal production output is low. Most of the produced coal has a low quality (lignite, bituminous coal: long-flame and fiery). Under increasing requirements for ecological cleanness of coal, the efficient use of coal products is only possible after improvement of their processing properties. The authors discuss the enhancement of flotation efficiency of low-rank coal using the mechanism of physisorption of a collecting agent in particle – bubble attachment. It is explained why the yield of concentrate with low ash content increases as a result of combination of collectors having different physical properties. It is shown that the surface activity of a heteropolar agent relative to the gas – liquid interface and the adsorption density of the agent govern its collecting properties. Based on the recovery – surface activity relationship, the correlation is found between the collecting activity of a chemical compound and the structure of its molecules. The combination of the collectors with different surface activity enables adjusting collectability and selectivity of the blend. The physisorption mechanism of collectors can be a framework for developing recommendations on modification of concentrate yield and ash content, and on selection of optimized ratios of surface activities of miscible collectors relative to the gas – liquid interface.
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Date submitted2023-03-16
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Date accepted2023-06-20
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Date published2023-07-19
Energy efficiency of the linear rack drive for sucker rod pumping units
- Authors:
- Oksana Yu. Ganzulenko
- Ani P. Petkova
At present, in order to increase oil production and reduce economic costs in the development of marginal fields, the development of a cluster method using compact mobile drives of sucker rod pumping units (SRPU) is relevant. The aim of the work is to analyze the ways to improve the energy efficiency of the SRPU by reducing the loss of mechanical and electrical energy, to select the most energy-efficient compact drive for the development of marginal fields in the cluster method, to carry out the kinematic and strength calculations of the drive of the selected size, to develop an adaptive control system for a group of drives in the cluster development of drillings. According to the results of the performed calculations, the linear rack-and-gear drive has the highest efficiency of the drive mechanism. The kinematic and strength calculations of a linear rack-and-gear drive with a stroke length of 1120 mm and a load of up to 8 tons are presented. It was shown that the usage of a direct torque control system and a kinetic energy storage system for the SRPU drive elements and a rod string is an effective means of reducing energy costs in oil production from marginal fields. The use of the developed system for storing and redistributing the potential energy of the rods between the SRPUs that lift oil made it possible to eliminate fluctuations in the power consumption, reduce the power peak value by three times, the peak value of the current consumed from the electric network by two times, and reduce losses in the input converter and cables by three times.
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Date submitted2022-12-03
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Date accepted2023-02-03
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Date published2023-08-28
Garnetites from Marun-Keu eclogite complex (Polar Urals): geochemistry and the problem of genesis
- Authors:
- Laysan I. Salimgaraeva
- Alexei V. Berezin
A comprehensive mineralogical and geochemical characterization (XRF, ICP-MS, SEM-EDS, SIMS methods) of garnetites and their protoliths from the Marun-Keu complex (Polar Urals), one of the key objects in understanding the evolution of the Uralian Orogen, is presented. Garnetites and their protoliths from the Marun-Keu complex, Polar Urals, a key locality for understanding the evolution of the Uralian Orogen, are described mineralogically and geochemically using XRF, ICP-MS, SEM-EDS and SIMS methods. Ultramafic (in most cases) and mafic rocks are understood as protoliths for garnetites. A general trend for garnetites is an increase in total REE concentration relative to that of their protoliths. All the analyzed garnetites display a considerable decrease in Cr, Ni and Co. V concentration in the garnetites is also lower than that of the protoliths, though not so markedly. Garnets from garnetites evolving after peridotites generally exhibit elevated (relative to garnets from garnetites evolving after mafic rocks, such as porphyrites) Prp and lowered Alm content, which seems to be due to high Mg concentration in the protolith. In garnetites after peridotites a garnet exhibiting an uncommon non-differentiated REE spectrum with a considerable positive Eu-anomaly was found, which could be due to the inheritance of a REE spectrum by garnet from a precursor mineral, in this case plagioclase. Slyudyanaya Gorka garnetites were probably formed from mafic and ultramafic rocks in oceanic crust, which migrated to higher levels of the section under the influence of the crustal fluid flowing along fracturing zones.
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Date submitted2022-09-27
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Date accepted2023-04-03
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Date published2023-12-25
The study of displacing ability of lignosulfonate aqueous solutions on sand packed tubes
This paper presents the findings of laboratory studies of rheological properties and oil displacing ability of aqueous solutions of technical grade lignosulfonate done on the sand packed tube models. The solutions containing lignosulfonate can be useful as displacement agents in development of watered reservoirs with heterogeneous porosity and permeability. When used at high concentrations, technical grade lignosulfonate can achieve selective shut-off while maintaining the reservoir pressure. The oil displacement efficiency is improved by means of redistributing the flows and selective isolation of high-permeability zones. The use of such compositions allows increasing the sweep of low-permeability reservoir zones by created pressure differential and displacing the residual oil.
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Date submitted2022-08-10
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Date accepted2023-02-28
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Date published2024-02-29
Selection of the required number of circulating subs in a special assembly and investigation of their performance during drilling of radial branching channels by sectional positive displacement motors
The task of sludge removal to the surface during construction of directional and horizontal wells and strongly curved radial channels is relevant. For stable operation of technical system “Perfobore”, it is proposed to use a circulating sub that ensures efficient cleaning of channel wellbore from the drilled rock. Two schemes of technical system “Perfobore” are considered, consisting of two seven-meter coiled tubing, a positive displacement motor, a bit and one circulating sub in the first scheme and two subs in the second scheme. For each of the schemes CFD modeling was implemented to determine values of pressure and speed. It was found out that the use of two circulating subs in the assembly is more efficient. In order to confirm the numerical experiment, bench tests were carried out. It was determined that the designed circulating sub can eject up to 25 % of pumped drilling fluid. The bench tests of full-size technical system “Perfobore” for drilling 14-meter channels with two circulating subs showed that the axial load on positive displacement motor produced by hydraulic loader was 3000 N and pressure drop depending on flow rate was 1.5-2.0 MPa. This allows the motor to operate at maximum power.
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Date submitted2022-09-30
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Date accepted2023-02-13
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Date published2023-04-25
Hydrogeoecological conditions of technogenic groundwater in waste disposal sites
The specific hydrogeoecological conditions of aquifers of some technogenic formations, mainly iron ore skarn-magnetite and titanium-magnetite formations, are considered. The resulting wastes, which are stored in waste disposal sites during development of deposits, due to the impact of a number of factors (natural and technogenic) form technogenic waters. Waste disposal facilities are complex engineering structures (dumps and sludge storages), which in turn create their own hydrogeoecological conditions, which must be investigated in order to prevent and minimize environmental and economic damage caused by these objects to the aquatic environment. The paper presents long-term field and laboratory studies of the aquatic environment under the influence of a waste disposal facility in the Middle Urals – one of the largest tailings, representing a potential environmental and man-made hazard. This tailing dump contains tens of tons of waste – enrichment tailings and creates specific hydrogeoecological conditions on the territory. Based on many years of monitoring studies, an analysis of these conditions was carried out – the quality of groundwater affected by the tailings was assessed. It is shown that groundwater is of technogenic nature, i.e. are man-made waters that have a significant impact on the surface and underground hydrospheres of the territory.
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Date submitted2022-03-22
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Date accepted2022-11-17
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Date published2023-02-27
Development of composition and study of sorbent properties based on saponite
The development of a comprehensive approach to preventing the pollution of natural objects is necessary due to the high requirements of environmental legislation for the discharge of industrial wastewater. Adsorbents are used in various industries to extract heavy metals from wastewater. In this study the possibility of using saponite clay as a raw material for the production of sorbent for the extraction of copper ions Cu 2+ from industrial wastewater is considered, a recipe and technology of sorbent production are developed, and its chemical composition is established. It has been established that the optimum temperature for heat treatment of the sorbent and corresponds to 550 ºC, since at this temperature saponite extrudates acquire strength (strength 34.1 kg/mm 2 ) and textural properties (specific surface area of pellets 22.803 m 2 /g), allowing them to be used as sorbents. The kinetics of molecular adsorption was studied using model solutions of copper (II) sulfate. The extraction efficiency of copper (II) ions from the model solutions is 93 %. Extraction efficiency of copper (II) ions from copper plating wastewater reaches 94 %. SEM results confirm the presence of metal on the sorbent surface.
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Date submitted2022-07-15
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Date accepted2022-12-13
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Date published2023-02-27
Mathematical modelling of displacement during the potash ores mining by longwall faces
In favourable mining conditions, in particular at the Starobinskoye potash deposit (Belarus), longwall mining systems are used. They cause a high human-induced load on the subsoil, including intense deformation of the ground surface. The presented investigations are aimed at studying the dynamics of the ground surface displacement during the longwall face advance. Mathematical modelling was carried out in an elastic-plastic formulation with numerical implementation by the finite element method. The condition for the roof rocks collapse was opening of the contact between the seams when its boundaries were reached by shear fractures or formation of the tensile stresses area at the outcrop. With the working front advance, an increase in subsidence is observed, followed by its stabilization to a value determined by the process parameters of mining operations and the physical and mechanical properties of collapsed rocks. In this case, each point of the ground surface experiences sign-alternating horizontal deformations: when the front approaches, it causes tension, and when it moves away, compression. The obtained results of mathematical modelling are in good agreement with the data of instrumental measurements of the ground surface displacements, which indicates the adequate description of the rock mass deformation during the slice excavation of sylvinite seams by longwall faces.
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Date submitted2022-03-14
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Date accepted2022-06-20
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Date published2022-11-10
Model of a walking sampler for research of the bottom surface in the subglacial lake Vostok
Technologies and technical means for investigation of subglacial lakes in Antarctic is a new developing scientific and technical direction, which today has no clearly established methodology. Based on the developed technology of drilling a new access well to lake Vostok and its penetration as well as analysis of existing methods and devices for bottom sediment sampling, a basic model of a sampler with a walking-type mover, capable of moving along different trajectories and operating in a wide technological range, is proposed. The proposed device model is equipped with different actuators for sampling the bottom surface with different physical and mechanical properties. Based on the presented basic model of the walking sampler, a mathematical model of the device was developed, which was based on the theoretical mechanics methods. As a result of conducted research the dependencies were obtained, which allow making a scientifically justified choice of optimal values for geometric and force parameters of the walking sampler. A conceptual design of the walking sampler has been developed, taking into account the mutual location and coupling of its main components, the overall dimensions of the delivery tool, as well as the esthetic component of the device.
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Date submitted2022-06-27
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Date accepted2022-09-09
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Date published2022-11-03
Study of the composition and properties of the beneficiation tailings of currently produced loparite ores
The increase in demand for rare earth metals and the depletion of natural resources inevitably causes the need to search for alternative unconventional sources of rare metal raw materials. The article presents the results of a study of the composition and properties of the beneficiation tailings of currently produced loparite ores. Sieve, mineralogical, chemical, and radionuclide analyses were carried out. The average content of loparite in tailings was determined. Using scanning electron microscopy, minerals-concentrators of rare earth elements in the loparite ore beneficiation tailings were diagnosed. The distribution of valuable components and thorium in the tailings was determined depending on the particle size class. The radium-thorium nature of radioactivity was established, the values of the effective specific activity of the samples were calculated. We concluded that it is necessary to develop an integrated technology for processing the beneficiation tailings of loparite ore, due to the complex and heterogeneous mineral and chemical composition of the tailings material.
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Date submitted2022-03-17
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Date accepted2022-10-04
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Date published2022-11-10
Improving the reliability of 3D modelling of a landslide slope based on engineering geophysics data
Landslides are among the most dangerous geological processes, posing a threat to all engineering structures. In order to assess the stability of slopes, complex engineering surveys are used, the results of which are necessary to perform computations of the stability of soil masses and assess the risks of landslide development. The results of integ-rated geological and geophysical studies of a typical landslide slope in the North-Western Caucasus spurs, composed of clayey soils, are presented. The purpose of the work is to increase the reliability of assessing the stability of a landslide mass by constructing a 3D model of the slope, including its main structural elements, identified using modern methods of engineering geophysics. Accounting for geophysical data in the formation of the computed 3D model of the slope made it possible to identify important structural elements of the landslide, which significantly affected the correct computation of its stability.
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Date submitted2022-04-29
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Date accepted2022-07-21
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Date published2022-11-10
Deep structure, tectonics and geodynamics of the Sea of Okhotsk region and structures of its folded frame
The use of the zonal-block model of the earth's crust for the construction of regional tectonic schemes and sections of the earth's crust based on a complex of geological and geophysical data makes it possible to consider the resulting maps and sections as tectonic models. The main elements of such models are blocks with an ancient continental base and interblock zones formed by complexes of island arcs, an accretionary prism, or oceanic crust. The developed geotectonic model of the Sea of Okhotsk region reflects the features of the deep structure, tectonics, and geodynamics. The Cimmerian Novosibirsk-Chukotka, Verkhoyansk-Kolyma, Kolyma-Omolon, and Amur folded regions and the Alpides of the Koryak-Kamchatka and Sakhalin-Sikhote-Alin folded regions are developed along the northern, western, and southern boundaries of the Sea of Okhotsk megablock with a continental crust type. From the east, the megablock is limited by oceanic basins and island arcs.
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Date submitted2022-03-21
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Date accepted2022-06-15
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Date published2022-07-26
Ti-Fe-Cr spinels in layered (stratified) complexes of the western slope of the Southern Urals: species diversity and formation conditions
- Authors:
- Sergey G. Kovalev
- Sergey S. Kovalev
Materials on geochemistry and ore Fe-Ti-Cr mineralization of rocks composing layered (stratified) bodies of the western slope of the Southern Urals are presented. A detailed analysis showed similarity in the redistribution of REE, noble metals, and Fe-Ti-Cr mineralization of practically all parameters in rocks of the Misaelga and Kusin-Kopan complexes. It has been established that the parameters of metamorphism, which influenced components redistribution in Fe-Ti-Cr minerals of the layered complexes, correspond to Misaelga – T = <550-750 °С, P = 0.1-2.8 kbar, Kusin-Kopan – T = <550-630 °С, P = 0.3-0.7 kbar, and Shuidinsky complexes – T = <550-760 °С, P = 0.5-2.5 kbar. The result of modelling the melt crystallization process showed that the Kusin-Kopan complex is an intrusive body with an ultramafic horizon in the idealized cross-section. Due to collisional processes, the lower part of the intrusion has been detached from the upper part. The proposed structure of the Kusin-Kopan complex sharply increases its prospects for such types of minerals as platinum group minerals + sulphide copper-nickel mine-ralization and/or chromites.
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Date submitted2020-08-20
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Date accepted2021-11-30
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Date published2021-12-27
Indicator role of rare and rare-earth elements of the Northwest manganese ore occurrence (South Africa) in the genetic model of supergene manganese deposits
- Authors:
- Aleksandr N. Evdokimov
- Benedict L. Pharoe
The authors analyzed the content of a number of rare and rare-earth elements in the rocks of the Northwest manganese ore occurrence, confined to the Neoarchean dolomites of the Malmani series of the Transvaal Basin. 30 samples of manganese ores and host rocks were analyzed by ICP-MS and XRF methods. Average values of Post-Archean Australian Shale (PAAS) were used as the geochemical standard for data calculation and normalization. The concentrations of elements normalized on PAAS reveal the LREE anomaly in manganese ores. Positive Ce and negative Y–anomalies indicate the hydro-genetical type of sedimentation of ore minerals from manganese-bearing aqueous solutions. This is consistent with the ratios of the elements: Ce and Y SN /Ho SN , Ce and Nd, Fe – Mn – (Co + Ni + Cu) × 10. A clear correlation between the contents of rare-earth elements in manganese nodules and the underlying Malmani dolomites indicates their close genetic relationship. Negative Ce and positive Y–anomalies in manganese wad minerals indicate differences in the conditions of their formation. The manganese wad formed earlier than the rest of the ore with the active participation of microorganisms.
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Date submitted2021-03-18
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Date accepted2021-11-30
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Date published2021-12-27
Deformations assessment during subway escalator tunnels construction by the method of artificial freezing of soil for the stage of ice wall formation
- Authors:
- Evgenii M. Volokhov
- Diana Z. Mukminova
The work is devoted to the study of the processes of displacement and deformation of the surface during the escalator tunnels construction of the subway by the method of artificial freezing of soils. The features of the construction and freezing technology, the rocks characteristics in which the escalator tunnels made are considered. The data of specially organized, full-scale surveying observations of deformations on the earth surface are presented. The main factors influencing deformation processes in the frozen strata of a layered inhomogeneous rock mass with inclined tunneling are determined, the complexity of the predictive task and the need to simplify the design scheme are shown. The work is focused on the assessment of the least studied geomechanical processes of soil heaving-uplifts and deformations during the periods of active and passive freezing stages. When studying the displacements processes of the earth surface and rock mass, the finite element method and analysis of the obtained data using field observations of displacements were used. A simplified calculation scheme is proposed for modeling, which allows taking into account the uneven influence of frozen rocks of an inhomogeneous layered rock mass with a large inclined tunneling. The satisfactory convergence of the data of field surveying observations on the earth surface and the results of modeling geomechanical processes for the period of active and passive freezing stages is shown. The proposed calculation scheme is recommended for the prediction of deformation at the stages of underground construction, characterized by the development of the most dangerous tensile deformations of buildings and structures on the surface.
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Date submitted2021-06-17
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Date accepted2021-10-18
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Date published2021-12-16
Dissolution kinetics of rare earth metal phosphates in carbonate solutions of alkali metals
- Authors:
- Tatyana E. Litvinova
- Ivan L. Oleynik
Treatment of apatite raw materials is associated with the formation of large-tonnage waste – phosphogypsum. The content of rare earth metals in such waste reaches 1 %, which makes it possible to consider it a technogenic source for obtaining rare earth metals and their compounds. Up to the present moment, there are neither processing plants, nor an efficient process flow to handle phosphogypsum dumps. It is rational to use a way that involves extraction of valuable components and overall reduction of phosphogypsum dumps. Such process flow is available with carbonate conversion of phosphogypsum to alkali metal or ammonium sulfate and calcium carbonate upon the condition of associated extraction of rare earth metal (REM) compounds. Associated extraction of REM compounds becomes possible since they form strong and stable complexes with hard bases according to Pearson, which among other things include carbonate, phosphate and sulfate anions. Formation of lanthanide complexes with inorganic oxygen-containing anions is facilitated by the formation of high-energy Ln-O bonds. The study focuses on the dissolution of lanthanide phosphates in carbonate media. It was established that formation of REM carbonate complexes from their phosphates is a spontaneous endothermic process and that formation of lanthanide carbonates and hydroxides serves as thermodynamic limitation of dissolution. A shift in equilibrium towards the formation of carbonate complexes is achieved by increasing the temperature to 90-100 °C and providing an excess of carbonate. The limiting stage of REM phosphate dissolution in carbonate media is external diffusion. This is indicated by increasing rate of the process with an intensification of stirring, first order of the reaction and the value of activation energy for phosphate dissolution from 27 to 60 kJ/mol. A combination of physical and chemical parameters of the process allowed to develop an engineering solution for associated REM extraction during carbonate conversion of phosphogypsum, which included a 4-5 h conversion of phosphogypsum at temperature of 90-110 °C by an alkali metal or ammonium carbonate solution with a concentration of 2-3 mol/l. As a result, a solution with alkali metal (ammonium) sulfate is obtained, which contains REMs in the form of carbonate complexes and calcium carbonate. The rate of REM extraction into the solution reaches no less than 93 %. Rare earth metals are separated from the mother liquor by precipitation or sorption on anion exchange resins, while the excess of alkali metal or ammonium carbonate is returned to the start of the process.
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Date submitted2021-04-23
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Date accepted2021-09-07
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Date published2021-12-16
Development of the concept of an innovative laboratory installation for the study of dust-forming surfaces
Currently, the determination of the emission rate of suspended solids from a unit of the surface area of a man-made mass at various parameters of the wind flow is not sufficiently described. The analysis of the world experience of researchers shows that existing laboratory installations have various design features that do not allow to correctly determine the mass of the dust being flapped and wind-blown. Based on the analysis results, the concept of an innovative laboratory installation for the study of dust-forming surfaces has been developed. It takes into account the influence of wind shadows, the deturbulization of an artificially created air flow, the possibility of regulating not only the flow velocity mode, but also the creation of a vacuum or disturbance in the area of sample placement, as well as the formation of a certain angle of wind flow attack relative to the surface. The concept provides for the possibility of determining the volume of dust emissions by the values of the lost dust masses in the sample and by the values of dust concentrations in the outgoing stream. The calculation of the main basic elements of the installation using the ANSYS FLUENT software package was carried out. The model and configuration of the wind tunnel have been developed and calculated, the main geometric parameters and functional elements for the possibility of use in scientific work have been determined. For practical use of the empirical roughness value of the underlying surface, its values are recommended in a wide range – from zero for the water surface to 0.44 for large cities with tall buildings and skyscrapers.