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Date submitted2023-04-10
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Date accepted2024-11-07
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Date published2025-02-25
Consideration of the geomechanical state of a fractured porous reservoir in reservoir simulation modelling
This paper presents reservoir simulation modeling of a hydrocarbon accumulation with a fractured porous reservoir, incorporating the geomechanical effects of fracture closure during variations in formation pressure. The fracture permeability parameter is derived from the impact of stress on fracture walls. The fracturing parameter is determined based on 3D seismic data analysis. A permeability reduction model is implemented in the tNavigator reservoir simulation platform. The proposed approach improves the convergence of formation pressure dynamics in well data while maintaining flow rate and water cut adaptation accuracy. This results in enhanced formation pressure prediction and optimization of the pressure maintenance system.
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Date submitted2024-05-30
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Date accepted2024-10-14
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Date published2024-11-12
Thermodynamic modelling as a basis for forecasting phase states of hydrocarbon fluids at great and super-great depths
The possibility of discovering oil and gas occurrences at great (more than 5 km) and super-great (more than 6 km) depths is considered in two aspects. The first one is the preservation conditions of large hydrocarbon accumulations forming at depths to 4 km and caused by different geological and tectonic processes occurring at great and super-great depths with partial oil-to-gas transformation. It was ascertained that among the factors controlling preservation of liquid and gaseous hydrocarbons are the temperature, pressure, subsidence rate (rate of temperature and pressure increase), time spent under ultrahigh thermobaric conditions, and initial composition of organic matter. The possibility of existence of liquid components of oil at great and super-great depths is characteristic of sedimentary basins of China, the Gulf of Mexico, the Santos and Campos basins on the Brazilian shelf, and in the Russian Federation it is most probable for the Caspian Depression, some submontane troughs and zones of intense accumulation of young sediments. Determination of critical temperatures and pressures of phase transitions and the onset of cracking is possible using the approach considered in the article, based on estimation of organic matter transformation degree, kinetic and thermobaric models taking into account the composition of hydrocarbon fluid. The second aspect is the estimation of composition of hydrocarbons associated with rocks forming at great depths or rocks transformed under conditions of critical temperatures and pressures. This aspect of considerable science intensity can hardly be considered as practically significant. The study focuses on the investigation of the possibilities of thermodynamic modelling and the use of alternative methods for studying the transformation degree of liquid formation fluid into components of the associated gas through the example of two areas with identified oil, condensate and gas accumulations.
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Date submitted2024-10-29
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Date accepted2024-10-29
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Date published2024-11-12
Study of thermodynamic processes of the Earth from the position of the genesis of hydrocarbons at great depths
In the context of significant depletion of traditional proven oil reserves in the Russian Federation and the inevitability of searching for new directions of study and expansion of the raw material base of hydrocarbon raw materials in hard-to-reach regions and on the Arctic shelf, a scientific search is underway for accumulations in complex geological conditions and in manifestations that differ significantly from traditional ones, which include the processes of oil and gas formation and preservation of oil and gas in low-permeability “shale” strata and in heterogeneous reservoirs at great and super-great depths. Within the oil and gas provinces of the world, drilling of a number of deep and super-deep wells has revealed deposits at great depths, established connections between hydrocarbon deposits and “traces” of hydrocarbon migration left in the core of deep wells, which has made it possible to significantly re-evaluate theoretical ideas on the issue of oil and gas formation conditions and the search for technologies aimed at solving applied problems. Modern geochemical, chromatographic, bituminological, coal petrographic and pyrolytic methods of studying oil and bitumoids extracted from the host rocks of deep well cores give a hope for identifying correlations in the oil-source system, revealing processes that determine the possibility of hydrocarbon formation and accumulation, and defining predictive criteria for oil and gas potential at great depths.
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Date submitted2024-05-13
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Date accepted2024-09-05
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Date published2024-11-12
Potential trace element markers of naphthogenesis processes: modeling and experimentation
With the growing demand for hydrocarbon energy resources, there is a need to involve oil fields at deeper horizons in processing and increase the profitability of their development. Reduction of expenses on prospecting works is possible at revealing and substantiation of physicochemical markers of the naphthogenesis processes. One of the key markers is the transition metals content, which are both a measure of oil age and markers of potential associated processes in the migration and formation of hydrocarbons in the Earth's strata. The elemental composition of samples of oil and reservoir rocks of the Timan-Pechora field was studied. Based on the results of thermodynamic modeling, plausible processes of contact rock minerals transformation were proposed. Based on the results of molecular modeling the probable structure of vanadium and nickel host molecules in the heavy fraction of oils is proposed. The ratios of transition metal and sulfur contents were experimentally established, and assumptions about possible mechanisms of formation of deep hydrocarbon reservoirs were made. Analysis of the obtained ratios of transition metal contents in reservoir rocks and oil samples allowed to suggest possible processes of mantle fluids contact with the host rock and subsequent accumulation of hydrocarbons on sorption active rocks. According to the combined results of experimental and theoretical studies it was found that polymers of heavy fraction more selectively capture vanadium, which indicates the predominance of vanadium content in oil-bearing rocks in relation to the content of nickel. In this case, oil acts as a transport of transition metals, leaching them from the bedrock.
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Date submitted2023-08-14
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Date accepted2023-12-27
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Date published2024-12-25
Modelling of compositional gradient for reservoir fluid in a gas condensate deposit with account for scattered liquid hydrocarbons
In oil and gas reservoirs with significant hydrocarbon columns the dependency of the initial hydrocarbon composition on depth – the compositional gradient – is an important factor in assessing the initial amounts of components in place, the position of the gas-oil contact, and variations of fluid properties throughout the reservoir volume. Known models of the compositional gradient are based on thermodynamic relations assuming a quasi-equilibrium state of a multi-component hydrodynamically connected hydrocarbon system in the gravity field, taking into account the influence of the natural geothermal gradient. The corresponding algorithms allow for calculation of changes in pressure and hydrocarbon fluid composition with depth, including determination of the gas-oil contact (GOC) position. Above and below the GOC, the fluid state is considered single-phase. Many oil-gas-condensate reservoirs typically have a small initial fraction of the liquid hydrocarbon phase (LHC) – scattered oil – within the gas-saturated part of the reservoir. To account for this phenomenon, a special modification of the thermodynamic model has been proposed, and an algorithm for calculating the compositional gradient in a gas condensate reservoir with the presence of LHC has been implemented. Simulation cases modelling the characteristic compositions and conditions of three real oil-gas-condensate fields are considered. The results of the calculations using the proposed algorithm show peculiarities of variations of the LHC content and its impact on the distribution of gas condensate mixture composition with depth. The presence of LHC leads to an increase in the level and possible change in the type of the fluid contact. The character of the LHC fraction dependency on depth can be different and is governed by the dissolution of light components in the saturated liquid phase. The composition of the LHC in the gas condensate part of the reservoir changes with depth differently than in the oil zone, where the liquid phase is undersaturated with light hydrocarbons. The results of the study are significant for assessing initial amounts of hydrocarbon components and potential efficiency of their recovery in gas condensate and oil-gas-condensate reservoirs with large hydrocarbon columns.
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Date submitted2021-01-21
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Date accepted2023-09-20
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Date published2023-12-25
Adaptation of transient well test results
Transient well tests are a tool for monitoring oil recovery processes. Research technologies implemented in pumping wells provide for a preliminary conversion of measured parameters to bottomhole pressure, which leads to errors in determining the filtration parameters. An adaptive interpretation of the results of well tests performed in pumping wells is proposed. Based on the original method of mathematical processing of a large volume of field data for the geological and geophysical conditions of developed pays in oil field, multidimensional models of well flow rates were constructed including the filtration parameters determined during the interpretation of tests. It is proposed to consider the maximum convergence of the flow rate calculated using a multidimensional model and the value obtained during well testing as a sign of reliability of the filtration parameter. It is proposed to use the analysis of the developed multidimensional models to assess the filtration conditions and determine the individual characteristics of oil flow to wells within the pays. For the Bashkirian-Serpukhovian and the Tournaisian-Famennian carbonate deposits, the influence of bottomhole pressure on the well flow rates has been established, which confirms the well-known assumption about possible deformations of carbonate reservoirs in the bottomhole areas and is a sign of physicality of the developed multidimensional models. The advantage of the proposed approach is a possibility of using it to adapt the results of any research technology and interpretation method.
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Date submitted2022-08-05
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Date accepted2022-11-17
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Date published2023-02-27
Feasibility study of using cogeneration plants at Kuzbass coal mines
The paper considers the problem of reducing greenhouse gas emissions in the process of coal mining during the coal mine methane utilization in power supply systems. An algorithm to form recommendations for the implementation of CMM generation is presented. A simulation model for one of the Kuzbass coal mines was developed in the PowerFactory software application. The simulation model considers the uneven nature of the power consumption of mining equipment. As a result of modeling, daily power consumption profiles and voltage levels in the coal mine power supply system were determined before and after the implementation of the proposed measures. Based on the results, the technical and economic effects was estimated, which consisted in reducing the direct and indirect carbon footprint, electricity and capacity fees. It has been established that the cost of carbon dioxide emission quotas significantly affects the investment attractiveness of cogeneration projects. Based on the results, recommendations are given to stimulate the development of small generation in coal mines.
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Date submitted2022-05-06
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Date accepted2022-11-17
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Date published2023-02-27
Comprehensive study of filtration properties of pelletized sandy clay ores and filtration modes in the heap leaching stack
There are the results of a study of the factors determining the formation and changes in the filtration properties of a heap leaching stack formed from pelletized poor sandy-clay ores. An analysis of methods of investigation of filtration properties of ore material for different stages of heap leaching plots functioning is carried out. Influence of segregation process during stack dumping on formation of zones with very different permeability parameters of ore has been established by experimental and filtration works. The construction and application of a numerical model of filtration processes in pelletized ores based on laboratory experiments is shown. By means of solution percolation simulation at different irrigation intensities the justification of optimal stack parameters is provided in terms of the geomechanical stability and prevention of solution level rise above the drainage layer.
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Date submitted2022-07-15
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Date accepted2022-12-13
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Date published2023-02-27
Mathematical modelling of displacement during the potash ores mining by longwall faces
In favourable mining conditions, in particular at the Starobinskoye potash deposit (Belarus), longwall mining systems are used. They cause a high human-induced load on the subsoil, including intense deformation of the ground surface. The presented investigations are aimed at studying the dynamics of the ground surface displacement during the longwall face advance. Mathematical modelling was carried out in an elastic-plastic formulation with numerical implementation by the finite element method. The condition for the roof rocks collapse was opening of the contact between the seams when its boundaries were reached by shear fractures or formation of the tensile stresses area at the outcrop. With the working front advance, an increase in subsidence is observed, followed by its stabilization to a value determined by the process parameters of mining operations and the physical and mechanical properties of collapsed rocks. In this case, each point of the ground surface experiences sign-alternating horizontal deformations: when the front approaches, it causes tension, and when it moves away, compression. The obtained results of mathematical modelling are in good agreement with the data of instrumental measurements of the ground surface displacements, which indicates the adequate description of the rock mass deformation during the slice excavation of sylvinite seams by longwall faces.
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Date submitted2022-05-31
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Date accepted2022-11-17
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Date published2022-12-29
Estimation of the influence of fracture parameters uncertainty on the dynamics of technological development indicators of the Tournaisian-Famennian oil reservoir in Sukharev oil field
Issues related to the influence of reservoir properties uncertainty on oil field development modelling are considered. To increase the reliability of geological-hydrodynamic mathematical model in the course of multivariate matching, the influence of reservoir properties uncertainty on the design technological parameters of development was estimated, and their mutual influence was determined. The optimal conditions for the development of the deposit were determined, and multivariate forecasts were made. The described approach of history matching and calculation of the forecast of technological development indicators allows to obtain a more reliable and a less subjective history match as well as to increase the reliability of long-term and short-term forecasts.
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Date submitted2022-06-20
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Date accepted2022-10-10
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Date published2022-11-03
Monitoring of grinding condition in drum mills based on resulting shaft torque
Grinding is the most energy-intensive process among all stages of raw material preparation and determines the course of subsequent ore beneficiation stages. Level of electricity consumption is determined in accordance with load characteristics forming as a result of ore destruction in the mill. Mill drum speed is one of process variables due to which it is possible to control ore destruction mechanisms when choosing speed operation mode of adjustable electric mill drive. This study on increasing energy efficiency due to using mill electric drive is based on integrated modelling of process equipment – grinding process and electromechanic equipment – electric drive of grinding process. Evaluating load torque by means of its decomposition into a spectrum, mill condition is identified by changing signs of frequency components of torque spectrum; and when studying electromagnetic torque of electric drive, grinding process is monitored. Evaluation and selection of efficient operation mode of electric drive is based on the obtained spectrum of electromagnetic torque. Research results showed that with increasing mill drum speed – increasing impact energy, load torque values are comparable for the assigned simulation parameters. From the spectra obtained, it is possible to identify mill load condition – speed and fill level. This approach allows evaluating the impact of changes in process variables of grinding process on parameters of electromechanical system. Changing speed operation mode will increase grinding productivity by reducing the time of ore grinding and will not lead to growth of energy consumption. Integration of digital models of the technological process and automated electric drive system allows forming the basis for developing integrated methods of monitoring and evaluation of energy efficiency of the entire technological chain of ore beneficiation.
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Date submitted2021-03-31
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Date accepted2022-04-26
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Date published2022-11-03
Features of obtaining metallurgical products in the solid-state hydride synthesis conditions
- Authors:
- Andrey G. Syrkov
- Lyudmila A. Yachmenova
A scientific substantiation of solid-phase feedstock choice and preparation has been carried out, and the thermodynamic and kinetic aspects of solid-state hydride synthesis (SHS) of metal products have been analyzed using the nickel dichloride reduction as an example. The preliminary dehydration modes and methods for controlling the complete removal of crystalline water from chloride raw materials and Olenegorsk superconcentrate, which is natural oxide raw material, are described. Conditions, including initial solid chloride particle sizes, are established under which diffusion complications of reduction to metal in methyldichlorosilane vapor are minimized. Thermodynamic estimates of nickel chlorides and oxides reduction possibility, iron and copper with ammonia and methane at temperatures of 400-1000 K in equilibrium conditions have been carried out. It has been shown that the stoichiometric coefficients of the nickel dichloride in ammonia overall reduction reaction calculated by thermodynamic modeling are in agreement with experimental data. In contrast to the copper dichloride reduction, for nickel dichloride the formation of metal monochloride at the intermediate stage is uncharacteristic, which is associated with a higher thermal stability of nickel dichloride. The main kinetic regularities of the reduction of nickel, copper, and iron to metal under SHS conditions in ammonia, monosilane, and methane, as well as the nickel dichloride with methyldichlorosilane vapor and methane successive reduction, are considered. Approximation of experimental data by topochemical equations in a linear form showed that for reduction degrees a up to 0.7-0.8, these data are satisfactorily described by the Roginsky – Schultz equation. For a > 0,8 the “shrinking sphere” model works better, which confirms the localization of the solid-state reduction reaction at the interface, moves deep into the crystal with the formation of a of interlocked metal germs. The importance and prospects of the results obtained for the theory development of metallurgical processes, deep complex processing of natural iron oxide raw materials, metal products and new generation materials production, including superhydrophobic ones, are discussed. The relevance of the study from the point of view of applying the method of physical and chemical analysis to the study of complex heterogeneous metallurgical processes is noted.
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Date submitted2022-05-03
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Date accepted2022-07-21
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Date published2022-11-03
Determination of rational steam consumption in steam-air mixture flotation of apatite-nepheline ores
Relevance of the study is determined by the decisions taken to increase the production volume of certain commercial products from mineral raw materials. The scale, impact and consequences of the projects on developing the resource-saving technologies for beneficiation of mineral raw materials are socially significant, and the economic growth of mining production complies with the sustainable development goals. The aim of the study is to develop the flotation circuit and mode that improve the technological performance of beneficiation of apatite-nepheline ores of the Khibiny Massif in the Kola Peninsula. The scientific idea of the work is to develop the flotation circuit, the movement of beneficiation products in which ensures a major increase in the content of the recovered component in the rougher flotation procedure with a simultaneous increase in dressability of the material. The above condition is met when mixing the feedstock with rough concentrate. Recovery of the valuable component from the resulting mixture is accomplished in a mode differing from the known ones in that the heat of steam condensation is used to increase water temperature in the interphase film between the particle and the bubble. For pulp aeration during flotation, a mixture of air and hot steam is used as the gas phase. A high recovery of the valuable component in ore flotation according to the developed circuit and mode is facilitated by increasing water temperature in wetting films due to the steam condensation heat. A high selectivity of flotation with a steam-air mixture can be explained using the concepts of a phonon component of disjoining pressure, the value and sign of which are associated with a difference in the dynamic structure of liquid in the wetting film and bulk liquid.
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Date submitted2022-04-14
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Date accepted2022-07-21
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Date published2022-07-13
Mullite production: phase transformations of kaolinite, thermodynamics of the process
The growing demand for mullite raw materials, which meet industrial requirements originates the search for new and alternative sources, as well as efficient technologies for obtaining the target products (nanocomposites). The article suggests a method for obtaining mullite from kaolinite experimentally (Vezhayu-Vorykvinsky deposit, Russia). Structural kaolinite transformations (Al-Si-O-Me system), mineral phases transformations, and thermodynamics of the process have been studied. Based on the estimation of the thermodynamics of the reactions, the preferable reaction of mullite formation was determined. The article shows, that formation of the target product, mullite nanocomposite, has several intermediate phases (metakaolinite, pseudomullite). The transformations of the initial kaolinite structure include the removal of structural water and separation of the silica-oxygen tetrahedral and alumina-oxygen octahedral layers, the decomposition into free oxides, breaking of bonds between the silica-oxygen tetrahedrons and the partial increase in the coordination number of aluminium ions, the formation of mullite and cristobalite from free oxides. The proposed approach controls the ratio of Al 2 O 3 and SiO 2 phases at certain stages, which will further improve the mechanical and other properties of the matrix of the obtained raw materials for the target prototypes of industrial products.
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Date submitted2021-09-17
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Date accepted2022-04-07
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Date published2022-12-29
Technique for calculating technological parameters of non-Newtonian liquids injection into oil well during workover
Technique for automated calculation of technological parameters for non-Newtonian liquids injection into a well during workover is presented. At the first stage the algorithm processes initial flow or viscosity curve in order to determine rheological parameters and coefficients included in equations of rheological models of non-Newtonian fluids. At the second stage, based on data from the previous stage, the program calculates well design and pump operation modes, permissible values of liquid flow rate and viscosity, to prevent possible hydraulic fracturing. Based on the results of calculations and dependencies, a decision is made on the necessity of changing the technological parameters of non-Newtonian liquid injection and/or its composition (components content, chemical base) in order to prevent the violation of the technological operation, such as unintentional formation of fractures due to hydraulic fracturing. Fracturing can lead to catastrophic absorptions and, consequently, to increased consumption of technological liquids pumped into the well during workover. Furthermore, there is an increased risk of uncontrolled gas breakthrough through highly conductive channels.
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Date submitted2020-06-10
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Date accepted2020-11-19
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Date published2021-04-26
Influence of jarosite precipitation on iron balance in heap bioleaching at Monywa copper mine
Ferric iron is an important oxidant in sulfide ore bioleaching. However, recirculating leach liquors leads to excess iron accumulation, which interferes with leaching kinetics and downstream metal recovery. We developed a method for controlling iron precipitation as jarosite to reduce excess iron in heap bioleaching at Monywa copper mine. Jarosite precipitation was first simulated and then confirmed using batch column tests. From the simulations, the minimum pH values for precipitation of potassium jarosite, hydronium jarosite, and natrojarosite at 25 °C are 1.4, 1.6, and 2.7, respectively; the minimum concentrations of potassium, sulfate, ferric, and sodium ions are 1 mM, 0.54, 1.1, and 3.2 M, respectively, at 25 °C and pH 1.23. Column tests indicate that potassium jarosite precipitation is preferential over natrojarosite. Moreover, decreased acidity (from 12 to 8 g/L), increased temperature (from 30 to 60 °C), and increased potassium ion concentration (from 0 to 5 g/L) increase jarosite precipitation efficiency by 10, 5, and 6 times, respectively. Jarosite precipitation is optimized by increasing the irrigating solution pH to 1.6. This approach is expected to reduce the operating cost of heap bioleaching by minimizing the chemicals needed for neutralization, avoiding the need for tailing pond construction, and increasing copper recovery.
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Date submitted2020-01-27
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Date accepted2020-05-22
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Date published2020-10-08
Sorption of rare earth coordination compounds
Rare earth elements (REEs) are valuable and strategically important in many high-technology areas, such as laser technology, pharmacy and metallurgy. The main methods of REE recovery are precipitation, extraction and sorption, in particular ion exchange using various sorbents, which allow to perform selective recovery and removal of associated components, as well as to separate rare earth metals with similar chemical properties. The paper examines recovery of ytterbium in the form of coordination compounds with Trilon B on weakly basic anion exchange resin D-403 from nitrate solutions. In order to estimate thermodynamic sorption parameters of ytterbium anionic complexes, ion exchange process was carried out from model solutions under constant ionic strength specified by NaNO 3 , optimal liquid to solid ratio, pH level, temperatures 298 and 343 K by variable concentrations method. Description of thermodynamic equilibrium was made using mass action law formulated for ion exchange equation and mathematically converted to linear form. Values of equilibrium constants, Gibbs free energy, enthalpy and entropy of the sorption process have been calculated. Basing on calculated values of Gibbs energy, a sorption series of complex REE ions with Trilon B was obtained over anion exchange resin D-403 from nitrate solutions at temperature 298 K. Sorption characteristics of anion exchange resin have been estimated: total capacity, limiting sorption of complex ions, total dynamic capacity and breakthrough dynamic capacity.
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Date submitted2019-07-17
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Date accepted2019-09-04
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Date published2019-12-24
On flood protection measures for potash mines
- Authors:
- A. A. Baryakh
- E. A. Gubanova
Development of water-soluble ore deposits is associated with the necessity to preserve water blocking strata (WBS), which separate aquifers from the mine gob. One indicator of the rate of man-induced load on WBS layers is subsidence of the earth surface, which defines the character of shift trough formation of the earth surface. The greatest threat of WBS discontinuity is posed by the areas located at the edges of a shift trough. From the perspective of Upper Kama deposit of potassium and magnesium salts, by means of mathematical modelling methods authors demonstrated that in the capacity of threat indicators of WBS hole destruction it is possible to use the following parameters of a shift trough: edge length scaled to the depth of mining operations and maximum subsidence of the earth surface. Critical combination of these factors is responsible for the discontinuity at the edges of water blocking strata. These parameters of a shift trough can easily be controlled by instrumental procedures and can be included in the basics of a general monitoring system of WBS state at potash mines. In order to protect the mine from the inrush of fresh water, it is necessary to form softening zones at the edges of mined-out areas near permanent or temporary borders of mining operations. Authors review different options of softening zone formation. Numerical tests have demonstrated that the most efficient way to protect water blocking strata is the formation of softening zones by means of backfilling the stopes of the workable seam or its exclusion from mining operations.
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Date submitted2019-05-02
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Date accepted2019-07-09
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Date published2019-10-23
Effect of Temperature on Solid-state Hydride Metal Synthesis According to Thermodynamic Modeling
Thermodynamic modeling of the reduction of copper dichloride in the media of various gaseous hydrides (ammonia, monosilane, methane) in the temperature range 273-1000 K was carried out. Calculations show that in narrower temperature ranges corresponding to the reactions of solid-state hydride synthesis (SHS) of metal sub- stances metal formation is usually supported by theoretical propositions. As a result of thermodynamic modeling, a principal result was obtained on the suppression of competing processes of nitriding, siliconizing and carbonization of metal under SHS conditions, which is important for metallurgical production. This additionally substantiates the correctness of previous experimental studies of SHS metals with modified surface and improved properties. By mod- eling, it was found that the reduction of solid copper dichloride to metal in ammonia or methane occurs stepwise (se- quentially, according to the Baykov rule) through the intermediate stages of the formation of a compound of low- valent copper – copper (I)chloride.
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Date submitted2019-03-18
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Date accepted2019-04-26
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Date published2019-08-23
Spatial Models Developed Using Laser Scanning at Gas Condensate Fields in the Northern Construction-Climatic Zone
Wide exploration and industrial exploitation of hydrocarbon fields in Yamal Peninsula pose in front of construction and mining companies critical problems of efficient construction at constantly evolving fields taking into account climatic and geocryological conditions of their location. Yamal Peninsula is characterized by unstable soils, the mobility of which has a substantial impact on the changes in spatial arrangement of field facilities, not only in the direct process of construction, but also during their scale-up and equipment overhaul. The paper examines implementation of 3D spatial arrangement modelling of industrial facilities into the process of construction and installation works at hydrocarbon fields in the northern construction-climatic zone. The purpose of implementing this method combined with 3D spatial modelling of equipment connections lies in reliability and safety enhancement of the facilities throughout their entire lifespan. Authors analyze statement and solution of the problem associated with alignment and installation of prefabricated equipment and pipelines, taking into account advanced technologies of 3D design and modelling. The study examines a 3D spatial model with the elements of equipment connection geometry; the model is related to existing production facilities at the field. Authors perform an analysis and in mathematical terms formulate the problem of optimal spatial arrangement for such models. The paper focuses on typical deviations, occurring in the installation process of constructions and connection facilities, their spatial arrangement is modelled. Possible solutions are offered, as well as an algorithm of their implementation at an operating field.
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Date submitted2019-01-13
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Date accepted2019-03-04
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Date published2019-06-25
Thermodynamic model of ion-exchange process as exemplified by cerium sorption from multisalt solutions
A complex heterogeneous process of ion exchange can be defined with an isotherm-isobar equation of the chemical reaction, which describes differential affinity between the process and its effect – the law of mass action. Ion exchange includes processes accompanied by changes in the charge of ions and functional groups caused by the passing of ionic bond into covalent one. Hence isotherm equations of ion exchange for such processes must differ from conventional stoichiometric equations, but they can be obtained by classical study approaches to ion exchange equilibrium. The paper describes a new thermodynamic model, based on linearization of mass action law, modified for the ion exchange equation. The application of this model allows to define stoichiometry of ion exchange and the shape of ions adsorbed by the solid phase of ion-exchange resins, as well as to estimate equilibrium constant and Gibbs free energy of the process. Comparative analysis has been carried out for the thermodynamic model of cerium sorption in the form of anionic complex with Trilon B from a multisalt solution with ionic strength of 1 mol/kg (NaNO 3 ) under рН = 3 and temperature 298 K on a test sample of weak-base anion-exchange resin Cybber EV009. Experimental isotherm of the sorption has been obtained. Calculations of thermodynamic parameters have been performed using Langmuir, Freundlich, Dubinin – Radushkevich, Temkin and Flory – Huggins models, as well as thermodynamic model of linearized mass action law, proposed by the authors. Calculated values of the equilibrium constant and Gibbs energy – K = 9.0±0.5 and ΔrG 0 298 = –5.54±0.27 kJ/mol – characterize the sorption of EDTA cerate ions by ion-exchange resin. The shape of adsorbed ions has been defined in Stern-Helmholtz layer of CeTr, and total capacity of anion resin EV009 for EDTA cerate ions has been estimated as q ∞ = 2.0±0.1 mol/kg.
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Date submitted2016-11-23
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Date accepted2016-12-28
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Date published2017-04-14
BIM technology and experience of their introduction into educational process for training bachelor students of major 08.03.01 «Construction»
- Authors:
- L. A. Goldobina
- P. S. Orlov
The article deals with issues of necessity of training and development of working staff for construction industry of Russian Federation for creation of competitive construction industry, meeting the high quality and efficiency standards, working in basis of modern financial and economic, technical and management mechanisms. One of the ways to solve this task of innovative development is modernization of architectural and building design, in particular implementation of BIM technology enabling making efficient decisions at all stages of building and structures life cycle – from investment concept till operation and even demolition. In relation to this the industry demands highly qualified workers and engineers (bachelor students) being able not only to get new knowledge but to use them for solving practical tasks of modern construction industry and market. The article present a concept of designing educational programme for training students with major 08.03.01 «Construction» (bachelor degree) focusing on systematized knowledge, skills and tools for training, in particular, through interconnection and continuity during course and diploma papers based on BIM technology.
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Date submitted2016-11-07
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Date accepted2016-12-27
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Date published2017-04-14
Method of determining characteristics for air heating system in railway tunnels in harsh climatic conditions
- Authors:
- S. G. Gendler
- S. V. Sinyavina
The article describes climatic and mining-technical conditions influencing frost formation process. It was noted that the radical tools for preventing frost formation in winter periods is creation of positive temperature in tunnels by heating the incoming outside air. We formulated tasks, which solution will promote development of engineering calculation method for heating systems parameters. The article provides results of theoretical studies based on mathematical modelling and analytical solutions and data on field instrumental measurements, which were processed with similarity criteria. It compares mathematical modelling results on determining amount of tunnel incoming air flow with portal gates and calculations data from experimentally determined coefficient of local resistance. We proved the energy efficiency of placing the tunnel portal gates and validated the places of preheated air injection points and removal of cool air from this flow, which provides maximal energy effect.
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Date submitted2009-09-01
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Date accepted2009-11-09
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Date published2010-06-25
Thermal, power and economic parameters of innovative technology of development of nearsurface geothermal deposits
- Authors:
- E. I. Boguslavskiy
Deficiency of organic fuel and necessity of protection of environment cause growth of rates of development practically inexhaustible, everywhere widespread and ecologically pure geothermal resources. For needs of a heat supply especially actively developing innovative technology of development of near-surface geothermal resources has great value. Operative mining of the production schedules containing optimum parametres and indicators PSGT is necessary for designing and building of near-surface systems of a geothermal heat supply (PSGT). The imitating economic-mathematical model is developed, the algorithm and the program of their optimisation are created. Computer calculations for a wide range of natural, power and economic conditions are carried out. Key parametres and indicators PSGT are defined. Their optimum values for a heat supply of local consumers (apartment houses) in the conditions of the Yaroslavl area are recommended.