Potential trace element markers of naphthogenesis processes: modeling and experimentation
- 1 — Ph.D., Dr.Sci. Corresponding Member of the RAS Empress Catherine II Saint Petersburg Mining University ▪ Orcid ▪ Elibrary ▪ Scopus ▪ ResearcherID
- 2 — Ph.D. Assistant Lecturer Empress Catherine II Saint Petersburg Mining University ▪ Orcid ▪ Scopus
- 3 — Ph.D. Associate Professor Empress Catherine II Saint Petersburg Mining University ▪ Orcid ▪ Elibrary ▪ Scopus ▪ ResearcherID
Abstract
With the growing demand for hydrocarbon energy resources, there is a need to involve oil fields at deeper horizons in processing and increase the profitability of their development. Reduction of expenses on prospecting works is possible at revealing and substantiation of physicochemical markers of the naphthogenesis processes. One of the key markers is the transition metals content, which are both a measure of oil age and markers of potential associated processes in the migration and formation of hydrocarbons in the Earth's strata. The elemental composition of samples of oil and reservoir rocks of the Timan-Pechora field was studied. Based on the results of thermodynamic modeling, plausible processes of contact rock minerals transformation were proposed. Based on the results of molecular modeling the probable structure of vanadium and nickel host molecules in the heavy fraction of oils is proposed. The ratios of transition metal and sulfur contents were experimentally established, and assumptions about possible mechanisms of formation of deep hydrocarbon reservoirs were made. Analysis of the obtained ratios of transition metal contents in reservoir rocks and oil samples allowed to suggest possible processes of mantle fluids contact with the host rock and subsequent accumulation of hydrocarbons on sorption active rocks. According to the combined results of experimental and theoretical studies it was found that polymers of heavy fraction more selectively capture vanadium, which indicates the predominance of vanadium content in oil-bearing rocks in relation to the content of nickel. In this case, oil acts as a transport of transition metals, leaching them from the bedrock.
References
- Radoushinsky D., Gogolinskiy K., Dellal Y. et al. Actual Quality Changes in Natural Resource and Gas Grid Use in Prospec-tive Hydrogen Technology Roll-Out in the World and Russia // Sustainability. 2023. Vol. 15. Iss. 20. № 15059. DOI: 10.3390/su152015059
- Litvinenko V.S., Leitchenkov G.L., Vasiliev N.I. Anticipated sub-bottom geology of Lake Vostok and technological approaches considered for sampling // Geochemistry. 2020. Vol. 80. Iss. 3. N 125556. DOI: 10.1016/j.chemer.2019.125556
- Мингалева Т., Горелик Г., Егоров А., Гулин В. Коррекция глубинно-скоростных моделей методом гравиметрической разведки для труднодоступных участков шельфовой зоны // Горный информационно-аналитический бюллетень. 2022. № 10-1. С. 77-86. DOI: 10.25018/0236_1493_2022_101_0_77
- Jianzhong Li, Xiaowan Tao, Bin Bai et al. Geological conditions, reservoir evolution and favorable exploration directions of marine ultra-deep oil and gas in China // Petroleum Exploration and Development. 2021. Vol. 48. Iss. 1. P. 60-79. DOI: 10.1016/S1876-3804(21)60005-8
- Haige Wang, Hongchun Huang, Wenxin Bi et al. Deep and ultra-deep oil and gas well drilling technologies: Progress and prospect // Natural Gas Industry B. 2022. Vol. 9. Iss. 2. P. 141-157. DOI: 10.1016/j.ngib.2021.08.019
- Филимонова И.В., Немов В.Ю., Проворная И.В., Мишенин М.В. Региональные особенности добычи и переработки нефти в России // Бурение и нефть. 2020. № 10. С. 3-10.
- Adeola A.O., Akingboye A.S., Ore O.T. et al. Crude oil exploration in Africa: socio-economic implications, environmental impacts, and mitigation strategies // Environment Systems and Decisions. 2022. Vol. 42. Iss. 1. Р. 26-50. DOI: 10.1007/s10669-021-09827-x
- Тимурзиев А.И. Миф «энергетического голода» от Хабберта и пути воспроизводства ресурсной базы России на основе реализации проекта «Глубинная нефть» // Бурение и нефть. 2019. № 1. С. 12-21.
- Chengzao Jia, Xiongqi Pang, Yan Song. The mechanism of unconventional hydrocarbon formation: Hydrocarbon self-sealing and intermolecular forces // Petroleum Exploration and Development. 2021. Vol. 48. Iss. 3. P. 507-526.
- Синица Н.В., Прищепа О.М. Концептуальная модель формирования зоны нефтегазонакопления в пределах палео-зойского основания юго-востока Западно-Сибирского бассейна // Актуальные проблемы нефти и газа. 2023. Вып. 1 (40). С. 14-26. DOI: 10.29222/ipng.2078-5712.2023-40.art2
- Ильинов М.Д., Петров Д.Н., Карманский Д.А., Селихов А.А. Аспекты физического моделирования процессов струк-турных изменений образцов горных пород при термобарических условиях больших глубин // Горные науки и технологии. 2023. Т. 8. № 4. С. 290-302. DOI: 10.17073/2500-0632-2023-09-150
- Zhijun Jin, Rukai Zhu, Xinping Liang, Yunqi Shen. Several issues worthy of attention in current lacustrine shale oil exploration and development // Petroleum Exploration and Development. 2021. Vol. 48. Iss. 6. P. 1471-1484. DOI: 10.1016/S1876-3804(21)60303-8
- Леушева Е.Л., Алиханов Н.Т., Бровкина Н.Н. Исследование реологических свойств безбаритного бурового раствора повышенной плотности // Записки Горного института. 2022. Т. 258. С. 976-985. DOI: 10.31897/PMI.2022.38
- Palaev A.G., Shammazov I.A., Dzhemilev E.R. Research of the impact of ultrasonic and thermal effects on oil to reduce its viscosity // Journal of Physics: Conference Series. 2020. Vol. 1679. № 052073. DOI: 10.1088/1742-6596/1679/5/052073
- Черданцев Г.А., Жарков А.М. Перспективы нефтегазоносности верхнепермских отложений юго-западной части Вилюйской синеклизы на основе анализа обстановок осадконакопления и геохимических условий нефтегазоносности // Записки Горного института. 2021. Т. 251. С. 698-711. DOI: 10.31897/PMI.2021.5.9
- Nyakairu G.W.A., Kasule J., Ouma O., Bahati G. Origin and hydrogeochemical formation processes of geothermal fluids from the Kibiro area, Western Uganda // Applied Geochemistry. 2023. Vol. 152. № 105648. DOI: 10.1016/j.apgeochem.2023.105648
- Xiaofeng Wang, Quanyou Liu, Wenhui Liu et al. Accumulation mechanism of mantle-derived helium resources in petrolifer-ous basins, eastern China // Science China Earth Sciences. 2022. Vol. 65. Iss. 12. P. 2322-2334. DOI: 10.1007/s11430-022-9977-8
- Serovaiskii A., Kutcherov V. Formation of complex hydrocarbon systems from methane at the upper mantle thermobaric conditions // Scientific Reports. 2020. Vol. 10. № 4559. DOI: 10.1038/s41598-020-61644-5
- Лурье М.А. Свойства и состав глубинных флюидов – источников углеводородов, гетерокомпонентов и микроэле-ментов абиогенных нефтей // Геология нефти и газа. 2020. № 3. С. 43-49. DOI: 10.31087/0016-7894-2020-3-43-49
- Chacón-Patiño M.L., Nelson J., Rogel E. et al. Vanadium and nickel distributions in Pentane, In-between C5-C7 Asphaltenes, and heptane asphaltenes of heavy crude oils // Fuel. 2021. Vol. 292. № 120259. DOI: 10.1016/j.fuel.2021.120259
- Chacón-Patiño M.L., Nelson J., Rogel E. et al. Vanadium and nickel distributions in selective-separated n-heptane asphaltenes of heavy crude oils // Fuel. 2022. Vol. 312. № 122939. DOI: 10.1016/j.fuel.2021.122939
- Aleksandrova T., Nikolaeva N., Afanasova A. et al. Extraction of Low-Dimensional Structures of Noble and Rare Metals from Carbonaceous Ores Using Low-Temperature and Energy Impacts at Succeeding Stages of Raw Material Transformation // Minerals. 2023. Vol. 13. Iss. 1. № 84. DOI: 10.3390/min13010084
- Афанасова А.В., Абурова В.А. Укрупнение низкоразмерных благородных металлов из углеродистых материалов с применением микроволновой обработки // Горный информационно-аналитический бюллетень. 2024. № 1. С. 20-35. DOI: 10.25018/0236_1493_2024_1_0_20
- Canhimbue L., Talovina I. Geochemical Distribution of Platinum Metals, Gold and Silver in Intrusive Rocks of the Norilsk Region // Minerals. Vol. 13. Iss. 6. № 719. DOI: 10.3390/min13060719
- Юдович Я.Э., Кетрис М.П. Основы литохимии. СПб: Наука, 2000. 479 с.
- Ruiying Xiong, Jixiang Guo, Kiyingi W. et al. Method for Judging the Stability of Asphaltenes in Crude Oil // ACS Omega. 2020. Vol. 5. Iss. 34. P. 21420-21427. DOI: 10.1021/acsomega.0c01779
- El Nagy H.A., El Sayed H. El Tamany, Abbas O.A. et al. Rapid and Simple Method for Measuring Petroleum Asphaltenes by the Centrifugation Technique // ACS Omega. 2022. Vol. 7. Iss. 50. P. 47078-47083. DOI: 10.1021/acsomega.2c06225
- Aleksandrova T., Nikolaeva N., Kuznetsov V. Thermodynamic and Experimental Substantiation of the Possibility of For-mation and Extraction of Organometallic Compounds as Indicators of Deep Naphthogenesis // Energies. 2023. Vol. 16. Iss. 9. № 3862. DOI: 10.3390/en16093862
- Пунанова С.А. Микроэлементный состав каустобиолитов и процессы нефтегенерации – от гипотезы Д.И.Менделеева до наших дней //Георесурсы. 2020. Т. 22. № 2. С. 45-55. DOI: 10.18599/grs.2020.2.45-55
- Prischepa O.M., Kireev S.B., Nefedov Yu.V. et al. Theoretical and methodological approaches to identifying deep accumu-lations of oil and gas in oil and gas basins of the Russian Federation // Frontiers in Earth Science. 2023. Vol. 11. № 1192051. DOI: 10.3389/feart.2023.1192051
- Якубова С.Г., Абилова Г.Р., Тазеева Э.Г. и др. Сопоставительный анализ ванадилпорфиринов, выделенных из асфальтенов тяжелых нефтей с высоким и низким содержанием ванадия // Нефтехимия. 2022. Т. 62. № 1. С. 99-110. DOI: 10.31857/S002824212201004X
- Иванова Ю.Б., Семейкин А.С., Пуховская С.Г., Мамардашвили Н.Ж. Синтез, спектральные и координационные свойства мезотетраарилпорфиринов // Журнал органической химии. 2019. Т. 55. № 12. С. 1888-1894. DOI: 10.1134/S0514749219120115