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Date submitted2023-08-31
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Date accepted2023-12-27
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Date published2024-11-12
Geochemical studies of rocks of the Siberian igneous province and their role in the formation theory of unique platinum-copper-nickel deposits
- Authors:
- Nadezhda А. Krivolutskaya
The Norilsk deposits, unique both in their geological structure and reserves of nickel and platinum, have attracted the attention of researchers for several decades. Several hypotheses have been proposed to explain their formation. Two of them are the most widely accepted: the model of ore formation in an intermediate chamber from picritic melt enriched in sulphides and the formation of sulphides in situ through the assimilation of sulphate-bearing sediments by tholeiitic magma as it rises to the surface. The main questions regarding the genesis of these deposits are: the composition of the parental magmas that formed the ore-bearing massifs; the relationship between intrusions and effusive rocks; and the extent and role of assimilation of host rocks by magmas. These issues are discussed in the article using a large amount of analytical data obtained by the author during the study of the magmatic rocks and geological structures in the Norilsk area. Based on these data, it was concluded that none of the proposed models could fully explain all observed geological features of the deposits as well as the appearance of the unique sulphide ores. In order to solve the problem of the genesis of the Norilsk deposits, it is necessary to analyse the evolution of P3-T1 magmatism over time in the Siberian large igneous province, especially in its eastern part, and to determine its association with ore-forming processes; and its investigating it is a priority task for understanding sulphide ore formation. Solving this task should be based not only on geophysical data but also on studies of the geochemistry of igneous rocks within the province.
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Date submitted2022-03-01
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Date accepted2024-06-03
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Date published2024-12-25
Study of the possibility of using high mineralization water for hydraulic fracturing
The results of laboratory studies aimed at developing hydraulic fracturing fluid based on alternative sources of high mineralization water are presented. It is shown that Cenomanian sources have the most stable mineralization parameters, while bottom water and mixed waters collected from pressure maintenance systems differ significantly in their properties, with iron content varying several times, and hardness and mineralization undergoing substantial changes. The quality of the examined hydraulic fracturing fluids based on alternative water sources is confirmed by their impact on residual permeability, as well as residual proppant pack conductivity and permeability. The experimental results show similar values for these parameters. The comprehensive laboratory studies confirm the potential for industrial use of high mineralization water in hydraulic fracturing operations.
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Date submitted2024-04-16
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Date accepted2024-06-03
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Date published2024-07-04
Quantitative determination of sulfur forms in bottom sediments for rapid assessment of the industrial facilities impact on aquatic ecosystems
- Authors:
- Ivan P. Sverchkov
- Vladimir G. Povarov
The article describes an X-ray fluorescence method for quantitative analysis of sulfate and total sulfur in bottom sediments of watercourses and reservoirs located in the area of industrial enterprises impact. The quantitative determination of sulfur forms was carried out by analyzing the characteristic curves SKα1,2 and SKβ1,3, as well as the satellite line SKβ′ on X-ray emission spectra measured by an X-ray fluorescence spectrometer with wavelength dispersion. The study shows that these characteristic curves allow not only to determine the predominant form of sulfur, but also to separately conduct quantitative analyses of sulfates and total sulfur after fitting peaks and to separately analyze overlapping spectral lines. The results of quantitative analysis of the chemical state of sulfur by the proposed X-ray fluorescence method were compared with the results of inductively coupled plasma atomic emission spectroscopy and elemental analysis, as well as certified standard samples of soils and sediments. The results are in good agreement with each other.
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Date submitted2024-03-30
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Date accepted2024-06-13
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Date published2024-07-04
Organotin pollutants in emerging coastal-marine sediments of the Kaliningrad shelf, Baltic Sea
Based on two years of monitoring of modern bottom sediments of two sections of the Kaliningrad shelf of the Baltic Sea – “Curonian Spit” and “Northern Sambian” – an assessment of the sources of pollution with organotin compounds (OTs) and heavy metals was carried out. The content of individual organotin compounds and OTCs spectra obtained by gas chromatography with mass spectrometry of relatively coarse-grained bottom sediments indicate the presence of organotins in significant quantities – the total OTs content (ΣOTs) is from 0.6 to 8.3 ng/g. However, the content of tributyltin (TBT), the main component of anti-fouling systems for marine vessels and the most dangerous endocrine-disrupting compound among the hazardous substances for marine ecosystems, is at a low level (0-2.3 ng/g) in all studied samples and has not increased over the two-year observation period (biodegradation index 1.7-12.4). At the same time, the presence of abnormally high concentrations of mono-, triphenyl- and tricyclohexyltin in the sediments of the ”Northern Sambian” site (up to 30, 7 and 6.4 ng/g, respectively) indicates an additional source of pollution of coastal waters and shelf sediments (for example, plastic litter and agricultural runoff). The absence of significant shipping in the study areas ensures a consistently low level of pollution with tributyltin and its derivatives (less than 0.3 and 2.3 ng/g of TBT in 2017 and less than 0.1 and 1.3 ng/g in 2018 for the sites “Curonian Spit” and “Northern Sambian”, respectively), which indicates the activity of the processes of TBT transformation and self-cleaning of sandy sediments. However, the identified trends and their predictive accuracy require long-term observation and monitoring of the sediment environment using data on the deep-water part of the shelf, enriched in clay and humus components.
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Date submitted2024-04-09
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Date accepted2024-06-03
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Date published2024-07-04
Analysis of the geochemical barriers effectiveness as the basis for the use of nature-like water purification technologies
Nature-like technologies are being introduced into many human activities including mining wastewater treatment. This work is based on long-term studies of the Sibay copper-zinc-pyrite deposit development. It is dedicated to assessment of geochemical barriers effectiveness in Cu, Zn, Cd removal from water of the Karagayly River (receiving quarry and dump drainage water). The research is based on the elements’ content and forms in water and bottom sediments, pH values etc. Four types of hydrogeochemical environment (formed due to changes in the water use over the past 20 years) were distinguished using discriminant analysis. The mechanisms of barriers formation and destruction were described. Statistical modeling of the metals’ precipitation was performed by multivariate regression analysis. Cu is adsorbed by recently formed Fe hydroxides, and, to a lesser extent, precipitates with sulfates as water pH increases. Antagonism to Mn hydroxides has been demonstrated, due to different physicochemical conditions for their precipitation. Zn enters solid phase mainly with sulfates, this element also forms its own mineral phases. The second mechanism is adsorption by recently formed Mn hydroxides, which corresponds to the idea of similar conditions for the precipitation of metal hydroxides. Cd behavior reflects conditions intermediate between these of Cu and Zn. Contribution of both mechanisms (related to Fe hydroxides and aqueous sulfates) is equal. Antagonism to Mn is absent. According to the assessment results using of nature-like technologies in situ in watercourses, canals and other water drainage systems is promising. Developed statistical models can be used for needs of experimental studies and artificial geochemical barriers engineering.
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Date submitted2023-05-21
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Date accepted2024-05-02
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Date published2024-08-26
Assessment of the influence of lithofacies conditions on the distribution of organic carbon in the Upper Devonian “Domanik” deposits of the Timan-Pechora Province
The study of high-carbon formations was instigated both by the decreasing raw material base of oil as a result of its extraction, and by the progress in development of low-permeability shale strata, primarily in the USA, Australia, and China. The most valuable formations occur in traditional hydrocarbon production areas – the West Siberian, Volga-Ural and Timan-Pechora, North Pre-Caucasian and Lena-Tunguska oil and gas provinces. Specific features of the Late Devonian-Early Carboniferous high-carbon formation occurring in the eastern marginal part of the East European Platform are: heterogeneous section due to intense progradation of the carbonate platform from west to east; succession of lithofacies environments that determined the unevenness of the primary accumulation and secondary distribution of organic matter (OM); possible migration or preservation in the source strata during the subsidence stages of the moving parts of bitumides, which determined the prospects for oil and gas potential. The distribution pattern of the present OM content was investigated depending on lithofacies conditions and lithological composition of rocks in the “Domanik type” Upper Devonian-Tournaisian deposits in the Timan-Pechora Province (TPP), its transformation degree to bring it to the initial content of organic carbon and further estimation of the share of stored “mobile oil” in oil and gas source formation. The study was based on the analysis of the data set on organic carbon content in core samples and natural exposures in the Ukhta Region in the Domanik-Tournaisian part of the section including more than 5,000 determinations presented in reports and publications of VNIGRI and VNIGNI and supplemented by pyrolytic and bituminological analyses associated with the results of microtomographic, macro- and lithological studies and descriptions of thin sections made at the Saint Petersburg Mining University. For each tectonic zone of the TPP within the investigated high-carbon intervals, the content of total volumes of organic carbon was determined. The data obtained allow estimating the residual mass of mobile bitumoids in a low-permeability matrix of the high-carbon formation.
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Date submitted2023-05-31
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Date accepted2023-12-27
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Date published2024-04-25
Velocity structure of the Earth’s crust and upper mantle in the Pechenga ore region and adjacent areas in the northwestern part of the Lapland-Kola orogen by the receiver function technique
- Authors:
- Andrei G. Goev
The article presents a study of the Earth’s crust and upper mantle in the Pechenga ore region, as well as areas adjacent to it in the northwestern part of the Kola region. Applying the receiver function technique to data acquired by three broadband seismic stations, we obtained one-dimensional seismic velocity distribution models to a depth of 300 km. The stations are located in the northern parts of Finland and Norway, as well as in the Pechenga region of the Russian Federation. Despite the stations being in relatively close proximity (within 100 km of each other), the velocity models turned out to be significantly different, which indicates structural discontinuity within the lithosphere. Thus, Finland station data set revealed a gradient crust-mantle transition, which is not present in the other two models. At depths of about 150 km, a low-velocity zone was discovered, associated with mid-lithospheric discontinuity, which was not found beneath the Pechenga ore region. Furthermore, the crustal structure of the Pechenga region has an anomalously high Vp/Vs ratio to a depth of about 20 km. Considering the fact that the Pechenga (Nikel) seismic station was installed in close proximity to major copper-nickel deposits, this anomaly can be interpreted as a relic of Proterozoic plume activity.
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Date submitted2022-09-30
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Date accepted2023-04-03
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Date published2024-02-29
Optimization of the location of a multilateral well in a thin oil rim, complicated by the presence of an extensive gas cap
- Authors:
- Кirill О. Тomskii
- Mariya S. Ivanova
The specific share of the reserves of hard-to-recover hydrocarbon raw materials is steadily growing. The search for technologies to increase the hydrocarbon recovery factor is one of the most urgent tasks facing the oil and gas industry. One of the methods to expand the coverage of oil reserves and increase oil recovery is to use the technology of drilling multilateral wells with a fishbone trajectory. In the Russian Federation, the most branched well was drilled in the Republic of Sakha (Yakutia) at the Srednebotuobinskoye oil and gas condensate field. The main object of development is the Botuobinsky horizon (Bt reservoir). About 75 % of the geological reserves of the reservoir are concentrated in a thin oil rim with an average oil-saturated layer thickness of 10 m with an extensive gas cap. This circumstance is one of the main complicating factors in the development of the Srednebotuobinskoye oil and gas condensate field. For such complex wells, one of the most important design stages is to determine the optimal location of the fishbone well in an oil-saturated reservoir. The article shows the results of sector modeling in the conditions of the Srednebotuobinskoye field to determine the optimal location of multilateral wells using Tempest simulator.
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Date submitted2022-08-22
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Date accepted2023-02-02
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Date published2023-08-28
Wodginite as an indicator mineral of tantalum-bearing pegmatites and granites
- Authors:
- Viktor I. Alekseev
In the composition of tantalum-niobates, the tin-bearing wodginite group minerals (WGM) were found: wod-ginite, titanowodginite, ferrowodginite, ferrotitanowodginite, lithiowodginite, tantalowodginite, “wolframowodginite”. We reviewed the worldwide research on WGM and created a database of 698 analyses from 55 sources including the author's data. WGM are associated with Li-F pegmatites and Li-F granites. Wodginite is the most prevalent mineral, occurring in 86.6 % of pegmatites and 78.3 % of granites. The occurrence of WGM in granites and pegmatites differs. For instance, titanowodginite and “wolframowodginite” occur three times more frequently in granites than in pegmatites, whereas lithiowodginite and tantalowodginite do not appear in granites at all. The difference between WGM in granites and pegmatites is in finer grain size, higher content of Sn, Nb, Ti, W, and Sc; lower content of Fe 3+ , Ta, Zr, Hf; higher ratio of Mn/(Mn + Fe); and lower ratio of Zr/Hf. The evolutionary series of WGM in pegmatites are as follows: ferrowodginite → ferrotitanowodginite → titanowodginite → “wolframowodginite” → wodginite → tantalowodginite; in granites: ferrowodginite → ferrotitanowodginite → “wolframowodginite” → wodginite → titanowodginite. WGM can serve as indicators of tantalum-bearing pegmatites and granites. In Russia the promising sources of tantalum are deposits of the Far Eastern belt of Li-F granites containing wodginite.
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Date submitted2022-11-02
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Date accepted2023-03-02
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Date published2023-04-25
Environmental damage from the storage of sulfide ore tailings
The mining industry is one of the most challenging in ensuring environmental safety. During the last century, the Karabash Copper Smelting Plant was processing sulfide ores and depositing the tailings into storage facilities that now occupy an area of more than 50 hectares. To date, abandoned tailings are a significant source of natural water, air, and soil pollution in the Karabash city district. The article comprehensively examines the environmental impact of the Karabashmed copper smelter, one of the oldest metallurgical enterprises in Russia. The effects of seepage from the two Karabashmed tailings facilities on water resources were assessed. We revealed that even outside the area of the direct impact of processing waste, the pH of natural water decreases to values 4-5. Further downstream, the infiltration water from the tailings pond No. 4 reduces the pH of river water to 3.0-3.5. The presented results of environmental engineering surveys are derived from sampling water and bottom sediments of the Ryzhiy Stream and the Sak-Elga River, sample preparation, and quantitative chemical analysis. The study revealed significant exceedances of the maximum permissible concentrations for a number of chemical elements in the impact zone of the copper ore processing tailings.
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Date submitted2022-08-20
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Date accepted2022-11-17
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Date published2022-12-29
Comparison of the approaches to assessing the compressibility of the pore space
- Authors:
- Vitaly S. Zhukov
- Yuri O. Kuzmin
Integral and differential approaches to determining the volumetric compression of rocks caused by changes in the stress state are considered. Changes in the volume of the pore space of rocks are analyzed with an increase in its all-round compression. Estimation of changes in the compressibility coefficients of reservoirs due to the development of fields is an urgent problem, since the spread in the values of compressibility factors reduces the adequacy of estimates of changes in the physical properties and subsidence of the earth's surface of developed fields and underground gas storages. This parameter is key in assessing the geodynamic consequences of the long-term development of hydrocarbon deposits and the operation of underground gas storage facilities. Approaches to the assessment differ in the use of cumulative (integral) or local (differential) changes in porosity with a change in effective pressure. It is shown that the coefficient of volumetric compressibility of pores calculated by the integral approach significantly exceeds its value calculated by the differential approach, which is due to the accumulative nature of pore compression with an increase in effective pressure. It is shown that the differential approach more accurately determines the value of the pore compressibility coefficient, since it takes into account in more detail the features of the change in effective pressure.
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Date submitted2022-05-26
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Date accepted2022-11-17
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Date published2022-12-29
Renovation method of restoring well productivity using wavefields
A stagewise theoretical substantiation of the renovation vibrowave method of influencing the near-wellbore zone of reservoir for restoring well productivity is presented. The area of treatment by the proposed method covers the reservoir with a heterogeneous permeability with fractures formed by fracking. In this method a decrease in concentration of colmatants occurs due to a change in direction of contaminants migration. Under the influence of pressure pulses, they move deep into the reservoir and disperse through the proppant pack. The results of mathematical modelling of the propagation of pressure wave and velocity wave and the calculations of particles entrainment in wave motion are presented.
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Date submitted2022-03-14
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Date accepted2022-06-20
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Date published2022-11-10
Model of a walking sampler for research of the bottom surface in the subglacial lake Vostok
Technologies and technical means for investigation of subglacial lakes in Antarctic is a new developing scientific and technical direction, which today has no clearly established methodology. Based on the developed technology of drilling a new access well to lake Vostok and its penetration as well as analysis of existing methods and devices for bottom sediment sampling, a basic model of a sampler with a walking-type mover, capable of moving along different trajectories and operating in a wide technological range, is proposed. The proposed device model is equipped with different actuators for sampling the bottom surface with different physical and mechanical properties. Based on the presented basic model of the walking sampler, a mathematical model of the device was developed, which was based on the theoretical mechanics methods. As a result of conducted research the dependencies were obtained, which allow making a scientifically justified choice of optimal values for geometric and force parameters of the walking sampler. A conceptual design of the walking sampler has been developed, taking into account the mutual location and coupling of its main components, the overall dimensions of the delivery tool, as well as the esthetic component of the device.
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Date submitted2022-05-10
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Date accepted2022-09-06
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Date published2022-11-03
Flotation separation of titanite concentrate from apatite-nepheline-titanite ores of anomalous zones of the Khibiny deposits
Titanium raw materials are widely used for the synthesis of various functional materials – sorbents of radionuclides and rare earth elements, various additives, filler pigments, etc. Since most of titanium concentrates are imported, in line with the import substitution program, production of titanite concentrate from apatite-nepheline ores of the Khibiny deposits is a promising trend for supplying national industry with titanium raw materials. The article presents the results of laboratory studies of flotation separation of titanite concentrate from apatite-nepheline-titanite ores extracted from the upper ore horizon of the Koashvinskoye deposit, where titanite-enriched ores are concentrated. Recovery of titanite concentrate was accomplished using two reagent modes – a mixture of alkyl hydroxamic and carboxylic acids with the addition of distilled tall oil and a mixture of tall oils with the addition of polyalkyl benzene sulfonic acids. The results of the research showed that the first flotation mode, which allows a selective recovery of titanite into the concentrate (titanite content in the concentrate was 93.5 %) is the most efficient. It was shown that flotation separation of titanite concentrate is preferable compared to the chemical method based on sulfuric acid leaching.
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Date submitted2022-06-02
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Date accepted2022-07-21
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Date published2022-10-05
Substantiation of the optimal performance parameters for a quarry during the stage-wise development of steeply dipping ore deposits
- Authors:
- Sergey I. Fomin
- Maxim P. Ovsyannikov
The use of stage-wise schemes in the development of deep quarries is one of the ways to increase the economic efficiency of mining a deposit and determining the optimal stage parameters remains an urgent task. Such parameters are stage depth, bench height, block length, etc. However, there is a wide range of values for these parameters. Therefore, to select the optimal values and evaluate the effectiveness of design solutions, it is advisable to use the net present value, which is an international notion. As a result of the analysis of data on deposits, a large number of variable indicators can be identified that presumably affect the efficiency of mining. The article proposes to divide all parameters of the quarry mining into two types: mine engineering and economic. The importance of each of them is determined by the measure of influence on the net present value. Thus, to assess the measure of influence of mining indicators, the average values of each of them are taken, and as a result of the alternating change of one parameter under study, the measure of its influence on the discounted income received is estimated. The results of the analysis of relevant factors, their evaluation and comparative analysis are important indicators that significantly affect the design decisions made and the effectiveness of the investment project.
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Date submitted2022-03-14
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Date accepted2022-05-13
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Date published2022-07-26
Unique titanium Deposits of Timan: genesis and age issues
The article critically analysesthe hypotheses about the formation, age, and sources of material of large Timan titanium deposits, which were previously considered ancient buried placers formed along the weathering crusts of the Riphean shales. We discuss an alternative hydrothermal-metamorphic hypothesis about the formation of these deposits and the source of ore material. It is established that the incoming zircon of different ages (570-3200 Ma), as well as two other geochronometers, rutile and monazite, underwent a thermal effect common for all varieties as a result of a hydrothermal process about 600 Ma ago. According to modern concepts, the closing temperature of the U-Pb system in rutile exceeds 500 °С, which suggests high-temperature conditions for the hydrothermal processing of rutile during the formation of the considered deposits in the Riphean.
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Date submitted2022-03-03
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Date accepted2022-04-27
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Date published2022-07-26
Peculiarities of rare-metal mineralization and genetic relationship of mineral associations in the eastern rim of Murzinsko-Aduysky anticlinorium (the Ural Emerald Belt)
- Authors:
- Mikhail P. Popov
The paper presents features of the location and composition, as well as a generalization of data on the age of rare-metal mineralization developed at the deposits and occurrences of rare metals and gemstones in the eastern rim of Murzinsko-Aduysky anticlinorium, within the Ural Emerald Belt, which is a classic ore and mineralogical object and has been studied for almost two hundred years. With a significant number and variety of prospecting, research and scientific works devoted mainly to emerald-bearing mica complexes and beryl mineralization, as well as rare-metal pegmatites, scientific literature has so far lacked generalizations on the formation of numerous mineral associations and ore formations that represents a uniform genetic process in this ore district. The aim of the work is a comprehensive geological-mineralogical analysis of mineral associations of the eastern rim of Murzinsko-Aduysky anticlinorium and studying their age, formation conditions and characteristic features to determine the possibility of expanding and using the mineral resource base of the Urals through developing new prognostic and prospecting criteria for rare-metal and gemstone ore formations and creating the new devices for promising objects prospecting
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Date submitted2021-03-23
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Date accepted2022-01-24
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Date published2022-04-29
Justification of the technological scheme parameters for the development of flooded deposits of construction sand
- Authors:
- Vladimir V. Ivanov
- Denis O. Dzyurich
The article describes the main types of technological schemes for working out the flooded strata of sand deposits using hydraulic shovel excavators. The analysis of scientific and technical literature describing the experience of using hydraulic shovel excavators in the open-pit mining, including pits for the extraction of construction sand, has been carried out. The proposed technological scheme is that the development of reserves of the flooded strata without preliminary water reduction is carried out by a hydraulic shovel excavator from under water by a downward digging with the storage of the extracted rock mass in bulk (for dewatering), placed in such a way that when working out the next mining bench width, it is located within the working area of the excavator for simultaneous processing of the next bench width and loading of dewatered sand from the pile. Calculations of the parameters of the operating platform and the excavator block of the proposed technological scheme for conducting open-pit mining were carried out. The dependence for determining the minimum length of the mining operations front of an excavator for drawing up a technological scheme of operation of a backhoe hydraulic excavator on working out the flooded strata with the pile formation for dewatering sand and its subsequent uploading from the pile by the same excavator is presented.
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Date submitted2021-10-19
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Date accepted2021-11-30
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Date published2021-12-27
Potential technological solution for sampling the bottom sediments of the subglacial lake Vostok: relevance and formulation of investigation goals
The subglacial Lake Vostok in Antarctic is a unique natural phenomenon, its comprehensive study involves sampling of water and bottom surface rocks. For further study of the lake, it is necessary to drill a new access well and develop environmentally safe technologies for its exploration. This article discusses existing and potential technologies for sampling bottom surface rocks of subglacial lakes. All these technologies meet environmental safety requirements and are conducive for sampling. The authors have proposed an alternative technology, using a walking device, which, due to its mobility, enables selective sampling of rocks across a large area from a single access well. The principal issues, related to the implementation of the proposed technology, are investigated within this article. This report is prepared by a team of specialists with many years of experience in drilling at the Vostok Station in Antarctic and in experimental work on the design of equipment and non-standard means of mechanization for complicated mining, geological and climatic conditions.
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Date submitted2021-05-28
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Date accepted2021-11-30
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Date published2021-12-27
Features of grouping low-producing oil deposits in carbonate reservoirs for the rational use of resources within the Ural-Volga region
A methodology has been developed and a procedure for selecting homogeneous groups has been implemented using a set of parameters characterizing the properties of formation fluids, layering conditions, geological and physical properties of formations at different levels of the hierarchy. An algorithm for identifying deposits for monitoring and justifying measures to improve the efficiency of development management is proposed. A justification for the selection of associative groups of long-term developed objects using the parameters of geological heterogeneity according to different tectonic-stratigraphic elements is presented. To reduce the degree of uncertainty in the evaluation of objects by the degree and nature of geological heterogeneity, the parameters reflecting the degree of uncertainty of the system using complex characteristics are proposed. For different deposit associations, a different influence of the features of the object structure on the degree of their division has been established. In the process of deposit drilling, as additional information about development objects is obtained, it is necessary to specify the nature of the distinguished groups of objects first of all based on the use of characteristics of geological heterogeneity. Comparison of various grouping options shows the need to take into account the geological heterogeneity of objects during their drilling. The identification of groups of objects using a limited number of parameters is approximate, but at the stage of drafting the first design documents, it is possible to solve certain tasks aimed at determining the strategy for the development of deposits
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Date submitted2021-06-24
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Date accepted2021-10-18
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Date published2021-12-16
Modeling the acid treatment of a polymictic reservoir
- Authors:
- Mars M. Khasanov
- Andrey А. Maltcev
Acid treatment of wells program is directly related to oil production efficiency. Investigations aimed at improving the efficiency of acid treatment in a terrigenous reservoir have mainly reviewed the changing and adapting the reagents to minimize bridging caused by acid-rock interaction. Under real conditions, application of new and unique acid compositions is a complex process from an organizational point of view and is therefore not widely used as compared with conventional compositions based on a mixture of hydrochloric and hydrofluoric acids. The paper is based on an approach to improve acid treatment efficiency through optimal design based on near-bottomhole zone treatment simulation. The aspects for practical application of the developed acid treatment simulator for terrigenous reservoirs based on a numerical model of hydrodynamic, physical and chemical processes in a porous medium on an unstructured PEBI-grid are described. The basic uncertainties of the model are identified and analyzed. Influence of empirical parameters within the system of equations on the calculation results and modeling of the mineralogical composition of rocks are considered. Algorithm for static modelling of near-bottomhole zone for acid treatment modelling is described, as well as an approach to optimizing the design of near-bottomhole zone treatment based on adapting the results of rock tests in the model. Using experimental data, the necessity of accounting for influence of secondary and tertiary reactions on the results of modeling physical and chemical processes during acid treatment of terrigenous reservoirs was proved. The distinctive features of West Siberian objects (polymictic reservoirs) with respect to the efficiency of near-bottomhole zone treatment with clay acid have been investigated. Series of calculations to determine the optimum volume of acid injection has been carried out. Experience of previously conducted measures under the considered conditions has been analyzed and recommendations to improve the efficiency of acid treatment have been given.
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Date submitted2020-12-08
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Date accepted2021-10-18
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Date published2021-12-16
Prospects for the oil and gas content of the Upper Permian deposits of the southwestern part of the Vilyui syneclise based on the analysis of sedimentary environments and geochemical conditions of oil and gas content
The article discusses the prospects for the oil and gas content of the Upper Permian deposits in the southwestern marginal part of the Vilyui syneclise. In this margin, the Permian terrigenous complex with proven oil and gas productivity in the central part of the syneclise, pinches out. The study area, represented by the monoclinal slopes of the Vilyui syneclise, is considered a promising area for the exploration of non-structural hydrocarbon traps in the Upper Paleozoic sediments. The objectives of the study include identifying general patterns of sediment formation, associated mainly with the development of the alluvial complex, and substantiating the potential opportunities of migration and accumulation of hydrocarbons in the predicted traps. The research is based on the interpretation of the latest seismic surveys and prior-years geological and geophysical data. Authors carried out structural and paleo-structural analysis, identified lithofacies in the well log, generalized and analyzed the geochemical conditions of the oil and gas content of the Upper Permian deposits, traced the pinching out of the Upper Permian deposits on the southwestern margin of the syneclise, and also outlined areas of river valleys development that form zones of advanced reservoirs. The results of the studies have validated promising oil and gas accumulation zones on the southwestern slopes of the syneclise associated with non-anticlinal hydrocarbon traps. Authors also drew up a diagram of the oil and gas potential of the Upper Permian deposits. The obtained results are of interest for prospecting for oil and gas in the area under study.
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Date submitted2021-02-24
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Date accepted2021-10-18
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Date published2021-12-16
A probabilistic approach to the dynamic cut-off grade assessment
Cut-off grade is an important conditioning parameter that determines the quantity and quality of recoverable reserves and development efficiency. Today, Russian mining companies operate with certified quality requirements. By setting permanent quality requirements, the government seeks to prevent depletion of reserves, reduced production during periods of falling prices, and decreased budget revenues, expressing the interests of all members of society. But to what extent do the permanent quality requirements protect the interests of the state? The answer to this question is ambiguous and does not lie on the surface. The State Commission for Reserves and domestic researchers are working to find a rational solution to the problem of quality requirements. One solution is dynamic quality requirements. The effectiveness of their application has been proven for individual mining companies, but it is incorrect to transfer these conclusions to the entire mineral resource base of the country. This article presents a new approach to determining the dynamic cut-off grade, which varies depending on the price of minerals. The dynamic cut-off grade is proposed to be determined based on the indicators of constant requirements to the quality of exploration work, using the maximum allowable costs in the region. The approach allows to calculate the effect of the introduction of dynamic cut-off grade in the practice of subsurface use for the state (in the form of the amount of taxes received) and for subsoil users (in the form of the amount of income). For a group of gold-bearing deposits with open-pit mining method, it was established that the development of reserves using dynamic values of the cut-off grade in periods of price changes ensures compliance with the interests of the state and subsoil users.
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Date submitted2021-03-11
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Date accepted2021-07-27
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Date published2021-10-21
Justification of a comprehensive technology for preventing the formation of asphalt-resin-paraffin deposits during the production of highlyparaffinic oil by electric submersible pumps from multiformation deposits
Production of highly solidifying abnormal oils (with a paraffin content of over 30 % by mass) in the Far North is complicated by the intensive formation of asphalt-resin-paraffin deposits (ARPD) in the bottomhole zone of the productive formation, well and surface equipment. Existing methods and technologies for countering the formation of organic deposits in well equipment have many advantages. However, their application in the production of highly paraffinic oil does not fully prevent the formation of ARPD in the tubing string. This leads to a significant reduction in oil production, reduction of turnaround and intertreatment periods of production wells operation, an increase in specific operating expenses for paraffin removal. Results of theoretical and laboratory investigations presented in the article show that one of the promising ways to improve the operational efficiency of wells equipped with electric submersible pumps during extraction of highly paraffinic oil from multiformation deposits is the application of a new integrated technology based on the joint production of highly solidifying abnormal oil with oil, characterized by a lower paraffin content and manifestation of structural and mechanical properties, in conjunction with the regulation of the parameters for the electric submersible pump. Results of numerical modeling using the PIPESIM steady-state multiphase flow simulator, physical, chemical and rheological investigations show that with a decrease of highly paraffinic oil from the productive formation D2ef in a blend with Stary Oskol oil from the Kyrtaelskoye field, a decrease in the mass content of paraffin in the blend and the temperature of its saturation with paraffin, depth and intensity of the organic deposits formation in the tubing string, pour point, as well as the improvement of the rheological properties of the investigated structured dispersed systems is observed. Article describes a promising assembly of well equipment for the single tubing separate production of highly paraffinic oil from multiformation deposits of the Timan-Pechora province, providing separation of the perforation zones in two productive formations using a packer-anchor system at simultaneous-separate operation of the formations by a double electric submersible pump unit.
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Date submitted2021-03-30
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Date accepted2021-07-27
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Date published2021-10-21
Integrated development of iron ore deposits based on competitive underground geotechnologies
- Authors:
- Vladimir L. Trushko
- Olga V. Trushko
The article presents an analytical review of the current state of the iron ore base of the ferrous metallurgy of Russia and the world, identifies the largest iron ore provinces and iron ore producers. The promising directions of development and improvement of the quality of the iron ore base of Russia and the features of the development of new deposits of rich iron ores are identified. Effective technologies for the development of rich iron ores deposits that ensure an increase in production volumes are proposed. The geomechanical justification of rational technological parameters that are easily adapted to changes in mining and geological conditions has been performed. Based on the results of field studies, the use of an elastic-plastic model with the Coulomb – Mohr strength criterion for modeling changes in the stress-strain state of an ore rock mass during mining operations is justified and recommendations for ensuring the stability of mine workings are developed. Effective engineering and technical solutions for the complex development and deep processing of rich iron ores with the production of fractionated sinter ore, which increases the efficiency of metallurgical processes, the production of high-grade iron oxide pigments and iron ore briquettes, which increase the competitiveness of iron ore companies and the full use of the resource potential of deposits, are presented.