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Date submitted2024-05-08
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Date accepted2024-11-07
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Date published2025-04-25
The effect of mechanical and thermal treatment on the characteristics of saponite-containing material
Solving the problems of modern building materials science is reduced to obtaining high-quality materials, expanding and searching for a rational raw material base, which can be carried out through the use of various industrial wastes. In this paper, the possibility of using waste from the mining industry – saponite-containing material (SCM) obtained during the enrichment of kimberlite ores from the Lomonosov diamond deposit, as an active mineral additive for cement binders and concretes is considered. The influence of mechanical and thermal treatment on a number of properties of the material selected from the tailings dump and in its initial state was studied. The study of the surface activity of SCM samples consisted in determining the sorption capacity, acid-base centers and their distribution. An increase in the activity of the surface of the material particles as a result of mechanical activation and its decrease during temperature treatment were determined. These effects are associated with phase rearrangements and structural changes in the sandy-clay rock, which was confirmed during thermal analysis. The temperature effect has no pronounced effect on the microstructure, the “smoothness” of the particles and the formation of a consolidated surface of the structural elements of the saponite-containing material are noted.
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Date submitted2023-10-28
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Date accepted2024-11-07
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Date published2025-02-25
Radiation characteristics of coals at different stages of metamorphism
The formation of deposits and subsequent metamorphic processes that affect concentrations of radioactive elements in coal can indicate ongoing geological activities, therefore, analyzing trends in the radiation characteristics of coal throughout the metamorphic series is highly relevant. The aim of this work is to experimentally evaluate the radiation characteristics of different coal ranks (metamorphic stages) using thermoluminescent (TL) dosimetry and beta activity measurements, and to identify correlations between these radiation characteristics and data obtained from technical, elemental, and thermogravimetric analyses, as well as mass spectrometric and electron paramagnetic resonance spectroscopy (EPR) measurements. For dosimetric measurements that indirectly characterize the content of radionuclides in coal, a modified dosimetric complex and original soil-equivalent thermoluminescent detectors based on SiO2 were used. The analysis of the obtained results supports the use of TL studies to determine the ash content of coals at low and medium stages of metamorphism (coal rank B→G), while indicating that this method is not feasible for coals at higher stages of metamorphism. The correlation dependencies in the metamorphism series suggest abrupt change in the conditions of coal formation during the time range corresponding to transformation from high to low volatile bituminous coals (coal rank G→Zh→K). These abrupt changes in regional metamorphism conditions (time, temperature, pressure, oxidation-reduction conditions) are confined to the boundary of the Permian and Triassic periods (~250 million years ago), during which both the transformation of existing coal deposits and the formation of new deposits occurred.
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Date submitted2024-04-12
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Date accepted2024-09-05
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Date published2024-11-12
Promising reagents for the extraction of strategic metals from difficult-to-enrich mineral raw materials
The need of the mining and processing industry for new types of directional reagents is due to the deterioration of the material composition of the processed ores. Low Au content (less than 0.5-1.0 g/t), finely dispersed Au inclusions (0.1-10.0 microns) in the ore, similar properties of the separated minerals have an extremely negative effect on flotation performance when using traditional reagents, which leads to significant losses of valuable metal with enrichment tailings. Expanding the range of domestic flotation reagents based on the latest achievements of fundamental research and their targeted application at mining and processing companies will compensate for the negative impact of the mineral composition of raw materials and ensure maximum extraction of strategic metals from difficult-to-enrich ores. The use of modern research methods (scanning electron and laser microscopy, UV spectrophotometry, XRF and chemical analysis) made it possible to visualize the adsorption layer of new reagents-collectors of a number of dithiocarbamates with different structures of a hydrocarbon radical and an organic modifier on the surface of gold-containing sulfides. The amount of adsorbed reagents on the surface of minerals has been experimentally determined. The specific features of the fixation of reagents on minerals of various compositions led to optimal correlations of their consumption in the flotation process. Scientifically based reagent regimes ensured an increase in the gold content in the concentrate and a decrease in the loss of gold with tailings by 5-6 % during flotation enrichment of the refractory ore of the Malinovskoe deposit.
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Date submitted2024-04-11
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Date accepted2024-06-03
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Date published2024-07-04
Assessment of the efficiency of acid mine drainage purification (using the example of copper-pyrite mines in the Middle Urals)
According to the results of the anti-rating of regions with extreme pollution of watercourses in the Sverdlovsk region, the largest number of polluted rivers has been recorded in recent years – more than a quarter of all high and extremely high pollution. One of the sources of pollution of natural water bodies in the Middle Urals are closed and flooded copper-pyrite mines, where acidic mine drainage continue to form and unload to the surface. Several of them have organized collection and a two-stage acidic drainage purification system, including neutralization with lime milk and settling in a clarifier pond. Despite the identical schemes, different indicators of pollutants are recorded during discharge into water bodies. The aim of the work is to evaluate the effectiveness of the applied acid mine drainage purification system and identify the parameters affecting the quality of treated mine water. Laboratory studies were performed using methods of flame emission spectrometry, flame atomic absorption, atomic absorption spectrometry, mass spectrometry with ionization in inductively coupled plasma, potentiometric, etc. It has been established that the existing mine drainage purification system at the Degtyarskii mine makes it possible to significantly reduce the concentrations of most toxic components of mine waters to almost standard values. At the Levikhinskii mine, the multiplicity of exceeding the maximum permissible concentrations reaches hundreds and thousands of times. To achieve a higher degree of purification, it is necessary that the duration of passive purification is sufficient for the reactant to interact with acidic waters. However, to ensure this possibility, it will require the creation of a cascade of ponds with an area of several thousand hectares. If the current two-stage system is quite effective for the Degtyarskii mine, then for Levikhinskii it is necessary to switch to the use of more modern systems, including three stages of purification.
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Date submitted2024-07-04
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Date accepted2024-07-04
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Date published2024-07-04
Environmental safety and sustainable development: new approaches to wastewater treatment
In 2015, the UN member states adopted the 2030 Agenda for Sustainable Development. Despite significant progress, billions of people – one in three people – do not have access to safe, clean drinking water. Modern wastewater treatment methods include a wide range of biological, chemical and physical processes, each having its own advantages and applications. This thematic volume considers the latest achievements in wastewater treatment technologies, wastewater purification and treatment as well as their potential applications at the local level. The problem of surface water pollution is relevant for all regions of the world. One of the largest sources of pollutants is mining and processing industry. The first stage in the development of wastewater treatment technologies is monitoring of anthropogenically modified water bodies.
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Date submitted2023-04-13
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Date accepted2023-10-25
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Date published2025-02-25
Assessment of the ecological state of aquatic ecosystems by studying lake bottom sediments
- Authors:
- Mariya A. Chukaeva
- Tatyana V. Sapelko
The article presents the results of coupled palynological and geochemical studies of five various genesis lakes, located along the route of the expedition “In the footsteps of Alexander von Humboldt in Siberia, Altai and Eastern Kazakhstan”, dedicated to the double anniversary: the 190th anniversary of the expedition across Russia of the famous scientist and his 250th birthday. A geochemical analysis of water and bottom sediments of Ik Lake (Siberia), Lakes Kolyvanskoe and Beloe (Altai), Lake Bezymyannoe (Kazakhstan) and Nagornyi Pond (Altai) was carried out. Based on their results an assessment of studied lakes ecological state was given through single and integral criteria. A high level of pollution was noted for Nagornyi Pond and Lake Bezymyannoe, which is caused by a significant technogenic load from nearby mines. This is consistent with the data of palynological research. The aquatic ecosystems of Lakes Kolyvanskoe and Beloe are characterized by a satisfactory ecological situation, but they experience an increased recreational load. The results of spore-pollen analysis and analysis of non-pollen palynomorphs showed the low ability of these lakes to self-healing. The most favorable ecological state and high self-cleaning capacity were noted for Lake Ik, which is consistent with the data of palynological studies. It is being confirmed with the results of palynological studies. It was therefore concluded about the ability to make a quick assessment of the aquatic ecosystems’ ecological state by studying lakes using coupled palynological and geochemical analysis.
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Date submitted2022-05-17
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Date accepted2023-04-03
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Date published2024-02-29
Improvement of concentrate quality in flotation of low-rank coal
- Authors:
- Sergei A. Kondratev
- Tatyana A. Khamzina
Percentage of high-rank coal with low content of ash, moisture, and sulfur in total coal production output is low. Most of the produced coal has a low quality (lignite, bituminous coal: long-flame and fiery). Under increasing requirements for ecological cleanness of coal, the efficient use of coal products is only possible after improvement of their processing properties. The authors discuss the enhancement of flotation efficiency of low-rank coal using the mechanism of physisorption of a collecting agent in particle – bubble attachment. It is explained why the yield of concentrate with low ash content increases as a result of combination of collectors having different physical properties. It is shown that the surface activity of a heteropolar agent relative to the gas – liquid interface and the adsorption density of the agent govern its collecting properties. Based on the recovery – surface activity relationship, the correlation is found between the collecting activity of a chemical compound and the structure of its molecules. The combination of the collectors with different surface activity enables adjusting collectability and selectivity of the blend. The physisorption mechanism of collectors can be a framework for developing recommendations on modification of concentrate yield and ash content, and on selection of optimized ratios of surface activities of miscible collectors relative to the gas – liquid interface.
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Date submitted2022-10-24
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Date accepted2023-03-03
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Date published2023-04-25
Use of clay-containing waste as pozzolanic additives
Growing productivity of mining and processing enterprises entails an increase in the volumes of liquid tailings impoundments and upstream impoundments of ore processing waste. Enterprises face the challenge of minimizing the environmental impact of waste and guaranteeing the sanitary and epidemiological safety of population. The article presents a possibility of recycling one type of such waste (clay-containing concentration tailings of apatite-nepheline and sylvinite ores, coal beneficiation tailings) by using them after preliminary thermochemical treatment as pozzolanic additives to cements and concretes, including concrete mixtures used for soil stabilization, development of territories, reclamation of mine workings, as a component of the insulating layer of landfills for the disposal of municipal solid waste. An analysis of the phase changes of kaolinite, one of the main minerals that make up clay-containing waste, in the temperature range of 200-1,000 °С showed that a change in its mineral form during heat treatment is the main factor in changing its pozzolanic activity. The effect of heat treatment of clay minerals at temperature of 700-800 °C on their pozzolanic activity, estimated by the ability to absorb calcium hydroxide (0.7 g Ca(OH) 2 per 1 g of modified kaolinite), is considered. It is shown that the addition of heat-treated samples (20 % by weight) improves the quality of cement increasing its activity by 15 %, in comparison with the use of unmodified clay minerals. It was proved experimentally that partial replacement of Portland cement with thermally modified kaolinite increases the strength of consolidating stowing mixture by up to 15 %. This approach to processing of ores containing layered silicates, which provides for thermochemical modification of run-of-mine ore, intensifies the processes of tailings thickening and filtering.
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Date submitted2022-09-30
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Date accepted2023-02-13
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Date published2023-04-25
Hydrogeoecological conditions of technogenic groundwater in waste disposal sites
The specific hydrogeoecological conditions of aquifers of some technogenic formations, mainly iron ore skarn-magnetite and titanium-magnetite formations, are considered. The resulting wastes, which are stored in waste disposal sites during development of deposits, due to the impact of a number of factors (natural and technogenic) form technogenic waters. Waste disposal facilities are complex engineering structures (dumps and sludge storages), which in turn create their own hydrogeoecological conditions, which must be investigated in order to prevent and minimize environmental and economic damage caused by these objects to the aquatic environment. The paper presents long-term field and laboratory studies of the aquatic environment under the influence of a waste disposal facility in the Middle Urals – one of the largest tailings, representing a potential environmental and man-made hazard. This tailing dump contains tens of tons of waste – enrichment tailings and creates specific hydrogeoecological conditions on the territory. Based on many years of monitoring studies, an analysis of these conditions was carried out – the quality of groundwater affected by the tailings was assessed. It is shown that groundwater is of technogenic nature, i.e. are man-made waters that have a significant impact on the surface and underground hydrospheres of the territory.
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Date submitted2022-03-22
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Date accepted2022-11-17
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Date published2023-02-27
Development of composition and study of sorbent properties based on saponite
The development of a comprehensive approach to preventing the pollution of natural objects is necessary due to the high requirements of environmental legislation for the discharge of industrial wastewater. Adsorbents are used in various industries to extract heavy metals from wastewater. In this study the possibility of using saponite clay as a raw material for the production of sorbent for the extraction of copper ions Cu 2+ from industrial wastewater is considered, a recipe and technology of sorbent production are developed, and its chemical composition is established. It has been established that the optimum temperature for heat treatment of the sorbent and corresponds to 550 ºC, since at this temperature saponite extrudates acquire strength (strength 34.1 kg/mm 2 ) and textural properties (specific surface area of pellets 22.803 m 2 /g), allowing them to be used as sorbents. The kinetics of molecular adsorption was studied using model solutions of copper (II) sulfate. The extraction efficiency of copper (II) ions from the model solutions is 93 %. Extraction efficiency of copper (II) ions from copper plating wastewater reaches 94 %. SEM results confirm the presence of metal on the sorbent surface.
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Date submitted2022-07-15
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Date accepted2022-12-13
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Date published2023-02-27
Mathematical modelling of displacement during the potash ores mining by longwall faces
In favourable mining conditions, in particular at the Starobinskoye potash deposit (Belarus), longwall mining systems are used. They cause a high human-induced load on the subsoil, including intense deformation of the ground surface. The presented investigations are aimed at studying the dynamics of the ground surface displacement during the longwall face advance. Mathematical modelling was carried out in an elastic-plastic formulation with numerical implementation by the finite element method. The condition for the roof rocks collapse was opening of the contact between the seams when its boundaries were reached by shear fractures or formation of the tensile stresses area at the outcrop. With the working front advance, an increase in subsidence is observed, followed by its stabilization to a value determined by the process parameters of mining operations and the physical and mechanical properties of collapsed rocks. In this case, each point of the ground surface experiences sign-alternating horizontal deformations: when the front approaches, it causes tension, and when it moves away, compression. The obtained results of mathematical modelling are in good agreement with the data of instrumental measurements of the ground surface displacements, which indicates the adequate description of the rock mass deformation during the slice excavation of sylvinite seams by longwall faces.
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Date submitted2022-03-01
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Date accepted2022-05-25
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Date published2022-12-29
Study on the rheological properties of barite-free drilling mud with high density
Improved drilling and reservoir penetration efficiency is directly related to the quality of the drilling mud used. The right choice of mud type and its components will preserve formation productivity, stability of the well walls and reduce the probability of other complications. Oil and gas operators use barite, less often siderite or hematite weighting agent as a weighting component in the composition of drilling muds for the conditions of increased pressure. But the use of these additives for the penetration of the productive formation leads to the reduction of filtration characteristics of the reservoir, as it is almost impossible to remove them from the pore channels. Therefore, barite-free drilling mud of increased density based on formic acid salts with the addition of carbonate weighting agent as an acid-soluble bridging agent is proposed. The results of experimental investigations on rheological parameters of barite-free solutions are given and the obtained data are analyzed. Based on the comparison of results it is recommended to use high-density drilling mud on the basis of formic acid salts (sodium and potassium formate) and with the addition of partially hydrolyzed polyacrylamide with molecular mass of 27 million.
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Date submitted2022-03-14
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Date accepted2022-06-20
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Date published2022-11-10
Model of a walking sampler for research of the bottom surface in the subglacial lake Vostok
Technologies and technical means for investigation of subglacial lakes in Antarctic is a new developing scientific and technical direction, which today has no clearly established methodology. Based on the developed technology of drilling a new access well to lake Vostok and its penetration as well as analysis of existing methods and devices for bottom sediment sampling, a basic model of a sampler with a walking-type mover, capable of moving along different trajectories and operating in a wide technological range, is proposed. The proposed device model is equipped with different actuators for sampling the bottom surface with different physical and mechanical properties. Based on the presented basic model of the walking sampler, a mathematical model of the device was developed, which was based on the theoretical mechanics methods. As a result of conducted research the dependencies were obtained, which allow making a scientifically justified choice of optimal values for geometric and force parameters of the walking sampler. A conceptual design of the walking sampler has been developed, taking into account the mutual location and coupling of its main components, the overall dimensions of the delivery tool, as well as the esthetic component of the device.
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Date submitted2022-03-17
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Date accepted2022-06-20
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Date published2022-11-03
Assessment of collecting activity of physically sorbed reagents on the example of easily floatable coking coal sludge
- Authors:
- Sergey A. Kondratev
- Tatyana A. Khamzina
The article presents one of the new approaches to theoretical assessment of collecting ability of reagents. The efficiency of reagents-collectors with different chemical composition used for flotation of coking coals was studied. A comparative assessment of the flotation activity of kerosene, mineral oil, thermal gas oil, KETGOL and FLOTEK is given. The criteria of collecting activity of the above reagents-collectors for coal sludge flotation were specified. A correlation was established between the indicators of coal sludge flotation by the above reagents and their physical parameters. It is shown that the rate of spreading over water surface can characterize the flotation activity of reagents. Based on dependence of the collecting activity of a reagent on its rate of spreading along the “gas – liquid” interface and surface pressure, the main approaches to determining the structure and composition of molecules of an effective flotation collector can be determined. A new concept of the function performed by a physically sorbed collector in the elementary act of flotation and a criterion for the flotation activity of reagents used in coal sludge beneficiation are proposed. It is shown that the collector used in coal flotation, in addition to hydrophobizing the surface of the extracted particles, should reduce the induction time and remove the kinetic constraint on formation of a flotation aggregate.
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Date submitted2022-03-17
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Date accepted2022-10-04
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Date published2022-11-10
Improving the reliability of 3D modelling of a landslide slope based on engineering geophysics data
Landslides are among the most dangerous geological processes, posing a threat to all engineering structures. In order to assess the stability of slopes, complex engineering surveys are used, the results of which are necessary to perform computations of the stability of soil masses and assess the risks of landslide development. The results of integ-rated geological and geophysical studies of a typical landslide slope in the North-Western Caucasus spurs, composed of clayey soils, are presented. The purpose of the work is to increase the reliability of assessing the stability of a landslide mass by constructing a 3D model of the slope, including its main structural elements, identified using modern methods of engineering geophysics. Accounting for geophysical data in the formation of the computed 3D model of the slope made it possible to identify important structural elements of the landslide, which significantly affected the correct computation of its stability.
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Date submitted2021-03-18
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Date accepted2021-11-30
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Date published2021-12-27
Deformations assessment during subway escalator tunnels construction by the method of artificial freezing of soil for the stage of ice wall formation
- Authors:
- Evgenii M. Volokhov
- Diana Z. Mukminova
The work is devoted to the study of the processes of displacement and deformation of the surface during the escalator tunnels construction of the subway by the method of artificial freezing of soils. The features of the construction and freezing technology, the rocks characteristics in which the escalator tunnels made are considered. The data of specially organized, full-scale surveying observations of deformations on the earth surface are presented. The main factors influencing deformation processes in the frozen strata of a layered inhomogeneous rock mass with inclined tunneling are determined, the complexity of the predictive task and the need to simplify the design scheme are shown. The work is focused on the assessment of the least studied geomechanical processes of soil heaving-uplifts and deformations during the periods of active and passive freezing stages. When studying the displacements processes of the earth surface and rock mass, the finite element method and analysis of the obtained data using field observations of displacements were used. A simplified calculation scheme is proposed for modeling, which allows taking into account the uneven influence of frozen rocks of an inhomogeneous layered rock mass with a large inclined tunneling. The satisfactory convergence of the data of field surveying observations on the earth surface and the results of modeling geomechanical processes for the period of active and passive freezing stages is shown. The proposed calculation scheme is recommended for the prediction of deformation at the stages of underground construction, characterized by the development of the most dangerous tensile deformations of buildings and structures on the surface.
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Date submitted2021-03-18
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Date accepted2021-09-10
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Date published2021-12-16
Development of blocking compositions with a bridging agent for oil well killing in conditions of abnormally low formation pressure and carbonate reservoir rocks
- Authors:
- Dmitrii V. Mardashov
Production well killing before workover operations in late-stage oil and gas-condensate fields can be complicated by abnormally low formation pressure, carbonate type of reservoir rocks, and high gas-oil ratio. These complications lead to the intensive absorption of technological fluids by the formation and gas ingresses, which, in its turn, increases the time of killing wells and putting them on production, reduction of productivity, and additional costs. Therefore, it is crucial to develop a high-performance well-killing composition that would allow improving the efficiency of killing wells in complicated geological, physical, and technological conditions at the expense of reliable overlapping of the perforation interval (or open wellbore) to prevent gas intakes and gas outflow from the formation. To develop blocking compounds, a set of laboratory tests has been carried out, including physical and chemical (determination of density, viscosity, thermal stability, sedimentation stability, etc.) and research of blocking and filtration properties of compositions during simulation of a fractured reservoir. In the course of laboratory tests, the choice of fractional composition and polymer filler concentration was substantiated in the blocking emulsion and polymer compositions to increase the efficiency of their application under the complicated conditions of killing oil wells. As a result of laboratory research and field tests, the emulsion and polymer blocking compositions containing bridging agent (microcalcite) were developed, which increase the oil well killing efficiency by preventing the absorption of technological fluids in the formations and, as a result, preserving its productivity.
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Date submitted2021-04-23
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Date accepted2021-09-07
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Date published2021-12-16
Development of the concept of an innovative laboratory installation for the study of dust-forming surfaces
Currently, the determination of the emission rate of suspended solids from a unit of the surface area of a man-made mass at various parameters of the wind flow is not sufficiently described. The analysis of the world experience of researchers shows that existing laboratory installations have various design features that do not allow to correctly determine the mass of the dust being flapped and wind-blown. Based on the analysis results, the concept of an innovative laboratory installation for the study of dust-forming surfaces has been developed. It takes into account the influence of wind shadows, the deturbulization of an artificially created air flow, the possibility of regulating not only the flow velocity mode, but also the creation of a vacuum or disturbance in the area of sample placement, as well as the formation of a certain angle of wind flow attack relative to the surface. The concept provides for the possibility of determining the volume of dust emissions by the values of the lost dust masses in the sample and by the values of dust concentrations in the outgoing stream. The calculation of the main basic elements of the installation using the ANSYS FLUENT software package was carried out. The model and configuration of the wind tunnel have been developed and calculated, the main geometric parameters and functional elements for the possibility of use in scientific work have been determined. For practical use of the empirical roughness value of the underlying surface, its values are recommended in a wide range – from zero for the water surface to 0.44 for large cities with tall buildings and skyscrapers.
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Date submitted2021-03-12
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Date accepted2021-04-12
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Date published2021-06-24
Increasing the efficiency of phosphate ore processing using flotation method
The paper presents flotation of two phosphate ore samples of different origin. Statistical analysis was used to study the effect of operating parameters on flotation efficiency. The paper proposes to increase the efficiency of flotation processing of magmatic phosphate ore with a low grade of the valuable component (P 2 O 5 = 10.88 %), containing nepheline and feldspars, by means of direct anionic flotation. Authors present an optimization of anionic flotation using tall oil fatty acids mixed with anionic phospholane as an anionic collector. The effect of adding soda ash to compensate for the influence of calcium cations on technological parameters of P 2 O 5 flotation was examined. The results of studying the flotation of nepheline ore (flotation tailings of magmatic phosphate ore) showed that replacement of phospholane with oxyethylated isotridecanol allowed to obtain a high-quality concentrate. It was estimated that with the addition of Na 2 CO 3 in the amount of 2,000 g/t, a concentrate was obtained with the grade and recovery of phosphorus pentoxide equal to 39.15 and 94.19 %, respectively. The paper proposes to increase the efficiency of flotation processing of sedimentary phosphate ore with a low grade of the valuable component (P 2 O 5 = 22.5 %), containing gypsum and quartz, by means of desliming followed by anionic or cationic reverse flotation. Tall oil fatty acid with anionic phospholane was used as a collector in anionic reverse flotation, and amine was used in cationic reverse flotation. Sodium tripolyphosphate was used as a P 2 O 5 depressant. It was found to be an effective depressant in both anionic and cationic flotation. When analyzing the statistical plan, it was estimated that the maximum grade of the valuable component in the concentrate (P 2 O 5 = 31.23 %) and the recovery to concentrate of 95.22 % were obtained in the chamber product at amine consumption of 950.88 g/t and sodium tripolyphosphate consumption of 500 g/t.
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Date submitted2020-06-16
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Date accepted2020-07-13
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Date published2020-11-24
Study of Aluminum Influence on the Adhesion of Stainless Steel in Flame Spraying
This paper is dedicated to a study of aluminum influence on the improvement of surface adhesion strength. The main purpose of this work is to investigate the strength of adhesion to the substrate by mixing flame spray powder with aluminum, which not only possesses high corrosion resistance and conductivity, but also provides additional strength, as it combines and reacts with other components of the powder. Research results of sandblasting dependence on surface roughness parameter Ra are demonstrated. The paper describes authors’ original device for a measuring instrument “Profilometer”, which was also used for measuring roughness parameter in order to obtain comparative results. Authors present results of adhesion measurements given obtained values of surface roughness by mixing nominal chemical composition of PR-30X13 powder, used as a testing material, with aluminum, which reacts with oxides on the surface of steel substrates, imparts strength to the bonding between the coating and the substrate, protects the base metal due to a combination of chemical components of the powder and creates a layer of dense surface coating. These dependencies are analyzed and parameters, exerting the greatest influence on their values, are identified. Taking into account the results obtained through numerical modeling, authors propose a mathematical model of a dependency between adhesion strength and certain values of surface roughness for different chemical compositions of flame spray powder. These studies will help in the development of certain material types for spraying and hardening of steel parts and products in order to improve their durability.
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Date submitted2020-06-19
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Date accepted2020-10-06
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Date published2020-11-24
Practice of using the magnetic treatment devices to intensify the processes of primary oil treating
During the primary treatment of oil, gas and water, complications arise associated with the presence of hard water-oil emulsions, which cause an increase in fluid pressure in the gathering systems, pipeline damage, as well as difficulties in gas separation and preliminary water discharge at the preliminary discharge unit (PRU). Additional problems arise during transportation of highly paraffinic oils associated with the crystallization of paraffin in the flow path of the oilfield equipment and on the inner surface of pipes, leading to a drop in the productivity of pipelines. Article discusses the technology of magnetic-reagent treatment of water-oil media, which allows intensifying the processes of primary oil treatment at the facilities of its production. Bench and pilot tests have shown the ability of the magnetic field to accelerate oil demulsification processes, increasing the percentage of separated water during subsequent settling, and to reduce asphalt-resin-paraffin deposits (ARPD) on the inner surface of oil and gas field equipment. Mechanism of the magnetic field effect on water-oil media is described. Effect of treatment on the integrity of the armour shells of oil-water emulsions was studied. Various modes of magnetic treatment have been investigated with evaluation of its effectiveness. It is shown that the best effect is achieved with the combined use of reagents and a magnetic field. Synergistic effect is observed, which consists in increasing their effectiveness. This made it possible to conclude that this method can be applied to reduce the consumption of reagents used in oil production while maintaining the treatment efficiency.
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Date submitted2019-05-30
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Date accepted2019-09-04
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Date published2020-02-25
Prospects for industrial methane production in the mine n.a. V.M.Bazhanov using vertical surface wells
The estimated methane resources in the coal stratum of Donbass are 798.5 billion m 3 , including 119.5 billion m 3 in the Donetsk-Makeevsky area. Such significant potential implies that methane can be used not only for industrial production and energy purposes but also as a commodity for the chemical industry. However, in practice, commercial production of methane from coal seams, as is done in the fields of the USA, Canada, India, and China, is not carried out, and methane, obtained as a by-product, is utilized for ensuring the safety of the main technological processes for coal mining. The main reasons for this are the difficult mining and geological conditions of bedding, low thickness and permeability, which does not allow to separate methane production into an independent type of activity due to its low profitability, especially with the use of new technologies based on hydraulic fracturing of coal seams. The assessment of the possibility of industrial methane production in the mine n.a. V.M.Bazhanov in the Donetsk-Makeevsky area of Donbass, which reserves equal to 23.7 billion m 3 , showed that a significant part of the methane reserves is concentrated in coal seams and interlayers with a gas content of 18.5-20.7 m 3 /m 3 . Moreover, in the host rocks, methane is practically in a liberated state. This circumstance makes possible the commercial production of methane for its utilization from the unloaded rock mass by wells drilled from the surface, without the use of hydraulic fracturing technology. The paper discusses the technology of methane extraction by a degassing well drilled from the surface into a coal-bearing stratum unloaded from rock pressure in a mining field of the 4th eastern face of the m 3 seam of the mine n.a. V.M.Bazhanov and its subsequent use as the fuel of an electric generator. It is shown that over the entire period of operation of the pilot well, the volume of actually produced methane exceeded the design value by 23 %, and the cost of the gas produced amounted to 1535 rubles per 1000 m 3 , which is more than 3 times lower than the market price for natural gas for consumers in the Russian Federation. This made it possible to make a conclusion about the possibility of industrial extraction of mine methane using vertical surface wells for its subsequent utilization in power plants, which does not imply the usage of hydraulic fracturing technology.
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Date submitted2019-03-05
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Date accepted2019-05-03
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Date published2019-08-23
Efficiency Estimation of the Single- and Multicomponent Anti-hydrate Reagents
- Authors:
- N. A. Shostak
- E. P. Zaporozhets
Different types of technological and technical problems in the oil, gas and chemical industries are connected with the hydrate formation process and with the using of anti-hydrate chemicals. That is why, it is necessary to estimate thermobaric ranges within which reagents does not let hydrate to grow or is their dissociation. Also, to estimate anti-hydrate influence we need to determine the chemicals’ anti-hydrate efficiency and chose the best one. They make the reagents consisting of several chemical components depending on the purpose of their application – for prevention of formation and (or) elimination of hydrates. It demands calculations of the optimum concentration and expenses and also the intensity (speed) of hydrates dissociation causing with the reagents. The analytical method of the anti-hydrate chemical reagents efficiency determination containing one or several components from different classes of chemical compounds – alcohols, salts, acids, compounds of nitrogen and oxygen – is presented in this paper. With its help it is possible to define decrease in temperature of hydrate formation from reagents influence, to count key parameters of reagents anti-hydrate efficiency depending on component compositions of hydrate gas and a phase condition of a hydrate-gas system, to select types of chemical components and their quantity in multicomponent reagents, i.e., to make new compounds. The method can be used for express assessment of anti-hydrate chemical reagents efficiency on criteria sign for practical application in oil, gas and processing industry.
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Date submitted2018-08-29
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Date accepted2018-10-25
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Date published2019-02-22
The study of the effect of temperature on the ability of metals to accumulate energy during their plastic deformation
The subject of research is the surface layer of highly loaded parts, friction units of mining machines and equipment. The article presents a theoretical analysis of the factors that determine the ability of the material of the surface layer of parts to accumulate energy in the process of plastic deformation. It is suggested that the activation character of the accumulation of energy by metals. Based on the theory of diffusion, it was shown that the mobility of atoms, as well as the accumulated energy, are determined by the ratio of the test temperature to the melting temperature.
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Date submitted2018-09-08
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Date accepted2018-10-27
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Date published2019-02-22
Special strategy of treatment of difficulty-profile conical screw surfaces of single-screw compressors working bodies
- Authors:
- A. S. Vasilev
- A. A. Goncharov
The article deals with the problems arising during the shaping of complex profile tapered helical surfaces. These surfaces form the geometry of the working bodies of single-screw miniature compressors, which have great prospects for use in mobile miniature compressor plants, which is especially important for medical and space technology, robotics, oil and gas and mining industries. Due to the fact that the capabilities of existing CAD systems do not allow obtaining three-dimensional models of these surfaces, the problem of preparing a control program for a CNC machine arises, since the calculation of the tool path in CAM systems when processing complex surfaces is impossible without a three-dimensional surface model. To solve the problem, an automated programming system was developed that implements a formalized toolpath calculation in accordance with the proposed special processing strategy for conical helical surfaces. As the initial data for calculating the toolpath, the system needs information about the tool geometry and the helical surface in a parametric form, which makes it possible to abandon the construction of a three-dimensional surface model. The results of processing prototypes for the proposed strategy are given.