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Date submitted2024-05-17
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Date accepted2025-03-27
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Date published2025-03-27
Determination of impact hazard potential of rocks in the Norilsk Industrial Region
The deeper the mineral deposits developments are, the worse the mining and geological conditions become. Significant growth of stress level in the rock mass contributes to possible manifestation of rock pressure in dynamic form. The resulting task of assessment of rock impact hazard is closely related to the task of obtaining more accurate results of compression tests of samples in rigid or servohydraulic test presses using graphs of their full deformation. This approach requires special expensive equipment, considerable time resources, and sufficient core material. Therefore, it is important to have an approach that allows to assess the propensity of rocks to brittle fracture with research methods simple enough not to result in the loss of quality and reliability of the obtained results. This paper presents the results of laboratory tests of rocks from the Norilsk Industrial Region to determine their tensile and compressive strengths. Test methods involved both domestic and foreign standards for determining the value of the brittleness coefficient. The impact hazard potential of rocks was determined using the Kaiser criterion. It is found that the tested lithological types (rich sulfide ores, hornblende, disseminated ores, and gabbro-dolerite rocks), with the exception of anhydrite, have a low impact hazard potential.
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Date submitted2024-04-24
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Date accepted2024-09-24
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Date published2024-11-12
Study and justification of the combination of beneficiation processes for obtaining flake graphite from technogenic carbon-containing dusts
The most important task of modern production development is to provide the mineral and raw materials sector of the economy with resources included in the list of strategic raw materials, including flake graphite. In addition to natural raw materials, the source of its obtaining can be metallurgical production wastes not involved in processing. Development of metallurgical dust beneficiation technology will solve the problem of obtaining high-purity flake graphite with a crystal structure close to ideal and in demand in the production of high-tech materials. It will allow creating a renewable raw material base of graphite and utilising metallurgical production wastes. The research included the study of dust beneficiation by coarseness, magnetic and flotation methods, the influence of dust disintegration processes on beneficiation indicators. Based on the established technological properties of the components of dusts, magnetic, flotation and gravity beneficiation methods can be applied for their separation in different sequence. It is shown that dusts from different sites have different enrichability by these methods, and it should be taken into account when developing a complex technology of their processing. The degree of beneficiation increases in a row of dusts from the blast furnace shop (BF) – electric steel smelting shop (ESS) – oxygen-converter shop (OCS). The method of grinding has a significant influence on the separation indicators – at dry grinding in a centrifugal-impact mill with subsequent pneumatic classification the quality of graphite concentrates increases by 22.7 % of carbon for BF dust and by 13.48 % of carbon for ESS dust. OCS dust beneficiation indicators are high at coarse grinding with steel medium – mass fraction of carbon 96.1 %.
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Date submitted2024-04-22
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Date accepted2024-06-13
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Date published2024-07-04
Lithification of leachate from municipal solid waste landfills with blast furnace slag
- Authors:
- Mariya A. Pashkevich
- Yuliya A. Kulikova
The article presents an alternative method of utilization of blast furnace slag and leachate from solid municipal waste landfills, the formation of which occurs during the infiltration of atmospheric precipitation through the thickness of deposited waste. The method is based on the conversion of leachate from the liquid phase to the solid aggregate state by lithification using blast furnace slag as an astringent material. The hydraulic activity of slag, which depends on the amount of oxides contained in it, has been estimated. The investigated slag belongs to the 3rd grade, which confirms the possibility of its use as an astringent material. The filtrate was analyzed for the content of various elements, and the maximum permissible concentrations for each element were found to be exceeded. Chemical and biological oxygen demand were determined, and critically high values were installed (17200 mgO2/l and 4750 mgO2/l, respectively). The lithification process was divided into two stages. The first stage was to reduce the organic component in the filtrate using a coagulant, aluminum sulfate; the second stage was slag hydration. The optimum ratio of lithificate components in terms of mixture solidification rate was established at 1:0.03:1.25 (leachate, coagulant, blast furnace slag). The obtained material was analyzed for the solubility and content of various forms of metal. It is established that at infiltration of atmospheric precipitations through lithificate only 3 % of material will be washed out; concentrations of gross and mobile forms of heavy metals do not exceed the maximum permissible, except for the gross content of arsenic, mobile, and water-soluble forms of which were not found. The values of chemical (687 mgO2/l) and biological (173 mgO2/l) oxygen demand in the aqueous extract from lithificate decreased more than 25 times in comparison with the initial filtrate. According to the results of toxicological studies, lithificate was assigned an IV class of waste hazard, which confirms the possibility of its use as bulk material at landfills.
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Date submitted2024-04-22
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Date accepted2024-06-13
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Date published2024-07-04
Comprehensive utilization of urban wastewater sludge with production of technogenic soil
The article presents the analysis of the existing approach to wastewater sludge treatment and justifies the selection of the most promising management technology that allows maximum use of wastewater sludge resource po-tential. To obtain a useful product (biocompost) suitable for use as part of technogenic soil, experimental studies of aerobic stabilization of organic matter of dehydrated urban wastewater sludge with the addition of other waste by using passive composting technology were carried out. The technology is included in the list of best available technologies (BAT). The selection of the most optimal components for the mixture was based on the results of determining the C and N content, humidity and pH of the components used that ensured the composting of organic waste. The results of laboratory studies of the obtained biocompost according to the main agrochemical and sanitary-epidemiological indicators are presented. Testing was carried out according to the criterion of toxicity of the biocompost’s aqueous extract. The assessment of the technogenic soil was performed when using biocompost in its composition for compliance with existing hygienic requirements for soil quality in the Russian Federation. Based on the results of the vegetation experiment, optimal formulations of the technogenic soil were determined, i.e., the ratio of biocompost and sand, under which the most favorable conditions for plant growth are observed according to a combination of factors such as the number of germinated seeds, the maximum height of plants and the amount of biomass. The conducted research makes it possible to increase the proportion of recycled urban wastewater sludge in the future to obtain soils characterized by a high degree of nutrient availability for plants and potentially suitable for use in landscaping, the biological stage of reclamation of technogenically disturbed lands, as well as for growing herbaceous plants in open and protected soil.
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Date submitted2024-03-29
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Date accepted2024-06-03
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Date published2024-07-04
Potential use of water treatment sludge for the reclamation of small-capacity sludge collectors
- Authors:
- Olga M. Guman
- Irina A. Antonova
In small settlements, collectors for the sludge produced during water treatment processes are small-sized and located in the vicinity of drinking water storage reservoirs or in coastal areas. Sludge removal is not economical. Besides, the relief depressions formed after sludge disposal are required to be reclaimed. In ore mining regions, where the main settlements of the Urals are located, sludge produced in water treatment has high contents of heavy metals typical of ore mining provinces. Consequently, places of sludge accumulation are potential sources of water pollution. The article discusses the possibility to mix sludge with slaked lime and local overburden with the help of special equipment. So far water treatment sludge in the region has been used to reclaim the surface of solid waste landfills by creating anaerobic conditions for waste decomposition. When placed inside the embankment dams as an independent object, sludge needs to be improved for the increase of its bearing capacity and the ability to bind heavy metals. The article aims at the substantiation of the composition and properties of the reclamation material made of the water treatment sludge mixed with local overburden and slaked lime (technosoil). For this reason the paper describes the composition of the sludge in a sludge collector, the composition and properties of the overburden rocks as a component of the mixtures with water treatment sludge, the composition and properties of the mixtures of water treatment sludge with overburden rocks and Ca(OH)2 as a component dewatering sludge and neutralizing toxicants. Furthermore, the research work provides the technology created for the optimal processing of the water treatment sludge in the process of the reclamation of a sludge collector. The research results and the experience obtained in reclamation of disturbed lands in the region have confirmed the possible use of technosoil for the reclamation of small-capacity sludge collectors. The analysis of the chemical composition and physical and mechanical properties of the mixtures under study has shown that the most economical and environmentally sound reclamation material is a mixture of water treatment sludge, loose overburden dump soils and Ca(OH)2 in a ratio of 60 : 30 : 10 %.
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Date submitted2023-04-13
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Date accepted2023-10-25
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Date published2025-02-25
Assessment of the ecological state of aquatic ecosystems by studying lake bottom sediments
- Authors:
- Mariya A. Chukaeva
- Tatyana V. Sapelko
The article presents the results of coupled palynological and geochemical studies of five various genesis lakes, located along the route of the expedition “In the footsteps of Alexander von Humboldt in Siberia, Altai and Eastern Kazakhstan”, dedicated to the double anniversary: the 190th anniversary of the expedition across Russia of the famous scientist and his 250th birthday. A geochemical analysis of water and bottom sediments of Ik Lake (Siberia), Lakes Kolyvanskoe and Beloe (Altai), Lake Bezymyannoe (Kazakhstan) and Nagornyi Pond (Altai) was carried out. Based on their results an assessment of studied lakes ecological state was given through single and integral criteria. A high level of pollution was noted for Nagornyi Pond and Lake Bezymyannoe, which is caused by a significant technogenic load from nearby mines. This is consistent with the data of palynological research. The aquatic ecosystems of Lakes Kolyvanskoe and Beloe are characterized by a satisfactory ecological situation, but they experience an increased recreational load. The results of spore-pollen analysis and analysis of non-pollen palynomorphs showed the low ability of these lakes to self-healing. The most favorable ecological state and high self-cleaning capacity were noted for Lake Ik, which is consistent with the data of palynological studies. It is being confirmed with the results of palynological studies. It was therefore concluded about the ability to make a quick assessment of the aquatic ecosystems’ ecological state by studying lakes using coupled palynological and geochemical analysis.
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Date submitted2022-10-31
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Date accepted2023-03-02
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Date published2023-12-25
Lightweight ash-based concrete production as a promising way of technogenic product utilization (on the example of sewage treatment waste)
- Authors:
- Tatyana E. Litvinova
- Denis V. Suchkov
The study is devoted to the development of a method for the technogenic raw materials utilization. Special attention is paid to the prospect of involving products based on them in the production of new building materials. The results of Russian and foreign studies on the reuse of wastes, such as phosphogypsum, metallurgical slag, waste from municipal and industrial wastewater treatment, etc., in the building materials industry are considered. It has been established that the use of incinerated sewage sludge ash in construction is a promising direction in terms of environmental and economic efficiency. The research confirmed the compliance of the lightweight ash-based concrete components to the regulatory documentation requirements for a number of indicators. As a result of the research, the composition of the raw mixture for the lightweight concrete production with incinerated sewage sludge ash as a replacement for a part of the cement has been developed. In terms of parameters, the developed concrete corresponds to standard lightweight concrete, marked in accordance with the regulatory documents of the Russian Federation as D1300 (density not less than 1.3 g/cm3), Btb2 (flexural strength not less than 2 MPa), M200/B15 (compressive strength not less than 15 MPa). Lightweight ash-based concrete is suitable for use in construction, repair of roads and improvement of urban areas.
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Date submitted2022-11-02
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Date accepted2023-03-02
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Date published2023-04-25
Environmental damage from the storage of sulfide ore tailings
The mining industry is one of the most challenging in ensuring environmental safety. During the last century, the Karabash Copper Smelting Plant was processing sulfide ores and depositing the tailings into storage facilities that now occupy an area of more than 50 hectares. To date, abandoned tailings are a significant source of natural water, air, and soil pollution in the Karabash city district. The article comprehensively examines the environmental impact of the Karabashmed copper smelter, one of the oldest metallurgical enterprises in Russia. The effects of seepage from the two Karabashmed tailings facilities on water resources were assessed. We revealed that even outside the area of the direct impact of processing waste, the pH of natural water decreases to values 4-5. Further downstream, the infiltration water from the tailings pond No. 4 reduces the pH of river water to 3.0-3.5. The presented results of environmental engineering surveys are derived from sampling water and bottom sediments of the Ryzhiy Stream and the Sak-Elga River, sample preparation, and quantitative chemical analysis. The study revealed significant exceedances of the maximum permissible concentrations for a number of chemical elements in the impact zone of the copper ore processing tailings.
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Date submitted2022-10-29
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Date accepted2023-02-13
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Date published2023-04-25
The use of unmanned aerial photography for interpreting the technogenic transformation of the natural environment during the oilfield operation
The traditional approach to monitoring observations of the technogenic processes development in oilfields, which consists in determining the concentration of marker pollutants in various natural environments, does not provide the necessary completeness of information and the efficiency of its receipt. The paper considers an example of expanding the range of observations due to unmanned aerial photography and a number of other methods. Interpretation signs (for panchromatic survey) were determined that register such consequences of technogenic transformation of the natural environment as mechanogenesis, bitumization, and halogenesis. Technogenic mechanogenesis is understood as a physical violation of the integrity of ecosystems, the movement of soils and grounds. Bitumization is expressed in the migration of petroleum hydrocarbons through soils, ground, surface, subsurface, and underground waters, and their destruction. Salt migration in these media is defined as halogenesis. The most reliable indicators are linearly elongated areas of dead forests, dark red spots in drying microdepressions and reservoirs. It was found out that the oilfield impact on the raised bog leads to anthropogenic eutrophication, the introduction of plant species, uncharacteristic coenotic groups, the replacement of subshrubs with grasses, and morphometric changes in forest pine. In the peat deposits of the disturbed area, an unusual interlayer of whitish, undecomposed moss was recorded. The moment of the beginning of a pronounced technogenic transformation was registered in the course of work with the archive of multispectral space images. Continuous remote sensing with the help of unmanned aerial photography and interpretation by sedimentological, geobotanical methods significantly expand the possibilities of studying the technogenic transformation of the natural environment. To ensure environmental safety, it is advisable to develop remote methods and technologies to include them in the environmental monitoring system.
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Date submitted2022-05-26
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Date accepted2022-11-17
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Date published2022-12-29
Renovation method of restoring well productivity using wavefields
A stagewise theoretical substantiation of the renovation vibrowave method of influencing the near-wellbore zone of reservoir for restoring well productivity is presented. The area of treatment by the proposed method covers the reservoir with a heterogeneous permeability with fractures formed by fracking. In this method a decrease in concentration of colmatants occurs due to a change in direction of contaminants migration. Under the influence of pressure pulses, they move deep into the reservoir and disperse through the proppant pack. The results of mathematical modelling of the propagation of pressure wave and velocity wave and the calculations of particles entrainment in wave motion are presented.
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Date submitted2022-02-22
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Date accepted2022-05-11
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Date published2022-11-03
Scientific substantiation and development of innovative processes for the extraction of zirconium and rare earth elements in the deep and comprehensive treatment of eudialyte concentrate
- Authors:
- Valentin A. Chanturiya
Based on a package of modern analysis methods, the influence of various acids and energy effects on the morphology, elemental composition, structural and chemical transformations of the mineral surface, and the efficiency of eudialyte concentrate leaching was studied. The mechanism and the optimal conditions and specific features of the destruction of eudialyte and rock minerals and the extraction of zirconium and REE under the influence of various acids, powerful nanosecond pulses, dielectric barrier discharge, electrochemical processing, mechanochemical activation and ultrasound were revealed. The mechanism of formation and the optimal conditions for the dispersion of silica gel, depending on the methods and parameters of energy effects, was theoretically and experimentally substantiated. A combined three-stage circuit of nitric acid leaching of eudialyte concentrate with ultrasonic treatment of the suspension, providing 97.1 % extraction of zirconium and 94.5 % REE, were scientifically substantiated and tested. The conditions for the selective deposition of zirconium and REE were theoretically and experimentally substantiated.
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Date submitted2022-06-01
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Date accepted2022-09-06
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Date published2022-11-10
Impact of EU carbon border adjustment mechanism on the economic efficiency of Russian oil refining
- Authors:
- Vladimir L. Ulanov
- Oleg N. Skorobogatko
The carbon border adjustment mechanism (CBAM) leads not only to the expected environmental changes, but also to the transformation of market environment. The study estimates the losses of the oil refining sector from the introduction of CBAM for the export of oil products from Russia to the countries of the European Union. An approach to assess the impact of CBAM on the cost of oil products has been formed and the mechanisms of its impact on the economy of Russian oil refineries have been identified. The study was carried out on the basis of actual data on the volume of greenhouse gas emissions in accordance with the current rules of the European emissions trading system. Decomposition of assessments of the CBAM impact was carried out into direct and indirect effects, as well as the effect of adaptation. It is shown that with the introduction of the CBAM mechanism, the prices of oil products in the domestic market will be determined not only by the logistical factor, but also by the requirements for environmental friendliness of oil refining. The introduction of CBAM will have a significant impact on the economics of oil refining, including refineries that do not export to the EU. The total impact of CBAM on the economy of Russian oil refineries will be about 250 mln dollars.
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Date submitted2021-11-10
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Date accepted2022-05-25
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Date published2022-12-29
Predicting the permeability of the near-bottomhole zone during wave impact
The research reveals that during selection of a method to increase oil recovery it is necessary to take into account rheological features of fluid movement through the formation, effect of capillary forces and heterogeneity of reservoir properties of the productive formation in thickness and along the bedding. Low-frequency wave impact, which is used to increase production in oil fields, is considered. At low-frequency impact new fractures appear and existing fractures in rocks increase in size. The greatest increase in porosity and permeability of rocks occurs at an impact frequency up to 10 Hz. Dynamics of oscillation amplitude during wave's movement in saturated porous medium is studied in the paper: essential attenuation of amplitude occurs at distance up to 1 m from borehole axis. With increase of frequency from 1 to 10 Hz the intensity of amplitude's attenuation decreases. The technology was tested on a well in Perm region (Russia). The actual permeability value was 50 % higher than the predicted value. According to the results of hydrodynamic investigations processing, it was noted that the greatest increase of permeability took place near the wellbore, while away from the wellbore axis permeability remained almost unchanged. In order to refine the mathematical model for prediction of wave impact on rock permeability it is necessary to take into account interconnection of pore space structure, change of adhesion layer, as well as to study transfer of particles during vibration.
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Date submitted2022-01-24
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Date accepted2022-04-26
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Date published2023-04-25
Forecast of radionuclide migration in groundwater of the zone affected by construction drainage at the Leningrad NPP-2
The distribution of natural (at the level of global background) and technogenic radionuclides in groundwater of the industrial zone in Sosnovy Bor town, where several nuclear power facilities are operating, was analyzed. The main technogenic radionuclides recorded in groundwater samples are cesium ( 137 Cs), strontium ( 90 Sr), and tritium isotopes. The first two aquifers from the surface are subject to contamination: the Quaternary and the upper zone of the Lomonosov aquifer. Based on extensive material on the engineering and geological studies of the work area, a 3D geological model and hydrodynamic and geomigration models of the industrial zone were constructed. By means of modeling, the extent and nature of changes in hydrogeological conditions of area resulting from the construction and operational drainage of the new stage of the Leningrad Nuclear Power Plant (LNPP-2) were determined. The “historical” halo of radioactive contamination of groundwater forming (1970-1990) at the site adjacent to the NPP, where the storage facility of low- and medium-level radioactive waste is located, falls into the zone of influence. Interpretation of monitoring data allowed obtaining the migration parameters for predictive estimates. Modeling has shown that during the time of the LNPP-2 operation there was no intake of contaminated water by the drainage system of the new power plant.
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Date submitted2021-09-22
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Date accepted2021-11-30
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Date published2021-12-27
Possibilities for creating Russian high-tech bottomhole assembly
Development of high-tech well electronic measuring systems is aimed at creating modern equipment: telemetry, well geophysical measurement equipment, the architecture of which is divided into basic (with measurement channels for gamma logging and inductive resistance) and advanced (with radioactive, acoustic, magnetic resonance and thermobarometric measurement channels, including azimuthal methods of investigation). Over-the-bit measurement modules, rotary steerable systems are being developed and channels for transmitting data to the surface are being improved. Vice versa, specialized surface equipment with highly integrated software is being created. Different measurement modules are manufactured by different companies, which creates uncertainties in the possibility of interfacing the manufacturers' measurement modules into a single well measurement system. The article presents an analysis of the readiness of Russian oil service companies to produce well and surface equipment for drilling Russian directional oil and gas wells, meeting modern requirements for accuracy, lifetime and operating conditions. The possibility of creating a fully Russian well high-tech equipment and the required resources, risks and measures to mitigate them when creating a modern well measurement system are considered.
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Date submitted2021-06-17
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Date accepted2021-10-18
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Date published2021-12-16
Dissolution kinetics of rare earth metal phosphates in carbonate solutions of alkali metals
- Authors:
- Tatyana E. Litvinova
- Ivan L. Oleynik
Treatment of apatite raw materials is associated with the formation of large-tonnage waste – phosphogypsum. The content of rare earth metals in such waste reaches 1 %, which makes it possible to consider it a technogenic source for obtaining rare earth metals and their compounds. Up to the present moment, there are neither processing plants, nor an efficient process flow to handle phosphogypsum dumps. It is rational to use a way that involves extraction of valuable components and overall reduction of phosphogypsum dumps. Such process flow is available with carbonate conversion of phosphogypsum to alkali metal or ammonium sulfate and calcium carbonate upon the condition of associated extraction of rare earth metal (REM) compounds. Associated extraction of REM compounds becomes possible since they form strong and stable complexes with hard bases according to Pearson, which among other things include carbonate, phosphate and sulfate anions. Formation of lanthanide complexes with inorganic oxygen-containing anions is facilitated by the formation of high-energy Ln-O bonds. The study focuses on the dissolution of lanthanide phosphates in carbonate media. It was established that formation of REM carbonate complexes from their phosphates is a spontaneous endothermic process and that formation of lanthanide carbonates and hydroxides serves as thermodynamic limitation of dissolution. A shift in equilibrium towards the formation of carbonate complexes is achieved by increasing the temperature to 90-100 °C and providing an excess of carbonate. The limiting stage of REM phosphate dissolution in carbonate media is external diffusion. This is indicated by increasing rate of the process with an intensification of stirring, first order of the reaction and the value of activation energy for phosphate dissolution from 27 to 60 kJ/mol. A combination of physical and chemical parameters of the process allowed to develop an engineering solution for associated REM extraction during carbonate conversion of phosphogypsum, which included a 4-5 h conversion of phosphogypsum at temperature of 90-110 °C by an alkali metal or ammonium carbonate solution with a concentration of 2-3 mol/l. As a result, a solution with alkali metal (ammonium) sulfate is obtained, which contains REMs in the form of carbonate complexes and calcium carbonate. The rate of REM extraction into the solution reaches no less than 93 %. Rare earth metals are separated from the mother liquor by precipitation or sorption on anion exchange resins, while the excess of alkali metal or ammonium carbonate is returned to the start of the process.
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Date submitted2020-05-25
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Date accepted2020-06-11
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Date published2020-12-29
Technological aspects of cased wells construction with cyclical-flow transportation of rock
- Authors:
- Andrei S. Kondratenko
A high-performance technology for constructing cased wells is proposed. Essence of the technology is the advance insertion of the casing pipe into the sedimentary rock mass and the cyclical-flow transportation of the soil rock portions using the compressed air pressure supplied to the open bottomhole end of the pipe through a separate line. Results of mathematical modeling for the process of impact insertion of a hollow pipe into a soil mass in horizontal and vertical settings are considered. Modeling of the technology is implemented by the finite element method in the ANSYS Mechanical software. Parameters of the pipe insertion in the sedimentary rock mass are determined - value of the cleaning step and the impact energy required to insert the pipe at a given depth. Calculations were performed for pipes with a diameter from 325 to 730 mm. Insertion coefficient is introduced, which characterizes the resistance of rocks to destruction during the dynamic penetration of the casing pipe in one impact blow of the pneumatic hammer. An overview of the prospects for the application of the proposed technology in geological exploration, when conducting horizontal wells of a small cross-section using a trenchless method of construction and borehole methods of mining, is presented. A variant of using the technology for determining the strength properties of rocks is proposed. Some features of the technology application at industrial facilities of the construction and mining industry are considered: for trenchless laying of underground utilities and for installing starting conductors when constructing degassing wells from the surface in coal deposits. Results of a technical and economic assessment of the proposed technology efficiency when installing starting conductors in sedimentary rocks at mining allotments of coal mines are presented.
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Date submitted2020-06-14
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Date accepted2020-06-14
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Date published2020-06-30
Geochemical approach in assessing the technogenic impact on soils
- Authors:
- Galina I. Sarapulova
The soil assessment was carried out in the technogenically-affected area of Irkutsk Oblast with the geochemical approach as a key geoecological method using physical and chemical techniques of analysis and ecodiagnostics. Diagnostic signs of the disturbed natural properties of the soil were revealed up to a depth of 40 cm in the profile based on macro- and micromorphometric parameters. The content of heavy metals (HM) – Pb, Zn, Hg, and Cu with an excess of standards was determined, and empirical HM – pH correlations were obtained by statistical clustering of the data array. The contributions of additional factors affecting the chemical element distribution in the soil layer were investigated. Significant soil contamination with sulfates and the possibility of implementing the ion-exchange of HM andfor element immobilization were revealed. It was shown that reactions with sulfates and the influence of pH, HM exchange processes involving mobile K and P can determine the nature of the described chemical element distribution in the multi-factor-contaminated technogenic soil. However, the effectiveness of such types of interaction is different for each metal and also depends on the quantitative ratio of substances and soil characteristics, even under a minor change in pH. Two-parameter correlations of HM distribution in sulfate-contaminated soils confirmed the different degrees of involvement of chemical elements in these types of interactions. The results obtained and the identified factors are of applied significance and can be used as the basis for geoecological differentiation of the contaminated soil, as well as for determining local geochemical fields in the technogenesis zone. Areas of advanced research are related to three-dimensional modeling for a more complete study of the cause-and-effect relationships of geochemical parameters.
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Date submitted2020-05-07
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Date accepted2020-05-24
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Date published2020-06-30
Study of the technogenesis of the Degtyarsky mine by audio-magnetotelluric express sounding
- Authors:
- Vadim A. Davydov
The audio-magnetotelluric express sounding was performed at four sections crossing the mine field of the currently not functioning Degtyarsky mine. Field measurements were carried out by a universal broadband receiver “OMAR-2m” with active electromagnetic field sensors developed at the Institute of Geophysics UB RAS. Based on the obtained data, deep sections of the electrophysical parameters of the medium – apparent resistivity and effective longitudinal conductivity – are drawn. The nature of the geoelectric structure of the section allows mapping of the major lithochemical contamination plume and identifying the tectonic disturbance zones that drain aggressive mine waters. The mine waters of the Degtyarsky mine are a source of dangerous technogenic pollution. Despite the neutralization of surface runoff, underground routes of acidic water migration occur along tectonic cracks, primarily in the zone of the regional Serovsko-Mauksky fault. Tectonic zones in the mine area contain contaminated fissure-vein water, which is transited at a depth of 70 to over 200 m. Discharging ascending springs of such waters can be located at a great distance from controlled hydrological objects and pollute sources of drinking and household water supply. Urban development in the western and eastern parts of Degtyarsk does not fall within the distribution zone of polluted water. The southern part of the city is located beyond the watershed of the mine water flow area, but a danger of local contamination by tectonic disturbance zones remains possible. The worst environmental situation is observed in the northern outskirts of Degtyarsk, which falls into the area of heavy pollution of underground and surface waters. Besides, acidic fumes from the flooded Kolchedanny quarry can affect the health of city residents when emitted to the atmosphere.
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Date submitted2019-04-28
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Date accepted2019-06-28
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Date published2019-10-23
Determination of Optimal Fluorine Leaching Parameters from the Coal Part of the Waste Lining of Dismantled Electrolytic Cells for Aluminum Production
- Authors:
- N. V. Nemchinova
- A. A. Tyutrin
- V. V. Somov
When aluminum is obtained by electrolysis of cryolite-alumina melts when the baths are sent for capital repairs, a solid technogenic product is formed – waste lining of electrolytic cells (WLEC). The volume of formation of WLEC is 30-50 kg per 1 ton of aluminum. Currently, it is mainly stored at landfills near industrial enterprises, causing harm to the environment. However, this technogenic raw material contains valuable components (fluorine, aluminum, sodium) that can be extracted to produce fluoride salts, which are in demand during the electrolytic production of aluminum. The objects of research were samples of the coal part of the waste lining of dismantled S-8BM (E) type electrolytic cells of «RUSAL Krasnoyarsk» JSC (Krasnoyarsk) of RUSAL company. According to the X-ray experiment diffraction analysis (using a Bruker D8 ADVANCE diffractometer) of the phase composition of the samples, it was found that the main fluorine-containing compounds are cryolite, chiolite, sodium and calcium fluorides. The total fluorine content in the studied samples averaged 13.1 %. We conducted studies on the leaching of fluorine from WLEC with a solution of caustic alkali (NaOH concentration – 17.5 g/dm 3 ). The process was carried out in a mechanically agitated reactor using a BIOSAN MM-1000 top drive laboratory stirrer with a two-blade nozzle. By the method of mathematical planning of a three-factor experiment, the mutual influence of three leaching conditions on the optimization parameter was established – the extraction of fluorine in solution (in percent). The maximum recovery of fluorine from WLEC to the leach solution averaged 86.4 % and was achieved with the following indicators:processtemperature–95 ° C, the ratio ofliquidtosolidphase–9:1,duration– 210 min.
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Date submitted2018-05-03
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Date accepted2018-07-07
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Date published2018-10-24
Regularities of material destruction of the impactor in repeated single punch
- Authors:
- V. I. Bolobov
- Le Tkhan' Bin
The technique and the results of experiments on the study of the laws of the process of the cone-shaped tip of a freely falling impactor made of 38HM, U8, H12MF steels, subjected to typical heat treatment and additionally treated with cold, when they apply multiple (up to 10000) single impacts on granite under conditions approaching hydraulic impactor peaks. To explain the processes, we used the values of stresses σ к , arising at the contact area of the impactor and the rock, calculated using the developed mathematical model. It has been established that the process of wear of an impactor with multiple single blows proceeds in three stages separated by critical values, , which correspond to the strength characteristics of the material of the impactor demonstrated in these dynamic conditions. With a small number of strokes (n ≤ n * ) and the small size of the blunting area (stage I interaction) values σ c exceed of steel and it is exposed to local destruction at the contact site, which is recorded as a significant loss of the impactor’s mass; with n * < n ≤ n ** (stage II) the resulting stresses are not enough to destroy the material, but it is enough for its plastic deformation, accompanied by the movement of metal from the central part of the contact area to the peripheral and the destruction of part of the deformed metal by rock; with n > n ** (stage III) arising σ к do not reach the level and the decrease in the mass of the impactor is determined by the resistance of the steel to abrasion by the products of rock destruction, displaced by the impactor from the well. The treatment of impactors from all tested steels with cold leads to an increase in their wear resistance; The total depth of the holes punctured by the cold-treated H12MF steel impactor at the time of the interruption of the rock penetration is four times higher than that of the 38HM steel impactor subjected to typical heat treatment.
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Date submitted2016-09-15
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Date accepted2016-11-07
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Date published2017-02-22
Open-pit mining of lignin waste storage
- Authors:
- A. V. Mikhailov
The purpose of this paper is to develop performance criteria for fleet selection in surface mining of lignin as a raw material for factory-made fuel. The East Siberian Biotechnical Plant (ESBP) proposes to close the Lignin Waste Storage (LWS) at Tulun, Irkutsk Region of Russia. The LWS is a 9.6 ha facility used for the long-term storage of hydrolysis lignin and some fly ash. The project provided whole-year open-pit mining of lignin storage with one mining ledge within 3 years. Productivity – 1500 t/day or 447 000 t/year. Excavated lignin will be stockpile on the Pellet Plant territory for later processing. Part of this closure effort would involve constructing an artificial reservoir on the place of LWS. The objectives of this project were as follows: determine equipment needs and develop optimal procedures for the lignin excavation and transportation. Lignin moving may include site preparation, excavation, transportation and road surfacing. Lignin excavation is conduct by using techniques similar to those used for open-pit mining of peat. For this project, the excavator is the most important piece of equipment required for lignin removal and handling. The mining process consist of excavating the lignin (using Kraneks ЕК-270LC) and hauling it to pellet plant via six off-road tractors&semitrailers (John Deere 7730& ISON-8520).
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Date submitted2009-10-18
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Date accepted2009-12-09
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Date published2010-09-22
Influence of blocky-hierarchy structure of geological medium on the forming of natural and technogenic geodynamic fields in the North-West part of the Amur geoblock
- Authors:
- I. Yu. Rasskazov
- B. G. Saksin
On the example of the South-Argun uranium ore district of Zabaikalie consideration is given to the interaction of regional and local fields of stresses. The district includes a number of deposits prone to rock bursts. The performed analysis contains data on recent geodynamics of the explored part of the Amur geoblock as well as on geomechanical and geologo-structural materials of Tulukuev caldera and of Antey deposit. It is shown that with the use of the M.A. Sadovsky relationship the indices of local structural forms of a row are subjected to unified laws of deformation and fracturing. Conclusion was made that at the beginning of deposit exploitation the direction of action of stress field within rock mass conformed to regional one, and then it considerably changed under influence of large-scale mining operations.
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Date submitted2009-10-10
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Date accepted2009-12-02
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Date published2010-09-22
Deformational precursors of technogenic earthquakes in mining the hydrocarbon deposits
During monitoring since 2005 to 2008 at the Astrakhan gas-field it has been recorded three technogenic earthquakes. Results of geodetic levelling for the given period allow to approve that seismic event is preceded by raisings of a surface and its subsequent subsidence as a its result of unloading. That allows to use geodetic levelling for the forecast of technogenic seismic phenomena for oil and gas fields.
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Date submitted2009-10-01
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Date accepted2009-12-02
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Date published2010-09-22
Specific manifestations of tectonic and seismic activity in Kuzbass
- Authors:
- A. I. Ekimov
- S. V. Tsirel
The conducted observations demonstrated the substantial growth and variation of nature of tectonic and seismic activity in Kuzbas. Growth of geodynamic risks is marked. Methods for study of observable processes are suggested.