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Date submitted2024-06-12
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Date accepted2024-07-18
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Date published2024-07-26
Development of parameters for an industry-specific methodology for calculating the electric energy storage system for gas industry facilities
- Authors:
- Ivan S. Tokarev
The issue of determining the main parameters of electric energy storage systems – power and energy intensity – is being considered, the determination of which is a fundamentally important task when introducing such devices into the power supply systems of enterprises for both technical (technological) and economic reasons. The work analyzes problems that can be solved by installing electricity storage systems at gas industry facilities. An industry-wide methodology has been developed for calculating the parameters of an electricity storage system based on traditional methods and methods aimed at minimizing the standardized cost of electricity with adaptation to the conditions of the gas industry. A distinctive feature of the presented methodology is the ability to determine the power and energy intensity of electricity storage systems when performing several functions. The methodology was tested at a typical gas industry facility – the Yarynskaya compressor station of OOO Gazprom Transgaz Ukhta, a characteristic feature of which is an autonomous power supply system. An example is given of calculating the electricity storage normalized cost using an improved LCOS indicator, which takes into account the effect of changing the fill factor of the electrical load schedule on the amount of gas consumption by a power plant for its own needs. To confirm the economic efficiency of introducing electricity storage systems calculated using the above methodology, calculations of the integral effect, net present value and efficiency index are presented.
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Date submitted2023-05-19
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Date accepted2024-03-05
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Date published2024-08-26
Development and research of backfill compounds with improved elastic and strength properties for oil and gas well lining
This article describes operations from the well construction cycle where the cement rock behind the casing is subjected to dynamic action (impacts of the drill stem during drilling and normalization of the cement sleeve, secondary drilling operations, hydraulic fracturing, etc.). The developed cement mortar compositions were tested following API 10B-2, API 10B-6, API STD-65-2, and GOST 28985-91 standards. The composition of the cement system without the use of imported components (CM-5) was developed, which improved elastic and strength properties compared to existing industry solutions. An improvement in the elastic and strength features and technological properties of cement rock when using epoxy resins was identified, the optimal composition of the cement-and-epoxy grout was determined, and the internal structure of the formed backfill rock, its permeability, and porosity were studied.
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Date submitted2022-05-20
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Date accepted2023-04-03
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Date published2024-02-29
Impact of carbon dioxide on the main geotechnical quality criteria and preparation cost of cemented paste backfill
There is a global upsurge in the use of cemented paste backfill (CPB) for various mining functions. However, the cost of the Portland cement binder is prohibitive, thus warranting strategies to reduce cement usage without overly diminishing the CPB quality. Since carbon dioxide is used for patented sand moulding processes, this study is premised on that physicochemical ability of CO2 to enhance the curing of consolidated inorganic materials. It evaluated the impact of carbon dioxide on the uniaxial compressive strength UCS and preparation cost of CPB standard samples (ASTM C109). The preparation cost was delimited to the purchase cost of the Portland cement. The backfill material was silica sand tailings with 4.5 wt.% Portland cement binder and a water-cement ratio of 7.6. Distilled water of pH 5.4 was used for the control samples while variable amounts of carbon dioxide were dissolved in distilled water to generate carbonated mixing water with pH values of 3.8; 4 and 4.2. The lower the carbonated water pH, the higher is the CO2 concentration. UCS tests were conducted on the samples after curing for 3, 7, 28, and 90 days. There was an observable increase in the UCSs and reduction in curing time with increasing carbon dioxide. Samples prepared with carbonated water of pH 3.8 had almost double the strength of those prepared with pure distilled water of pH 5.4, implying that more dissolved CO2 corresponds to higher CPB strength. This is supported by the trendline equations for the graphical simulation of strength on curing time. Thus, CPB with much less binder can be expected to attain the requisite UCS if carbon dioxide is incorporated. The average reduction in Portland cement consumption was 0.61 %, which translates to a cost saving of the same percentage points. If calculated over the operational life of a mine, this is a massive saving of millions of dollars.
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Date submitted2022-09-27
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Date accepted2023-04-03
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Date published2023-12-25
The study of displacing ability of lignosulfonate aqueous solutions on sand packed tubes
This paper presents the findings of laboratory studies of rheological properties and oil displacing ability of aqueous solutions of technical grade lignosulfonate done on the sand packed tube models. The solutions containing lignosulfonate can be useful as displacement agents in development of watered reservoirs with heterogeneous porosity and permeability. When used at high concentrations, technical grade lignosulfonate can achieve selective shut-off while maintaining the reservoir pressure. The oil displacement efficiency is improved by means of redistributing the flows and selective isolation of high-permeability zones. The use of such compositions allows increasing the sweep of low-permeability reservoir zones by created pressure differential and displacing the residual oil.
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Date submitted2022-08-10
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Date accepted2023-02-28
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Date published2024-02-29
Selection of the required number of circulating subs in a special assembly and investigation of their performance during drilling of radial branching channels by sectional positive displacement motors
The task of sludge removal to the surface during construction of directional and horizontal wells and strongly curved radial channels is relevant. For stable operation of technical system “Perfobore”, it is proposed to use a circulating sub that ensures efficient cleaning of channel wellbore from the drilled rock. Two schemes of technical system “Perfobore” are considered, consisting of two seven-meter coiled tubing, a positive displacement motor, a bit and one circulating sub in the first scheme and two subs in the second scheme. For each of the schemes CFD modeling was implemented to determine values of pressure and speed. It was found out that the use of two circulating subs in the assembly is more efficient. In order to confirm the numerical experiment, bench tests were carried out. It was determined that the designed circulating sub can eject up to 25 % of pumped drilling fluid. The bench tests of full-size technical system “Perfobore” for drilling 14-meter channels with two circulating subs showed that the axial load on positive displacement motor produced by hydraulic loader was 3000 N and pressure drop depending on flow rate was 1.5-2.0 MPa. This allows the motor to operate at maximum power.
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Date submitted2022-10-17
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Date accepted2023-02-13
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Date published2023-04-25
Environmental geotechnology for low-grade ore mining with the creation of conditions for the concurrent disposal of mining waste
Due to the constantly deteriorating environmental situation in the regions with mining enterprises, the article considers the topical issue of disposing the maximum possible volume of waste from the mining and processing of low-grade ferrous ores through the creation of an effective underground environmental geotechnology. Traditional procedure with descending mining of reserves with a caving system does not allow waste to be disposed of in a gob. The idea is to use geotechnology based on the ascending order of mining the ore body, room excavation, leaving truncated pillars, and staggered arrangement of adjacent rooms in height, which makes it possible to form containers for waste disposal in the form of a cementless backfill. The main characteristics of the proposed procedure are investigated and compared with the traditional procedure of low-grade iron ores mining. It was established that from the point of view of the complete extraction of reserves and the unit costs for the preparatory-development operations, the processes are comparable, while in terms of the mining quality, the proposed option is much more efficient. Evaluation of environmental geotechnology by the criterion of waste disposal, performed according to the proposed methodology, showed that the combination of these technical solutions ensures the placement in the formed gob from 80 to 140% of all waste generated during the mining and beneficiation of low-grade iron ores.
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Date submitted2022-07-15
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Date accepted2022-12-13
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Date published2023-02-27
Mathematical modelling of displacement during the potash ores mining by longwall faces
In favourable mining conditions, in particular at the Starobinskoye potash deposit (Belarus), longwall mining systems are used. They cause a high human-induced load on the subsoil, including intense deformation of the ground surface. The presented investigations are aimed at studying the dynamics of the ground surface displacement during the longwall face advance. Mathematical modelling was carried out in an elastic-plastic formulation with numerical implementation by the finite element method. The condition for the roof rocks collapse was opening of the contact between the seams when its boundaries were reached by shear fractures or formation of the tensile stresses area at the outcrop. With the working front advance, an increase in subsidence is observed, followed by its stabilization to a value determined by the process parameters of mining operations and the physical and mechanical properties of collapsed rocks. In this case, each point of the ground surface experiences sign-alternating horizontal deformations: when the front approaches, it causes tension, and when it moves away, compression. The obtained results of mathematical modelling are in good agreement with the data of instrumental measurements of the ground surface displacements, which indicates the adequate description of the rock mass deformation during the slice excavation of sylvinite seams by longwall faces.
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Date submitted2021-03-18
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Date accepted2021-11-30
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Date published2021-12-27
Deformations assessment during subway escalator tunnels construction by the method of artificial freezing of soil for the stage of ice wall formation
- Authors:
- Evgenii M. Volokhov
- Diana Z. Mukminova
The work is devoted to the study of the processes of displacement and deformation of the surface during the escalator tunnels construction of the subway by the method of artificial freezing of soils. The features of the construction and freezing technology, the rocks characteristics in which the escalator tunnels made are considered. The data of specially organized, full-scale surveying observations of deformations on the earth surface are presented. The main factors influencing deformation processes in the frozen strata of a layered inhomogeneous rock mass with inclined tunneling are determined, the complexity of the predictive task and the need to simplify the design scheme are shown. The work is focused on the assessment of the least studied geomechanical processes of soil heaving-uplifts and deformations during the periods of active and passive freezing stages. When studying the displacements processes of the earth surface and rock mass, the finite element method and analysis of the obtained data using field observations of displacements were used. A simplified calculation scheme is proposed for modeling, which allows taking into account the uneven influence of frozen rocks of an inhomogeneous layered rock mass with a large inclined tunneling. The satisfactory convergence of the data of field surveying observations on the earth surface and the results of modeling geomechanical processes for the period of active and passive freezing stages is shown. The proposed calculation scheme is recommended for the prediction of deformation at the stages of underground construction, characterized by the development of the most dangerous tensile deformations of buildings and structures on the surface.
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Date submitted2021-03-05
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Date accepted2021-04-28
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Date published2021-09-20
Rational design justification of the tunnel boring shield executive body for the conditions of the mines of Saint Petersburg Metrostroy
The article discusses the features of running tunnels in difficult mining and geological conditions of the Saint Petersburg Metrostroy using modern tunnel boring shields of Herrenknecht company with hybrid executive bodies equipped with a incisors and rock cutters. The work of a hybrid executive body is analyzed when driving along a heterogeneous bottomhole massif consisting of Cambrian clay with limestone interlayers. Theoretical and experimental studies of vibroactive cones, a graphical representation of the dependence of the depth of their penetration on the axial force and axial force together with the applied shock load (the dependences of the penetration depth are interpreted as a linear dependence) have been carried out. An increase in the intensity of destruction of a heterogeneous bottomhole massif consisting of Cambrian clay and limestone interlayers using vibroactive rock-cutting tools (spiked roller) was theoretically and experimentally confirmed, while the growth of the penetration rate is determined depending on the number of their parameters. The design is considered, the principle of operation and the method of power calculation of a rotary executive body equipped with vibroactive cutters are described, on the basis of which a nomogram of the dependence of the torque and performance of the tunnel boring shield on the feed rate of the executive body to the bottom is built.
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Date submitted2021-01-25
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Date accepted2021-02-22
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Date published2021-04-26
Conducting industrial explosions near gas pipelines
The problem to ensure the safety of objects which are in the area of blasting operations, ensuring the destruction of hard rocks, remains relevant. The article presents the results of a large-scale experiment to determine the safe conditions for conducting drilling and blasting operations near the active gas pipeline. The simplest and most reliable way to ensure the safety of the protected object from seismic impact is to reduce the intensity of the seismic wave, which is achieved by changing the parameters of drilling and blasting operations. This requires research to determine the impact of blasting operations on the parameters of seismic waves and the development of methods for measuring these parameters. The paper presents a detailed analysis of the seismic blast wave impact on the displacement of the ground and the model gas pipeline. The features of seismic monitoring during blasting operations near the active gas pipeline are shown. The seismic coefficients and attenuation coefficient of seismic waves are determined. It is proved that the readings of the seismic receivers on the surface and in the depth of the massive differ by two or more times.
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Date submitted2020-05-21
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Date accepted2020-10-05
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Date published2020-11-24
Method of calculating pneumatic compensators for plunger pumps with submersible drive
- Authors:
- Eduard O. Timashev
One of the most promising ways to improve the efficiency of mechanized oil production is a plunger pump with a submersible drive, which allows obtaining harmonic reciprocating movement of the plunger. In the pumping process of well products by plunger pumps, oscillations in the velocity and pressure of the liquid in the lifting pipes occur, which lead to an increase in cyclic variable loads on the plunger, a decrease in the drive life period and the efficiency of the pumping unit. To eliminate the pulsation characteristics of the plunger pump and increase the reliability indicators of the pumping unit (in particular, the overhaul period), pneumatic compensators can be used. A method for calculating the optimal technological parameters of a system of deep pneumatic compensators for plunger pumping units with a submersible drive, based on mathematical modeling of hydrodynamic processes in pipes, has been developed. Calculations of the forming flow velocity and pressure in the lifting pipes of submersible plunger units equipped with pneumatic compensators (PC) have been carried out. Influence of the PC technological parameters on the efficiency of smoothing the oscillations of velocity and pressure in the pipes has been analyzed. Non-linear influence of the charging pressure and PC total volume on the efficiency of their work has been established. Optimal pressure of PC charging, corresponding to the minimum pressure in the tubing during the pumping cycle for the considered section of the tubing, is substantiated. Two ultimate options of PC system placement along the lifting pipes are considered. In the first option, PC are placed sequentially directly at the outlet of the plunger pump, in the second - evenly along the lift. It is shown that the first option provides the minimum amplitude of pressure oscillations at the lower end of the tubing and, accordingly, variable loads on the pump plunger. Nature of the pressure and flow velocity oscillations in the tubing at the wellhead for both options of PC placement has similar values .
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Date submitted2020-05-05
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Date accepted2020-10-05
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Date published2020-11-24
Assessment of the Influence of Water Saturation and Capillary Pressure Gradients on Size Formation of Two-Phase Filtration Zone in Compressed Low-Permeable Reservoir
The paper examines the influence of capillary pressure and water saturation ratio gradients on the size of the two-phase filtration zone during flooding of a low-permeable reservoir. Variations of water saturation ratio s in the zone of two-phase filtration are associated with the pressure variation of water injected into the reservoir; moreover the law of variation of water saturation ratio s ( r , t ) must correspond to the variation of injection pressure, i.e. it must be described by the same functions, as the functions of water pressure variation, but be subject to its own boundary conditions. The paper considers five options of s ( r , t ) dependency on time and coordinates. In order to estimate the influence of formation and fluid compressibility, the authors examine Rapoport – Lis model for incompressible media with a violated lower limit for Darcy’s law application and a time-dependent radius of oil displacement by water. When the lower limit for Darcy’s law application is violated, the radius of the displacement front depends on the value of capillary pressure gradient and the assignment of s function. It is shown that displacement front radii contain coefficients that carry information about physical properties of the reservoir and the displacement fluid. A comparison of two-phase filtration radii for incompressible and compressible reservoirs is performed. The influence of capillary pressure gradient and functional dependencies of water saturation ratio on oil displacement in low-permeable reservoirs is assessed. It is identified that capillary pressure gradient has practically no effect on the size of the two-phase filtration zone and the share of water in the arbitrary point of the formation, whereas the variation of water saturation ratio and reservoir compressibility exert a significant influence thereupon.
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Date submitted2020-05-29
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Date accepted2020-09-16
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Date published2020-11-24
Numerical modeling of a double-walled spherical reservoir
Extensive and important class of multilayer shell structures is three-layer structures. In a three-layer structure, a rigid filler plays an important role, due to which the bearing layers are spaced that gives the layer stack high rigidity and durability with a relatively low weight. By combining the thicknesses of the bearing layers and the filler, the desired properties of a three-layer shell structure can be achieved. Compared with traditional single-walled, three-layer construction has increased rigidity and durability, which allows reducing the thickness and weight of the shells. In order to reduce the metal content of the spherical reservoir for storing liquefied gases, this work considers the design of a double-walled reservoir, in which the inter-wall space is filled with reinforced polyurethane. Numerical modeling made it possible to determine the parameters of the stress-strain state of the structure with an error of no more than 5 %. It has been established on the example of a reservoir with a volume of 4000 m 3 that the spatial structure of the spherical reservoir wall can reduce the metal content up to 19 %. Field of application for the research results is the assessment of the stress-strain state of spherical reservoirs at their designing. Method for building the structure of a double-walled spherical reservoir in the SCAD software has been developed, which allows calculating the stress-strain state (SSS) by the finite element method. Numerical model of a double-walled spherical reservoir has been developed. It was found that to obtain calculation results with an error of P ≤ 5 % the size of the final element should not exceed 300×300×δ mm. Design of a double-walled spherical reservoir was investigated. Design parameters have been established to ensure the operational reliability of the structure with a decrease in metal content in comparison with a single-wall reservoir by 19 %.
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Date submitted2019-07-09
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Date accepted2019-09-26
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Date published2020-04-24
Development of mathematical models to control the technological properties of cement slurries
Oil and gas producing enterprises are making increasingly high demands on well casing quality, including the actual process of injection and displacement of cement slurry, taking into account requirements for the annular cement level, eliminating possible hydraulic fracturing, with developing a hydraulic cementing program. It is necessary to prevent deep invasion of cement slurry filtrate into the formation to exclude bridging of productive layers. It is impossible to fulfill all these requirements at the same time without application of modifying additives; complex cement compositions are being developed and applied more often. Furthermore, need to adjust cement slurries recipes appears for almost every particular well. In order to select and justify cement slurries recipes and their prompt adjustment, taking into account requirements of well construction project, as well as geological and technical conditions for cementing casing strings, mathematical models of the main technological properties of cement slurries for cementing production casing strings in the Perm Region were developed. Analysis of the effect of polycarboxylic plasticizer (Pl) and a filtration reducer (fluid loss additive) based on hydroxyethyl cellulose (FR) on plastic viscosity (V), spreadability (S) and filtration (F) of cement slurries is conducted. Development of mathematical models is performed according to more than 90 measurements.
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Date submitted2019-05-14
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Date accepted2019-07-05
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Date published2020-04-24
Development of spacer fluids and cement slurries compositions for lining of wells at high temperatures
Article is devoted to creation of new compositions of process solutions for lining of directional wells at high temperatures. Developed compositions provide high durability characteristics of cement stone. It is shown that with an increase in packing density of cementing slurry components durability characteristics increase and porosity and permeability of cement stone decrease, whereas an increase in temperature and pressure leads to a significant increase in compressive and bending durability, which is associated with presence of quartz in them. It has been established that introduction of special structure-forming additives to the composition of developed cementing solutions allows formation of sedimentation-resistant cement systems that can provide an increase in durability characteristics of cement stone and, in general, quality lining of directional wells. Study of rheological properties of developed cementing compositions showed that the systems have high yield strength at increased temperatures and pressures. Developed compositions of water-based spacer fluids increase the cleansing degree for both casing and rocks surfaces from mud and clay cake residues, which improves the cementing quality of oil and gas wells. Mechanism for increasing the washing ability of spacer fluids and durability characteristics of cement stone, depending on composition and properties of their constituent components, is disclosed.
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Date submitted2018-11-20
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Date accepted2019-01-14
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Date published2019-04-23
Low-density cement compositions for well cementing under abnormally low reservoir pressure conditions
- Authors:
- N. I. Nikolaev
- E. L. Leusheva
The paper considers variants of lightweight cement compositions with additives of various substances, such as clay components, ash systems, silica additives, kerogen, gilsonite, microspheres, as well as the process of cement slurry aeration. Recommendations on the use of compositions in different conditions are presented. A decrease in the density of the solution is achieved not only due to the low density of the materials used, but also as a result of an increase in the water-cement ratio. In such conditions, it is not possible to ensure the formation of a durable and impermeable cement stone in the well, which creates high quality inter-reservoir insulation. The characteristics of the physical and mechanical properties of existing lightening additives are given, which allows determining the most rational conditions for the use of cement slurries for improvement of the well cementing quality.
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Date submitted2018-05-14
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Date accepted2018-07-15
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Date published2018-10-24
Experience of Integrated use of gold-bearing raw material in the production of precious metals
- Authors:
- V. V. Zhmurova
- N. V. Nemchinova
With the depletion of rich gold-bearing ores, the processing started to use polymetallic ores, which, in addition to precious metals, contain other elements that could be valuable after recovery. The problem of using such ores is extremely difficult because of the high cost of recovery of associated valuable components. The paper presents the results of studies on the integrated use of extracted gold-bearing raw materials based on the example of the Berezitovoye deposit (Amurskaya oblast), they have low content of precious metals and many heavy non-ferrous metals (copper, lead). Experimental work was carried out to obtain copper by the method of cementation from solutions formed after the leaching of the impurities of gold-containing cathode deposits with hydrochloric acid. The cementing metal was iron turnings (waste products of the turning shop of the enterprise). Next, it was proposed to use cemented copper as a collector during re-melting of slags – wastes of processing of low-grade polymetallic ores containing precious metals. The authors obtained ingots of alloyed gold with gold weight fraction of 16 %, which meets the requirements of TU 117-2-7-75 on the content of non-ferrous metals. During hydrochloric acid treatment of cathodic deposits silver partially passed into the solution, it was recovered together with cemented copper and, in subsequent melting, passed into alloyed gold. Thus, the method proposed by the authors helps to reduce the content of precious metals in the «incomplete production cycle» of the gold recovery factory. The opportunity of selling the cementation copper at the enterprises specializing on manufacturing of jewels is shown; the expected economic effect at the same time amounted to more than 1.8 million rubles.
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Date submitted2018-01-15
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Date accepted2018-02-28
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Date published2018-06-22
About the role of hydrafed calcium carboaluminates in improving the technology of complex processing of nephelines
- Authors:
- V. M. Sizyakov
- V. N. Brichkin
The scientific justification and development of the method for industrial synthesis of complex aluminates of alkaline earth metals is an innovative solution that determined several directions in the development of technology for complex processing of nepheline raw materials. It ensures the production of high-quality metallurgical alumina, the effective utilization of nepheline sludge and production of new types of multipurpose by-products. The modern development of these technical solutions is associated with ensuring the energy efficiency of the synthesis of hydrafed calcium carboaluminates (HCCA) and increasing the level of purification of aluminate solutions. The conditions for synthesizing HCCA with the use of calcareous materials of natural and technogenic origin have been experimentally determined, which makes it possible to isolate the average particle diameter as one of the determining factors of this process. The effect of the turnover of the hydrogarnet sludge on the removal of kinetic limitations in the process of deep desalination of aluminous solutions is theoretically justified. The conditions of a two-stage dosage of HCCA are experimentally determined. It is shown that the optimum ratio of the amount of the reagent supplied in the first and second stages is about 3: 2. At the same time, the maximum degree of precipitation of silica provides the production of aluminate solutions with a silicon module at the level of 95,000, which is achieved by using a HCCA synthesized based on chemically precipitated calcium carbonate in the processing of wastes from the production of mineral fertilizers.
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Date submitted2015-08-25
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Date accepted2015-10-24
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Date published2016-04-22
The modern technology of drilling and casing of well during the exploration of gas hydrates
- Authors:
- N. I. Nikolaev
- Lyu Tyanle
In the paper, the perspectives of exploration and completion of gas hydrate fields and the drilling problems in the gas hydrates of the northwest china are studied. It has been established, that the main reasons of complications in the Muli field are the secondary hydrate formation on the walls of the well and drilling assembly and ice formation inside the set cement during the well drilling and completion in permafrost. It has been shown, that in the areas with permafrost during the drilling of the layers containing gas hydrates, temperature and pressure changes can lead to the dissociation of hydrates. At the same time, pressure increase in the annular space due to the gas release, can lead to the secondary formation of gas hydrates, drill string stuck, ceasing of drilling fluid circulation, which is the reason of serious trouble in the wellbore. The results of the research on the development of drilling fluids compositions, which lower the drilling troubles of permafrost, are presented. Comparative experiments have been conducted to evaluate the effectiveness of thermodynamic and kinetic inhibitors, which prevent the repeated hydrate formation. It has been established, that the kinetic inhibitors have the clear advantage: they have good inhibiting effects even with low amounts of additives. In the laboratory conditions, the researches have been conducted to evaluate the phase equilibrium of gas hydrates during their reaction with the water solutions, containing kinetic inhibitor PVP. A thin clay drilling mud has been developed on the water base, providing the holding of the temperature in the level of –2 °С and its effectiveness for the gas hydrate fields in the PRC has been shown. Casing effectiveness of unstable rocks during the drilling in the conditions of negative temperatures inside the well largely depends on their physical-mechanical properties, composition and the technical indicators of cement materials. The authors suggest the composition of quick-setting cements based on aluminum binding materials. It has been established, that the analyzed compositions have the ability to considerably improve the results of cementing.
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Date submitted2015-07-14
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Date accepted2015-09-27
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Date published2016-02-24
Chemical and technological mechanisms of a alkaline aluminum silicates sintering and a hydrochemical sinter processing
- Authors:
- V. M. Sizyakov
Complex mineral raw material, as alkali aluminum silicates, is an interest for aluminum industry, chemical industry and for the production of constructional materials. They are well represented in the earth's crust, characterized by the complexity of material composition and variable content of the main components such as alumina, silica and alkalies. They often occur where due to the geological conditions there is no bauxite, for instance, in the United States, Canada, Venezuela, Mexico, Iran, Egypt, Portugal, Spain, Bulgaria and other countries. At the present time for the Russian economy the nephelines from this list are the most valuable and have the great concern for the raw materials balance of the national aluminum industry. Because of limited reserves the bauxites proportion of alumina produced from nephelines by sintering is 40 % and in time this proportion will increase due to the involvement in the production of new deposits of alkali aluminum silicates. Many of foreign companies have also shown interest to the complex processing of ores. The investigation of technology is based on the method of sintering ore with limestone. As a result, the after-sintering mixture consists of alkali metal aluminates and dicalcium silicate; after-sintering mixture is leached by circulating alkaline aluminate solution, alumina, soda and potash are thrown out from the solution. Dicalcium silicate (nepheline sludge) is processed to Portland. For the investigated after-sintering mixture the tendency shows the increasing of optimum sintering temperature with the lowering Al 2 O 3 content. With the increasing of silicate module (SiO 2 / Al 3 O 3 ) of the initial alkali aluminum silicates charges the temperature of after-sintering mixture formation increases. After-sintering mixtures that are on base of alkali aluminum silicates have different microstructure and the degree of crystallization in which b-С 2 S and sodium aluminate is improved with a decrease of the aluminate phase amount. Results of investigations show a very limited solubility of aluminate phase in dicalcium silicate, which theoretically justifies a sufficiently high level of useful components chemical extraction in the processing of different types of alkali aluminum silicates by sintering.
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Date submitted2015-07-14
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Date accepted2015-09-09
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Date published2016-02-24
Engineering and geomechanical forecast for waste disposal in underground caverns including earthquake-prone zones
- Authors:
- O. V. Kovalev
The article aims at obtaining representative scientifically based data to determine parameters of a necessary-safe condition of the rock massif (RM) in underground waste diposal caverns zones, including earthquake-prone zones. The main requirements for underground caverns for hazardous waste disposal and for their construction technology are described. The subject of the research is underground solution caverns in halogen rocks. Data for justification of safe waste disposal conditions in underground salt caverns and its stages are presented. A complex approach to the solution of the research problem is described. The main aspects of dynamic influence of seismic waves on underground caverns stability are considered. Taking into account seismic-risk zoning data on the research region some significant parameters of a possible seismic impact on the experimental cavern are calculated. The article points out the necessity of superincumbent rock and surface displacement assessment for the experimental site zone using the suggested complex approach and including the analysis of surveying data and results of rock mass geomechanical modeling.
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Date submitted2009-10-14
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Date accepted2009-12-28
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Date published2010-09-22
Geodynamic model of hydrogen sulphide’s formation in natural gas and oil in the process of rocks impulsive compression under conditions оf earthquakes
- Authors:
- A. V. Petukhov
By experiments, conducted on the installation like Bridgeman’s anvil it was determined that under conditions of high pressure, displacement deformations and elastic wave’s effect of short duration, sulphates are reclaimed by hydrocarbons. As a result of this reaction sulphur and hydrogen sulphide are produced.
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Date submitted2009-10-13
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Date accepted2009-12-14
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Date published2010-09-22
The evaluation of geodynamic consequences оf long-term exploration of lower cretaceous sediments at the Yamburg oil-gas condensate field with join of additional wells
Within the framework of the engineering design of the join up of additional wells of Lower Cretaceous sediments at the Yamburg oil-gas condensate field the evaluation of geodynamic consequences of long-term exploitation of the mentioned field was performed, as well as the hazardous geodynamic process permanent survey program was developed.
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Date submitted2009-10-04
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Date accepted2009-12-19
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Date published2010-09-22
Modeling of the volumetric stress-strain condition of the rock massive in the near mine which are crossing zone of weakening
- Authors:
- A. G. Protosenya
- D. N. Petrov
- M. G. Popov
According to geological data which was received at the Yakovlevsky deposit, the volumetric model was developed. This model taking into consideration the driving of the mine through zone of weakening. During the analysis of the stress-strain condition near the mine the character of distribution and numerical results of tangential and longitudinal stresses have been revealed. The zone of weakening affects to the distribution of stresses and displacements around the mine. To select the parameters of the lining support it is necessary to take into consideration weakenings and contacts in the ore massive and the distance for these zones.
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Date submitted2009-08-06
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Date accepted2009-10-10
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Date published2010-02-01
Allocation of tellurium from difficult on structure of sulfuric acid solutions
- Authors:
- S. B. Fokina
As the main source of reception of tellurium serve electrolytic copper refinery slimes. In the conditions of manufacture expansion and transition on technology decopperizing slimes by pressure leaching O 2 -H 2 SO 4 media, the solution (decopperized product) becomes the basic concentrator of tellurium. Extraction of tellurium from a decopperized (pressure-leached) liquid products is considered. The method allows to raise percent of extraction of tellurium from initial raw materials and to enrich pressure-leached solid product with precious metals.