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Date submitted2024-05-15
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Date accepted2024-11-07
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Date published2025-04-14
Metacarbonate rocks of the Paleoproterozoic Khapchan series (southeastern part of the Anabar Shield): mineral and chemical composition, metamorphic conditions
The mineral composition of metacarbonate rocks (silicate marbles and carbonate-silicate rocks) of the Khapchan series (southeastern part of the Anabar Shield) was studied, and the PT (pressure and temperature)-parameters of their formation were established. Silicate marbles contain calcite, dolomite, forsterite, clinohumite, spinel, enstatite, diopside, pargasite, meionite, phlogopite, and feldspars. Carbonate-silicate rocks are composed of calcite, quartz, feldspars, diopside, grossular, marialite, and vesuvianite. Carbonate-silicate rocks are significantly enriched in SiO2, Al2O3, FeO, Na2O, K2O, TiO2 and contain less MgO, CaO than silicate marbles. A difference was revealed in PT-parameters determined for silicate marbles (temperatures 700-900 °C and pressure no more than 8 kbar) and for carbonate-silicate rocks (temperatures 680-820 °C, pressures 8-15 kbar). Silicate marbles have a primary sedimentary nature, as evidenced by their rare-element composition and the presence of fragments of host terrigenous rocks. There is no doubt about the primary sedimentary nature of carbonate-silicate rocks, which are very similar in REE distribution spectra and in rare-element composition to silicate marbles. A number of features indicate that metacarbonate rocks have undergone metasomatic alteration. Thus, in silicate marbles, reaction rims are observed around orthopyroxene, forsterite, potassium feldspar, as well as quartz veins bordered by accumulations of phlogopite, feldspars, and diopside. In carbonate-silicate rocks, the development of secondary marialite on potassium feldspar has been established; the rare-element composition of garnet may indicate its metasomatic origin.
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Date submitted2024-05-03
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Date accepted2024-11-07
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Date published2025-04-02
Assessment of ancylite ore dressability by flotation method
For more than 50 years, most rare earth elements were extracted from carbonatite deposits, which can contain different rare earth phases, but the main extracted minerals are bastnaesite, monazite and xenotime. Many studies focused on the improvement and development of dressing circuits for ores of these minerals. However, in some carbonatite complexes, rare earth deposits are composed partly or mainly of ancylite ores. This type of rare earth ores was very poorly studied in terms of dressability – previous experiments with ancylite ores are rare and not productive enough. Ancylite is the main concentrator of rare earth elements in most carbonatite complexes of the Devonian Kola Alkaline Province (northwest Russia). Dressability of ancylite ore from the Petyayan-Vara carbonatite field in the Vuorijärvi alkaline-ultramafic complex was assessed using the flotation method. The complex is one of the most potential rare earth deposits associated with carbonatites in the Kola Region. Petrographic and mineralogical studies demonstrated the occurrence of abundant iron and barite oxide inclusions in ancylite, which imposes restrictions on physical separation of these three minerals. The study of petrogeochemical and mineralogical composition of fractions formed during mechanical grinding of ores to a size less than 2.0 mm showed that even at this stage of sample preparation, the finest-grained fractions (less than 0.071 mm) were enriched in ancylite (to 19 vol.% or more with a content of 15 vol.% in ore). Three classes of reagents were considered as collectors in flotation experiments: fatty acids, alkyl hydroxamic acids, and amino acid derivatives. The reagent from the amino acid derivative class was highly efficient. The use of such a collector in combination with sodium hexametaphosphate depressant made it possible to obtain a flotation concentrate in an open circuit with total rare earth oxides content 33.4 wt.% at 64.7 % extraction.
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Date submitted2023-06-25
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Date accepted2024-11-07
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Date published2025-02-25
Study of wormhole channel formation resulting from hydrochloric acid treatment in complex-type reservoirs using filtration and X-ray computed tomography methods
- Authors:
- Andrei A. Аbrosimov
The primary function of hydrochloric acid treatment (HAT) is to create the maximum number of high-conductivity channels in the near-wellbore zone of the reservoir to restore its permeability and enhance hydraulic connectivity between the undisturbed part of the formation and the well. The objective of this study is to physically model HAT on core samples from the Orenburg oil and gas condensate field and to research the impact of such treatment on the structure of the pore space of rocks related to complex-type reservoirs. The complexity of the rock's pore space and the low permeability of the formations are distinguishing features of the study object. For this reason, HAT is a widely applied method for production intensification, necessitating the verification of acid injection rates, where the success criterion is the formation of high-conductivity filtration channels (wormholes) in the near-wellbore zone. These channels significantly expand the drainage area of wells, thereby bringing additional reservoir sections into development. The study examined the characteristics of filtration channel development resulting from acid treatment. Their structure was characterized and analyzed using X-ray computed tomography. The complex study confirmed the accuracy of the selected injection rate and provided practical recommendations for enhancing the efficiency of HAT.
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Date submitted2024-03-22
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Date accepted2024-09-24
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Date published2025-02-25
Behaviour of cerium (III) phosphate in a carbonate-alkaline medium
- Authors:
- Tatyana E. Litvinova
- Stepan A. Gerasev
The article investigates the behaviour of rare earth metals in carbonate-alkaline systems. The results of experimental studies on rare earth element extraction from phosphogypsum, a large-tonnage industrial waste forming in production of phosphoric acid are presented. Using the liquid phase leaching method, it was possible to extract more than 53 % of rare earth elements from old phosphogypsum and more than 69 % from fresh phosphogypsum due to solid phase treatment with a 4 mol/l potassium carbonate solution at temperature 90 °C. The behaviour of model cerium (III) phosphate in a carbonate-alkaline medium is characterized: a solubility isotherm is obtained as well as the dependences of the degree of cerium extraction into solution on temperature, carbonate ion concentration, interphase ratio, stirring intensity, and pH. The ability of soluble rare earth element complexes to precipitate over time was established, which was confirmed using cerium and neodymium as an example. Within 240 h after the end of the experiment, approximately 25 % of cerium and 17 % of neodymium were precipitated from the liquid phase. A similar property was recorded in representatives of the light group and was not noted in elements of the heavy group. The ability to self-precipitate in future can serve as a basis for developing an alternative approach to separating rare earth metals into groups after extraction in a carbonate ion medium. Also, based on the analysis of experimental data, the mechanism of cerium (III) phosphate dissolution in a carbonate-alkaline medium was characterized. An assumption was made that rare earth metal phosphates dissolve sequentially passing into an insoluble carbonate and then into a soluble carbonate complex.
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Date submitted2024-04-12
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Date accepted2024-09-05
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Date published2024-11-12
Promising reagents for the extraction of strategic metals from difficult-to-enrich mineral raw materials
The need of the mining and processing industry for new types of directional reagents is due to the deterioration of the material composition of the processed ores. Low Au content (less than 0.5-1.0 g/t), finely dispersed Au inclusions (0.1-10.0 microns) in the ore, similar properties of the separated minerals have an extremely negative effect on flotation performance when using traditional reagents, which leads to significant losses of valuable metal with enrichment tailings. Expanding the range of domestic flotation reagents based on the latest achievements of fundamental research and their targeted application at mining and processing companies will compensate for the negative impact of the mineral composition of raw materials and ensure maximum extraction of strategic metals from difficult-to-enrich ores. The use of modern research methods (scanning electron and laser microscopy, UV spectrophotometry, XRF and chemical analysis) made it possible to visualize the adsorption layer of new reagents-collectors of a number of dithiocarbamates with different structures of a hydrocarbon radical and an organic modifier on the surface of gold-containing sulfides. The amount of adsorbed reagents on the surface of minerals has been experimentally determined. The specific features of the fixation of reagents on minerals of various compositions led to optimal correlations of their consumption in the flotation process. Scientifically based reagent regimes ensured an increase in the gold content in the concentrate and a decrease in the loss of gold with tailings by 5-6 % during flotation enrichment of the refractory ore of the Malinovskoe deposit.
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Date submitted2024-04-24
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Date accepted2024-09-24
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Date published2024-11-12
Study and justification of the combination of beneficiation processes for obtaining flake graphite from technogenic carbon-containing dusts
The most important task of modern production development is to provide the mineral and raw materials sector of the economy with resources included in the list of strategic raw materials, including flake graphite. In addition to natural raw materials, the source of its obtaining can be metallurgical production wastes not involved in processing. Development of metallurgical dust beneficiation technology will solve the problem of obtaining high-purity flake graphite with a crystal structure close to ideal and in demand in the production of high-tech materials. It will allow creating a renewable raw material base of graphite and utilising metallurgical production wastes. The research included the study of dust beneficiation by coarseness, magnetic and flotation methods, the influence of dust disintegration processes on beneficiation indicators. Based on the established technological properties of the components of dusts, magnetic, flotation and gravity beneficiation methods can be applied for their separation in different sequence. It is shown that dusts from different sites have different enrichability by these methods, and it should be taken into account when developing a complex technology of their processing. The degree of beneficiation increases in a row of dusts from the blast furnace shop (BF) – electric steel smelting shop (ESS) – oxygen-converter shop (OCS). The method of grinding has a significant influence on the separation indicators – at dry grinding in a centrifugal-impact mill with subsequent pneumatic classification the quality of graphite concentrates increases by 22.7 % of carbon for BF dust and by 13.48 % of carbon for ESS dust. OCS dust beneficiation indicators are high at coarse grinding with steel medium – mass fraction of carbon 96.1 %.
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Date submitted2023-09-08
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Date accepted2024-06-03
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Date published2024-12-25
Modern approaches to barium ore benefication
Barite is one of the critically important minerals in several industries, including the fuel and energy, nuclear, and medical sectors. For decades, its extraction did not require any complex techniques; however, with the depletion of rich barite-bearing veins around the world, the circumstances have changed. While the demand for barite is growing widely, it is necessary to optimize and improve the existing methods for benefication of barite and barite-containing ores, and create new approaches to extracting this mineral, as well as develop technogenic barite deposits accumulated in large quantities during the previous ore production. Dumps and tailings often demonstrate high barite content, while new mining technologies make its extraction cost-efficient. Russian and foreign papers of the last 14 years provide data on the current state of primary and technogenic deposits, areas of barite use and the approaches employed for its benefication. Considering the expansion of the range of barite applications, the growing need for the mineral in the oil and gas industry and the difficulties in developing new barite deposits in Russia, the importance of new approaches to the enrichment of ore tailings in polymetallic deposits is revealed.
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Date submitted2023-06-21
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Date accepted2023-10-25
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Date published2024-08-26
Specific action of collector from phosphoric acid alkyl esters class in flotation of apatite-nepheline ores
Increasing amount of apatite-nepheline ores with complex mineral composition involved in processing, growing content of the associated minerals in ore which are similar in their floatability to apatite lead to the necessity of using highly selective collectors. Non-frothing flotation method gave a comparative assessment of floatability of pure minerals and demonstrated a high selectivity of the action of phosphoric acid esters in relation to apatite. The effect of four reagent modes differing in the number of selective synthetic collectors was studied using the example of flotation of an apatite-nepheline ore sample containing 17.27 % apatite and 40.18 % nepheline. Mineralogical analysis of crushed ore showed that it contained two apatite varieties – coarse-grained free and finer poikilitic as inclusions in rock-forming minerals. Free apatite opens and occurs as open grains even in coarse-grained (+0.16 mm) grades. Poikilitic apatite occurs as intergrowths with different minerals, mainly with nepheline and its alteration products (natrolite, spreustein, sodalite, etc.), and pyroxene. Optical microscopy demonstrated that a growing share of reagent from the phosphoric acid oxyethylated esters class in the composition of the collector mixture allows improving the quality of the produced apatite concentrates by reducing the number of apatite intergrowths with nepheline and pyroxenes in the concentrates. In the concentrate obtained in the most selective reagent mode, the intergrowths are characterized by a 50/50 and higher ratio in favour of apatite. Concentrates of lower quality comprised intergrowths with lower apatite content, to 20/80 or less.
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Date submitted2024-04-08
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Date accepted2024-06-13
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Date published2024-12-25
Analysing the problems of reproducing the mineral resource base of scarce strategic minerals
The results of studying the scarcity of strategic minerals in the Russian Federation are presented, domestic consumption of which is largely provided by forced imports and/or stored reserves. Relevance of the work is due to aggravation of the geopolitical situation and a growing necessity to meet the demand of national economy for raw materials from own sources. Analysis of the state of mineral resource base of scarce minerals in the Russian Federation was accomplished, problems were identified and prospects for its development were outlined taking into account the domestic demand for scarce minerals, their application areas and the main consumers. Reducing the deficit through the import of foreign raw materials and the development of foreign deposits does not ensure the reproduction of the domestic mineral resource base, independence of the country from imported raw materials as well as additional competitive advantages, economic stability and security. It was ascertained that a major factor holding back the development of the mineral resource base is insufficient implementation of new technological solutions for the use of low-quality ore. Improving the technologies in the industry is relevant for all types of scarce minerals to solve the problem of reproducing their resource base. Taking into account the prospects for the development of the resource base for the minerals under consideration (manganese, uranium, chromium, fluorspar, zirconium, titanium, graphite) requires a set of legal and economic measures aimed at increasing the investment attractiveness of geological exploration for subsoil users at their own expense without attracting public funding. The proposed measures, taking into account the analysis of positive experience of foreign countries, include the development of junior businesses with expansion of the “declarative” principle, the venture capital market, various tax incentives, preferential loans as well as conditions for the development of infrastructure in remote regions. The proposed solution to the problem of scarcity of strategic minerals will make it possible in future to present measures to eliminate the scarcity of certain types of strategic minerals taking into account their specificity.
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Date submitted2023-07-07
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Date accepted2023-12-27
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Date published2024-12-25
A new insight into recording the mineral composition of carbonate reservoirs at well killing: experimental studies
Well killing operation remains an important technological stage before well workover or servicing, during which filtrate penetrates the bottomhole area of the formation. The impact of process fluids and their filtrate on rock has a significant influence on permeability and porosity of carbonate reservoirs, which decrease due to fines migration. There are few known scientific studies of the interaction of killing fluid filtrate with carbonate rock and fines migration. In our experiments, an aqueous phase was used which is the basis for well killing in pure form, for the preparation of blocking agents and is used in reservoir pressure maintenance system. Core samples taken from the pay of the reservoir were used to simulate the well killing process with generation of reservoir thermobaric conditions. Killing fluid filtrate was kept for seven days, which characterizes the average workover time at flowing wells in the fields of the Perm Territory. Using micro-X-ray tomography and scanning electron microscope, images were obtained before and after the experiment, which allowed confirming a decrease in total number of voids due to fines migration and, as a consequence, a decreasing permeability of samples. Measurement of pH and fines concentration in the aqueous phase was performed before and after the experiment and pointed to mineral reactions occurring as a result of rock dissolution. The results of experiments made it possible to record a decrease in permeability of carbonate samples by an average of 50 % due to clogging of void space and migration of fines (clayey and non-clayey).
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Date submitted2023-02-07
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Date accepted2023-06-20
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Date published2024-02-29
Origin of carbonate-silicate rocks of the Porya Guba (the Lapland-Kolvitsa Granulite Belt) revealed by stable isotope analysis (δ18O, δ13C)
- Authors:
- Dmitrii P. Krylov
- Ekaterina V. Klimova
Carbonate-silicate rocks of unclear origin have been observed in granulites of the Porya Guba of the Lapland-Kolvitsa Belt within the Fennoscandinavian Shield. The present work aims to reconstruct possible protoliths and conditions of metamorphic transformation of these rocks based on oxygen and carbon isotopic ratios combined with phase equilibria modeling. Isotope analysis and lithochemical reconstructions suggest that carbonate-silicate rocks of the Porya Guba represent metamorphosed sediments (possibly marls) with the isotopic composition corresponding to the Precambrian diagenetically transformed carbonates (δ18O ≈ 17.9 ‰, SMOW and δ13C ≈ –3.4 ‰, PDB). The chemical composition varies depending on the balance among the carbonate, clay, and clastic components. Significant changes of the isotopic composition during metamorphism are caused by decomposition reactions of primary carbonates (dolomite, siderite, and ankerite) producing CO2 followed by degassing. These reactions are accompanied by δ18O and δ13C decrease of calcite in isotopic equilibrium with CO2 down to 15 ‰ (SMOW) and –6 ‰ (PDB), respectively. The isotopic composition is buffered by local reactions within individual rock varieties, thus excluding any pronounced influence of magmatic and/or metasomatic processes.
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Date submitted2022-05-17
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Date accepted2023-04-03
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Date published2024-02-29
Improvement of concentrate quality in flotation of low-rank coal
- Authors:
- Sergei A. Kondratev
- Tatyana A. Khamzina
Percentage of high-rank coal with low content of ash, moisture, and sulfur in total coal production output is low. Most of the produced coal has a low quality (lignite, bituminous coal: long-flame and fiery). Under increasing requirements for ecological cleanness of coal, the efficient use of coal products is only possible after improvement of their processing properties. The authors discuss the enhancement of flotation efficiency of low-rank coal using the mechanism of physisorption of a collecting agent in particle – bubble attachment. It is explained why the yield of concentrate with low ash content increases as a result of combination of collectors having different physical properties. It is shown that the surface activity of a heteropolar agent relative to the gas – liquid interface and the adsorption density of the agent govern its collecting properties. Based on the recovery – surface activity relationship, the correlation is found between the collecting activity of a chemical compound and the structure of its molecules. The combination of the collectors with different surface activity enables adjusting collectability and selectivity of the blend. The physisorption mechanism of collectors can be a framework for developing recommendations on modification of concentrate yield and ash content, and on selection of optimized ratios of surface activities of miscible collectors relative to the gas – liquid interface.
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Date submitted2023-01-12
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Date accepted2023-06-20
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Date published2023-07-19
Improvement of energy efficiency of ore-thermal furnaces in smelting of alumosilicic raw materials
The issues of energy saving in pyrometallurgical production during processing of mineral raw materials in ore-thermal furnaces are particularly important for the development of new energy-efficient technologies. The reduction of the specific power consumption during melting at different stages of heating and melting of charge materials when modeling is related to obtaining kinetic curves in the process of kyanite concentrate regeneration in polythermal conditions. Based on practical data of carbo-thermal reduction the mathematical modeling of reduction processes from alumosilicic raw materials – kyanite was carried out. In this work, the nonisothermal method based on a constant rate of charge heating (i.e. a linear dependence between time and temperature) was used for the reduction of kyanite charge, which saves electrical energy. The experiments were carried out on a high-temperature unit with a heater placed in a carbon-graphite crucible. Based on the obtained kinetic dependences of nonisothermal heating of enriched kyanite concentrates in plasma heating conditions we obtained a number of kinetic anamorphoses of the linear form which point to the possibility of describing the reaction rate using the modified Kolmogorov – Erofeev equation for given heating conditions and within a narrow temperature range. The complex of mathematical modeling makes it possible to create a control algorithm of technological process of reduction of kyanite concentrate to a metallized state within the specified temperature range for the full flow of reaction exchange and to reduce the specific power consumption by 15-20 %. With the help of the received kinetic dependences, taking into account the thermodynamics of processes and current state of the art it is possible to create a universal thermal unit for the optimal carbothermal reduction of charge to a metallized state (alloy) with minimum power inputs compared to existing technologies.
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Date submitted2022-10-31
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Date accepted2023-04-21
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Date published2024-02-29
Study of the properties and action of polyelectrolytes in the treatment of the dressing plant’s discharges
The organization of intrafactory water circulation at mining and processing enterprises, when production wastes and discharges are not sent to an external tailings dump, is an urgent environmental and economic task. Returning even a part of water into the technological process after preliminary treatment will significantly reduce the volume of polluted water discharged into tailings, which will reduce energy costs for waste transportation and the negative environmental impact. One of the wastes sent to the tailings during the ore dressing wastes from the Kovdor deposit to the tailings dump is the discharge of thickeners for the preparation of apatite flotation feed. In order to choose the effective discharge cleaning regime, the authors have evaluated the action of polyacrylamide flocculants. It has been discovered that the apatite and calcite particles interact more effectively with the anionic flocculant. This fact determines its advantage for the treatment of suspended particles. The influence of the residual concentration of a flocculant on the apatite flotation, where a part of the returned treated water goes, has been assessed. Compared to flotation with recycled water, there is a decrease of P2O5 extraction into apatite concentrate of equal quality. In order to obtain the required enrichment indicators on the treated water, it is necessary to adjust the collector (tall oil fatty acids) and depressor (liquid glass) costs.
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Date submitted2022-12-01
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Date accepted2023-01-19
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Date published2023-12-25
Inclusions of diamond crystals in the tourmaline of the schorl-uvite series: problems of genesis
The mineralogical and geochemical features of diamond-bearing tourmaline crystals (schorl-uvite series) from garnet-clinopyroxene rocks of the Kumdy-Kol deposit (Northern Kazakhstan) have been studied in detail. The formation of the main rock-forming minerals (garnet + K-bearing clinopyroxene) occurred in the diamond stability field at 4-6 GPa and 950-1000 °C. Crystallization of K-bearing clinopyroxene at these parameters is possible in the presence of an ultra-potassic fluid or melt formed because of crustal material melting in subduction zones. Tourmaline crystals (up to 1 cm) containing diamond inclusions perform veins crosscutting high-pressure associations. The composition of individual zones varies from schorl to uvite within both a single grain and the sample as a whole. The potassium content in this tourmaline does not exceed 0.1 wt.% K2O, and the isotopic composition of boron δ11B varies from –10 to –15.5 ‰, which significantly differs from the previously established isotopic composition of boron in maruyamaite crystals (δ11B 7.7 ‰ in the core and –1.2 ‰ in the rim) of the same deposit. Analysis of the obtained data on δ11B in the tourmalines from the diamond-grade metamorphic rocks within the Kumdy-Kol deposit suggests the existence of two boron sources that resulted in crystallization of K-bearing tourmaline crystals (maruyamaite-dravite series) and potassium-free tourmalines of the schorl-uvite series.
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Date submitted2022-06-20
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Date accepted2023-01-10
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Date published2023-08-28
Laboratory, numerical and field assessment of the effectiveness of cyclic geomechanical treatment on a tournaisian carbonate reservoir
Results are discussed for evaluation of effectiveness of the cyclic geomechanical treatment (CGT) on a Tournaisian carbonate reservoir. Analysis of laboratory experiments performed according to a special program to assess permeability changes for Tournaisian samples under cyclic changes in pore pressure is presented. The main conclusion is the positive selectivity of the CGT: an increase in permeability is observed for samples saturated with hydrocarbons (kerosene) with connate water, and maximal effect is related to the tightest samples. For water-saturated samples, the permeability decreases after the CGT. Thus, the CGT improves the drainage conditions for tight oil-saturated intervals. It is also confirmed that the CGT reduces the fracturing pressure in carbonate reservoirs. Using flow simulations on detailed sector models taking into account the results of laboratory experiments, a possible increase in well productivity index after CGT with different amplitudes of pressure variation was estimated. Results of a pilot CGT study on a well operating a Tournaisian carbonate reservoir are presented, including the interpretation of production logging and well testing. The increase in the well productivity index is estimated at 44-49 % for liquid and at 21-26 % for oil, with a more uniform inflow profile after the treatment. The results of the field experiment confirm the conclusions about the mechanisms and features of the CGT obtained from laboratory studies and flow simulations.
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Date submitted2022-08-01
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Date accepted2022-11-17
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Date published2023-02-27
Use of machine learning technology to model the distribution of lithotypes in the Permo-Carboniferous oil deposit of the Usinskoye field
- Authors:
- Denis V. Potekhin
- Sergei V. Galkin
Permo-Carboniferous oil deposit of the Usinskoye field is characterized by an extremely complex type of the void space with intense cross-sectional distribution of cavernous and fractured rock. In this study, for this production site, the process of 3D geological modeling has been implemented. At the first stage, it provided for automated identification of reservoir volumes by comparing the data of core and well logging surveys; at the second stage, identification of rock lithotypes according to Dunham classification is performed on the basis of comparison of thin sections examination and well logging data. A large array of factual information enables the use of machine learning technology on the basis of Levenberg – Marquardt neural network apparatus toward achievement of our research goals. The prediction algorithms of reservoir and rock lithotype identification using well logging methods obtained on the basis of the training samples are applied to the wells without core sampling. The implemented approach enabled complementing the 3D geological model with information about rock permeability and porosity, taking into account the structural features of the identified lithotypes. For the Permo-Carboniferous oil deposit of the Usinskoye field, the volumetric zoning of the distribution of different rock lithotypes has been established. Taking into account the lithotypes identified based on machine learning algorithms, density and openness of fractures were determined, and fracture permeability in the deposit volume was calculated. In general, during the implementation, the machine learning errors remained within 3-5 %, which suggests reliability of the obtained predictive solutions. The results of the research are incorporated in the existing 3D digital geological and process model of the deposit under study.
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Date submitted2022-11-08
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Date accepted2022-11-21
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Date published2023-02-27
Assessment of the role of the state in the management of mineral resources
Mineral resources as natural capital can be transformed into human, social and physical capital that guarantees the sustainable development of a country, exclusively through professional public management. Public management of a country's mineral resource potential is seen as an element of transnational governance which provides for the use of laws, rules and regulations within the jurisdictional and sectoral capabilities of the state, minimising its involvement as a producer of minerals. The features of the ideology of economic liberalism, which polarises the societies of mineral-producing countries and denies the role of the state as a market participant, have been studied. The analysis of the influence of the radical new order of neoliberal world ideology on the development of the extractive sector and state regulation has been presented.
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Date submitted2022-04-15
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Date accepted2022-11-17
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Date published2023-04-25
Uranium in man-made carbonates on the territory of Ufa
The paper presents the results of analyzing uranium content in man-made carbonates (scale crusts) on the territory of Ufa based on examination of 42 samples. The median uranium content in the investigated samples stands at 1.44 mg/kg, which is significantly lower than the background values (scales from the Lake Baikal water, a clarke of sedimentary carbonate rocks) and data on other settlements of the Republic of Bashkortostan. Low values of uranium content are probably associated with the effects of the three leading factors, i.e. specific subsurface geology of the territory (gypsum, limestone); types of water supply; water treatment processes for the centralized type of water supply. Spatial distribution of uranium in man-made carbonates is characterized with uniformity, which is disturbed in two cases, i.e. a change of the water supply type (from centralized to individual); and material of the vessels used for boiling the water. No significant differences were detected when comparing samples of man-made carbonates associated with different sources of water supply (the bucket and infiltration types of water intake) and the types of household filters.
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Date submitted2022-06-17
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Date accepted2022-10-18
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Date published2022-11-03
Scientific experimental bases for dry beneficiation of mineral ores
The article presents the results of research on the development of processes and equipment for ore preparation and pneumatic dry beneficiation of mineral ores. The methods of crushing and grinding before enrichment of minerals have been considered, dry enrichment of geomaterials is investigated. Highly efficient prototypes of beneficiation equipment are developed and tested: crushers of multiple dynamic impact RD-MDV-900, DKD-300, centrifugal grinders CMVU-800 and VCI-12, pneumatic separator POS-2000. Fundamental designs are created, and a number of new ore preparation and pneumatic beneficiation instruments are being designed. The efficiency of approbation of an autonomous dry beneficiation complex with new safe environmental standards for the processing of gold-bearing ores, which makes it possible to fully release and extract free gold with a particle size from 10,000 to 100 µm, is shown. The introduction of the dry beneficiation method is very promising for the mining industry. It will allow to reduce capital costs for the construction of stationary beneficiation plants, completely or partially withdraw from the use of process water, the construction of a water supply system, a traditional tailing dam, etc.
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Date submitted2022-05-17
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Date accepted2022-09-06
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Date published2022-11-03
On the need to classify rock mass fed to dry magnetic separation
The hypothesis of a possible use of dry magnetic separation is substantiated on the example of ores from ferruginous quartzite deposits operated by plants of PAO “Severstal” Holding. Size class of ore after medium crushing is –80+0 mm when the vibrating feeder is used for feeding ore mass to the separation zone. The rationale is based on the analysis of video recording of physical simulation on a laboratory drum magnetic separator of SMBS-L series, in the VSDC Video Editor, and simulation modelling of dry magnetic separation on its virtual prototype in Rocky DEM software package. It has been proved that the use of a vibrating feeder for feeding the material to the working area of a magnetic separator makes it possible to: form a monolayer on the surface of the vibrating feeder chute with a thickness close to the maximum size of a lump of separated ore; implement batch feed of material to the separation zone; increase the spacing between lumps in the separation zone when passing through the free fall area, thereby allowing dry magnetic separation of ferruginous quartzites of size class –80+0 mm without pre-preparation.
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Date submitted2022-03-17
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Date accepted2022-06-20
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Date published2022-11-03
Assessment of collecting activity of physically sorbed reagents on the example of easily floatable coking coal sludge
- Authors:
- Sergey A. Kondratev
- Tatyana A. Khamzina
The article presents one of the new approaches to theoretical assessment of collecting ability of reagents. The efficiency of reagents-collectors with different chemical composition used for flotation of coking coals was studied. A comparative assessment of the flotation activity of kerosene, mineral oil, thermal gas oil, KETGOL and FLOTEK is given. The criteria of collecting activity of the above reagents-collectors for coal sludge flotation were specified. A correlation was established between the indicators of coal sludge flotation by the above reagents and their physical parameters. It is shown that the rate of spreading over water surface can characterize the flotation activity of reagents. Based on dependence of the collecting activity of a reagent on its rate of spreading along the “gas – liquid” interface and surface pressure, the main approaches to determining the structure and composition of molecules of an effective flotation collector can be determined. A new concept of the function performed by a physically sorbed collector in the elementary act of flotation and a criterion for the flotation activity of reagents used in coal sludge beneficiation are proposed. It is shown that the collector used in coal flotation, in addition to hydrophobizing the surface of the extracted particles, should reduce the induction time and remove the kinetic constraint on formation of a flotation aggregate.
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Date submitted2022-05-17
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Date accepted2022-09-06
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Date published2022-11-03
Methodological substantiation of the choice for optimal modes of equipment operation during the stage-wise concentrate removal in iron ores beneficiation
- Authors:
- Alexandr S. Opalev
- Svetlana A. Alekseeva
The urgent task of improving the quality of iron ore concentrates was studied. We propose to use the stage-wise removal of the concentrate by combining fine screening, regrinding, and magnetic-gravity separation. Exemplified by magnetite ore from the Stoilensky GOK, a scientific and methodological approach to the search for optimal separation parameters and modes was substantiated. It includes several stages: studying the particle size distribution and release of useful components in the feed product to select classification parameters; a series of experiments on grinding oversize products to diverse sizes; beneficiation of the obtained products by MG separation. To select the optimal parameters of ore preparation, an analysis of the beneficiation efficiency was used, which is calculated according to the Hancock – Luyken criterion. The results of the research are experimental dependences that connect the process parameters of beneficiation with those of fine vibratory screening. For the studied ferruginous quartzite ore processed at the Stoilensky GOK, the obtained dependences can be described by a second-order polynomial with a high accuracy of approximation. The best performance is achieved with a particle size of 0.1 mm: Fe tot content in the concentrate is 69.7 %, recovery is 85 %, classification efficiency is 80.4 %. The top size of the product in this case is 0.076 mm, which corresponds to 70-73 % grinding size of –0.045 class.
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Date submitted2022-05-10
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Date accepted2022-09-06
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Date published2022-11-03
Flotation separation of titanite concentrate from apatite-nepheline-titanite ores of anomalous zones of the Khibiny deposits
Titanium raw materials are widely used for the synthesis of various functional materials – sorbents of radionuclides and rare earth elements, various additives, filler pigments, etc. Since most of titanium concentrates are imported, in line with the import substitution program, production of titanite concentrate from apatite-nepheline ores of the Khibiny deposits is a promising trend for supplying national industry with titanium raw materials. The article presents the results of laboratory studies of flotation separation of titanite concentrate from apatite-nepheline-titanite ores extracted from the upper ore horizon of the Koashvinskoye deposit, where titanite-enriched ores are concentrated. Recovery of titanite concentrate was accomplished using two reagent modes – a mixture of alkyl hydroxamic and carboxylic acids with the addition of distilled tall oil and a mixture of tall oils with the addition of polyalkyl benzene sulfonic acids. The results of the research showed that the first flotation mode, which allows a selective recovery of titanite into the concentrate (titanite content in the concentrate was 93.5 %) is the most efficient. It was shown that flotation separation of titanite concentrate is preferable compared to the chemical method based on sulfuric acid leaching.
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Date submitted2022-05-03
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Date accepted2022-07-21
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Date published2022-11-03
Determination of rational steam consumption in steam-air mixture flotation of apatite-nepheline ores
Relevance of the study is determined by the decisions taken to increase the production volume of certain commercial products from mineral raw materials. The scale, impact and consequences of the projects on developing the resource-saving technologies for beneficiation of mineral raw materials are socially significant, and the economic growth of mining production complies with the sustainable development goals. The aim of the study is to develop the flotation circuit and mode that improve the technological performance of beneficiation of apatite-nepheline ores of the Khibiny Massif in the Kola Peninsula. The scientific idea of the work is to develop the flotation circuit, the movement of beneficiation products in which ensures a major increase in the content of the recovered component in the rougher flotation procedure with a simultaneous increase in dressability of the material. The above condition is met when mixing the feedstock with rough concentrate. Recovery of the valuable component from the resulting mixture is accomplished in a mode differing from the known ones in that the heat of steam condensation is used to increase water temperature in the interphase film between the particle and the bubble. For pulp aeration during flotation, a mixture of air and hot steam is used as the gas phase. A high recovery of the valuable component in ore flotation according to the developed circuit and mode is facilitated by increasing water temperature in wetting films due to the steam condensation heat. A high selectivity of flotation with a steam-air mixture can be explained using the concepts of a phonon component of disjoining pressure, the value and sign of which are associated with a difference in the dynamic structure of liquid in the wetting film and bulk liquid.