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Date submitted2023-07-31
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Date accepted2024-11-07
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Date published2025-02-25
Environmental assessment of biochar application for remediation of oil-contaminated soils under various economic uses
- Authors:
- Tatiana V. Minnikova
- Sergey I. Kolesnikov
Remediation is an important area of oil-contaminated soil restoration in Russia, since oil refining industry is the major one for Russia and neighbouring countries, and the issues of environmentally effective and economically profitable remediation of oil contamination have not yet been solved. Soils under various economic uses have different surface areas and degrees of soil particles envelopment with oil due to the presence or absence of cultivation, the amount of precipitation and plant litter. The introduction of various substances for remediation into oil-contaminated soils of steppes (arable land), forests, and semi-deserts, considering their differences, gives different results. Biochar is coal obtained by pyrolysis at high temperatures and in the absence of oxygen. The uniqueness of this coal lies in the combination of biostimulating and adsorbing properties. The purpose of the study is to conduct an environmental assessment of biochar application for remediation of oil-contaminated soils under various economic uses. The article compares the environmental assessments of biochar application in oil-contaminated soils with different particle size fraction. The following indicators of soil bioactivity were determined: enzymes, indicators of initial growth and development intensity of radish, microbiological indicators. We found that the most informative bioindicator correlating with residual oil content is the total bacteria count, and the most sensitive ones are the roots length (ordinary chernozem and brown forest soil) and the shoots length (brown semi-desert soil). The use of biochar on arable land and in forest soil (ordinary chernozem and brown forest soil) is less environmentally efficient than in semi-desert soil (brown semi-desert soil). The study results can serve to develop measures and managerial and technical solutions for remediation of oil-contaminated soils under various economic uses.
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Date submitted2024-05-03
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Date accepted2024-09-05
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Date published2024-11-12
Platinum group elements as geochemical indicators in the study of oil polygenesis
This study examines elements of the platinum group (PGE), primarily platinum and palladium, as geochemical indicators in the investigation of oil polygenesis. It has been found that, like other trace elements such as nickel, vanadium, and cobalt, platinum group elements and gold can occur in oil fields at both background levels and in elevated or even anomalously high concentrations. The objective of this research is to analyze PGE and trace elements as geochemical markers to identify the geological factors, including endogenous processes, responsible for these unusually high concentrations in oil. A comprehensive review of the literature on this subject was conducted, along with new data on the presence of precious metals in oils from Russia and globally. The study explores the geological mechanisms behind elevated PGE concentrations in oils, utilizing atomic absorption spectroscopy with atomization in the HGA-500 graphite furnace to measure PGE content. Previously, the tellurium co-deposition method (ISO 10478:1994) was used to isolate noble metals from associated elements. Possible geological origins of abnormally high concentrations of platinum metals in oils have been identified. These include endogenous factors such as the spatial proximity of oil fields to ultrabasic rock massifs, the effects of contact-metasomatic processes, and influences from mantle dynamics. Moreover, data concerning mantle elements can serve as indicators of the depth origins of certain hydrocarbon fluids, thus contributing to the study of oil polygenesis.
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Date submitted2024-04-10
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Date accepted2024-10-14
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Date published2024-11-12
The influence of ocean anoxia on conditions for the Domanik deposits formation
The article considers one of conditions for the Domanik facies formation on the example of Tatarstan and Bashkortostan. The main emphasis is on the influence of anoxic paleobasin conditions on the high-carbon strata formation. A detailed study of the hydrocarbon composition of Domanik deposits made it possible to find characteristic biomarkers in their composition. They are based on the composition and structure of diagenetic products of biological compounds composing the sulphur bacteria living in anoxic/euxinic paleobasin conditions. Such compounds include C40 diaryl isoprenoids – isorenieratane and paleorenieratane. C10 tetramethylbenzenes also occupy a special place in the Domanik deposits study. Their appearance in the composition of organic matter of these deposits results from the transformation of sulphur bacteria compounds. Diaryl isoprenoids and tetramethylbenzenes are a reliable indicator of anoxic conditions of the Domanik deposits formation. The thermodynamic state of the hydrocarbon environment can be determined from the ratio of tetramethylbenzene isomers.
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Date submitted2024-10-29
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Date accepted2024-10-29
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Date published2024-11-12
Study of thermodynamic processes of the Earth from the position of the genesis of hydrocarbons at great depths
In the context of significant depletion of traditional proven oil reserves in the Russian Federation and the inevitability of searching for new directions of study and expansion of the raw material base of hydrocarbon raw materials in hard-to-reach regions and on the Arctic shelf, a scientific search is underway for accumulations in complex geological conditions and in manifestations that differ significantly from traditional ones, which include the processes of oil and gas formation and preservation of oil and gas in low-permeability “shale” strata and in heterogeneous reservoirs at great and super-great depths. Within the oil and gas provinces of the world, drilling of a number of deep and super-deep wells has revealed deposits at great depths, established connections between hydrocarbon deposits and “traces” of hydrocarbon migration left in the core of deep wells, which has made it possible to significantly re-evaluate theoretical ideas on the issue of oil and gas formation conditions and the search for technologies aimed at solving applied problems. Modern geochemical, chromatographic, bituminological, coal petrographic and pyrolytic methods of studying oil and bitumoids extracted from the host rocks of deep well cores give a hope for identifying correlations in the oil-source system, revealing processes that determine the possibility of hydrocarbon formation and accumulation, and defining predictive criteria for oil and gas potential at great depths.
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Date submitted2022-10-04
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Date accepted2024-03-05
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Date published2024-08-26
Localization and involvement in development of residual recoverable reserves of a multilayer oil field
During waterflooding of a multilayer oil field there is a constant deterioration of the structure and composition of residual reserves due to geological and technological reasons. The largest share of residual reserves is localized in pillars, which arise from uneven development of the production facility and are undrained or poorly drained zones. The results of a quantitative assessment of the distribution of residual oil reserves in the Middle and Upper Devonian deposits of the Romashkinskoe oil field of the Republic of Tatarstan are presented. A retrospective method is proposed to identify reserves by analyzing and summarizing historical exploration data and the long history of reservoir development, and a calculation algorithm is proposed to quantify them. It has been established that residual oil reserves are localized in rows of dividing and injection wells, as well as in the central rows of producing wells in a three-line drive, in abandoned and piezometric wells, in the areas adjacent to the zones of reservoir confluence, pinch-out, oil-bearing contours, distribution of reservoirs with deteriorated porosity and permeability properties. Depending on geological conditions, algorithms for selecting geological and technical measures to include localized reserves in development and forecasting production profiles were proposed. According to the proposed method, residual recoverable reserves were identified and a number of wells were recommended for experimental works on their additional recovery: in well 16 (hereinafter in the text, conventional well numbers are used) after isolation of overlying high-water-cut formations, the additional perforation was carried out and oil flow was obtained. Additional perforation in well 6 resulted in oil recovery during development as well. Thus, the developed approaches to identifying residual recoverable reserves and patterns of their spatial distribution can be recommended in other multilayer oil fields with a long history of development.
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Date submitted2022-04-07
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Date accepted2023-04-21
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Date published2023-08-28
Development of a new assessment system for the applicability of digital projects in the oil and gas sector
Digital transformation is one of the global trends that has covered most sectors of the economy and industry. For oil and gas companies, the introduction of digital technologies has become not just a trend, but one of the factors for ensuring competitiveness and maintaining a stable position in the market in a rapidly changing macro environment. At the same time, despite the positive effects achieved, digital transformation is a complex process from the point of view of implementation and is associated with high technological, financial, and economic risks. The work aims to develop and test a new system for evaluating the applicability of digital projects in the oil and gas sector. The research methodology includes the application of the Gartner curve, methods of expert assessments, and tools for assessing the economic efficiency of investment projects. The developed assessment system is based on a comprehensive accounting of four components: the level of digital maturity of the company; compliance of the implemented technology with the goals and objectives of the organization; the level of reliability of the implemented technology; the level of innovation of the implemented project. Particular attention is paid to the practical testing of the proposed methodology based on the evaluation of a digital project implemented by a Russian oil and gas company.
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Date submitted2022-09-30
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Date accepted2023-04-03
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Date published2024-02-29
Optimization of the location of a multilateral well in a thin oil rim, complicated by the presence of an extensive gas cap
- Authors:
- Кirill О. Тomskii
- Mariya S. Ivanova
The specific share of the reserves of hard-to-recover hydrocarbon raw materials is steadily growing. The search for technologies to increase the hydrocarbon recovery factor is one of the most urgent tasks facing the oil and gas industry. One of the methods to expand the coverage of oil reserves and increase oil recovery is to use the technology of drilling multilateral wells with a fishbone trajectory. In the Russian Federation, the most branched well was drilled in the Republic of Sakha (Yakutia) at the Srednebotuobinskoye oil and gas condensate field. The main object of development is the Botuobinsky horizon (Bt reservoir). About 75 % of the geological reserves of the reservoir are concentrated in a thin oil rim with an average oil-saturated layer thickness of 10 m with an extensive gas cap. This circumstance is one of the main complicating factors in the development of the Srednebotuobinskoye oil and gas condensate field. For such complex wells, one of the most important design stages is to determine the optimal location of the fishbone well in an oil-saturated reservoir. The article shows the results of sector modeling in the conditions of the Srednebotuobinskoye field to determine the optimal location of multilateral wells using Tempest simulator.
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Date submitted2022-09-27
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Date accepted2023-04-03
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Date published2023-12-25
The study of displacing ability of lignosulfonate aqueous solutions on sand packed tubes
This paper presents the findings of laboratory studies of rheological properties and oil displacing ability of aqueous solutions of technical grade lignosulfonate done on the sand packed tube models. The solutions containing lignosulfonate can be useful as displacement agents in development of watered reservoirs with heterogeneous porosity and permeability. When used at high concentrations, technical grade lignosulfonate can achieve selective shut-off while maintaining the reservoir pressure. The oil displacement efficiency is improved by means of redistributing the flows and selective isolation of high-permeability zones. The use of such compositions allows increasing the sweep of low-permeability reservoir zones by created pressure differential and displacing the residual oil.
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Date submitted2022-09-30
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Date accepted2023-02-13
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Date published2024-02-29
Improving the efficiency of oil vapor recovery units in the commodity transport operations at oil terminals
- Authors:
- Vladimir V. Pshenin
- Gulnur S. Zakirova
In this paper the problem of losses from evaporation of light fractions of hydrocarbons during loading operations of tanker fleets vessels is considered. It was found that there is no unified approach to modeling the system “tanker – gas phase pipeline – vapor recovery units” in open sources. The absence of a generally recognized model makes it impossible to scientifically justify the application of instruments to reducing losses and the development of corresponding measures. In work it is showed that the dynamics of growth of pressure in the inner tanker capacity is described by a differential equation, considering for non-stationary essence of the process. This equation is converted to a non-dimensional form and investigated in relation to the similarity criteria of this system. This research has allowed to establish unambiguously the general character of pressure changes in the inner tanker capacity, and to predict the peak values of its growth at the initial stage of the loading operation. The obtained equations were tested on real tanker loading data and showed satisfactory convergence with the experimental data. At different stages of the loading opera-tion the component composition of vapor changes, which is shown by chromatographic analysis of the gas mixture. With the availability of a model of hydrocarbon vapor displacement from the inner of tanker, it is possible to propose measures to minimize the negative impact on the environment and return valuable vapors of the product to the technological chain of transportation.
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Date submitted2022-11-11
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Date accepted2023-01-19
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Date published2023-12-25
Evaluation of the efficiency of sorbents for accidental oil spill response in the Arctic waters
The development and operation of new oil fields on the Arctic shelf increases the risks of oil spills, which require the use of oil spill response tools and materials that are efficient in harsh climatic conditions. The question of actual efficiency of sorbents for reducing the level of oil pollution in the conditions of the Arctic and subarctic waters is relevant. The work is aimed at a comparative study of the efficiency of sorbents of mineral and organic origin used by coastal enterprises in the Kola Bay as well as a sorbent based on chitin in model systems simulating real conditions in sea waters. The characteristics of sorption agents were determined applying ASTM F716-18 procedure. Sorption capacity was evaluated in respect of ARCO grade oil, diesel fuel and marine oil. The efficiency of sorbents was estimated in model systems “sea water – oil” at water temperature corresponding to the average annual surface temperature in the Barents Sea. Actual data on sorption capacity of commercial sorbents “Lessorb”, “Novosorb”, a sorbent based on vermiculite and chitin sorbent in relation to potential pollutants of waters were obtained. The dynamics of sea water saturation with oil products at –0.5 (±1) and 10 (±1) °С was determined. It is shown that at higher temperature the concentration of oil products in sea water column (in the presence of an oil film on the surface) is on average four times higher than at low temperature. Kinetic dependences were obtained that describe the content of oil products in water column and near-surface layer of sea water in the presence of the studied sorbents at 5 (±1) °C, corresponding to the average annual temperature in the Kola Bay of the Barents Sea. A method is proposed for evaluating the efficiency of sorbents from the values of regression coefficients characterizing the dependence of oil products content in sea water on the character of sorbent and duration of its action.
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Date submitted2022-06-09
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Date accepted2022-11-17
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Date published2022-12-29
Drilling of deep and ultra-deep wells for prospecting and exploration of new raw mineral fields
Scientific and technological progress over the last century has led to an enormous increase in the consumption of minerals, including energy resources. Most of the exploited oil and gas fields are already considerably depleted, so it is necessary to search for new hydrocarbon resources, particularly at great depths. Deep drilling plays a special role in solving this problem. The article considers the world and Russian experience of ultra-deep wells drilling. The methods and technologies used in the construction of wells, as well as complications and accidents occurring during their drilling were analyzed. The analysis revealed that the existing limitations for drilling parameters of deep and ultra-deep wells are caused by the technical characteristics of surface and bottomhole drilling equipment, which do not meet the extreme drilling conditions. The directions for development of deep and ultra-deep well drilling machinery and technologies are suggested. The notion of extreme rock and geological drilling conditions is introduced, which describes drilling in conditions of hydrostatic pressure of flushing fluid column and high bottomhole temperature both at stable and unstable wellbore conditions, coming close to the upper limit of operating technical characteristics of bottomhole assembly, the drill string and flushing fluid.
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Date submitted2022-06-20
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Date accepted2022-10-10
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Date published2022-11-03
Monitoring of grinding condition in drum mills based on resulting shaft torque
Grinding is the most energy-intensive process among all stages of raw material preparation and determines the course of subsequent ore beneficiation stages. Level of electricity consumption is determined in accordance with load characteristics forming as a result of ore destruction in the mill. Mill drum speed is one of process variables due to which it is possible to control ore destruction mechanisms when choosing speed operation mode of adjustable electric mill drive. This study on increasing energy efficiency due to using mill electric drive is based on integrated modelling of process equipment – grinding process and electromechanic equipment – electric drive of grinding process. Evaluating load torque by means of its decomposition into a spectrum, mill condition is identified by changing signs of frequency components of torque spectrum; and when studying electromagnetic torque of electric drive, grinding process is monitored. Evaluation and selection of efficient operation mode of electric drive is based on the obtained spectrum of electromagnetic torque. Research results showed that with increasing mill drum speed – increasing impact energy, load torque values are comparable for the assigned simulation parameters. From the spectra obtained, it is possible to identify mill load condition – speed and fill level. This approach allows evaluating the impact of changes in process variables of grinding process on parameters of electromechanical system. Changing speed operation mode will increase grinding productivity by reducing the time of ore grinding and will not lead to growth of energy consumption. Integration of digital models of the technological process and automated electric drive system allows forming the basis for developing integrated methods of monitoring and evaluation of energy efficiency of the entire technological chain of ore beneficiation.
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Date submitted2021-03-31
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Date accepted2022-04-26
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Date published2022-11-03
Features of obtaining metallurgical products in the solid-state hydride synthesis conditions
- Authors:
- Andrey G. Syrkov
- Lyudmila A. Yachmenova
A scientific substantiation of solid-phase feedstock choice and preparation has been carried out, and the thermodynamic and kinetic aspects of solid-state hydride synthesis (SHS) of metal products have been analyzed using the nickel dichloride reduction as an example. The preliminary dehydration modes and methods for controlling the complete removal of crystalline water from chloride raw materials and Olenegorsk superconcentrate, which is natural oxide raw material, are described. Conditions, including initial solid chloride particle sizes, are established under which diffusion complications of reduction to metal in methyldichlorosilane vapor are minimized. Thermodynamic estimates of nickel chlorides and oxides reduction possibility, iron and copper with ammonia and methane at temperatures of 400-1000 K in equilibrium conditions have been carried out. It has been shown that the stoichiometric coefficients of the nickel dichloride in ammonia overall reduction reaction calculated by thermodynamic modeling are in agreement with experimental data. In contrast to the copper dichloride reduction, for nickel dichloride the formation of metal monochloride at the intermediate stage is uncharacteristic, which is associated with a higher thermal stability of nickel dichloride. The main kinetic regularities of the reduction of nickel, copper, and iron to metal under SHS conditions in ammonia, monosilane, and methane, as well as the nickel dichloride with methyldichlorosilane vapor and methane successive reduction, are considered. Approximation of experimental data by topochemical equations in a linear form showed that for reduction degrees a up to 0.7-0.8, these data are satisfactorily described by the Roginsky – Schultz equation. For a > 0,8 the “shrinking sphere” model works better, which confirms the localization of the solid-state reduction reaction at the interface, moves deep into the crystal with the formation of a of interlocked metal germs. The importance and prospects of the results obtained for the theory development of metallurgical processes, deep complex processing of natural iron oxide raw materials, metal products and new generation materials production, including superhydrophobic ones, are discussed. The relevance of the study from the point of view of applying the method of physical and chemical analysis to the study of complex heterogeneous metallurgical processes is noted.
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Date submitted2022-01-28
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Date accepted2022-04-26
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Date published2022-07-26
On the presence of the postmagmatic stage of diamond formation in kimberlites
- Authors:
- Sergey K. Simakov
- Yuri B. Stegnitskiy
On nowadays multiphase and the facies heterogeneity of the formations are distinguished at the study of kimberlite pipes. Most researchers associate the formation of diamonds only with the mantle source. To date, satellite minerals with specific compositions associated with kimberlite diamonds have been identified as deep mantle diamond association. They are extracted from the concentrate of the kimberlites heavy fraction and may reflect the diamond grade of the pipe. For some minerals in the diamond association, however, they can not be reliable. Some researchers also revealed shallow diamond associations, related to the formation of serpentine, calcite, apatite, and phlogopite. There is recent data on the formation of diamonds in rocks of the oceanic crust. In the last years microdiamonds were identified in chromites of the oceanic crust in association with antigorite formed at 350-650 °C and 0.1-1.6 GPa. As a result, the authors established a postmagmatic kimberlitic stage of diamond formation associated with secondary mineral associations based on the experimental and mineralogical data for the conditions of the shallow upper mantle and crust. Mineralogical and petrographic studies of Angolan kimberlite pipe show that antigorite is the indicator mineral of this stage.
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Date submitted2021-09-22
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Date accepted2021-11-30
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Date published2021-12-27
Possibilities for creating Russian high-tech bottomhole assembly
Development of high-tech well electronic measuring systems is aimed at creating modern equipment: telemetry, well geophysical measurement equipment, the architecture of which is divided into basic (with measurement channels for gamma logging and inductive resistance) and advanced (with radioactive, acoustic, magnetic resonance and thermobarometric measurement channels, including azimuthal methods of investigation). Over-the-bit measurement modules, rotary steerable systems are being developed and channels for transmitting data to the surface are being improved. Vice versa, specialized surface equipment with highly integrated software is being created. Different measurement modules are manufactured by different companies, which creates uncertainties in the possibility of interfacing the manufacturers' measurement modules into a single well measurement system. The article presents an analysis of the readiness of Russian oil service companies to produce well and surface equipment for drilling Russian directional oil and gas wells, meeting modern requirements for accuracy, lifetime and operating conditions. The possibility of creating a fully Russian well high-tech equipment and the required resources, risks and measures to mitigate them when creating a modern well measurement system are considered.
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Date submitted2021-02-28
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Date accepted2021-11-30
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Date published2021-12-27
Substantiation of analytical dependences for hydraulic calculation of high-viscosity oil transportation
- Authors:
- Alexander K. Nikolaev
- Natalia А. Zaripova
One of the development priorities in oil and gas industry is to maintain gas and oil pipeline networks and develop pipeline-connected gas and oil fields of the Arctic zone of the Russian Federation, a promising region the resource potential of which will not only meet a significant portion of internal and external demand for various types of raw materials and primary energy carriers, but will also bring great economic benefits to subsoil users and the state. The mineral and raw material centers of the Nadym-Purskiy and Pur-Tazovskskiy oil and gas bearing areas are among the most attractive regions of the Arctic zone. It is necessary to develop a scientifically substantiated approach to improve the methods of oil transportation from the field to the existing pipelines. As it is known, the task of increasing the efficiency of pipeline transportation of high-viscosity oil is inseparably connected with solving problems in the field of thermal and hydraulic calculation of pipeline system. The article presents the substantiation of dependencies for hydraulic calculation of pipelines transporting high-viscosity oil exhibiting complex rheological properties. Based on the laws of hydraulics for non-Newtonian fluids, the formulas for calculating head losses for fluids obeying Ostwald's law are proposed, their relationship to the classical equations of hydraulics is shown. The theoretical substantiation of looping installation for increasing the efficiency of pipeline transportation of high-viscosity oil taking into account the received dependences for power fluid is considered.
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Date submitted2021-03-05
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Date accepted2021-10-18
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Date published2021-12-16
Physical and mathematical model of rock destruction by a milling machine cutter
As a result of the analysis of the work on rock destruction by cutters of milling of machines, it was found that the existing developments do not allow us to proceed to the derivation of calculation d dependencies for determining fracture resistance, or can be used only in preliminary calculations of the known by design parameters of milling machines. To eliminate these disadvantages, a combined physical and mathematical model of the process of interaction of a single milling cutter with a spherical tip with the rock has been developed. Consideration of the physical picture of the action of forces and stresses acting from the cutter with spherical tips on the separating rock element in the limiting condition allowed to describe analytically the components of total resistance, which are the mathematical part of the physical and mathematical model of rock destruction by cutters. Analytical dependences for determining the tangential and normal components of fracture resistance of rocks of medium hardness have been obtained. The adequacy of the physical and mathematical model to the physical process of destruction of rocks of different hardness by cutters on a universal stand was tested both in the field and in the laboratory conditions. Technical evaluation of the results of experimental studies confirms the reliability of the developed physical and mathematical model.
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Date submitted2021-03-11
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Date accepted2021-07-27
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Date published2021-10-21
Justification of a comprehensive technology for preventing the formation of asphalt-resin-paraffin deposits during the production of highlyparaffinic oil by electric submersible pumps from multiformation deposits
Production of highly solidifying abnormal oils (with a paraffin content of over 30 % by mass) in the Far North is complicated by the intensive formation of asphalt-resin-paraffin deposits (ARPD) in the bottomhole zone of the productive formation, well and surface equipment. Existing methods and technologies for countering the formation of organic deposits in well equipment have many advantages. However, their application in the production of highly paraffinic oil does not fully prevent the formation of ARPD in the tubing string. This leads to a significant reduction in oil production, reduction of turnaround and intertreatment periods of production wells operation, an increase in specific operating expenses for paraffin removal. Results of theoretical and laboratory investigations presented in the article show that one of the promising ways to improve the operational efficiency of wells equipped with electric submersible pumps during extraction of highly paraffinic oil from multiformation deposits is the application of a new integrated technology based on the joint production of highly solidifying abnormal oil with oil, characterized by a lower paraffin content and manifestation of structural and mechanical properties, in conjunction with the regulation of the parameters for the electric submersible pump. Results of numerical modeling using the PIPESIM steady-state multiphase flow simulator, physical, chemical and rheological investigations show that with a decrease of highly paraffinic oil from the productive formation D2ef in a blend with Stary Oskol oil from the Kyrtaelskoye field, a decrease in the mass content of paraffin in the blend and the temperature of its saturation with paraffin, depth and intensity of the organic deposits formation in the tubing string, pour point, as well as the improvement of the rheological properties of the investigated structured dispersed systems is observed. Article describes a promising assembly of well equipment for the single tubing separate production of highly paraffinic oil from multiformation deposits of the Timan-Pechora province, providing separation of the perforation zones in two productive formations using a packer-anchor system at simultaneous-separate operation of the formations by a double electric submersible pump unit.
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Date submitted2021-02-09
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Date accepted2021-07-27
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Date published2021-10-21
Development of an algorithm for determining the technological parameters of acid composition injection during treatment of the near-bottomhole zone, taking into account economic efficiency
Relevance of the research is due to the low proportion of successful hydrochloric acid treatments of near-bottomhole zones of carbonate reservoirs in the Perm region caused by insufficiently careful design and implementation of measures to stimulate oil production. Within the framework of this article, the development of a program is presented, which is based on an algorithm that allows determining the volume and rate of injection for an acid composition into a productive formation corresponding to the maximum economic efficiency during hydrochloric acid treatment. Essence of the proposed algorithm is to find the greatest profit from measures to increase oil recovery, depending on the cost of its implementation and income from additionally produced oil. Operation of the algorithm is carried out on the principle of enumerating the values of the volume and rate of injection for the acid composition and their fixation when the maximum difference between income and costs, corresponding to the given technological parameters of injection, is reached. The methodology is based on Dupuis's investigations on the filtration of fluids in the formation and the results of the experiments by Duckord and Lenormand on the study of changes in the additional filtration resistance in the near-well zone of the formation when it is treated with an acid composition. When analyzing and including these investigations into the algorithm, it is noted that the developed technique takes into account a large number of factors, including the lithological and mineralogical composition of rocks, technological parameters of the injection of a working agent and its properties, well design, filtration properties of the formation, properties of well products. The article provides an algorithm that can be implemented without difficulty using any programming language, for example, Pascal. Selection of the optimal values for the volume and rate of injection is presented in this paper, using the example of a production well at the Chaikinskoye oil field, located within the Perm region. Introduction of the developed algorithm into the practice of petroleum engineering will allow competent and effective approach to the design of hydrochloric acid treatments in carbonate reservoirs without a significant investment of time and additional funds.
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Date submitted2020-06-16
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Date accepted2020-11-09
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Date published2020-12-29
Investigation of probabilistic models for forecasting the efficiency of proppant hydraulic fracturing technology
To solve the problems accompanying the development of forecasting methods, a probabilistic method of data analysis is proposed. Using a carbonate object as an example, the application of a probabilistic technique for predicting the effectiveness of proppant hydraulic fracturing (HF) technology is considered. Forecast of the increase in the oil production of wells was made using probabilistic analysis of geological and technological data in different periods of HF implementation. With the help of this method, the dimensional indicators were transferred into a single probabilistic space, which allowed performing a comparison and construct individual probabilistic models. An assessment of the influence degree for each indicator on the HF efficiency was carried out. Probabilistic analysis of indicators in different periods of HF implementation allowed identifying universal statistically significant dependencies. These dependencies do not change their parameters and can be used for forecasting in different periods of time. Criteria for the application of HF technology on a carbonate object have been determined. Using individual probabilistic models, integrated indicators were calculated, on the basis of which regression equations were constructed. Equations were used to predict the HF efficiency on forecast samples of wells. For each of the samples, correlation coefficients were calculated. Forecast results correlate well with the actual increase (values of the correlation coefficient r = 0.58-0.67 for the examined samples). Probabilistic method, unlike others, is simple and transparent. With its use and with careful selection of wells for the application of HF technology, the probability of obtaining high efficiency increases significantly.
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Date submitted2020-06-19
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Date accepted2020-10-06
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Date published2020-11-24
Practice of using the magnetic treatment devices to intensify the processes of primary oil treating
During the primary treatment of oil, gas and water, complications arise associated with the presence of hard water-oil emulsions, which cause an increase in fluid pressure in the gathering systems, pipeline damage, as well as difficulties in gas separation and preliminary water discharge at the preliminary discharge unit (PRU). Additional problems arise during transportation of highly paraffinic oils associated with the crystallization of paraffin in the flow path of the oilfield equipment and on the inner surface of pipes, leading to a drop in the productivity of pipelines. Article discusses the technology of magnetic-reagent treatment of water-oil media, which allows intensifying the processes of primary oil treatment at the facilities of its production. Bench and pilot tests have shown the ability of the magnetic field to accelerate oil demulsification processes, increasing the percentage of separated water during subsequent settling, and to reduce asphalt-resin-paraffin deposits (ARPD) on the inner surface of oil and gas field equipment. Mechanism of the magnetic field effect on water-oil media is described. Effect of treatment on the integrity of the armour shells of oil-water emulsions was studied. Various modes of magnetic treatment have been investigated with evaluation of its effectiveness. It is shown that the best effect is achieved with the combined use of reagents and a magnetic field. Synergistic effect is observed, which consists in increasing their effectiveness. This made it possible to conclude that this method can be applied to reduce the consumption of reagents used in oil production while maintaining the treatment efficiency.
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Date submitted2020-06-09
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Date accepted2020-11-02
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Date published2020-11-24
Method of drilling process control and experimental studies of resistance forces during bits drilling with PDC cutters
A rational, theoretically proved and empirically verified control system is a condition for optimal management of the drilling process in compliance with the criteria for minimizing the cost of time and material resources. A new generation of rock-cutting tools using PDC cutters (polycrystalline diamante cutters), which are extremely ef fective when drilling wells for various purposes in medium-hard rocks, dictates the need to develop methods and criteria for optimal control of the drilling process using this tool. The paper presents an analysis of the force interaction between rock-cutting elements, face rock, and drilling mud sa turated with slam, highlights the influencing factors and provides dependencies for determining the parameters of rock failure. Empirical verification of the theoretical propositions was carried out based on the data analysis from experimental bit drilling of marble with PDC cutters with a diameter of 76.2 mm, processed using the method of full factor experiment to obtain mathematical models of factors and their graphical interpretation. The method of controlling the drilling process based on the optimal ratio of the tool rotation frequency, axial weight and deepening per one turnover is considered, which allows determining the rock failure mode at the well bottom by indirect signs and choose the optimal values of the drilling mode parameters that correspond to the most optimal conditions in terms of achieving the maximum mechanical drilling speed in conjunction with the rational mode of rock-cutting tool operation. A scheme is presented that contains possible variants of the bit run mode and ways to recognize them by the ratio of the deepening per turnover and the rotation frequency of the rock-cutting tool.
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Date submitted2019-07-21
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Date accepted2019-09-20
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Date published2020-02-25
Assessment of operational reliability of quarry excavator-dump truck complexes
- Authors:
- V. M. Kurganov
- M. V. Gryaznov
- S. V. Kolobanov
The method proposed in the article is based on the mathematical apparatus for quantitative assessment of the reliability of majority schemes of structural redundancy of transport processes, which provide the availability and usage of several backup delivery channels in the transport process in case of any malfunction. The principle of multi-channel haulage is commonly used in quarries for transportation of overburden and minerals from benches by dump trucks, when excavators and dump trucks performing cyclic operations function as a single excavator-dump truck complex. This pattern of work significantly increases the likelihood of fulfilling the daily plan for transporting rock mass due to the redistribution of dump trucks between mining and overburden excavators in the event of failure of one or more units of mining and handling equipment. The reliability of excavator-dump truck complexes is assessed in three stages: initial data collection for mathematical modeling of excavator-dump truck complex performance; solving the problem of optimizing the distribution of dump trucks between excavators, ensuring maximum productivity of the excavator-dump truck complex; assessment of the reliability of its work depending on the probability of fulfilling the daily plan for the transportation of rock mass. The proposed method is implemented as part of a computer program and makes it possible to automate the operational management of the process of transporting rock mass in a quarry using a mobile application. The developed guidelines can be used for any quarries with automobile transport, regardless of the type of mineral extracted, the mining method, the loading pattern, the capacity of the excavation and loading equipment fleet, and the capacity of operated dump trucks.
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Date submitted2019-05-30
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Date accepted2019-09-03
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Date published2020-02-25
Study on influence of two-phase filtration transformation on formation of zones of undeveloped oil reserves
- Authors:
- S. I. Grachev
- V. A. Korotenko
- N. P. Kushakova
In order to study the process of fluid filtration during flooding of an oil field, article uses Rapoport – Lis model of non-piston oil displacement by water. During plane-radial filtration in a homogeneous formation, radii of disturbance zones are determined with and without taking into account the end effect. Influence of changes in value of capillary pressure gradient on distribution of water saturation coefficient in the non-piston displacement zone for high and low permeability reservoirs is revealed. Application of an element model for a five-point injection and production well placement system showed that, using traditional flooding technology, flat-radial fluid filtration is transformed into rectilinear-parallel. At solving equation of water saturation, Barenblatt method of integral relations was used, which allows determining the transformation time. By solving the saturation equation for rectilinear-parallel filtration, change in the value of water saturation coefficient at bottomhole of production well for an unlimited and closed deposit is determined. It is shown that an increase in water cut coefficient of a production well is possible only for a closed formation. To determine coefficient of water saturation in a closed deposit, a differential equation with variable coefficients is obtained, an iterative solution method is proposed. In the element of the five-point system, oil-saturated zones not covered by development were identified. For channels of low filtration resistance, conditions for their location in horizontal and vertical planes are established. It is shown that, at maintaining formation pressure, there is an isobar line in formation, corresponding to initial formation pressure, location of which determines direction of fluid crossflow rates. Intensity of crossflows affects application efficiency of hydrodynamic, physical and chemical, thermal and other methods of enhanced oil recovery.
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Date submitted2019-07-11
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Date accepted2019-09-04
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Date published2019-12-24
Recent scientific research on electrothermal metallurgical processes
- Authors:
- E. Baake
- V. A. Shpenst
A wide range of industrial metallurgical heating and melting processes are carried out using electrothermal technologies. The application of electrothermal processes offers many advantages from technological, ecological and economical point of view. Although the technology level of the electro heating and melting installations and processes used in the industry today is very high, there are still potentials for improvement and optimization due to the increasing complexity of the applications and the strong requirements regarding the performance and quality of the products but also regarding the reduction of time and costs for the development of new processes and technologies. In this paper recent applications and future development trends for efficient heating and melting by electrothermal technologies in metallurgical processes are described along selected examples like induction heating for forging or rolling of billets, heat treatment of strips and plates, press-hardening processes, induction surface hardening of complex geometries, induction welding as well as induction melting processes.