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Date submitted2022-04-14
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Date accepted2022-07-21
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Date published2022-07-13
Mullite production: phase transformations of kaolinite, thermodynamics of the process
The growing demand for mullite raw materials, which meet industrial requirements originates the search for new and alternative sources, as well as efficient technologies for obtaining the target products (nanocomposites). The article suggests a method for obtaining mullite from kaolinite experimentally (Vezhayu-Vorykvinsky deposit, Russia). Structural kaolinite transformations (Al-Si-O-Me system), mineral phases transformations, and thermodynamics of the process have been studied. Based on the estimation of the thermodynamics of the reactions, the preferable reaction of mullite formation was determined. The article shows, that formation of the target product, mullite nanocomposite, has several intermediate phases (metakaolinite, pseudomullite). The transformations of the initial kaolinite structure include the removal of structural water and separation of the silica-oxygen tetrahedral and alumina-oxygen octahedral layers, the decomposition into free oxides, breaking of bonds between the silica-oxygen tetrahedrons and the partial increase in the coordination number of aluminium ions, the formation of mullite and cristobalite from free oxides. The proposed approach controls the ratio of Al 2 O 3 and SiO 2 phases at certain stages, which will further improve the mechanical and other properties of the matrix of the obtained raw materials for the target prototypes of industrial products.
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Date submitted2022-04-04
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Date accepted2022-05-13
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Date published2022-07-13
Distribution of trace elements controlled by sector and growth zonings in zircon from a miaskite pegmatite of the Vishnegorsky massif, the Southern Urals
Data on the content and distribution of trace and rare-earth elements (SIMS method) in sectors and growth zones of a large zircon crystal from miaskite pegmatites of the Vishnegogorsky massif are presented. The morphology of the zircon crystal is a combination of a dipyramid {111} and prism {010}. It has been established that the growth sector of dipyramid {111} is characterized by almost one order of magnitude higher contents of Y, Nb, REE, Th; higher Th/U and Eu/Eu* values; REE distribution spectra are flatter compared to prism {010} growth sector. A regular decrease in the content of trace and rare-earth elements in the direction from the central zone to the marginal zone of crystal growth was revealed. A smooth regression of zircon crystallization temperature of zircon from 960 °C in the central zone to 740 °C in the marginal zone of the dipyramid sector and 700-650 °C in the prism sector has been revealed, which may be a reflection of thermal evolution of the crystallization process. It is assumed that crystallization of the central zone of zircon occurred at early stages from a relatively trace-еlement-rich melt. The crystallization was completed at lower temperatures, probably, simultaneously with the formation of REE-concentrating minerals, which resulted in natural decrease of content of trace and rare-earth elements in the melt and, consequently, in zircon crystallizing from it.
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Date submitted2022-02-18
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Date accepted2022-05-25
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Date published2022-07-13
Remote sensing techniques in the study of structural and geotectonic features of Iturup Island (the Kuril Islands)
The article presents structural and geotectonic features of Iturup Island, the largest island in the Greater Kuril Ridge, a unique natural site, which can be considered as a geological reference. The structural and geotectonic analysis carried out on the basis of a comprehensive study of the new Earth remote sensing data, maps of anomalous geophysical geophysical fields, and other geological and geophysical materials using modern modelling methods made it possible for the first time to identify or clarify the location of previously discovered discontinuous faults, typify them and determine the kinematics, as well as to establish a more reliable spatial relationship of the identified structures with magmatism with the stages of the geological development of the region. The constructed diagram of the density distribution of the zones with increased tectonic fracturing shows a significant correlation between the distribution of minerals and weakened areas of the Earth's crust and can be used as an alternative method for predicting minerals in the study region, especially in remote and hard-to-reach areas. The presented approach can be extended to the other islands of the Greater Kuril Ridge, thereby bringing research geologists closer to obtaining the answers to questions about the features of the geotectonic structure and evolution of the island arc. The use of customized software products significantly speeds up the process of interpreting a large array of geological and geophysical data.
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Date submitted2022-05-02
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Date accepted2022-05-25
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Date published2022-07-13
Features of olivine crystallization in ordinary chondrites (Saratov meteorite): geochemistry of trace and rare earth elements
The paper discusses the geochemistry of major (EPMA) and trace (SIMS) elements in olivine of porphyritic, nonporphyritic chondrules, and the matrix of equilibrated ordinary chondrite Saratov (L4). Olivine corresponds to forsterite and is rather heterogeneous (Fo 73-77). No differences in the content of the major elements in the olivine of the chondrule and the matrix of the meteorite were found. However, the content of major and trace elements in olivine within chondrules varies considerably; high values found in olivine from barred chondrules. Olivine from porphyritic chondrules and the matrix of the Saratov meteorite have similar concentrations of trace elements. High concentrations of refractory (Zr, Y, Al) and moderately volatile (Sr and Ba) trace elements in barred olivine chondrule indicate the chondrule melt formation due to the melting of precursor minerals and its rapid cooling in the protoplanetary disk, which is consistent with the experimental data. The olivine of the chondrules center of the Saratov meteorite differs from the olivine of the chondrules rims and meteorite matrix by the increased values of the Yb/La ratio. No relict grains and magnesian cores of olivine were found in meteorite chondrules. Individual grains in the chondrules are distinguished by their enrichment in trace elements relative to the rest of the olivine grains in the chondrule.
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Date submitted2021-07-19
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Date accepted2022-05-31
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Date published2022-07-13
Study of a set of factors influencing the error of surveying mine facilities using a geodesic quadcopter
The factors influencing the qualitative and quantitative components of the result of surveying in open-pit mining using a quadcopter were identified and systematized, and the mathematical dependence of the influence of factors on the final error of surveying was determined. After a large number of field observations – numerous flights of a geodesic quadcopter over mining facilities – the subsequent mathematical justification of the results of the aerial photogrammetric surveying was made, which allowed to analyze the degree of participation in the final accuracy of the survey of each of the considered factors. The results of this study demonstrate the source of errors, which provide the surveyor with the opportunity to efficiently and competently carry out pre-flight preparation and planning of fieldwork. The study and subsequent consideration of the factors affecting the accuracy of surveying with the use of an unmanned aerial vehicle are the basis for the subsequent development and formation of a methodology for using a geodesic quadcopter in the conditions of open-pit mining.
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Date submitted2021-12-16
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Date accepted2022-04-07
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Date published2022-07-13
The Upper Kotlin clays of the Saint Petersburg region as a foundation and medium for unique facilities: an engineering-geological and geotechnical analysis
- Authors:
- Regina E. Dashko
- Georgiy A. Lokhmatikov
The article reviews the issues concerned with correctness of the engineering-geological and hydrogeological assessment of the Upper Kotlin clays, which serve as the foundation or host medium for facilities of various applications. It is claimed that the Upper Kotlin clays should be regarded as a fissured-block medium and, consequently, their assessment as an absolutely impermeablestratum should be totally excluded. Presence of a high-pressure Vendian aquifer in the lower part of the geological profile of the Vendian sediments causes inflow of these saline waters through the fissured clay strata, which promotes upheaval of tunnels as well as corrosion of their lining. The nature of the corrosion processes is defined not only by the chemical composition and physical and chemical features of these waters, but also by the biochemical factor, i.e. the availability of a rich microbial community. For the first time ever, the effect of saline water inflow into the Vendian complex on negative transformation of the clay blocks was studied. Experimental results revealed a decrease in the clay shear resistance caused by transformation of the structural bonds and microbial activity with the clay’s physical state being unchanged. Typification of the Upper Kotlin clay section has been performed for the region of Saint Petersburg in terms of the complexity of surface and underground building conditions. Fissuring of the bedclays, the possibility of confined groundwater inflow through the fissured strata and the consequent reduction of the block strength as well as the active corrosion of underground load-bearing structures must be taken into account in designing unique and typical surface and underground facilities and have to be incorporated into the normative documents.
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Date submitted2021-12-19
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Date accepted2022-05-13
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Date published2022-07-13
Development of a pump-ejector system for SWAG injection into reservoir using associated petroleum gas from the annulus space of production wells
Implementation of SWAG technology by means of water-gas mixtures is a promising method of enhanced oil recovery. The use of associated petroleum gas as a gas component in the water-gas mixture allows to significantly reduce the amount of irrationally consumed gas and carbon footprint. Relevant task is to choose a simple, reliable and convenient equipment that can operate under rapidly changing operating conditions. Such equipment are pump-ejector systems. In order to create water-gas mixture it is proposed to use associated gas from the annulus space. This solution will reduce the pressure in the annulus space of the production well, prevent supply disruption and failure of well equipment. The paper presents a principal technological scheme of the pump-ejector system, taking into account the withdrawal of gas from the annulus space of several production wells. The layout of the proposed system enables more efficient implementation of the proposed technology, which expands the area of its application. Experimental investigations of pressure and energy characteristics of the ejector have been carried out. Analysis of the obtained data showed that it was possible to increase the value of maximum efficiency. The possibility of adapting the system in a wide range of changes in operating parameters has been established. Recommendations on selection of a booster pump depending on the values of working pressure and gas content are given.
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Date submitted2021-04-19
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Date accepted2022-05-25
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Date published2022-07-13
Development of the technology of stowing the developed space during mining
- Authors:
- Evgenii R. Kovalskii
- Kirill V. Gromtsev
An analysis of the world experience in the development of potash deposits shows that the main problems arising during their development are a high level of mineral losses, an increased risk of flooding of mine workings as a result of water-proof layer discontinuance and the development of emergency water inflows in the mined-out spaces. Reduction of potash ore losses can be achieved by using a long-pillar mining system, but this method is limited by the peculiarities of the geological structure of the potash deposits and the need to preserve the continuity of the water-proof layer during its underworking. The safety of underworking of the water-proof layer can be improved by using the stowing of the developed longwall space. However, the question of the influence of the stowing on the height of the zone of water supply cracks development remains little-studied. The world experience of stowing the developed spaces in the development of layers with long pillars is analyzed and the technology of placing the stowing masses, which can solve these problems, is proposed. The considered technology and the proposed solutions are supported by laboratory tests of stowing materials and mathematical modeling of deformation zones in the overlying rocks.
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Date submitted2021-05-31
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Date accepted2022-03-24
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Date published2022-07-13
Mathematical model of linear and non-linear proppant concentration increase during hydraulic fracturing – a solution for sequential injection of a number of proppant types
It is known that much of the technology aimed at intensifying fluid inflow by means of hydraulic fracturing involves the use of proppant. In order to transport and position grains in the fracture, a uniform supply of proppant with a given concentration into the fracturing fluid is ensured. The aim of the operation is to eliminate the occurrence of distortions in the injection program of proppant HF. A mathematically accurate linear increase of concentration under given conditions is possible only if the transient concentration is correctly defined. The proposed approach allows to correctly form a proppant HF work program for both linear and non-linear increase in proppant concentration. The scientific novelty of the work lies in application of a new mathematical model for direct calculation of injection program parameters, previously determined by trial and error method. A mathematical model of linear and non-linear increase of proppant concentration during HF was developed. For the first time, an analytical solution is presented that allows direct calculation of parameters of the main HF stages, including transient concentrations for given masses of the various types of proppant. The application of the mathematical model in formation of a treatment plan allows maintaining correct proppant mass distribution by fractions, which facilitates implementation of information and analytical systems, data transfer directly from a work program into databases. It is suggested to improve spreadsheet forms used in production, which would allow applying mathematical model of work program formation at each HF process without additional labour costs. The obtained mathematical model can be used to improve the software applied in the design, modelling and engineering support of HF processes.
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Date submitted2021-10-31
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Date accepted2022-04-26
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Date published2022-07-13
Identification of structural control factors of primary gold ore occurrences by method of unmanned aeromagnetic survey by the example of the Neryungrisky district of Yakutia
The long-term development of the geophysical industry, in which the methods of magnetometry are in maximum demand, as the simplest in instrumental and methodological execution, has determined the development of remote measurement methods implemented both from space and airborne carriers. The necessity to use the latter as an obligatory component of field surveys, providing coverage of significant areas, determines the need for using the unmanned low-tonnage carriers. Their use is implemented to search for predictive elements of structural (spatial, genetic) control of endogenous gold ore occurrences that allow predictive constructions, i.e., solving the problem of increasing gold reserves, which is being performed within the framework of federal programs. The purpose of the survey is to develop a system of instrumental and subsequent interpretation approaches in the organization of unmanned magnetometer survey, implemented for structural and geological mapping by the example of the Neryungrinsky district of Yakutia. Within the framework of the digital model formation of the relief and the anomalous magnetic field, a survey method using an unmanned aircraft, its technical characteristics are considered; the analysis and the author's modification of the office analysis of magnetometry data are performed. Based on the obtained materials, a physical and geological model of the investigated area was created, which is presented in the form of a geological and structural cut, accompanied by the physical characteristics of the structural and material complexes. The refinement of the physical and geological model was implemented by a joint morphostructural analysis of the remote base and the anomalous magnetic field using the results of quantative interpretation of the anomalous magnetic field. The result of the study is presented by an updated geological basis with the allocation of promising ore sites for their detailing as part of the planned large-scale geological and geophysical surveys. The scientific novelty of the work consists in the synthesis of the tried and tested methods of unmanned aeromagnetometric measurements and geostructural reconstructions, which allow the processing of both potential and non-potential geofields.
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Date submitted2021-09-29
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Date accepted2022-05-11
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Date published2022-07-13
Tensor compaction of porous rocks: theory and experimental verification
Compaction in sedimentary basins has been traditionally regarded as a one-dimensional process that ignores inelastic deformation in directions orthogonal to the active load. This study presents new experiments with sandstone demonstrating the role of three-dimensional inelastic compaction in cyclic true triaxial compression. The experiments were carried out on the basis of a triaxial independent loading test system in the Laboratory of Geomechanics of the Ishlinsky Institute for Problems in Mechanics of the Russian Academy of Science. The elastic moduli of the material were estimated from the stress-strain curves and the elastic deformations of the sample in each of the three directions were determined. Subtracting the elastic component from the total deformation allowed to show that inelastic compaction of the sandstone is observed in the direction of active loading, whereas in the orthogonal directions there is a expansion of the material. To describe the three-dimensional nature of the compaction, a generalization of Athy law to the tensor case is proposed, taking into account the role of the stress deviator. The compaction tensor and the kinetic equation to describe the evolution of inelastic deformation, starting from the moment of the load application are introduced. On the basis of experiments on cyclic multiaxial compression of sandstone, the identification and verification of the constructed model of tensor compaction were carried out. The possibility of not only qualitative, but also quantitative description of changes in inelastic deformation under complex cyclic triaxial compression is shown.
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Date submitted2021-04-06
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Date accepted2022-04-27
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Date published2022-07-13
Experimental study on the effect of rock pressure on sandstone permeability
The results of laboratory studies to determine the effect of effective stress on the permeability of sandstone are presented. During the test, the samples were subjected to a stepwise increase or decrease of the effective stress (at a constant pore pressure) in a specified step. The values of rock permeability at different values of effective stress were determined, and the influence of the grain size of the reservoir rock matrix on the character of the change in the sandstone permeability coefficient was also established. During the test, a decrease in permeability was observed with an increase in effective stress. It was found that as a result of gradual loading/unloading of the sandstone sample, the original permeability values were not restored, which indicates the beginning of the formation of residual strains in the rock. This effect should be taken into account when modeling field development because in the process of reserves extraction the effective stress acting on the reservoir rock skeleton changes, which results in a significant chang in rock permeability. The results of laboratory studies showed that the deviation of permeability in medium-grained sandstones relative to the initial value was greater than in medium- and fine-grained sandstones. The pressure sensitivity coefficient and constant of material, which are used in empirical relationships between permeability and effective stress, were numerically estimated. At the same time, the constant of material showed no such convergence, which indicates that the values of this parameter are individual for each rock.
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Date submitted2021-04-20
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Date accepted2022-04-26
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Date published2022-07-13
Prediction of the stress-strain state and stability of the front of tunnel face at the intersection of disturbed zones of the soil mass
The article presents a numerical solution of the spatial elastic-plastic problem of determining the stability of the tunnel face soils at the intersection of disturbed zones of the soil mass. The relevance of the study is related to the need to take into account the zones of disturbed soils when assessing the face stability to calculate the parameters of the support. Based on the finite element method implemented in the PLAXIS 3D software package, the construction of a finite element system "soil mass-disturbance-face support" and modeling of the intersection of the disturbed zones of the soil mass were performed. To assess the condition of soils, deformation and strength criteria are taken. The deformation criterion is expressed by the value of the calculated displacement of the tunnel contour in the face, and the strength criterion - by the safety coefficient until the maximum values of the stress state are reached according to the Coulomb–Mohr criterion. The results of the study are presented in the form of histograms of the safety coefficient dependences on the distance to the disturbance at different bending stiffness of the face support structure, as well as the isofields of deformation development. The parameters of rockfall formation in the face zone at the intersection of zones of disturbed soils were determined. The local decrease in strength and deformation properties in the rock mass along the tunnel track should be taken into account when assessing the stability of the tunnel face and calculating the parameters of the support. Within the framework of the constructed closed system, a qualitative agreement of the simulation results with the case of a collapse in the face during the construction of the Vladimirskaya-2 station of the St. Petersburg Metro was obtained.
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Date submitted2021-02-24
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Date accepted2022-04-06
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Date published2022-07-13
Study of the kinetics of the process of producing pellets from red mud in a hydrogen flow
The reduction kinetics of serial phase transitions of iron oxides during reduction to a metallized state with different modes of technical hydrogen supply has been studied and substantiated. The results of the pellets formation when 3-5 % molasses is added to the red mud as a binding reagent are presented. The dependences of the reduction rate of iron oxides on the hydrogen flow rate are obtained. Based on the results of the experiments, a kinetic model was constructed, and with the help of X-ray phase and spectral analysis, it was proved that the agglomerates formed after heat treatment received high strength due to the adhesion of reduced iron particles with red mud particles. The use of a new type of charge materials in melting units will reduce the amount of emissions and dust fractions, as well as increase the metal yield.