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Date submitted2022-09-21
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Date accepted2024-06-03
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Date published2024-12-25
Analysis of the assessment of the prospects for the burial of CO2 in unexplored aquifer complexes on the example of a facility in the Perm Region
One of the most important problems of our time is the annual increase in greenhouse gas emissions into the atmosphere. It is possible to combat this phenomenon by reducing emissions or developing and applying technologies for capturing, storing, using and disposing of CO2. In this work, an assessment of the expediency and possibility of carbon dioxide burial in deep aquifers is considered, the study of which is carried out to a small extent and due to the lack of useful material in them. The parameters and results of CO2 injection into the aquifer of one of the oil fields of the Perm Region, the geological properties and characteristics of which are determined in this work, are studied. The criteria of applicability, methods of estimating the volume of the reservoir and laboratory studies to determine the properties of CO2 and the features of its interaction with the model of the reservoir fluid are considered. The injection object and reservoir volume were determined, PVT studies of the target gas were performed, and its solubility in reservoir water was determined. The duration of filling the full volume of the trap when capturing 400 thousand tons of CO2 per year from the target industrial facility is calculated to be 202 years. This conclusion signals the prospects for the burial of carbon dioxide in the underground deposits of an undeveloped aquifer complex in the Perm Region, which reflects the importance of studying such geological CO2 burial sites in order to achieve global carbon neutrality goals.
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Date submitted2023-09-29
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Date accepted2023-10-25
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Date published2024-08-26
Laboratory studies of transformation of porosity and permeability and chemical composition of terrigenous reservoir rocks at exposure to hydrogen (using the example of the Bobrikovskii formations in the oil field in the northeast Volga-Ural oil and gas province)
The article describes the methodology for laboratory studies of reservoir rock exposure to hydrogen. The stages of sample research and the instruments used in the experiments are considered. A comparative analysis of the results of studies on porosity and permeability of core samples was performed. It was shown that after exposure to hydrogen, the porosity decreased by 4.6 %, and the permeability by 7.9 %. The analysis of correlation dependencies demonstrated a typical change in the relationship of these characteristics: after the samples exposure to hydrogen the scatter of the values increased and the correlation coefficient decreased, which indicates a change in the structure of the void space. Based on the research results, it was concluded that the decrease in porosity and permeability of the core samples occurred due to their minor compaction under the action of effective stresses. The chemical analysis of the rock showed no major difference in the composition of the basic oxides before and after exposure to hydrogen, which points to the chemical resistance of the studied formation to hydrogen. The experimental results showed that the horizon under consideration can be a storage of the hydrogen-methane mixture.
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Date submitted2024-04-10
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Date accepted2024-06-03
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Date published2025-04-25
Combined method for processing spent acid etching solution obtained during manufacturing of titanium products
Possessing high strength, low density and significant chemical resistance, titanium has found wide application in various fields of the national economy – the chemical industry, aviation and rocket technology, mechanical engineering, medicine, etc. The production of titanium products is hampered by a fairly strong oxide film covering its surface. Removal of the oxide film from the surface of titanium workpieces is carried out by etching in solutions of mineral acids of various compositions. A spent acid etching solution (SAES) is formed, containing titanium salt and the remainder of unreacted acids. Almost all etching solutions contain HF and one of the strong acids. This is H2SO4, HCl or HNO3. Thus, the SAES includes ions of titanium, fluorine or chlorine, orsulfate, or nitrate. SAES is quite toxic and must be diluted or cleaned several times before being discharged into a reservoir. Most of the methods used to extract impurities contained in SAES lead to a decrease in their content. As a result of such purification, there is a loss of substances contained in SAES in significant quantities and of interest for further use. The work presents experimental results obtained from the combined processing of SAES containing titanium fluoride, hydrofluoric and hydrochloric acids. At the first stage, SAES is treated with sodium hydroxide. The resulting titanium hydroxide precipitate is filtered off. At the second stage, the filtrate containing sodium fluoride and chloride is processed in a membrane electrolyzer. In this case, not only the extraction of sodium salts from the filtrate occurs, but also the production of sodium hydroxide and a mixture of hydrofluoric and hydrochloric acids. Sodium hydroxide can be used for processing SAES, and a mixture of acids for etching titanium workpieces.
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Date submitted2024-03-30
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Date accepted2024-06-03
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Date published2024-07-04
Preparation and use of complex titanium-containing coagulant from quartz-leucoxene concentrate
- Authors:
- Evgenii N. Kuzin
The search for the new high-efficiency reagents for wastewater treatment is a challenging and urgent task. Titanium-containing coagulants represent a new trend in water treatment and have a much higher efficiency that the traditional aluminium and iron-containing coagulants. The high cost of reagents significantly hinders their implementation. Complex titanium-containing reagents are coagulants prepared by modifying the traditional coagulants by adding 2.5-10.0 wt.% titanium compounds. In this work, titanium tetrachloride prepared from quartz-leucoxene concentrate was prehydrolyzed with subsequent double decomposition with sulfuric acid. The resulting mixture of hydrochloric and sulfuric acids was neutralized with aluminium hydroxide/oxide to form a self-hardening mixture (chemical dehydration). The sample of a complex sulfate-chloride titanium-containing coagulant was a mixture of AlCl3·6H2O – 5-20 wt.%, Al2(SO4)3·18H2O – 70-90 wt.% and TiOSO4 – 2.5-10.0 wt.%. It was proved that by changing the ratio of aluminium oxide/hydroxide and titanium tetrachloride at the stage of prehydrolysis and double decomposition, it is possible to obtain samples of a complex coagulant with different contents of the modifying additive of titanium compounds. An assessment of the coagulation properties of the complex reagent demonstrated its higher efficiency in cold water compared to aluminium sulfate. Studies on the use of the complex titanium-containing coagulant in the process of wastewater treatment from phosphate anions and suspended matter demonstrated its higher efficiency as compared to that of traditional reagents. The advantages of the prepared reagent are a reduction in the effective dose of the reagent, minimization of residual concentrations of pollutants in purified water, intensification of the processes of sedimentation and filtration of coagulation sludge. Purified water can be reused in the recycling water supply system. The use of quartz-leucoxene concentrate and titanium tetrachloride obtained from it as the source material would not only minimize the cost of the resulting complex coagulant, but also take a step towards the implementation of the Zero Waste concept.
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Date submitted2022-05-20
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Date accepted2023-04-03
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Date published2024-02-29
Impact of carbon dioxide on the main geotechnical quality criteria and preparation cost of cemented paste backfill
There is a global upsurge in the use of cemented paste backfill (CPB) for various mining functions. However, the cost of the Portland cement binder is prohibitive, thus warranting strategies to reduce cement usage without overly diminishing the CPB quality. Since carbon dioxide is used for patented sand moulding processes, this study is premised on that physicochemical ability of CO2 to enhance the curing of consolidated inorganic materials. It evaluated the impact of carbon dioxide on the uniaxial compressive strength UCS and preparation cost of CPB standard samples (ASTM C109). The preparation cost was delimited to the purchase cost of the Portland cement. The backfill material was silica sand tailings with 4.5 wt.% Portland cement binder and a water-cement ratio of 7.6. Distilled water of pH 5.4 was used for the control samples while variable amounts of carbon dioxide were dissolved in distilled water to generate carbonated mixing water with pH values of 3.8; 4 and 4.2. The lower the carbonated water pH, the higher is the CO2 concentration. UCS tests were conducted on the samples after curing for 3, 7, 28, and 90 days. There was an observable increase in the UCSs and reduction in curing time with increasing carbon dioxide. Samples prepared with carbonated water of pH 3.8 had almost double the strength of those prepared with pure distilled water of pH 5.4, implying that more dissolved CO2 corresponds to higher CPB strength. This is supported by the trendline equations for the graphical simulation of strength on curing time. Thus, CPB with much less binder can be expected to attain the requisite UCS if carbon dioxide is incorporated. The average reduction in Portland cement consumption was 0.61 %, which translates to a cost saving of the same percentage points. If calculated over the operational life of a mine, this is a massive saving of millions of dollars.
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Date submitted2023-01-12
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Date accepted2023-06-20
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Date published2023-07-19
Improvement of energy efficiency of ore-thermal furnaces in smelting of alumosilicic raw materials
The issues of energy saving in pyrometallurgical production during processing of mineral raw materials in ore-thermal furnaces are particularly important for the development of new energy-efficient technologies. The reduction of the specific power consumption during melting at different stages of heating and melting of charge materials when modeling is related to obtaining kinetic curves in the process of kyanite concentrate regeneration in polythermal conditions. Based on practical data of carbo-thermal reduction the mathematical modeling of reduction processes from alumosilicic raw materials – kyanite was carried out. In this work, the nonisothermal method based on a constant rate of charge heating (i.e. a linear dependence between time and temperature) was used for the reduction of kyanite charge, which saves electrical energy. The experiments were carried out on a high-temperature unit with a heater placed in a carbon-graphite crucible. Based on the obtained kinetic dependences of nonisothermal heating of enriched kyanite concentrates in plasma heating conditions we obtained a number of kinetic anamorphoses of the linear form which point to the possibility of describing the reaction rate using the modified Kolmogorov – Erofeev equation for given heating conditions and within a narrow temperature range. The complex of mathematical modeling makes it possible to create a control algorithm of technological process of reduction of kyanite concentrate to a metallized state within the specified temperature range for the full flow of reaction exchange and to reduce the specific power consumption by 15-20 %. With the help of the received kinetic dependences, taking into account the thermodynamics of processes and current state of the art it is possible to create a universal thermal unit for the optimal carbothermal reduction of charge to a metallized state (alloy) with minimum power inputs compared to existing technologies.
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Date submitted2022-10-23
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Date accepted2023-02-13
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Date published2023-12-25
Sorption purification of acid storage facility water from iron and titanium on organic polymeric materials
Obtaining and production of metals from natural raw materials causes a large amount of liquid, solid, and gaseous wastes of various hazard classes that have a negative impact on the environment. In the production of titanium dioxide from ilmenite concentrate, hydrolytic sulphuric acid is formed, which includes various metal cations, their main part is iron (III) and titanium (IV) cations. Hydrolytic acid waste is sent to acid storage facilities, which have a high environmental load. The article describes the technology of ion exchange wastewater treatment of acid storage facility from iron (III) and titanium (IV) cations, which form compounds with sulphate ions and components of organic waste in acidic environments. These compounds are subjected to dispersion and dust loss during the evaporation of a water technogenic facility, especially in summer season. Sorption of complex iron (III) cations [FeSO4]+ and titanyl cations TiO2+ from sulphuric acid solutions on cation exchange resins KU-2-8, Puromet MTS9580, and Puromet MTS9560 was studied. Sorption isotherms were obtained both for individual [FeSO4]+ and TiO2+ cations and in the joint presence. The values of the equilibrium constants at a temperature of 298 K and the changes in the Gibbs energy are estimated. The capacitive characteristics of the sorbent were determined for individual cations and in the joint presence.
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Date submitted2022-10-14
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Date accepted2022-12-13
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Date published2023-02-27
Carbon capture and storage: net zero contribution and cost estimation approaches
Carbon capture, utilization, and storage (CCUS) are a combination of necessary and promising technologies that can help reduce CO2 emissions, which are not used on a large scale due to the high cost of solutions. This article aims to review and analyze carbon capture and storage (CCS) projects in terms of their net zero contribution and cost estimates. The study identified a wide range of cost estimation methods that can be applied to CCS projects and revealed such issues as a lack of standardization, limited data, and cost data variability. Still, several common trends were found, including the classification of CCS adopters into low-cost and high-cost industries, cost estimation by CCS step (capture, transportation, storage) and industry (power generation, other sectors), and calculation of relative indices to make comparisons with other decarbonization options. The results of the study can serve as a foundation for developing approaches to estimating the costs of CCS in Russia, which are necessary for planning government support measures and involving businesses in the implementation of these initiatives.
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Date submitted2022-03-25
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Date accepted2022-09-06
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Date published2022-12-29
Autoclave modeling of corrosion processes occurring in a gas pipeline during transportation of an unprepared multiphase medium containing CO2
The problem of selecting a method for ensuring the reliability of the unprepared fluid transport facilities of an unprepared fluid in the presence of carbon dioxide is considered. Carbon dioxide corrosion is one of the dangerous types of damage to field and main pipelines. It has been shown that dynamic autoclave tests should be carried out during staged laboratory tests in order to determine the intensity of carbon dioxide corrosion and to select the optimal method of protection. A hypothesis about the imperfection of the existing generally accepted approaches to dynamic corrosion testing has been put forward and confirmed. A test procedure based on the use of an autoclave with an overhead stirrer, developed using elements of mathematical modeling, is proposed. The flows created in the autoclave provide corrosive wear of the sample surface similar to the internal surfaces elements wear of the pipelines piping of gas condensate wells. The autoclave makes it possible to simulate the effect of the organic phase on the flow rate and the nature of corrosion damage to the metal surface, as well as the effect of the stirrer rotation speed and, accordingly, the shear stress of the cross section on the corrosion rate in the presence/absence of a corrosion inhibitor. The given results of staged tests make it possible to judge the high efficiency of the developed test procedure.
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Date submitted2022-04-14
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Date accepted2022-07-21
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Date published2022-11-03
Technological mineralogy: development of a comprehensive assessment of titanium ores (exemplified by the Pizhemskoye deposit)
Technological mineralogy of titanium ores is the basis for assessing their complexity. It enables, from a unified standpoint, to trace the entire course of changes in mineral matter through operating procedures, including beneficiation, processing, and obtaining target industrial products. The study targets are Pizhemskoye ilmenite-leucoxene sandstones, which are distinguished by a complex polymineral composition. Along with the main ore components, there are other metals with different speciation (isomorphic admixture, independent mineral phases). The optimal set of mineralogical analysis methods for the predictive assessment of their further use is substantiated exemplified by titanium ores of the Pizhemskoye deposit, which are complex, noted for a variable content of iron oxides and contain rare earth metals. Examinations by X-ray phase analysis and scanning electron microscopy confirm that the main titanium phases of sandstones are pseudorutile and a polymineral aggregate, “leucoxene”. Considering the granulometric peculiarities of the magnetic and non-magnetic fractions of the gravity concentrate, the prospects of technologies for processing titanium raw materials are discussed. Along with the problems of obtaining high-quality raw materials, the transformations of mineral phases as a result of extreme impacts and their physicochemical properties as a consequence of isomorphic substitution of a part of Ti atoms with natural modifier agents (Fe and V) in the synthesis of titanium oxide nanostructures for industrial applications are considered (photocatalytic nanoreactor).
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Date submitted2021-04-15
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Date accepted2021-07-27
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Date published2021-10-21
Analysis of the application and impact of carbon dioxide media on the corrosion state of oil and gas facilities
Products of several currently operated production facilities (Bovanenkovskoye, Urengoyskoye oil and gas condensate fields, etc.) contain an increased amount of corrosive CO 2 . Effect of CO 2 on the corrosion of steel infrastructure facilities is determined by the conditions of its use. Carbon dioxide has a potentially wide range of applications at oil and gas facilities for solving technological problems (during production, transportation, storage, etc.). Each of the aggregate states of CO 2 (gas, liquid and supercritical) is used and affects the corrosion state of oil and gas facilities. Article analyzes the results of simulation tests and evaluates the corrosion effect of CO 2 on typical steels (carbon, low-alloy and alloyed) used at field facilities. The main factors influencing the intensity of carbonic acid corrosion processes in the main conditions of hydrocarbon production with CO 2 , storage and its use for various technological purposes are revealed. Development of carbon dioxide corrosion is accompanied and characterized by the localization of corrosion and the formation of defects (pitting, pits, etc.). Even alloyed steels are not always resistant in the presence of moisture and increased partial pressures of CO 2 , especially in the presence of additional factors of corrosive influence (temperature, aggressive impurities in gas, etc.).
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Date submitted2020-10-22
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Date accepted2021-03-02
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Date published2021-04-26
Dynamic simulation of industrial-scale gibbsite crystallization circuit
- Authors:
- Vladimir O. Golubev
- Tatyana E. Litvinova
Population balance model is crucial for improving the method of aluminum hydroxide massive crystallization and enhancing the quality of control over industrial precipitation trains. This paper presents the updated population balance model, which can be used for simulation of industrial-scale precipitation. Processes of birth-and-spread and particle breakage are considered integral parts of the precipitation process along with secondary nucleation, growth and agglomeration of particles. The conceptual difference of the proposed system of equations is its ability to reproduce the oscillatory process that occurs in precipitation circuits as a result of cyclic changes in the quality of the seed surface. It is demonstrated that self-oscillations can occur in the system without any external influence. The updated model is adjusted and verified using historical industrial data. The simulation of seed-recycle precipitation circuit showed an exact correspondence between the calculated dynamic pattern of changes in particle size distribution of aluminum hydroxide and the actual data.
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Date submitted2019-11-20
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Date accepted2020-01-20
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Date published2020-10-08
Effect of shear stress on the wall of technological pipelines at a gas condensate field on the intensity of carbon dioxide corrosion
The object of the study is a section of the gas and gas condensate collection system, consisting of an angle throttle installed on a xmas tree and a well piping located after the angle throttle. The aim of the study is to assess the impact of the flow velocity and wall shear stress (WSS) on the carbon dioxide corrosion rate in the area of interest and to come up with substantiated recommendations for the rational operation of the angle throttle in order to reduce the corrosion intensity. In the course of solving this problem, a technique was developed and subsequently applied to assess the influence of various factors on the rate of carbon dioxide corrosion. The technique is based on a sequence of different modeling methods: modeling the phase states of the extracted product, three-dimensional (solid) modeling of the investigated section, hydrodynamic flow modeling of the extracted product using the finite volume method, etc. The developed technique has broad possibilities for visualization of the obtained results, which allow identifying the sections most susceptible to the effects of carbon dioxide corrosion. The article shows that the average flow velocity and its local values are not the factors by which it is possible to predict the occurrence of carbon dioxide corrosion in the pipeline section after the angle throttle. The paper proves that WSS has prevailing effect on the corrosion intensity in the section after the angle choke. The zones of corrosion localization predicted according to the technique are compared with the real picture of corrosion propagation on the inner surface of the pipe, as a result of which recommendations for the rational operation of the angle throttle are formed.
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Date submitted2020-04-24
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Date accepted2020-05-20
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Date published2020-10-08
Prospects and social effects of carbon dioxide sequestration and utilization projects
The issues of global warming and occurrence of the greenhouse effect are widely discussed on a global scale. Various methods of reducing greenhouse gas emissions are actively being investigated and tested, including technologies for sequestration of carbon dioxide, the implementation of which is carried out in the form of CC(U)S (carbon capture, utilization and storage) projects related to capture, disposal and, in some cases, use of CO 2 . In Russia, CC(U)S technologies are not yet used, but there is a significant potential for their development and distribution. CC(U)S technologies acquire a special role in the context of the development of the energy and industrial sectors of Russia, which are key sources of emissions, and the geological objects belonging to them are potential carbon storages. The purpose of this study is to conceptually analyze the CC(U)S technological cycle and typify such projects, assess the prospects for their implementation in Russia, and identify social effects from the implementation of CC(U)S projects. The main results of the study are presented in the form of a typology of CC(U)S projects, a strategic analysis of the prospects for introduction of such technologies in Russia, as well as development of approaches to assessing social effects with systematization and highlighting a set of indicators for their assessment, which can serve as a basis for re-estimation of the values of CC(U)S projects. The main research methods used were methods of decomposition, systematization and typology, as well as strategic analysis with a focus on relevant practical materials on the topic of the work. Directions for further research are related to the substantiation of the methodology for assessing social effects of CC(U)S projects, including for the conditions of Russia, based on the principles of balancing the interests of key participants.
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Date submitted2019-07-11
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Date accepted2019-09-02
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Date published2019-12-24
Stakeholders management of carbon sequestration project in the state – business – society system
Prevention of catastrophic effects of climate change is one of the most pressing challenges of this century. A prominent place in the low-carbon development system today is carbon capture and storage technology (CCS). This technology can significantly reduce greenhouse gas emissions, leading to global warming. Effectiveness of technology has been proven through successful implementation of a number of CCS projects. CCS projects are implemented in the context of national and often international interests, consolidating efforts of many parties. Sequestration projects involve government bodies, public, industrial and scientific sectors, as well as a number of other business structures. Each participant presents his own expectations for results of the project, which can compete among themselves, creating threats to its successful implementation. World experience in implementing CCS projects indicates that opposition from a certain group of stakeholders can lead to closure of a project, therefore, interaction with environment is one of the key elements in managing such projects. This study focuses on specifics of stakeholder management in implementation of CO 2 sequestration projects. Based on the analysis of world experience, role of the state, business and society in such projects is determined, their main expectations and interests are summarized. The main groups of stakeholders of CCS and CCUS (carbon capture, utilization and storage) projects were identified, differences in their interests and incentives to participate were analyzed. It is proved that system of interaction with stakeholders should be created at the early stages of the project, while management of stakeholders is a continuous process throughout the life cycle. An author’s tool is proposed for assessing degree of stakeholder interest, the use of which allowed us to determine interaction vectors with various groups of stakeholders.
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Date submitted2019-01-22
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Date accepted2019-03-16
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Date published2019-06-25
Key factors of public perception of carbon dioxide capture and storage projects
- Authors:
- S. V. Fedoseev
- Pavel S. Tcvetkov
One of the major challenges of the modern world is the problem of global warming, the solution of which requires the implementation of a set of strategic projects in the field of transition of the energy sector to the path of environmentally balanced development. One of the ways to implement this transition is the development of technologies for capturing and storage of technogenic carbon dioxide, which is recognized as the main one of greenhouse gases. At the same time, in the Russian context, the most expedient is the implementation of technological chains for capturing and storing CO 2 which are aimed at enhanced oil recovery, the effectiveness of which has been proven by world practice. Implementation of these projects requires consolidation of efforts of many parties, including government agencies, enterprises-issuers (power generating facilities and energy-intensive industry), oil-producing enterprises, non-state environmental organizations, media and public. World practice has many examples when uncoordinated actions of one of the stakeholders led to the closure of such a project, and therefore it is necessary to develop a mechanism of interaction between them, taking into account the specifics of Russian conditions. One of the least studied and controversial aspects of this interaction is to involve the public in the implementation of national carbon intensity programs and the local population in the implementation of a specific project. Research in this field has been conducted in the world over the past 14 years, which allowed the current research base to be used to develop fundamental principles for the development and promotion of CO 2 capture and storage technologies in Russia. Key factors affecting the perception of such projects by public were also analyzed and systematized. The research identified the main arguments for and against the development of CO 2 capture and storage technologies.
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Date submitted2018-11-09
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Date accepted2019-01-08
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Date published2019-04-23
Effect of chalk thermal treatment mode on its strength
- Authors:
- V. A. Lipin
- D. A. Trufanov
Natural chalk is characterized by a fine-grained structure. The processing of chalk in conditions traditional for calcium carbonate baking is accompanied by its almost destruction and the formation of a huge amount of dust. The paper presents strength characteristics of chalk and chalky stone baking obtained with different temperature-time conditions of heating the raw material to a temperature of 450-600 °C. The uniaxial compression method was used to determine the strength depending on variable factors. Based on the experimental data, a model was constructed that determines the dependence of chalk strength on time and heating temperature. In the temperature range of 450-600 °C, the strength of chalk stone increases with increasing temperature and decreases with the increasing heating rate. In the process of isothermal heating, several factors will immediately affect the strength of a chalky stone: the formation and growth of calcite crystals, the evaporation of water, and the agglomeration of calcite grains. With an increase in the heating temperature from 450 to 600 °C, the average size of the crystals significantly increases and crystals with an estimated size of more than 4 microns are detected. An increase in the size of crystals is associated with an increase in their growth rate. The agglomeration of grains occurs at a temperature of 600 °C.
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Date submitted2017-12-29
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Date accepted2018-03-26
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Date published2018-06-22
Methods to enhance oil recovery in the process of complex field development of the Yarega oil and titanium deposit
- Authors:
- I. E. Dolgii
Yarega oil and titanium deposit is a unique facility due to a combination of two mineral resources – oil and titanium ore – in one geologic structure. The paper describes mining and geologic conditions of the field, as well as engineering solutions to enhance oil recovery and the efficiency of heat transfer. The author focuses on the issues of deposit opening and preparation for development, and provides recommendations regarding the exploitation procedure of the oil and titanium parts of the field, which take into account field data on the extraction rates of high viscosity oil and titanium ore from the start of deposit development. The paper contains analysis of existing technological schemes of high viscosity oil extraction and steam heating of the oil bed, as well as assessment of their feasibility. Issues of field preparation for development are reviewed from the position of accumulated practical experience, and recommendations on the feasibility of combined underground and open-pit mining are supported with evidence. The main advantages of the proposed system are explained; key technical and economic indicators are calculated.
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Date submitted2017-11-15
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Date accepted2018-01-13
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Date published2018-04-24
Use of nano-dimensional hydrophobic coatings for obtaining electrets based on silicon dioxide
- Authors:
- N. S. Pshchelko
The article considers the physical-technological foundations of formation of the silicon dioxide (SiO 2 ) based electret for use in devices of MEMS technology. Studies have shown that the best electret properties are in SiO 2 obtained in «wet» oxygen medium as compared to samples obtained by other oxidation methods. This is probably due to the large number of Si-OH groups on the surface of the oxide in the «wet» SiO 2 , which increases the effectiveness of the hydrophobic coatings during the modification of the SiO 2 surface. It has been found that other methods of obtaining oxide, for example, electrochemical or plasmachemical, do not make it possible to obtain SiO 2 with good electret properties. The decrease of the charge injected into an electret can occur due to the presence of volume or surface conductivity, as well as the screening of this charge by opposite charges from the medium, leading to significant decrease of electret surface potential at high ambient humidity. To increase the stability of the electret effect, it is necessary to perform water-repellency treatment of SiO 2 surface by applying thin (nanosized) water-repellent coatings. Experimental results on the stability of the electret surface potential are presented for usage of various water repellents. The most promising water repellents are high-temperature photoresist FPT-1-40 and polyimide nanolayer compositions – Langmuir-Blodgett films.
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Date submitted2016-09-02
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Date accepted2016-11-08
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Date published2017-02-22
Mathematical models of gas-dynamic and thermophysical processes in underground coal mining at different stages of mine development
- Authors:
- M. V. Gryazev
- N. M. Kachurin
- S. A. Vorobev
New trends have been traced and the existing ones refined regarding filtration and diffusive motion of gases in coal beds and surrounding rock, spontaneous heating of coal and transport of gas traces by ventilation currents in operating coal mines. Mathematical models of gas-dynamic and thermophysical processes inside underworked territories after mine abandonment have been justified. Mathematical models are given for feasible air feeding of production and development areas, as well as for the development of geotechnical solutions to ensure gas-dynamic safety at every stage of coal mine operation. It is demonstrated that the use of high-performance equipment in the production and development areas requires more precise filtration equations used when assessing coal mine methane hazard. A mathematical model of pressure field of non-associated methane in the edge area of the coal seam has been justified. The model is based on one-dimensional hyperbolic equation and takes into consideration final rate of pressure distribution in the seam. Trends in gas exchange between mined-out spaces of high methane- and CO 2 -concentration mines with the earth surface have been refined in order to ensure environmental safety of underworked territories.
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Date submitted2015-08-17
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Date accepted2015-10-25
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Date published2016-04-22
Ecological aspects of vehicle tunnels ventilation in the conditions of megalopolises
- Authors:
- S. G. Gendler
The characteristic of Russia and foreign vehicle tunnels are provided in paper and advantages of their placement in the conditions of the city are noted. It is shown that one of the main factors defining negative impact on environment in the period of tunnels driving is mine equipment, and at operation – vehicles. The analysis of essential differences of features of pollution of atmospheric air at construction of tunnels from its pollution at construction of buildings on a surface is given. The examples illustrating levels of negative impact of the upcast ventilation shaft airflow on atmospheric air are given and the ventilation schemes reducing this influence are offered. It is shown that during operation of road tunnels of pollution of the air environment can extend on considerable distances from tunnel portals. Numerical calculations of concentration of carbon oxides and nitrogen during removal of the upcast ventilation shaft airflow through portals and through the mines built near them are executed. Technical solutions on purifications of tunnel air by means of electrostatic filters are described.
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Date submitted2014-11-19
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Date accepted2015-01-12
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Date published2015-10-26
Scientific heritage of academician Nikolay Semenovich Kurnakov
- Authors:
- O. A. Dubovikov
Once N.V.Lipin, a professor of mathematics at the Leningrad Mining Institute, told N.S.Kurnakov that M.V.Lomonosov had complained about his lack of familiarity with mathematics. The outstanding scientist replied «That’s absolutely true, and I have already told you about it: we all need mathematics, and the more chemistry develops, the more it needs a mathematical justification». According to one scenario of the international nongovernmental organization, the Club of Rome, there will be a three-fold decrease in the world’s raw materials resources and multifold volume reduction in industrial production by the middle of the 21st century. Another scenario claims that raw materials will reduce only by one third, and the volume of industrial production will remain at the level of the beginning of the century. Not only the first scenario, but also the second one forecasts industrial stagnation. It is unacceptable for dynamic and sustainable development of the technological civilization. Intensively developing economies in China, India, Brazil and Russia defy the forecast of the Club of Rome, as it has not taken into account the possibility of scientific and technological progress in reducing energy consumption and using alternative sources, as well as the increased technological potential of the humanity. Due to depletion of the main sources of energy (oil and gas), many experts link the future of the world’s power industry with the possible use of solid energy resources. From the environmental point of view solid fuel gasification technology is the most preferable. As the calorific value of producer gas is relatively low in comparison with natural gas, some research of possible use of producer gas (as an alternative to natural gas which is available not in all regions) at Russian industrial enterprises has been conducted.
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Date submitted2009-08-06
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Date accepted2009-10-10
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Date published2010-02-01
Allocation of tellurium from difficult on structure of sulfuric acid solutions
- Authors:
- S. B. Fokina
As the main source of reception of tellurium serve electrolytic copper refinery slimes. In the conditions of manufacture expansion and transition on technology decopperizing slimes by pressure leaching O 2 -H 2 SO 4 media, the solution (decopperized product) becomes the basic concentrator of tellurium. Extraction of tellurium from a decopperized (pressure-leached) liquid products is considered. The method allows to raise percent of extraction of tellurium from initial raw materials and to enrich pressure-leached solid product with precious metals.
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Date submitted2008-10-30
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Date accepted2008-12-22
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Date published2009-12-11
Investigations of the mechanism of methane desorption in coal saturation with carbon dioxide
- Authors:
- A. T. Karmansky
The article considers the developed unit for investigations of interaction between coal and gas, and gas outflow from the coal surface by gravimetric method under gas pressure up to 6 MPa. Relationship between the sorption ability and metamorphism stage is explained by the microstructure of coal. The adsorption increment indices of volume V and velocity of changes in pressure P – during adsorption may be used for prediction of outburst-hazard of coal and gas.
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Date submitted2008-10-01
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Date accepted2008-12-05
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Date published2009-12-11
Nickel-containing iron oxides in the Buruktal deposit, South Urals
In the Buruktal supergene nickel deposit, iron oxides possess vertical mineralogical zoning (bottom-up): magnetite-maghemite-goethite-hematite. The main rock- and ore-forming mineral in the iron-oxide zone of the deposit is magnetite, presented by three generations: primary relic magnetite, surviving from ultramafic rocks; secondary magnetite, forming at serpentinization process and neogenic supergene magnetite. Supergene magnetite, like a goethite, is nickel ore mineral, containing about 1 % NiO. Under the complex thermal analysis data, maghemite-magnetite and goethite have two main diagnostic maximums: exothermal effect of magnetite, caused by magnetite oxidation to maghemite in the interval 317‑340 °С, displays maximum at 327 °С («magnetite» point), and endothermic effect of goethite, connected with loss of constitutional water of the mineral and its transition to hematite in the interval 269‑296 °С, displays maximum at 288 °С («goethite» point).