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Date submitted2024-03-22
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Date accepted2024-09-24
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Date published2025-02-25
Behaviour of cerium (III) phosphate in a carbonate-alkaline medium
- Authors:
- Tatyana E. Litvinova
- Stepan A. Gerasev
The article investigates the behaviour of rare earth metals in carbonate-alkaline systems. The results of experimental studies on rare earth element extraction from phosphogypsum, a large-tonnage industrial waste forming in production of phosphoric acid are presented. Using the liquid phase leaching method, it was possible to extract more than 53 % of rare earth elements from old phosphogypsum and more than 69 % from fresh phosphogypsum due to solid phase treatment with a 4 mol/l potassium carbonate solution at temperature 90 °C. The behaviour of model cerium (III) phosphate in a carbonate-alkaline medium is characterized: a solubility isotherm is obtained as well as the dependences of the degree of cerium extraction into solution on temperature, carbonate ion concentration, interphase ratio, stirring intensity, and pH. The ability of soluble rare earth element complexes to precipitate over time was established, which was confirmed using cerium and neodymium as an example. Within 240 h after the end of the experiment, approximately 25 % of cerium and 17 % of neodymium were precipitated from the liquid phase. A similar property was recorded in representatives of the light group and was not noted in elements of the heavy group. The ability to self-precipitate in future can serve as a basis for developing an alternative approach to separating rare earth metals into groups after extraction in a carbonate ion medium. Also, based on the analysis of experimental data, the mechanism of cerium (III) phosphate dissolution in a carbonate-alkaline medium was characterized. An assumption was made that rare earth metal phosphates dissolve sequentially passing into an insoluble carbonate and then into a soluble carbonate complex.
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Date submitted2024-04-16
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Date accepted2024-09-24
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Date published2024-11-12
Deep-buried Lower Paleozoic oil and gas systems in eastern Siberian Platform: geological and geophysical characteristics, estimation of hydrocarbon resources
The study of deep-buried oil and gas systems is a promising trend in the preparation of hydrocarbon resources. The study of the factors determining oil and gas potential is extremely important. The Lena-Vilyui sedimentary basin in the eastern Siberian Platform has a potential for the discovery of large oil and gas fields in deep-buried Cambrian deposits. The use of original methodological approaches to the analysis of black shale and overlying deposits, generalization of the results of lithological, biostratigraphic and geochemical studies of Cambrian deposits in territories adjoining the study area, modern interpretation of geophysical data showed that siliceous, carbonate, mixed rocks (kerogen-mixtite) of the Kuonamka complex and clastic clinoform-built Mayan deposits are most interesting in terms of oil and gas potential. Oil and gas producing rocks of the Lower and Middle Cambrian Kuonamka complex subsided to the depths of 14 km. The interpretation of modern seismic surveying data confirms the hypothesis of a limited occurrence of the Upper Devonian Vilyui rift system. Based on generalization of geological, geophysical and geochemical archival and new materials on the Lower Paleozoic deposits of the eastern Siberian Platform, a probabilistic estimation of geological hydrocarbon resources of the Cambrian and younger Paleozoic complexes in the Lena-Vilyui sedimentary basin was performed. Based on basin modelling results it was concluded that the resources were mainly represented by gas. It is presumed that oil resources can be discovered in traps of the barrier reef system as well as on the Anabar and Aldan slopes of the Vilyui Hemisyneclise. With a confidence probability of 0.9, it can be stated that total initial resources of oil and gas (within the boundaries of the Vilyui Hemisyneclise) exceed 5 billion t of conventional hydrocarbons. The recommended extremely cautious estimate of resources of the pre-Permian complexes is 2.2 billion t of conventional hydrocarbons. In the study area, it is necessary to implement a program of deep and super-deep parametric drilling without which it is impossible to determine the oil and gas potential of the Lower Paleozoic.
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Date submitted2022-11-21
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Date accepted2024-05-02
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Date published2024-08-26
M1 formation tectono-structural features and gas-oil potential within Archinskaya area Paleozoic basement (Western Siberia)
- Authors:
- Vladimir B. Belozerov
- Mikhail O. Korovin
Western Siberian Plate basement oil and gas potential evaluation largely depends on structural and stratigraphic complex architecture representation. New modern procedures for seismic data processing, detailed Paleozoic deposits stratigraphic studies and expanded geophysical well logging significantly change the representation of the basement rocks fold-block structure and previously developed hydrocarbon reservoirs models. Detailed studies conducted within the Archinskii uplift showed that Paleozoic sediments form a contrasting folded structure complicated by block tectonics. The significant block displacements amplitude determines the lithological and stratigraphic basement rocks erosional-tectonic surface, while the identified stratigraphic blocks control the oil productivity distribution within the Archinskaya area. The filtration-capacity heterogeneity folded structure of the Paleozoic sediments is reflected in the distribution of hydrocarbon saturation in the well section, forming independent gas, oil, and oil-water zones for the development process. The relationship between anticlinal structural forms of basement rocks to lowered, and synclinal to elevated blocks, determines the necessity to conduct exploration prospecting within younger stratigraphic blocks when assessing the deep Paleozoic oil and gas potential.
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Date submitted2024-03-30
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Date accepted2024-06-03
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Date published2024-07-04
Preparation and use of complex titanium-containing coagulant from quartz-leucoxene concentrate
- Authors:
- Evgenii N. Kuzin
The search for the new high-efficiency reagents for wastewater treatment is a challenging and urgent task. Titanium-containing coagulants represent a new trend in water treatment and have a much higher efficiency that the traditional aluminium and iron-containing coagulants. The high cost of reagents significantly hinders their implementation. Complex titanium-containing reagents are coagulants prepared by modifying the traditional coagulants by adding 2.5-10.0 wt.% titanium compounds. In this work, titanium tetrachloride prepared from quartz-leucoxene concentrate was prehydrolyzed with subsequent double decomposition with sulfuric acid. The resulting mixture of hydrochloric and sulfuric acids was neutralized with aluminium hydroxide/oxide to form a self-hardening mixture (chemical dehydration). The sample of a complex sulfate-chloride titanium-containing coagulant was a mixture of AlCl3·6H2O – 5-20 wt.%, Al2(SO4)3·18H2O – 70-90 wt.% and TiOSO4 – 2.5-10.0 wt.%. It was proved that by changing the ratio of aluminium oxide/hydroxide and titanium tetrachloride at the stage of prehydrolysis and double decomposition, it is possible to obtain samples of a complex coagulant with different contents of the modifying additive of titanium compounds. An assessment of the coagulation properties of the complex reagent demonstrated its higher efficiency in cold water compared to aluminium sulfate. Studies on the use of the complex titanium-containing coagulant in the process of wastewater treatment from phosphate anions and suspended matter demonstrated its higher efficiency as compared to that of traditional reagents. The advantages of the prepared reagent are a reduction in the effective dose of the reagent, minimization of residual concentrations of pollutants in purified water, intensification of the processes of sedimentation and filtration of coagulation sludge. Purified water can be reused in the recycling water supply system. The use of quartz-leucoxene concentrate and titanium tetrachloride obtained from it as the source material would not only minimize the cost of the resulting complex coagulant, but also take a step towards the implementation of the Zero Waste concept.
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Date submitted2024-02-01
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Date accepted2024-05-02
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Date published2024-06-18
Methodology for managing energy development of production facilities in the gas industry
- Authors:
- Anatolii A. Shapovalo
The current stage of Russia's development is characterized by dynamic changes in the operating conditions of gas industry enterprises, which leads, among other things, to significant adjustments in approaches to the development of energy production facilities. The article examines on the system level the ways to improve energy supply, taking into account the goals and objectives of the development of production facilities from the conditions of solving a single technological problem of the gas industry – high-quality gas supply to consumers. The optimal functioning of energy supply systems, taking into account the peculiarities of technological processes at production facilities, presupposes the development models coordination of production facilities energy complexes with the gas industry enterprises parameters based on an integrated unified information space at all stages of their life cycle. The structure of production facility energy complex and the connections of its elements with related systems are justified taking into account the purposes of their creation and the requirements for production facilities. Problem solving for each system element as well as the exchange of information between equivalent systems is done on the basis of a developed hierarchy of optimization problems adjusted depending on the type of tasks of energy supply improvement of a production facility. Determining the values of parameters and indicators of energy complexes, as well as optimizing the lists and content of work to improve the energy supply of production facilities, is planned to be carried out in accordance with the methodology under consideration using a set of mathematical models.
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Date submitted2023-04-06
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Date accepted2023-12-27
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Date published2024-04-25
Localization of sites for the development of geomechanical processes in underground workings based on the results of the transformation and classification analysis of seismic data
The paper considers an approach to localizing the intervals of development of geomechanical processes in underground structures based on the classification and transformation of seismic data. The proposed approach will make it possible to identify the intervals of fracturing, rock decompression, water inflow and other geomechanical processes when interpreting the results of seismic surveys. The technique provides for the formation of matrices of longitudinal (Vp), transverse (Vs) velocities and velocity ratios (Vs/Vp) along the research profile to perform sequential filtration. The filtration results serve as the basis for the formation of a bank of informative materials for further classification. Based on the domestic KOSKAD 3D software, four approaches have been implemented for a combined digital model of the Vp, Vs and Vs/Vp parameters. One of the key elements in the classification process is to combine grids to increase the probability of detecting intervals with heterogeneous identification features. The result of the application of this methodical approach is the construction of a comprehensive interpretative model, on which potential zones of geomechanical risks development are clearly manifested.
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Date submitted2023-03-20
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Date accepted2023-09-20
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Date published2023-10-27
Experimental simulation of a system of swamp biogeocenoses to improve the efficiency of quarry water treatment
Mining activities were producing large quantities of wastewater contaminated with nitrogen compounds and metals. With insufficient treatment, these pollutants are released into the environment and have a toxic effect on living organisms. Constructed wetlands are now widely adopted as wastewater treatment systems because of the combination of physical, chemical and biological processes for the removal of contaminants. In this study, an experimental system was modeled to improve the efficiency of the quarry wastewater treatment of a mining enterprise by sharing the higher aquatic vegetation: broad-leaved cattail (Typha latifolia L.), common water-plantain (Alisma plantago-aquatica L.), jointed rush (Juncus articulatus L.) and lower aquatic vegetation (Chlorella sp.). Concentrations of nitrogen compounds and metal were analyzed both in the model and in the treated solution of quarry wastewater for calculation of treatment efficiency. Concentrations of the pollutants in the tissues of the higher aquatic vegetation were analyzed to assess the accumulation capacity and efficiency of translocation of the pollutants. The results of the experimental study showed the practical applicability of the constructed integrated treatment system to reduce the concentration of pollutants in quarry wastewater, as well as increasing the efficiency of treatment by introducing lower aquatic vegetation into the system
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Date submitted2023-04-11
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Date accepted2023-09-20
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Date published2023-10-27
Current state of above-ground and underground structures of the Alexander Column: an integral basis for its stability
- Authors:
- Regina E. Dashko
- Angelina G. Karpenko
The Alexander Column as a compositional center of the architectural ensemble of Palace Square in Saint Petersburg, Russia, has always been a matter of concern for both the public and specialists due to progressive deterioration of its granite shaft caused by crack formation. The article examines previous studies related to the inspection and restoration of the column's shaft and other parts above ground level, as well as reasons for crack initiation and propagation in the column. An analysis was performed on the anomalies in the Fennoscandian Shield and the structural-tectonic conditions at the Montferrand quarry site, revealing the presence of faults and circular features within the studied area. The research considers N.Hast's measurements of excess tectonic stresses in anomaly zones (southeastern Finland), which acted horizontally and resulted in the development of tensile cracks within the granite massif and later in the column’s shaft after its installation. The most dangerous type of deformation for the Alexander Column is its tilt in the northeast direction, recorded in 1937 and 2000. The article analyzes the construction features of the column's foundations and additional underground elements, as well as soil and groundwater characteristics based on archival data. The contamination history of the underground space is taken into account, and an analogy-based method is used to assess the engineering-geological and hydrogeological conditions of the underground load-bearing structures within the placement zone of the Alexander Column and the New Hermitage buildings. The results of visual observations on the nature of deterioration and deformation of the pavement around the monument, as well as its pedestal, indicating the development of uneven settlement of the foundation, are presented. The article concludes with general recommendations for organizing and implementing comprehensive monitoring to forecast the deformation dynamics of the Alexander Column.
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Date submitted2023-03-14
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Date accepted2023-06-20
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Date published2023-07-19
The wireless charging system for mining electric locomotives
The electric vehicles development has a high potential for energy saving: an energy-saving traffic control can reduce energy resource consumption, and integration with the power grid provides the ability of daily load pattern adjustment. These features are also relevant for underground mining. The critical element of vehicle-to-grid integration is the charging infrastructure, where wireless charging is promising to develop. The implementation of such systems in underground mining is associated with energy efficiency issues and explosion safety. The article discusses the development and research of a wireless charging system for mining electric locomotive A-5.5-600-U5. The analytic hierarchy process is used for justification of the circuitry and design solution by a comparison of different technical solutions based on energy efficiency and safety criteria. A complex computer model of the wireless charging system has been developed that gives the transients in the electrical circuit of a wireless charging system and the high-frequency field density distribution near the transmitting and receiving coils in a 3D setting. An approach to ignition risk evaluation based on the analysis of high-frequency field density in the charging area between the coils of the wireless charging system is proposed. The approach using a complex computer model is applied to the developed system. The study showed that the wireless charging system for mining electric locomotives operating in the gaseous-and-dusty mine is technically feasible and there are designs in which it is explosion safe.
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Date submitted2023-01-12
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Date accepted2023-06-20
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Date published2023-07-19
Improvement of energy efficiency of ore-thermal furnaces in smelting of alumosilicic raw materials
The issues of energy saving in pyrometallurgical production during processing of mineral raw materials in ore-thermal furnaces are particularly important for the development of new energy-efficient technologies. The reduction of the specific power consumption during melting at different stages of heating and melting of charge materials when modeling is related to obtaining kinetic curves in the process of kyanite concentrate regeneration in polythermal conditions. Based on practical data of carbo-thermal reduction the mathematical modeling of reduction processes from alumosilicic raw materials – kyanite was carried out. In this work, the nonisothermal method based on a constant rate of charge heating (i.e. a linear dependence between time and temperature) was used for the reduction of kyanite charge, which saves electrical energy. The experiments were carried out on a high-temperature unit with a heater placed in a carbon-graphite crucible. Based on the obtained kinetic dependences of nonisothermal heating of enriched kyanite concentrates in plasma heating conditions we obtained a number of kinetic anamorphoses of the linear form which point to the possibility of describing the reaction rate using the modified Kolmogorov – Erofeev equation for given heating conditions and within a narrow temperature range. The complex of mathematical modeling makes it possible to create a control algorithm of technological process of reduction of kyanite concentrate to a metallized state within the specified temperature range for the full flow of reaction exchange and to reduce the specific power consumption by 15-20 %. With the help of the received kinetic dependences, taking into account the thermodynamics of processes and current state of the art it is possible to create a universal thermal unit for the optimal carbothermal reduction of charge to a metallized state (alloy) with minimum power inputs compared to existing technologies.
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Date submitted2022-12-03
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Date accepted2023-02-03
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Date published2023-08-28
Garnetites from Marun-Keu eclogite complex (Polar Urals): geochemistry and the problem of genesis
- Authors:
- Laysan I. Salimgaraeva
- Alexei V. Berezin
A comprehensive mineralogical and geochemical characterization (XRF, ICP-MS, SEM-EDS, SIMS methods) of garnetites and their protoliths from the Marun-Keu complex (Polar Urals), one of the key objects in understanding the evolution of the Uralian Orogen, is presented. Garnetites and their protoliths from the Marun-Keu complex, Polar Urals, a key locality for understanding the evolution of the Uralian Orogen, are described mineralogically and geochemically using XRF, ICP-MS, SEM-EDS and SIMS methods. Ultramafic (in most cases) and mafic rocks are understood as protoliths for garnetites. A general trend for garnetites is an increase in total REE concentration relative to that of their protoliths. All the analyzed garnetites display a considerable decrease in Cr, Ni and Co. V concentration in the garnetites is also lower than that of the protoliths, though not so markedly. Garnets from garnetites evolving after peridotites generally exhibit elevated (relative to garnets from garnetites evolving after mafic rocks, such as porphyrites) Prp and lowered Alm content, which seems to be due to high Mg concentration in the protolith. In garnetites after peridotites a garnet exhibiting an uncommon non-differentiated REE spectrum with a considerable positive Eu-anomaly was found, which could be due to the inheritance of a REE spectrum by garnet from a precursor mineral, in this case plagioclase. Slyudyanaya Gorka garnetites were probably formed from mafic and ultramafic rocks in oceanic crust, which migrated to higher levels of the section under the influence of the crustal fluid flowing along fracturing zones.
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Date submitted2022-10-10
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Date accepted2023-01-19
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Date published2023-12-25
Assessment of the possibility of using leucoxene-quartz concentrate as raw material for production of aluminium and magnesium titanates
Leucoxene-quartz concentrate is a large-tonnage by-product of development of the Timan oil-titanium field (oil-saturated sandstones) which is not commercially used at present. High content of titanium compounds (to 50 % by weight) and lack of industrial, cost-effective, and safe technologies for its processing determine a high relevance of the work. Conventional processing technologies allow increasing the concentration of TiO2, but they are only a preparation for complex and hazardous selective chlorination. The process of pyrometallurgical conversion of leucoxene-quartz concentrate into aluminium and magnesium titanates was investigated. It was ascertained that the temperature of solid-phase reaction in Al2O3-TiO2-SiO2 system necessary for the synthesis of aluminium titanate (Al2TiO5) is 1,558 °С, and for MgO-TiO2-SiO2 system – 1,372 °С. Scaling up the process made it possible to synthesize a significant number of samples of titanate-containing products, the phase composition of which was studied by X-ray phase analysis. Two main phases were identified in the products: 30 % aluminium/magnesium titanate and 40 % silicon dioxide. In products of pyrometallurgical processing in the presence of aluminium, phases of pseudobrookite (3.5 %) and titanite (0.5 %) were also found. It was ascertained that in magnesium-containing system the formation of three magnesium titanates is possible: MgTiO3 – 25, Mg2TiO4 – 35, MgTi2O5 – 40 %. Experiments on sulphuric acid leaching of samples demonstrated a higher degree of titanium compounds extraction during sulphuric acid processing. An integrated conceptual scheme for processing leucoxene-quartz concentrate to produce a wide range of potential products (coagulants, catalysts, materials for ceramic industry) was proposed.
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Date submitted2022-11-06
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Date accepted2022-11-29
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Date published2022-12-29
Technological sovereignty of the Russian Federation fuel and energy complex
- Authors:
- Oleg V. Zhdaneev
The review to achieve technological sovereignty of the Russian fuel and energy complex (FEC) in the ongoing geopolitical situation is presented in the article. The main scope has been to identify the key technology development priorities, restrictions and internal resources to overcome these utilizing the developed by the author the innovative methodology that consists of novel approaches to calculate level of local content, digitalization, business continuity andinteractions with military-industrial complex. Some organizational changes have been proposed to intensify the development of hi-tech products for the FEC and related industries, including establishment of the state committee for science and technology and the project office of lead engineers for the critical missing technologies. Two successful examples to utilize the described in the paper methodology is presented: the first domestic hydraulic fracturing fleet and polycrystalline diamond compact cutter bit inserts.
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Date submitted2022-04-14
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Date accepted2022-07-21
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Date published2022-11-03
Technological mineralogy: development of a comprehensive assessment of titanium ores (exemplified by the Pizhemskoye deposit)
Technological mineralogy of titanium ores is the basis for assessing their complexity. It enables, from a unified standpoint, to trace the entire course of changes in mineral matter through operating procedures, including beneficiation, processing, and obtaining target industrial products. The study targets are Pizhemskoye ilmenite-leucoxene sandstones, which are distinguished by a complex polymineral composition. Along with the main ore components, there are other metals with different speciation (isomorphic admixture, independent mineral phases). The optimal set of mineralogical analysis methods for the predictive assessment of their further use is substantiated exemplified by titanium ores of the Pizhemskoye deposit, which are complex, noted for a variable content of iron oxides and contain rare earth metals. Examinations by X-ray phase analysis and scanning electron microscopy confirm that the main titanium phases of sandstones are pseudorutile and a polymineral aggregate, “leucoxene”. Considering the granulometric peculiarities of the magnetic and non-magnetic fractions of the gravity concentrate, the prospects of technologies for processing titanium raw materials are discussed. Along with the problems of obtaining high-quality raw materials, the transformations of mineral phases as a result of extreme impacts and their physicochemical properties as a consequence of isomorphic substitution of a part of Ti atoms with natural modifier agents (Fe and V) in the synthesis of titanium oxide nanostructures for industrial applications are considered (photocatalytic nanoreactor).
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Date submitted2022-03-21
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Date accepted2022-06-15
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Date published2022-07-26
Ti-Fe-Cr spinels in layered (stratified) complexes of the western slope of the Southern Urals: species diversity and formation conditions
- Authors:
- Sergey G. Kovalev
- Sergey S. Kovalev
Materials on geochemistry and ore Fe-Ti-Cr mineralization of rocks composing layered (stratified) bodies of the western slope of the Southern Urals are presented. A detailed analysis showed similarity in the redistribution of REE, noble metals, and Fe-Ti-Cr mineralization of practically all parameters in rocks of the Misaelga and Kusin-Kopan complexes. It has been established that the parameters of metamorphism, which influenced components redistribution in Fe-Ti-Cr minerals of the layered complexes, correspond to Misaelga – T = <550-750 °С, P = 0.1-2.8 kbar, Kusin-Kopan – T = <550-630 °С, P = 0.3-0.7 kbar, and Shuidinsky complexes – T = <550-760 °С, P = 0.5-2.5 kbar. The result of modelling the melt crystallization process showed that the Kusin-Kopan complex is an intrusive body with an ultramafic horizon in the idealized cross-section. Due to collisional processes, the lower part of the intrusion has been detached from the upper part. The proposed structure of the Kusin-Kopan complex sharply increases its prospects for such types of minerals as platinum group minerals + sulphide copper-nickel mine-ralization and/or chromites.
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Date submitted2021-04-04
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Date accepted2022-04-26
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Date published2022-07-26
Vendian age of igneous rocks of the Chamberlain valley area (Northern part of the Wedel Jarlsberg Land, Svalbard Archipelago)
The geological structure, structural relations with the underlying complexes, mineral composition, age and origin of sedimentary-volcanogenic and intrusive formations of the Chamberlain valley area (northern part of the Wedel Jarlsberg Land, Svalbard Archipelago) are considered. As a result of the studies, two stages of the Late Precambrian endogenous activity in this area have been identified. For the first time the Vendian ages (593-559 Ma) of intrusive (dolerites) and effusive (basalts, andesites, tuffs) rocks were determined by U-Pb-method (SHRIMP-II) for Svalbard Archipelago. At the same time, the Grenville ages for large bodies of gabbro-diorites, metadolerites bodies (1152-967 Ma), and metagranites (936 Ma) were determined for the first time for this area, which correlates well with the ages of magmatic formations obtained earlier in the southern part of Wedel Jarlsberg Land. A detailed petrographic and petrochemical characterization of all the described objects were compiled and the paleotectonic conditions of their formation were reconstructed. Based on these data, the Chemberlendalen series, which is dated to the Late Vendian, and the Rechurchbreen series, which the authors attribute to the Middle Riphean and correlate with the lower part of the Nordbucht series are distinguished. The data obtained indicate a two-stage Precambrian magmatism in this area of the Svalbard archipelago and, most importantly, provide evidence for the first time ever of endogenous activity on Svalbard in the Vendian time. This fact makes it possible to reconsider in the future the history of the formation of folded basement of the Svalbard archipelago and the nature of the geodynamic conditions in which it was formed.
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Date submitted2022-02-26
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Date accepted2022-04-27
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Date published2022-07-26
Type intrusive series of the Far East belt of lithium-fluoric granites and its ore content
- Authors:
- Viktor I. Alekseev
The evolution and ore content of granitoid magmatism in the Far East belt of lithium-fluoric granites lying in the Russian sector of the Pacific ore belt have been studied. Correlation of intrusive series in the Novosibirsk-Chukotka, Yana-Kolyma and Sikhote-Alin granitoid provinces of the studied region allowed to establish the unity of composition, evolution, and ore content of the Late Mesozoic granitoid magmatism. On this basis, a model of the type potentially ore-bearing intrusive series of the Far East belt of lithium-fluoric granites has been developed: complexes of diorite-granodiorite and granite formations → complexes of monzonite-syenite and granite-granosyenite formations → complexes of leucogranite and alaskite formations → complexes of rare-metal lithium-fluoric granite formation. The main petrological trend in granitoid evolution is increasing silicic acidity, alkalinity, and rare-metal-tin specialization along with decreasing size and number of intrusions. At the end of the intrusive series, small complexes of rare-metal lithium-fluoric granites form. The main metallogenic trend in granitoid evolution is an increasing ore-generating potential of intrusive complexes with their growing differentiation. Ore-bearing rare-metal-granite magmatism of the Russian Far East developed in the Late Cretaceous and determined the formation of large tungsten-tin deposits with associated rare metals: Ta, Nb, Li, Cs, Rb, In in areas with completed intrusive series. Incompleteness of granitoid series of the Pacific ore belt should be considered as a potential sign of blind rare-metal-tin mineralization. The Far East belt of lithium-fluoric granites extends to the Chinese and Alaskan sectors of the Pacific belt, which allows the model of the type ore-bearing intrusive series to be used in the territories adjacent to Russia.
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Date submitted2022-03-31
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Date accepted2022-05-11
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Date published2022-07-26
Carbonatite complexes of the South Urals: geochemical features, ore mineralization, and geodynamic settings
- Authors:
- Irina L. Nedosekova
The article presents the results of study of the Ilmeno-Vishnevogorsky and Buldym carbonatite complexes in the Urals. It has been established that the carbonatites of the Ilmeno-Vishnevogorsky complex are represented by high-temperature calciocarbonatites (sövites I and II) with pyrochlore ore mineralization. U-Ta-rich populations of uranium pyrochlores (I) and fluorocalciopyrochlores (II) crystallize in miaskite-pegmatites and sövites I; fluorocalciopyrochlores (III) and Sr-REE-pyrochlores (IV) of late populations form in sövites II. In the Buldym complex, along with high-temperature calciocarbonatites containing fluorocalciopyrochlore (III), medium-temperature varieties of magnesiocarbonatites with REE-Nb mineralization (monazite, niobo-aeschynite, columbite, etc.) are widespread. Miaskites and carbonatites of the Urals are characterized by high contents of LILE (Sr, Ba, K, Rb) and HFSE (Nb, Ta, Zr, Hf, Ti), which are close to the contents in rift-related carbonatite complexes of intraplate settings and significantly differ from synorogenic collisional carbonatite complexes. The Ural carbonatite complexes formed on continental rift margins during the opening of the Ural Ocean at the time of transition from extensional to compressional tectonics. Later on, they were captured and deformed in the suture zone as a result of collision. Plastic and brittle deformations, anatexis, recrystallization of rocks and ores of carbonatite complexes in the Urals are associated with orogenic and post-collision settings.
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Date submitted2021-12-16
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Date accepted2022-04-07
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Date published2022-07-13
The Upper Kotlin clays of the Saint Petersburg region as a foundation and medium for unique facilities: an engineering-geological and geotechnical analysis
- Authors:
- Regina E. Dashko
- Georgiy A. Lokhmatikov
The article reviews the issues concerned with correctness of the engineering-geological and hydrogeological assessment of the Upper Kotlin clays, which serve as the foundation or host medium for facilities of various applications. It is claimed that the Upper Kotlin clays should be regarded as a fissured-block medium and, consequently, their assessment as an absolutely impermeablestratum should be totally excluded. Presence of a high-pressure Vendian aquifer in the lower part of the geological profile of the Vendian sediments causes inflow of these saline waters through the fissured clay strata, which promotes upheaval of tunnels as well as corrosion of their lining. The nature of the corrosion processes is defined not only by the chemical composition and physical and chemical features of these waters, but also by the biochemical factor, i.e. the availability of a rich microbial community. For the first time ever, the effect of saline water inflow into the Vendian complex on negative transformation of the clay blocks was studied. Experimental results revealed a decrease in the clay shear resistance caused by transformation of the structural bonds and microbial activity with the clay’s physical state being unchanged. Typification of the Upper Kotlin clay section has been performed for the region of Saint Petersburg in terms of the complexity of surface and underground building conditions. Fissuring of the bedclays, the possibility of confined groundwater inflow through the fissured strata and the consequent reduction of the block strength as well as the active corrosion of underground load-bearing structures must be taken into account in designing unique and typical surface and underground facilities and have to be incorporated into the normative documents.
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Date submitted2021-10-08
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Date accepted2022-01-24
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Date published2022-04-29
Methodology for thermal desorption treatment of local soil pollution by oil products at the facilities of the mineral resource industry
- Authors:
- Mariya A. Pashkevich
- Marina V. Bykova
The analysis of the main environmental consequences of leaks and local spills of petroleum products at the enterprises of the mineral resource complex is presented. It is established that the problem of soil contamination with petroleum products at the facilities of the mineral resource complex and enterprises of other industries is caused by significant volumes of consumption of the main types of oil products. Based on the results of the author's previous field research, a series of experiments was carried out, consisting in modeling artificial soil pollution with petroleum products such as gasoline, diesel fuel, highly refined oil, motor oil, and transmission oil, followed by their purification by heat treatment at temperatures of 150, 200, and 250 °C. The 250 °C limit of the heating temperature was set due to the need to partially preserve the structure and quality of the soil after heat treatment to preserve its fertility. When the processing temperature rises to 450 °C, all humates are completely burned out and, as a result, productivity is lost. Confirmation is provided by the results of experiments to determine the humus content in uncontaminated soil and soil treated at different temperatures. It was found that at a maximum processing temperature of 250 °C, about 50 % of the initial organic carbon content is preserved. According to the results of the conducted experimental studies, the dependences of the required processing temperature on the concentration of petroleum products to reduce the concentration of petroleum products to an acceptable level have been established. The methodology of thermal desorption cleaning of soils with varying degrees of contamination at enterprises of the mineral resource complex is presented.
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Date submitted2021-09-02
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Date accepted2022-01-24
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Date published2022-04-29
Complex processing of high-carbon ash and slag waste
The paper considers a current issue of ash and slag processing for the Polyus Aldan JSC, that has accumulated over 1 million tons of this waste. Following the results of the review of Russian and foreign literature, four promising areas of their use were selected: road construction, building materials, reclamation of disturbed lands, and inert aggregates. To assess the possibility of implementing the selected disposal directions, the samples of ash and slag waste of the enterprise were sampled and analyzed. Fuel characteristics, chemical and mineral composition, as well as physico-chemical and mechanical properties of waste were determined. Taking into account the results of complex laboratory studies and the requirements of regulatory documents, each of the selected areas of using ash and slag waste was evaluated. It was found that their disposal by traditional methods has limitations, mainly related to the high content of unburned fuel residues. The high content of combustible substances and the high specific heat of combustion with a relatively low ash content suggested the possibility of thermal disposal of the studied waste. Based on the literature data, the characteristics of the preparation of organic coal-water suspensions based on the studied ash and slag waste were selected. As a result of a series of experiments on their flaring, the expediency of using the obtained fuel at the enterprise under consideration has been proved. The authors note the possibility of using ash obtained after thermal waste disposal in the road construction industry. The prospects for further research of technologies for the preparation and combustion modes of suspension fuel based on ash and slag waste are determined.
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Date submitted2021-03-11
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Date accepted2021-04-12
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Date published2022-04-29
Operation mode selection algorithm development of a wind-diesel power plant supply complex
- Authors:
- Yaroslav E. Shklyarskiy
- Daria E. Batueva
The power supply system is affected by external disturbances, so it should be stable and operate normally in compliance with power quality standards. The power supply system goes into abnormal modes operation when, after a short-term failure or disturbance, it does not restore normal mode. The electrical complex, which includes a wind power plant, as well as a battery and a diesel generator connected in parallel, is able to provide reliable power supply to consumers which meets the power quality indicators. The article develops an algorithm that is implemented by an automatic control system to select the operating mode depending on climatic factors (wind) and the forecast of energy consumption for the day ahead. Forecast data is selected based on the choice of the methods, which will have the smallest forecast error. It is concluded that if the energy consumption forecast data is added to the automatic control system, then it will be possible to increase the efficiency of the power supply complex. In the developed algorithm the verification of normal and abnormal modes of operation is considered based on the stability theory. The criteria for assessing the normal mode of operation are identified, as well as the indicators of the object’s load schedules for assessing the load of power supply sources and the quality standards for power supply to consumers for ranking the load by priority under critical operating conditions and restoring normal operation are considered.
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Date submitted2021-06-17
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Date accepted2021-10-18
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Date published2021-12-16
Dissolution kinetics of rare earth metal phosphates in carbonate solutions of alkali metals
- Authors:
- Tatyana E. Litvinova
- Ivan L. Oleynik
Treatment of apatite raw materials is associated with the formation of large-tonnage waste – phosphogypsum. The content of rare earth metals in such waste reaches 1 %, which makes it possible to consider it a technogenic source for obtaining rare earth metals and their compounds. Up to the present moment, there are neither processing plants, nor an efficient process flow to handle phosphogypsum dumps. It is rational to use a way that involves extraction of valuable components and overall reduction of phosphogypsum dumps. Such process flow is available with carbonate conversion of phosphogypsum to alkali metal or ammonium sulfate and calcium carbonate upon the condition of associated extraction of rare earth metal (REM) compounds. Associated extraction of REM compounds becomes possible since they form strong and stable complexes with hard bases according to Pearson, which among other things include carbonate, phosphate and sulfate anions. Formation of lanthanide complexes with inorganic oxygen-containing anions is facilitated by the formation of high-energy Ln-O bonds. The study focuses on the dissolution of lanthanide phosphates in carbonate media. It was established that formation of REM carbonate complexes from their phosphates is a spontaneous endothermic process and that formation of lanthanide carbonates and hydroxides serves as thermodynamic limitation of dissolution. A shift in equilibrium towards the formation of carbonate complexes is achieved by increasing the temperature to 90-100 °C and providing an excess of carbonate. The limiting stage of REM phosphate dissolution in carbonate media is external diffusion. This is indicated by increasing rate of the process with an intensification of stirring, first order of the reaction and the value of activation energy for phosphate dissolution from 27 to 60 kJ/mol. A combination of physical and chemical parameters of the process allowed to develop an engineering solution for associated REM extraction during carbonate conversion of phosphogypsum, which included a 4-5 h conversion of phosphogypsum at temperature of 90-110 °C by an alkali metal or ammonium carbonate solution with a concentration of 2-3 mol/l. As a result, a solution with alkali metal (ammonium) sulfate is obtained, which contains REMs in the form of carbonate complexes and calcium carbonate. The rate of REM extraction into the solution reaches no less than 93 %. Rare earth metals are separated from the mother liquor by precipitation or sorption on anion exchange resins, while the excess of alkali metal or ammonium carbonate is returned to the start of the process.
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Date submitted2021-03-11
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Date accepted2021-05-21
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Date published2021-09-20
The influence of solar energy on the development of the mining industry in the Republic of Cuba
Cuba is traditionally considered a country with an underdeveloped industry. The share of the mining and metallurgical industries in the gross industrial production of the republic is small – about 3 % of GDP. The development of deposits and the extraction of nickel ores is an important sector of the economy of the Republic of Cuba, since the largest reserves of nickel and cobalt on the North American continent are located on the territory of the country. The development of the country energy system can serve as a growth factor in this sector of the economy. Due to climatic features and impossibility of integrating new capacities into the energy system through the construction of hydroelectric power plants, solar energy is a promising direction. Determining the feasibility of using solar tracking systems to increase the generation of electricity from solar power plants is one of the main challenges faced by engineers and renewable energy specialists. Currently, there are no solar tracking systems in Cuba that can provide information to assess the effectiveness of this technology in the country. The lack of the necessary technologies, as well as the high cost of developing solar power plants with tracking systems, limit the widespread introduction of such complexes. Hence follows the task of creating an inexpensive experimental model that allows assessing the effectiveness of tracking systems in specific weather conditions of the Republic of Cuba. This model will allow in future to increase the efficiency of electrical complexes with solar power plants, which provide power supply to the objects of the mineral resource complex and other regions.
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Date submitted2020-05-13
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Date accepted2021-05-21
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Date published2021-09-20
Increasing the efficiency of technological preparation for the production of the manufacture components equipment for the mineral resource complex
An increase of components production for the equipment intended for oil and gas production is a key factor for analyzing existing technological processes and searching for new technological solutions to improve the efficiency of the production process and the quality of components. The article presents a simulation model designed to determine the rational technological processing parameters for the production of the “Centralizer shell” part. The basis for optimizing the working cycle of a production line is synchronization based on the principle of proportionality, which involves equalizing the duration of all technological operations with the rhythm of the production line. Synchronization of technological operations on the production line is carried out by choosing rational cutting parameters for each technological transition (cutting speed, feedrate, number of working passes). The “Centralizer shell” part is made of titanium alloy VT16, which has high strength, corrosion resistance and ductility. For the part under consideration, the permissible values of the cutting parameters were determined based on the calculation of the total processing error, as well as the frequency of replacement of the worn cutting tool. The simulation model described in the article made it possible to increase the efficiency of the production process due to the synchronization of technological operations and the search for rational technological parameters, as well as to improve the manufacturing quality of the “Centralizer shell” part by analyzing the processing error at various parameters of the technological process.