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Date submitted2022-09-30
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Date accepted2023-02-13
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Date published2024-02-29
Improving the efficiency of oil vapor recovery units in the commodity transport operations at oil terminals
- Authors:
- Vladimir V. Pshenin
- Gulnur S. Zakirova
In this paper the problem of losses from evaporation of light fractions of hydrocarbons during loading operations of tanker fleets vessels is considered. It was found that there is no unified approach to modeling the system “tanker – gas phase pipeline – vapor recovery units” in open sources. The absence of a generally recognized model makes it impossible to scientifically justify the application of instruments to reducing losses and the development of corresponding measures. In work it is showed that the dynamics of growth of pressure in the inner tanker capacity is described by a differential equation, considering for non-stationary essence of the process. This equation is converted to a non-dimensional form and investigated in relation to the similarity criteria of this system. This research has allowed to establish unambiguously the general character of pressure changes in the inner tanker capacity, and to predict the peak values of its growth at the initial stage of the loading operation. The obtained equations were tested on real tanker loading data and showed satisfactory convergence with the experimental data. At different stages of the loading opera-tion the component composition of vapor changes, which is shown by chromatographic analysis of the gas mixture. With the availability of a model of hydrocarbon vapor displacement from the inner of tanker, it is possible to propose measures to minimize the negative impact on the environment and return valuable vapors of the product to the technological chain of transportation.
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Date submitted2022-05-26
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Date accepted2022-11-17
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Date published2022-12-29
Renovation method of restoring well productivity using wavefields
A stagewise theoretical substantiation of the renovation vibrowave method of influencing the near-wellbore zone of reservoir for restoring well productivity is presented. The area of treatment by the proposed method covers the reservoir with a heterogeneous permeability with fractures formed by fracking. In this method a decrease in concentration of colmatants occurs due to a change in direction of contaminants migration. Under the influence of pressure pulses, they move deep into the reservoir and disperse through the proppant pack. The results of mathematical modelling of the propagation of pressure wave and velocity wave and the calculations of particles entrainment in wave motion are presented.
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Date submitted2022-01-31
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Date accepted2022-09-06
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Date published2022-11-10
Filtration studies on cores and sand packed tubes from the Urengoy field for determining the efficiency of simultaneous water and gas injection on formation when extracting condensate from low-pressure reservoirs and oil from oil rims
- Authors:
- Nikolay A. Drozdov
Oil rims as well as gas condensate reservoirs of Russia's largest Urengoy field are developed by depletion drive without formation pressure maintenance, which has led to serious complications in production of oil, gas and condensate. In addition, field development by depletion drive results in low values of oil and condensate recovery. These problems are also relevant for other oil and gas condensate fields. One of the possible solutions is simultaneous water and gas injection. Rational values of gas content in the mixture for affecting gas condensate fields and oil rims of oil and gas condensate fields should be selected using the data of filtration studies on core models. The article presents the results of filtration experiments on displacement of condensate and oil by water, gas and water-gas mixtures when simulating the conditions of the Urengoy field. Simultaneous water and gas injection showed good results in the experiments on displacement of condensate, residual gas and oil. It has been ascertained that water-gas mixtures with low gas content (10-20 %) have a better oil-displacement ability (9.5-13.5 % higher) than water. An experiment using a composite linear reservoir model from cemented core material, as regards the main characteristics of oil displacement, gave the same results as filtration experiments with sand packed tubes and demonstrated a high efficiency of simultaneous water and gas injection as a method of increasing oil recovery at oil and gas condensate fields.
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Date submitted2021-11-10
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Date accepted2022-05-25
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Date published2022-12-29
Predicting the permeability of the near-bottomhole zone during wave impact
The research reveals that during selection of a method to increase oil recovery it is necessary to take into account rheological features of fluid movement through the formation, effect of capillary forces and heterogeneity of reservoir properties of the productive formation in thickness and along the bedding. Low-frequency wave impact, which is used to increase production in oil fields, is considered. At low-frequency impact new fractures appear and existing fractures in rocks increase in size. The greatest increase in porosity and permeability of rocks occurs at an impact frequency up to 10 Hz. Dynamics of oscillation amplitude during wave's movement in saturated porous medium is studied in the paper: essential attenuation of amplitude occurs at distance up to 1 m from borehole axis. With increase of frequency from 1 to 10 Hz the intensity of amplitude's attenuation decreases. The technology was tested on a well in Perm region (Russia). The actual permeability value was 50 % higher than the predicted value. According to the results of hydrodynamic investigations processing, it was noted that the greatest increase of permeability took place near the wellbore, while away from the wellbore axis permeability remained almost unchanged. In order to refine the mathematical model for prediction of wave impact on rock permeability it is necessary to take into account interconnection of pore space structure, change of adhesion layer, as well as to study transfer of particles during vibration.
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Date submitted2021-12-19
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Date accepted2022-05-13
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Date published2022-07-13
Development of a pump-ejector system for SWAG injection into reservoir using associated petroleum gas from the annulus space of production wells
Implementation of SWAG technology by means of water-gas mixtures is a promising method of enhanced oil recovery. The use of associated petroleum gas as a gas component in the water-gas mixture allows to significantly reduce the amount of irrationally consumed gas and carbon footprint. Relevant task is to choose a simple, reliable and convenient equipment that can operate under rapidly changing operating conditions. Such equipment are pump-ejector systems. In order to create water-gas mixture it is proposed to use associated gas from the annulus space. This solution will reduce the pressure in the annulus space of the production well, prevent supply disruption and failure of well equipment. The paper presents a principal technological scheme of the pump-ejector system, taking into account the withdrawal of gas from the annulus space of several production wells. The layout of the proposed system enables more efficient implementation of the proposed technology, which expands the area of its application. Experimental investigations of pressure and energy characteristics of the ejector have been carried out. Analysis of the obtained data showed that it was possible to increase the value of maximum efficiency. The possibility of adapting the system in a wide range of changes in operating parameters has been established. Recommendations on selection of a booster pump depending on the values of working pressure and gas content are given.
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Date submitted2021-09-16
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Date accepted2022-02-24
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Date published2022-04-29
Production of microfluidic chips from polydimethylsiloxane with a milled channeled surface for modeling oil recovery during porous rock waterflooding
Microfluidic chips with porous structures are used to study the flow of oil-containing emulsion in the rock. Such chips can be made from polydimethylsiloxane by casting into a master mold. At the initial stages of research, fast and cheap prototyping of a large number of different master molds is often required. It is proposed to use milling to make a channeled surface on a polymethyl methacrylate plate, from which a negative image should be taken, which is the master mold for casting positive polydimethylsiloxane chips in it. Several epoxy compositions have been tested to make this master mold. The main requirement in the search for the material was the exact replication of the geometry and sufficiently low adhesion to polymethyl methacrylate and polydimethylsiloxane for removing the product with minimal damage to the mold. It was possible to make master molds from all the materials used, but with defects and various degrees of damage. One of the epoxy compositions was found suitable for making a master mold with many elements simulating the grains of a porous medium (height to width ratio 2:3). The developed method makes it possible to use polydimethylsiloxane for prototyping chips simulating the porous structure of an oil rock.
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Date submitted2021-07-07
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Date accepted2021-10-18
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Date published2021-12-16
Influence of hydraulic compression on porosity and permeability properties of reservoirs
Active development of hard-to-recover oil reserves causes the need for an innovative approach to methods of oil recovery and intensification of its production, based on taking into account the specifics of filtration processes in low-productive reservoirs and complex geological and physical conditions. Pilot works for studying the mechanism of changes in porosity and permeability properties of reservoirs during swabbing of wells are presented. Based on the hydrodynamic investigations performed, the results of the work are analyzed. The method of oil production intensification using hydraulic compression of formation has been developed. It has been shown that when using hydraulic compression technology in the pore space of the formation, the effect of capillary and gravitational forces is strongly reduced. The influence of these forces decreases when significant pressure gradients with changing direction are formed during well swabbing for depression impact on the bottomhole zone of the formation. Hydraulic compression induced an increase in well productivity and flow rate; insights into how how permeability and porosity properties change during well swabbing were clarified. The range of compressive durability (minimum and maximum values) was determined for the Verean deposits of the Melekeskaya Depression and the South Tatar arch. The impact of formation hydraulic compression caused changes in permeability and porosity properties of the reservoir in the bottomhole zone on a qualitative level. Piezo- and hydraulic conductivity increased by 20 %. Experimental work in well 1545 of Keremetyevskoe field showed an increase of piezo- and hydraulic conductivity coefficients, effective formation thickness, change of filtration flows character.
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Date submitted2021-06-15
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Date accepted2021-10-18
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Date published2021-12-16
Study on hydrometallurgical recovery of copper and rhenium in processing of substandard copper concentrates
- Authors:
- Denis S. Lutskiy
- Aleksander S. Ignatovich
Over the past decade, there has been a steady growth in demand for rare metals, with rhenium being one of the most highly demanded, but also one of the most expensive and difficult to obtain. The high demand for rhenium is due to its use as a key component of metallurgical alloys or as a component of catalysts used in the oil refining industry. The aggregate of facts causes profitability of processing of the rhenium-containing mineral resources, which also are the copper substandard concentrates obtained at processing of the Zhezkazgan sandstones. The study focuses on the processes of extraction of copper and sorption recovery of rhenium from solutions of ammonia leaching of copper substandard concentrates. Model solutions similar in the elemental composition to solutions of ammonia leaching solutions of copper substandard concentrates obtained during the processing of Zhezkazgan sandstones were used as an object of the study. The paper estimates extraction characteristics of copper recovery using LIX 84-I solution in kerosene, as well as sorption characteristics of the rhenium recovery process using the Purolite PPA100 anion exchanger. Based on the obtained characteristics the possibility of hydrometallurgical processing of ammonia leaching solutions of substandard copper-sulfide concentrates, and recovery of the obtained commercial products is shown.
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Date submitted2021-02-09
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Date accepted2021-07-27
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Date published2021-10-21
Development of an algorithm for determining the technological parameters of acid composition injection during treatment of the near-bottomhole zone, taking into account economic efficiency
Relevance of the research is due to the low proportion of successful hydrochloric acid treatments of near-bottomhole zones of carbonate reservoirs in the Perm region caused by insufficiently careful design and implementation of measures to stimulate oil production. Within the framework of this article, the development of a program is presented, which is based on an algorithm that allows determining the volume and rate of injection for an acid composition into a productive formation corresponding to the maximum economic efficiency during hydrochloric acid treatment. Essence of the proposed algorithm is to find the greatest profit from measures to increase oil recovery, depending on the cost of its implementation and income from additionally produced oil. Operation of the algorithm is carried out on the principle of enumerating the values of the volume and rate of injection for the acid composition and their fixation when the maximum difference between income and costs, corresponding to the given technological parameters of injection, is reached. The methodology is based on Dupuis's investigations on the filtration of fluids in the formation and the results of the experiments by Duckord and Lenormand on the study of changes in the additional filtration resistance in the near-well zone of the formation when it is treated with an acid composition. When analyzing and including these investigations into the algorithm, it is noted that the developed technique takes into account a large number of factors, including the lithological and mineralogical composition of rocks, technological parameters of the injection of a working agent and its properties, well design, filtration properties of the formation, properties of well products. The article provides an algorithm that can be implemented without difficulty using any programming language, for example, Pascal. Selection of the optimal values for the volume and rate of injection is presented in this paper, using the example of a production well at the Chaikinskoye oil field, located within the Perm region. Introduction of the developed algorithm into the practice of petroleum engineering will allow competent and effective approach to the design of hydrochloric acid treatments in carbonate reservoirs without a significant investment of time and additional funds.
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Date submitted2021-01-18
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Date accepted2021-05-21
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Date published2021-09-20
Improving the efficiency of the technology and organization of the longwall face move during the intensive flat-lying coal seams mining at the Kuzbass mines
The reasons for the lag of the indicators of the leading Russian coal mines engaged in the longwall mining of the flat-lying coal seams from similar foreign mines are considered. The analysis of the efficiency of the longwall face move operations at the JSC SUEK-Kuzbass mines was carried out. A significant excess of the planned deadlines for the longwall face move during the thick flat-lying seams mining, the reasons for the low efficiency of disassembling operations and the main directions for improving the technology of disassembling operations are revealed. The directions of ensuring the operational condition of the recovery room formed by the longwall face are considered. The recommended scheme of converged coal seams mining and a three-dimensional model of a rock mass to justify its parameters are presented. Numerical studies using the finite element method are performed. The results of modeling the stress-strain state of a rock mass in the vicinity of a recovery room formed under conditions of increased stresses from the boundary part of a previously mined overlying seam are shown. The main factors determining the possibility of ensuring the operational condition of the recovery rooms are established. It is shown that it is necessary to take into account the influence of the increased stresses zone when choosing timbering standards and organizing disassembling operations at a interbed thickness of 60 m or less. A sufficient distance from the gob of above- or undermined seams was determined to ensure the operational condition of the recovery room of 50 m, for the set-up room – 30 m. Recommendations are given for improving technology and organization of the longwall face move operations at the mines applied longwall mining of flat-lying coal seams with the formation of a recovery room by the longwall face.
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Date submitted2020-07-29
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Date accepted2021-03-30
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Date published2021-06-24
Model of baddeleyite recovery from dump products of an apatite-baddeleyite processing plant using a CVD6 concentrator
The paper is devoted to developing a model of baddeleyite recovery from dump products of an apatite-baddeleyite processing plant using centrifugal concentrators. The relevance of the work arises from the acquisition of new knowledge on the optimization of technological parameters of centrifugal concentrators using Knelson CVD (continuous variable discharge) technology – in particular, setting the frequency of valve opening and the duration of valves remaining open. The purpose of the research was to assess the applicability of CVD technology in the treatment of various dump products of the processing plant and to build a model of dependencies between the concentrate and tailings yields and the adjustable parameters, which will allow to perform preliminary calculations of the efficiency of implementing this technology at processing plants. The research objects are middling and main separation tailings of the coarse-grained stream and combined product of main and recleaner separation tailings of the fine-grained stream. The study uses general methods of mathematical statistics: methods of regression analysis, aimed at building statistically significant models, describing dependence of a particular variable on a set of regressors; group method of data handling, the main idea of which is to build a set of models of a given class and choose the optimal one among them. Authors proposed an algorithm for processing experiment results based on classical regression analysis and formulated an original criterion for model selection. Models of dependencies between the concentrate and tailings yields and the adjustable parameters were built, which allowed to establish a relationship between the concentrate yield and the valve opening time, as well as a relationship between the tailings yield and the G-force of the installation.
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Date submitted2019-06-19
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Date accepted2019-09-11
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Date published2020-02-25
Method for estimating the spectrum density of the resistance moment on the working body of a peat milling unit
- Authors:
- K. V. Fomin
The main source of dynamic loads in the drive elements and the design of the peat milling unit is the working body. The forces of external resistance arising in the process of performing a technological operation are sharply variable, random in nature. The article proposes a model of formation of the moment of resistance on the mill when interacting with peat. The case when there are several cutting planes with the same radius at the ends of the cutting elements is considered. When developing the model, it was taken into account that the operating conditions of the knives, determined by the type of cutting (blocked, semi-blocked, etc.), their width and type in each cutting plane can vary. Factors that determine the nature of loading, such as the frequency of interaction of the cutting elements with the fallow and the randomness of the operating conditions of the unit, lead to the presentation of the loads in the form of a sequence of pulses with random parameters. Expressions are obtained for determining the spectral density of the moment of resistance on the mill at the design stage, taking into account its design, operating modes, physico-mechanical properties of peat and their probabilistic characteristics. To illustrate the application of the developed approaches, a technique is presented for determining the spectral density of the moment on the working body of deep milling machines and in their drive elements based on a linear model. An example of calculation is given, and the obtained expressions are verified on the basis of experimental data. The probabilistic characteristics of the loads on the mill serve as initial information for the dynamic analysis of the drive system and the design of the unit, its strength analysis, the selection of optimal parameters and operating modes.
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Date submitted2019-07-11
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Date accepted2019-08-25
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Date published2019-12-24
Improving the efficiency of using resource base of liquid hydrocarbons in Jurassic deposits of Western Siberia
Under conditions of the same type of oil deposits with hard-to-recover reserves in Jurassic terrigenous reservoirs of the West Siberian oil and gas province, a study was made about the influence of the geological structure features of objects and water flooding technologies on the response degree of production wells to water injection. Response degree of the wells was determined by analyzing the time series of production rates and injection volumes of injection wells with the calculation of inter-correlation function (ICF) values. It was believed that with ICF values in a given injection period of more than 0.5, production well responds to the injection. Factors that have a prevailing effect on water flooding success have been identified. Among them: effective oil-saturated thickness of the formation in production wells; relative amplitude of the self polarization of the formation in both production and injection wells; grittiness coefficient of the formation in injection wells; monthly volume of water injection and distance between wells. Methodological approach is proposed based on the application of the proposed empirical parameter of water flooding success, which involves the use of indirect data in conditions of limited information about the processes occurring in the formation at justification and selection of production wells for transferring them to injection during focal flooding; drilling of additional production and injection wells – compaction of the well grid; shutdown of injection and production wells; use of a transit wells stock; use of cyclic, non-stationary flooding in order to change the direction of filtration flows; determining the design of dual-purpose L-shaped wells (determining length of the horizontal part); limitation of flow rate in highly flooded wells with a high degree of interaction; determination of decompression zones (without injection of indicators), stagnant zones for drilling sidetracks, improving the location of production and injection wells, transferring wells from other horizons; choosing the purpose of the wells during implementation of the selective water flooding system in order to increase the efficiency of using the resource base of liquid hydrocarbons.
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Date submitted2019-07-10
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Date accepted2019-08-30
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Date published2019-12-24
Methodology for calculating technical efficiency of power sections in small-sized screw downhole motors for the «Perfobur» system
With an increase in the share of old and low-yield wells and for the efficient exploitation of fields, it is necessary to include low-capacity formations into production. There are many wells where sidetracking and hydraulic fracturing are difficult due to the close proximity of the gas cap and underlying water caused by geological and technological reasons, and the use of existing secondary drilling-in technologies is not effective due to the extensive colmatated zone or annular circulation. Relevance of radial drilling technologies is growing, which allows drilling-in of the formation with a network of extended channels to establish high-quality hydraulic communication between the formation and the well without affecting the permeability of the formation. In contrast to radial drilling technologies using hydraulic washing, technical system (TS) «Perfobur» uses small-sized screw downhole motors (SDM) and rock cutting tools for channel construction. For efficient milling of production casing and destruction of rock, the hydraulic downhole motor must have high torque, and for the possibility of drilling with a high rate of angle gain, it must have short power section. Existing Russian and foreign SDM have limited number of standard sizes and do not meet the requirements specified for the development of the downhole module of TS «Perfobur». The paper discusses the development of universal small-sized sectional screw downhole motors for milling casing strings and drilling a network of branched channels of super-small diameter and radius of curvature as a part of the TS «Perfobur». Methodology proposed in the article for selecting optimal configuration of the SDM power sections allows constructing small-sized sectional downhole motor that meets the technical requirements and has improved characteristics compared to standard SDM.
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Date submitted2019-01-22
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Date accepted2019-03-16
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Date published2019-06-25
Key factors of public perception of carbon dioxide capture and storage projects
- Authors:
- S. V. Fedoseev
- Pavel S. Tcvetkov
One of the major challenges of the modern world is the problem of global warming, the solution of which requires the implementation of a set of strategic projects in the field of transition of the energy sector to the path of environmentally balanced development. One of the ways to implement this transition is the development of technologies for capturing and storage of technogenic carbon dioxide, which is recognized as the main one of greenhouse gases. At the same time, in the Russian context, the most expedient is the implementation of technological chains for capturing and storing CO 2 which are aimed at enhanced oil recovery, the effectiveness of which has been proven by world practice. Implementation of these projects requires consolidation of efforts of many parties, including government agencies, enterprises-issuers (power generating facilities and energy-intensive industry), oil-producing enterprises, non-state environmental organizations, media and public. World practice has many examples when uncoordinated actions of one of the stakeholders led to the closure of such a project, and therefore it is necessary to develop a mechanism of interaction between them, taking into account the specifics of Russian conditions. One of the least studied and controversial aspects of this interaction is to involve the public in the implementation of national carbon intensity programs and the local population in the implementation of a specific project. Research in this field has been conducted in the world over the past 14 years, which allowed the current research base to be used to develop fundamental principles for the development and promotion of CO 2 capture and storage technologies in Russia. Key factors affecting the perception of such projects by public were also analyzed and systematized. The research identified the main arguments for and against the development of CO 2 capture and storage technologies.
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Date submitted2019-01-17
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Date accepted2019-03-20
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Date published2019-06-25
Improving methodological approach to measures planning for hydraulic fracturing in oil fields
Goal of the research is development of an integrated approach to the planning of hydraulic fracturing (HF) treatment taking into account geo-technical, hydrodynamic, technological and economic criteria for the selection of wells for inclusion in the programs of HF with increasing importance of economic criteria. Stages of formation of the program for HF of the oil company are selected, systematized and analyzed. It is shown that high potential effectiveness of enhanced oil recovery method in fields with hard-to-recover reserves, on the one hand, and the complexity and high cost of application, on the other, determine the need to optimize the parameters of this business process at all stages of implementation and improve its planning methods. The priority directions for improving the hydraulic fracturing planning were justified: a clear definition of the criterion for the payback period of hydraulic fracturing activities, taking into account their technological features, improving the procedure for calculating the costs of implementing this technology and improving the reasonableness of selecting candidate wells for inclusion in the hydraulic fracturing program. Feasibility of using an additional criterion in the formation of hydraulic fracturing programs – marginal minimum cost-effective wall capacity – has been shown and a method for calculating it has been developed. The use of this criterion will allow to take into account not only technological limitations, but also limits of economic efficiency of conducting hydraulic fracturing at each specific well and, at the preliminary selection of candidate wells, exclude a priori unprofitable measures.
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Date submitted2018-05-14
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Date accepted2018-07-15
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Date published2018-10-24
Experience of Integrated use of gold-bearing raw material in the production of precious metals
- Authors:
- V. V. Zhmurova
- N. V. Nemchinova
With the depletion of rich gold-bearing ores, the processing started to use polymetallic ores, which, in addition to precious metals, contain other elements that could be valuable after recovery. The problem of using such ores is extremely difficult because of the high cost of recovery of associated valuable components. The paper presents the results of studies on the integrated use of extracted gold-bearing raw materials based on the example of the Berezitovoye deposit (Amurskaya oblast), they have low content of precious metals and many heavy non-ferrous metals (copper, lead). Experimental work was carried out to obtain copper by the method of cementation from solutions formed after the leaching of the impurities of gold-containing cathode deposits with hydrochloric acid. The cementing metal was iron turnings (waste products of the turning shop of the enterprise). Next, it was proposed to use cemented copper as a collector during re-melting of slags – wastes of processing of low-grade polymetallic ores containing precious metals. The authors obtained ingots of alloyed gold with gold weight fraction of 16 %, which meets the requirements of TU 117-2-7-75 on the content of non-ferrous metals. During hydrochloric acid treatment of cathodic deposits silver partially passed into the solution, it was recovered together with cemented copper and, in subsequent melting, passed into alloyed gold. Thus, the method proposed by the authors helps to reduce the content of precious metals in the «incomplete production cycle» of the gold recovery factory. The opportunity of selling the cementation copper at the enterprises specializing on manufacturing of jewels is shown; the expected economic effect at the same time amounted to more than 1.8 million rubles.
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Date submitted2017-11-20
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Date accepted2018-01-09
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Date published2018-04-24
Sulfidization of silver-polymetallic ores of «Goltsovoe» deposit for decreasing loss of silver in mill tailings
- Authors:
- L. V. Shumilova
- O. S. Kostikova
The results of laboratory studies of flotation concentration of silver-polymetallic ores of the Goltsovoe deposit at the Omsukchansk concentrator are presented. The results of sieve analysis of mill tailings of the experimental sample of MTP N 101 (N 7577-i) are described. They indicate that a large amount of silver (123 g/t) is lost in the size class – 0.040 mm (yield 50.25 %). According to the results of mineralogical analysis, it is established that the major losses of noble metal are associated with its fine impregnation in oxides, sulfides and silicate rocks. The main silver-bearing minerals are acanthite, polybasite and kustelite (class – 0.040 mm). Experimental studies were carried out in two stages. The purpose of the first stage is to determine the influence of grinding fineness in flotation feed (for a finished class content of 0.074 mm in the range of 60-95 %) for silver recovery at different amounts of butyl potassium xanthate (50, 150, 300 g/t). The purpose of the second stage is to evaluate the effectiveness of sulfidization at different consumption of sodium sulfide Na 2 S·9H 2 O (50, 150, 200, 450, 750 g/t – 1 % aqueous solution) under the conditions of the optimal reagent mode established in the first stage of the study. The results of experiments to determine the optimum grinding fineness and studies on the enrichment of silver-polymetallic ore with the use of sodium sulfide as a sulfidizer are presented. The efficiency of the sulfidization process is estimated. The following experimental dependencies of silver recovery are established: on the degree of grinding and consumption of butyl potassium xanthate; on variations of grinding fineness and the consumption of sodium sulphide (with a consumption of butyl xanthate 150 g/t); and on grinding fineness at optimum consumption of sodium sulfide 150 g/t and butyl potassium xanthate 300 g/t. A comparative evaluation of dependence of silver recovery index from the degree of grinding fineness before and after introduction of sodium sulphide (collecting agent consumption of 150 g/t) is given. T\
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Date submitted2017-08-30
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Date accepted2017-11-21
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Date published2018-02-22
Simulation of operation of pneumatic compensator with quasi-zero stiffness in the electric centrifugal submersible pump unit
- Authors:
- A. N. Zotov
- K. R. Urazakov
- E. B. Dumler
The ECSPU pneumatic compensators with quasi-zero stiffness are proposed. The pneumatic compensator with quasi-zero stiffness is suggested to be made in the form of pneumatic spring assemblies having a power characteristic with a positive stiffness working area and a set of successively connected Belleville springs and a power characteristic with a working area of negative stiffness. Structurally, a set of Belleville springs is located inside the air spring and supports pneumatic compensator piston. As a result of adding the negative stiffness of the disc spring washers set and the positive stiffness of the pneumatic spring, the resulting system (the proposed pneumatic compensator) acquires a quasi-zero or specified low stiffness. The efficiency of the suggested pneumatic compensator was determined by the possibility of moving its piston from the effects of various pressure drops. It was assumed that the greater the distance the piston can move under a given action, the more effective the pneumatic compensator is. The effect of various forces acting on the piston in the case of pressure drops on the discharge line of the electric centrifugal submersible pump units (ECSPU) is simulated: a rapidly decreasing load; a sudden increase in the force acting on the piston and vibration impact. In all the considered examples, the displacement of the piston was several meters, which corresponds to the length of the working area of the power characteristic of the considered pneumatic compensator with quasi-zero stiffness. It is shown that existing pneumatic compensators, which are like gas caps, are in principle unable to provide the same displacement of the piston under the same effects on it. For their effective operation, the size of the gas cap should be several tens of meters, which is impossible in the conditions of the well. In the calculations, it is shown that it is possible to manufacture the necessary disk spring washers from various materials: steel; fiberglass FGM; beryllium bronze. Of particular interest are disk spring washers made of beryllium bronze, which are capable of withstanding up to 20 billion load cycles.
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Date submitted2016-11-14
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Date accepted2017-01-09
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Date published2017-04-14
Method of restoring strength determination test
- Authors:
- S. M. Apollonskii
- Yu. V. Kuklev
The main requirements for an electric unit at the stages of its design, development, production and usage are described in technical specifications (TS) and standards (GOST). The electric unit should work in accordance with a specific purpose and have significant reliability, durability and safety. The reliability and durability of electric unit significantly depends on restoring strength speed value, that is growth of breakage voltage in arc pass for eliminating repeated arc strike. This article describes several methods of test identification of restoring strength, which were carried out at special testing laboratory units. They are described in relation to conditions of measuring the residual arc column of AC current after it reaches zero point and can be used in designing arc blowout units of low voltage.
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Date submitted2016-10-27
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Date accepted2017-01-02
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Date published2017-04-14
Chemistry as a basis for solving environmental issues
- Authors:
- V. E. Kogan
- T. S. Shakhparonova
The article summarizes over 40 years of authors’ experience in the field of physical chemistry and chemical technology of glassy state of materials. It is shown that environmental issues are caused not by Chemistry as a science but by actions of ecologically illiterate humans using its advances. It is noted that without chemistry humankind cannot live comfortably and solve existing environmental problems. In support these facts we describe several developments made by authors of this article in energy industry, high temperature machinery, glass production technology, glassy phosphate fertilizers, production of non-waste systems and complex research of physical-chemical principles of glassy oil sorbents production of organic and non-organic nature.
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Date submitted2015-07-05
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Date accepted2015-09-01
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Date published2016-02-24
Substantiation of intrastratal water shutoff technology in low permeability reservoirs
- Authors:
- M. K. Rogachev
- A. O. Kondrashev
The article presents the results of the filtration tests of the developed polymeric waterproofing compound GPS-1, which is a mixture of a water-alkaline hydrolyzed acryl-containing polymer solution with a nonionic surfactant. The obtained results indicate significant improvements of main operational parameters – penetrating and water-insulating power of the developed polymeric composition GPS-1 in comparison with the original one: addition of the nonionic surfactant reduced the pressure gradient of injection twice. Also, considerable (5 times) increase of the residual resistance factor, that is explained by deeper and more uniform penetration of the solution into the porous medium and the corresponding raise of isolation efficiency of pore channels, is established. Experiments on the model of a heterogeneous oil-filled formation showed that after the injection of the polymeric solution water mobility decreases in a highly porous interlayer and increases in a low-permeability interlayer indicating a redistribution of filtration flows in the model of a heterogeneous bed. The decrease of water mobility in a high-permeability zone contributes to the leveling of the displacement front and, ultimately, the additional extraction of oil from the less permeable area. As a result of the complex of filtration tests conducted, the efficiency of the developed polymeric composition GPS-1 for the regulation of filtration flows in low-permeability heterogeneous reservoirs is proved.
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Date submitted2014-11-19
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Date accepted2015-01-12
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Date published2015-10-26
Scientific heritage of academician Nikolay Semenovich Kurnakov
- Authors:
- O. A. Dubovikov
Once N.V.Lipin, a professor of mathematics at the Leningrad Mining Institute, told N.S.Kurnakov that M.V.Lomonosov had complained about his lack of familiarity with mathematics. The outstanding scientist replied «That’s absolutely true, and I have already told you about it: we all need mathematics, and the more chemistry develops, the more it needs a mathematical justification». According to one scenario of the international nongovernmental organization, the Club of Rome, there will be a three-fold decrease in the world’s raw materials resources and multifold volume reduction in industrial production by the middle of the 21st century. Another scenario claims that raw materials will reduce only by one third, and the volume of industrial production will remain at the level of the beginning of the century. Not only the first scenario, but also the second one forecasts industrial stagnation. It is unacceptable for dynamic and sustainable development of the technological civilization. Intensively developing economies in China, India, Brazil and Russia defy the forecast of the Club of Rome, as it has not taken into account the possibility of scientific and technological progress in reducing energy consumption and using alternative sources, as well as the increased technological potential of the humanity. Due to depletion of the main sources of energy (oil and gas), many experts link the future of the world’s power industry with the possible use of solid energy resources. From the environmental point of view solid fuel gasification technology is the most preferable. As the calorific value of producer gas is relatively low in comparison with natural gas, some research of possible use of producer gas (as an alternative to natural gas which is available not in all regions) at Russian industrial enterprises has been conducted.
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Date submitted2009-10-01
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Date accepted2009-12-02
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Date published2010-09-22
Typization of coalbed-methane deposits оf the kuznetsk basin by promising methane output with using different technologies of gas recovery intensification of coal seams
Experts of «Gazprom promgaz» Co based on international experience of coalbed methane (CBM) mining have developed recommendations for expedient application of various methods of coalbed gas recovery intensification under different mining conditions. It will result in reduction of wells number and increase in methane extraction degree.