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Date submitted2024-05-03
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Date accepted2024-07-11
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Date published2025-04-02
Assessment of ancylite ore dressability by flotation method
For more than 50 years, most rare earth elements were extracted from carbonatite deposits, which can contain different rare earth phases, but the main extracted minerals are bastnaesite, monazite and xenotime. Many studies focused on the improvement and development of dressing circuits for ores of these minerals. However, in some carbonatite complexes, rare earth deposits are composed partly or mainly of ancylite ores. This type of rare earth ores was very poorly studied in terms of dressability – previous experiments with ancylite ores are rare and not productive enough. Ancylite is the main concentrator of rare earth elements in most carbonatite complexes of the Devonian Kola Alkaline Province (northwest Russia). Dressability of ancylite ore from the Petyayan-Vara carbonatite field in the Vuorijärvi alkaline-ultramafic complex was assessed using the flotation method. The complex is one of the most potential rare earth deposits associated with carbonatites in the Kola Region. Petrographic and mineralogical studies demonstrated the occurrence of abundant iron and barite oxide inclusions in ancylite, which imposes restrictions on physical separation of these three minerals. The study of petrogeochemical and mineralogical composition of fractions formed during mechanical grinding of ores to a size less than 2.0 mm showed that even at this stage of sample preparation, the finest-grained fractions (less than 0.071 mm) were enriched in ancylite (to 19 vol.% or more with a content of 15 vol.% in ore). Three classes of reagents were considered as collectors in flotation experiments: fatty acids, alkyl hydroxamic acids, and amino acid derivatives. The reagent from the amino acid derivative class was highly efficient. The use of such a collector in combination with sodium hexametaphosphate depressant made it possible to obtain a flotation concentrate in an open circuit with total rare earth oxides content 33.4 wt.% at 64.7 % extraction.
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Date submitted2024-05-17
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Date accepted2025-03-27
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Date published2025-03-27
Determination of impact hazard potential of rocks in the Norilsk Industrial Region
The deeper the mineral deposits developments are, the worse the mining and geological conditions become. Significant growth of stress level in the rock mass contributes to possible manifestation of rock pressure in dynamic form. The resulting task of assessment of rock impact hazard is closely related to the task of obtaining more accurate results of compression tests of samples in rigid or servohydraulic test presses using graphs of their full deformation. This approach requires special expensive equipment, considerable time resources, and sufficient core material. Therefore, it is important to have an approach that allows to assess the propensity of rocks to brittle fracture with research methods simple enough not to result in the loss of quality and reliability of the obtained results. This paper presents the results of laboratory tests of rocks from the Norilsk Industrial Region to determine their tensile and compressive strengths. Test methods involved both domestic and foreign standards for determining the value of the brittleness coefficient. The impact hazard potential of rocks was determined using the Kaiser criterion. It is found that the tested lithological types (rich sulfide ores, hornblende, disseminated ores, and gabbro-dolerite rocks), with the exception of anhydrite, have a low impact hazard potential.
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Date submitted2024-05-11
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Date accepted2025-01-28
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Date published2025-03-21
Research and development of technology for the construction of snow airfields for accommodating wheeled aircraft in Antarctica
- Authors:
- Sergey P. Polyakov
- Sergey V. Popov
Construction of a new wintering complex at the Antarctic Vostok Station required prompt delivery of builders and mechanics to Progress Station to move them further to the work area. To solve this major logistical issue, a new landing site, later named Zenit, certified for accommodating heavy wheeled aircraft, was prepared in the Progress Station area from March to August 2022. Its snow pavement slab with a total area of 350 thousand m2 is from 100 to 120 cm high. It was made by applying snow layers with their subsequent compaction by a specially designed compaction platform for snow airfields suitable for heavy wheeled aircraft. As a result, the pavement has a surface hardness of at least 1 MPa. The layer from 30 to 60 cm has a hardness of at least 0.8 MPa, and the bottom layer at least 0.6 MPa. The first Il-76TD-90VD aircraft of the Russian company Volga-Dnepr was accommodated to the new runway on 7 November 2022. The aircraft landed in normal mode. The depth of the chassis wheels track after landing did not exceed 3 cm. The research provided in-depth understanding of the mechanisms for forming the supporting base of the runway from snow and ice in Antarctica. The experience gained can be used to solve similar issues in the Far North.
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Date submitted2024-03-11
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Date accepted2024-11-07
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Date published2025-03-06
Geochemical characteristics of weathering crusts on the Dzhezhimparma Ridge and the Nemskaya Upland (South Timan)
Numerous local varieties of weathering crusts are known in the South Timan. They differ in their position in the section, type of weathering products, substrates, and occurrence. The aim of the research is to identify patterns in the distribution of rock-forming, rare and rare earth elements and the composition of clay minerals in clay formations of the weathering crusts. The main task is to describe the occurrence and geochemical features that enable determining the genetic type and formation conditions of weathering crusts. The paper presents the results of a study of the distribution of petrogenic, rare earth, rare elements, and clay minerals in weathering crust of different ages, genetic types and occurrence conditions on the Dzhezhimparma Ridge and the Nemskaya Upland in the South Timan. We found that hydromica-kaolinite-type weathering crust is developed after the Late Riphean Dzhezhim Fm. rocks in the basement-cover contact zone on the Dzhezhimparma Upland, and the layer of fine-grained rock at the base of the Devonian section previously considered a weathering crust was formed as a result of mechanical destruction of the Devonian sandstones during movement in the thrust zone. In the Vadyavozh quarry located on the Nemskaya Upland, we studied and described the formations of Mesozoic-Cenozoic areal and linear weathering crusts after the Late Riphean Dzhezhim Fm. rocks. We found that micaceous siltstones in the siltstone-sandstone strata of the Dzhezhim Fm. are associated with the Riphean stage of crust formation and are composed of weathering crust material redeposited in the epicontinental basin.
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Date submitted2024-04-27
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Date accepted2024-11-07
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Date published2025-03-05
Comprehensive studies of the snow-firn layer in the area of the Russian Antarctic Vostok Station
The article presents the findings from research conducted at Vostok Station during the 69th Russian Antarctic expedition. The primary goal of the research is to perform a thorough investigation of the snow-firn layer using both direct (drilling and core analysis) and indirect (georadiolocation and seismic exploration) methods. As part of the research, fundamental tasks related to the study of the structure and dynamics of the upper part of the ice sheet were addressed, as well as applied tasks aimed at justifying the depth of explosive charge placement for seismic work with the goal of conducting a detailed study of Lake Vostok and selecting the point for drilling access to the lake. Data on the microstructure and physical properties of the snow-firn layer were collected. The findings will allow for future improvements to the firn densification model, which is required to understand the evolution of ice grains during the early stages of metamorphism. The study's findings aided in the understanding of the structural features of the ice sheet's surface layer, allowing for more precise determination of the structural and physical characteristics of the snow-firn layer and ice, potentially leading to a better understanding of climatic and geological processes in Antarctica.
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Date submitted2022-09-30
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Date accepted2024-11-07
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Date published2025-02-25
Carbon dioxide corrosion inhibitors: current state of research and development
Among the methods of corrosion control in the oil and gas production industry the leading place belongs to inhibitor protection, since there is no need for technological and technical changes in the existing equipment. The combination of high variability of inhibitor composition with changing conditions of its application and low capital investments makes it an indispensable reagent at oil and gas fields. The main classes of compounds used as active bases of carbonic acid corrosion inhibitors for the protection of oil and gas equipment are described. Classical organic active bases containing heteroatoms (oxygen, sulfur, nitrogen) are examined. Special attention was paid to alkylimidazolines and other nitrogen-containing compounds as the most frequently used as active bases of carbonic acid corrosion inhibitors in Russia and abroad. A wide range of possibilities to achieve the desired properties of corrosion inhibitors by varying the substitutes has been demonstrated. Nowadays, in addition to the traditional requirements for corrosion inhibitors, their safety for the environment is equally important. The information on prospective research and development aimed at improving the environmental characteristics of the reagents used is given. Plant extracts, synthetic and biological polymers involved in traditional corrosion inhibitors or used as new independent compounds are considered. It is shown that the effectiveness of corrosion inhibitors significantly depends on the pH of the medium, temperature, partial pressure of СО2, flow rate, and other factors.
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Date submitted2023-04-10
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Date accepted2024-11-07
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Date published2025-02-25
Consideration of the geomechanical state of a fractured porous reservoir in reservoir simulation modelling
This paper presents reservoir simulation modeling of a hydrocarbon accumulation with a fractured porous reservoir, incorporating the geomechanical effects of fracture closure during variations in formation pressure. The fracture permeability parameter is derived from the impact of stress on fracture walls. The fracturing parameter is determined based on 3D seismic data analysis. A permeability reduction model is implemented in the tNavigator reservoir simulation platform. The proposed approach improves the convergence of formation pressure dynamics in well data while maintaining flow rate and water cut adaptation accuracy. This results in enhanced formation pressure prediction and optimization of the pressure maintenance system.
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Date submitted2023-07-31
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Date accepted2024-11-07
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Date published2025-02-25
Environmental assessment of biochar application for remediation of oil-contaminated soils under various economic uses
- Authors:
- Tatiana V. Minnikova
- Sergey I. Kolesnikov
Remediation is an important area of oil-contaminated soil restoration in Russia, since oil refining industry is the major one for Russia and neighbouring countries, and the issues of environmentally effective and economically profitable remediation of oil contamination have not yet been solved. Soils under various economic uses have different surface areas and degrees of soil particles envelopment with oil due to the presence or absence of cultivation, the amount of precipitation and plant litter. The introduction of various substances for remediation into oil-contaminated soils of steppes (arable land), forests, and semi-deserts, considering their differences, gives different results. Biochar is coal obtained by pyrolysis at high temperatures and in the absence of oxygen. The uniqueness of this coal lies in the combination of biostimulating and adsorbing properties. The purpose of the study is to conduct an environmental assessment of biochar application for remediation of oil-contaminated soils under various economic uses. The article compares the environmental assessments of biochar application in oil-contaminated soils with different particle size fraction. The following indicators of soil bioactivity were determined: enzymes, indicators of initial growth and development intensity of radish, microbiological indicators. We found that the most informative bioindicator correlating with residual oil content is the total bacteria count, and the most sensitive ones are the roots length (ordinary chernozem and brown forest soil) and the shoots length (brown semi-desert soil). The use of biochar on arable land and in forest soil (ordinary chernozem and brown forest soil) is less environmentally efficient than in semi-desert soil (brown semi-desert soil). The study results can serve to develop measures and managerial and technical solutions for remediation of oil-contaminated soils under various economic uses.
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Date submitted2023-09-05
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Date accepted2024-11-07
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Date published2025-02-25
Investigation of the accuracy of constructing digital elevation models of technogenic massifs based on satellite coordinate determinations
At all stages of the life cycle of buildings and structures, geodetic support is provided by electronic measuring instruments – a laser scanning system, unmanned aerial vehicles, and satellite equipment. In this context, a set of geospatial data is obtained that can be presented as a digital model. The relevance of this work is practical recommendations for constructing a local quasigeoid model and a digital elevation model (DEM) of a certain accuracy. A local quasigeoid model and a DEM were selected as the study objects. It is noted that a DEM is often produced for vast areas, and, therefore, it is necessary to build a local quasigeoid model for such models. The task of assessing the accuracy of constructing such models is considered; its solution will allow obtaining a better approximation to real data on preassigned sets of field materials. A general algorithm for creating both DEM and local quasigeoid models in the Golden Software Surfer is presented. The constructions were accomplished using spatial interpolation methods. When building a local quasigeoid model for an area project, the following methods were used: triangulation with linear interpolation (the least value of the root mean square error (RMSE) of interpolation was 0.003 m) and kriging (0.003 m). The least RMSE value for determining the heights by control points for an area project was obtained using the natural neighbour (0.004 m) and kriging (0.004 m) methods. To construct a local quasigeoid model for a linear project, the following methods were applied: kriging (0.006 m) and triangulation with linear interpolation (0.006 m). Construction of the digital elevation model resulted in the least aggregate value of the estimated parameters: on a flat plot of the earth’s surface – the natural neighbour method, for a mountainous plot with anthropogenic topography – the quadric kriging method, for a mountainous plot – quadric kriging.
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Date submitted2023-10-03
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Date accepted2024-11-07
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Date published2025-02-25
Investigation of the effectiveness of the use of various substances for dust suppression during the transshipment of granular sulfur
The article is devoted to the problem of dusting during the transshipment of granular sulfur and existing methods of dust suppression. The analysis of various methods for reducing dust emission at granulated sulfur storage and transportation facilities is presented. The necessity of using special reagents to increase the efficiency of dust suppression and re-granulation of sulfur crushed by abrasion is noted. The sulfur dust obtained from the port terminal during the transshipment of technical sulfur was analyzed for granulometric composition. The results of experimental studies of the effectiveness of the use of various substances for sulfur dust suppression (alkyl polyglycosides, sodium silicate, starch) are presented. The laboratory installation was a hopper, inside which a test sample of dusty material was placed. The sample was subjected to an aerodynamic effect by an air flow at a given speed. The concentrations of suspended solids were measured with a dust meter-nephelometer with a sampling tube placed in the geometric center of the hopper. The effectiveness of dust suppression agents was determined based on a comparison of the concentration values obtained on dry and treated samples. For dust suppression at granulated sulfur treatment facilities, it is proposed to use a composition based on nonionic surfactants represented by a mixture of C12-14-alkylglycosides oligomers (1-1.5 %), additionally containing a mixture of amylose and amylopectin polysaccharides in the form of soluble starch (1-2.5 %) and water. The dust suppressor showed consistently high dust suppression efficiency both when measured immediately after irrigation (98.3 %) and after the expected time (99.7 %). The developed composition provides an increase in the dust-suppressing ability of the solution and the elimination of the possibility of repeated dusting due to the formation of a polymer film on the surface, as well as the regranulation of the product crushed by abrasion.
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Date submitted2023-10-04
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Date accepted2024-09-24
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Date published2025-02-25
Crustal movement model in the ITRF2020 – a case study in Northern Vietnam
- Authors:
- Bui Thi Hong Tham
- Phi Truong Thanh
In the North area of Vietnam, the crustal movement velocity of 38 GNSS points belonging to different international Earth reference frames (ITRF2000, ITRF2005, ITRF2008) is adjusted to the international Earth reference frame ITRF2020. This is the latest frame up to now. Since then, the picture of crustal movement in the North area of Vietnam has been unified in a dynamic coordinate system. In the study area, the rate of crustal movement is about 35 mm/year, and the direction of displacement is from northwest to southeast. To build a model of the crustal movement of the Earth in the northern area of Vietnam, the movement velocity data of 38 stations in ITRF2020 is evaluated with high accuracy. All points are also satisfactory. And then, the crustal movement velocity model is built by using the collocation method in the form of the 3-order Markov function. Within 38 stations, 34 stations are used to build the model and 4 remaining stations are used as checked stations. The obtained results show that the Earth's crust movement velocity model has an accuracy of about 2 mm/year for movement velocity and 2 deg for movement direction. This is the first model of Earth's crust movement in the North of Vietnam that has been built in the latest dynamic coordinate system ITRF2020. These results have important significance in the research and practical application of the movement of the Earth's crust. The steps of building the movement velocity model in this study can be applied to other experimental areas in the territory of Vietnam.
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Date submitted2024-03-22
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Date accepted2024-09-24
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Date published2025-02-25
Behaviour of cerium (III) phosphate in a carbonate-alkaline medium
- Authors:
- Tatyana E. Litvinova
- Stepan A. Gerasev
The article investigates the behaviour of rare earth metals in carbonate-alkaline systems. The results of experimental studies on rare earth element extraction from phosphogypsum, a large-tonnage industrial waste forming in production of phosphoric acid are presented. Using the liquid phase leaching method, it was possible to extract more than 53 % of rare earth elements from old phosphogypsum and more than 69 % from fresh phosphogypsum due to solid phase treatment with a 4 mol/l potassium carbonate solution at temperature 90 °C. The behaviour of model cerium (III) phosphate in a carbonate-alkaline medium is characterized: a solubility isotherm is obtained as well as the dependences of the degree of cerium extraction into solution on temperature, carbonate ion concentration, interphase ratio, stirring intensity, and pH. The ability of soluble rare earth element complexes to precipitate over time was established, which was confirmed using cerium and neodymium as an example. Within 240 h after the end of the experiment, approximately 25 % of cerium and 17 % of neodymium were precipitated from the liquid phase. A similar property was recorded in representatives of the light group and was not noted in elements of the heavy group. The ability to self-precipitate in future can serve as a basis for developing an alternative approach to separating rare earth metals into groups after extraction in a carbonate ion medium. Also, based on the analysis of experimental data, the mechanism of cerium (III) phosphate dissolution in a carbonate-alkaline medium was characterized. An assumption was made that rare earth metal phosphates dissolve sequentially passing into an insoluble carbonate and then into a soluble carbonate complex.
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Date submitted2024-03-29
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Date accepted2024-11-07
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Date published2025-02-26
Well killing with absorption control
The development of new fields with low-permeability reservoirs required the introduction of new production technologies, of which the most significant for well killing and underground repair were multi-ton hydraulic fracturing, the simultaneous operation of two or three development sites by one well grid, and an increase in the rate of fluid extraction. These global decisions in field development have led to the need to search for new effective materials and technologies for well killing. The article is devoted to the analysis of problems associated with the process of killing production wells in fields characterized by increased fracturing, both natural and artificial (due to hydraulic fracturing), with reduced reservoir pressure and a high gas factor. The relevance of the analysis is due to the increase in the number of development sites where complications arise when wells are killed. Particular attention is paid to technical solutions aimed at preserving the filtration and capacity properties of the bottomhole formation zone, preventing the absorption of process fluid, and blocking the manifestation of gas. The classification of block-packs used in killing is given, based on the nature of the process fluid. Suspension thickened water-salt solutions are considered, forming a waterproof crust on the surface of the rock, which prevents the penetration of water and aqueous solutions into the formation. This approach ensures the safety and efficiency of killing operations, especially when working with formations in which maintaining water saturation and preventing the ingress of the water phase are of critical importance. Modern trends in the development of technology are revealed, and promising areas for further improvement of well killing with absorption control are outlined.
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Date submitted2024-04-11
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Date accepted2024-11-07
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Date published2025-01-17
Thyristor booster device for voltage fluctuation reduction in power supply systems of ore mining enterprises
The article is devoted to solving the problem of voltage fluctuations in the power supply systems of ore mining enterprises. The connection of high-power consumers with abruptly variable operating mode (for example, high-voltage mining excavators) causes voltage fluctuations and sags, disabling electrical equipment, communication, and automation devices in the 6-10 kV distribution network, which disrupts technological processes, etc. The use of existing solutions and methods to reduce voltage variations caused by dynamic loads is not effective. To solve the problem, booster transformers with high-speed thyristor switches can be used to work out switching the control steps towards increasing or decreasing the voltage. The authors offer a new circuitry solution for a thyristor booster device (TBD) with a pulse-phase control method. The purpose of the research is to determine the control laws of TBD, which enable to effectively reduce voltage fluctuations from dynamic load in the power supply systems of mining enterprises. The article provides a schematic diagram of the TBD and describes the principle of operation of the device. Some modes of increasing and decreasing the output voltage of the TBD, as well as the basic mode (without voltage addition) are provided. Mathematical modeling of TBD control processes was carried out and adjustment characteristics were set taking into account the load power factor. On a simulation computer model of a 6 kV electric network with a dynamic load, the verification of the adjustment characteristics of TBD obtained during mathematical modeling was carried out. Based on the research results, the laws for regulating the output voltage of TBD were established. The TBD effective control range with normal permissible limits of odd harmonics have been determined. The conducted research will make it possible to implement the device control system.
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Date submitted2024-07-28
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Date accepted2024-11-26
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Date published2024-12-12
From import substitution to technological leadership: how local content policy accelerates the development of the oil and gas industry
- Authors:
- Oleg V. Zhdaneev
- Ivan R. Ovsyannikov
Achieving technological sovereignty implies accelerating innovation and reducing import dependence. An effective tool for addressing these challenges is local content policy (LCP). The purpose of this study is to assess the impact of LCP on innovation activity in oil and gas companies and to provide recommendations for enhancing the effectiveness of this policy in Russia. The paper analyzes the influence of LCP on innovation levels in the oil and gas sector, drawing on examples from 10 countries. A positive short-term impact of LCP on innovation was identified in Brazil, Malaysia, and Saudi Arabia, with long-term effects observed in China and South Africa. Recommendations for improving the effectiveness of LCP in Russia are supplemented with a methodology for calculating the level of technological sovereignty. A refinement of the method for solving the «responsiveness» problem, incorporating the level of localization, has been proposed.
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Date submitted2024-05-08
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Date accepted2024-11-07
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Date published2024-12-12
The effect of mechanical and thermal treatment on the characteristics of saponite-containing material
Solving the problems of modern building materials science is reduced to obtaining high-quality materials, expanding and searching for a rational raw material base, which can be carried out through the use of various industrial wastes. In this paper, the possibility of using waste from the mining industry – saponite-containing material (SCM) obtained during the enrichment of kimberlite ores from the Lomonosov diamond deposit, as an active mineral additive for cement binders and concretes is considered. The influence of mechanical and thermal treatment on a number of properties of the material selected from the tailings dump and in its initial state was studied. The study of the surface activity of SCM samples consisted in determining the sorption capacity, acid-base centers and their distribution. An increase in the activity of the surface of the material particles as a result of mechanical activation and its decrease during temperature treatment were determined. These effects are associated with phase rearrangements and structural changes in the sandy-clay rock, which was confirmed during thermal analysis. The temperature effect has no pronounced effect on the microstructure, the “smoothness” of the particles and the formation of a consolidated surface of the structural elements of the saponite-containing material are noted.
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Date submitted2024-03-11
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Date accepted2024-09-24
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Date published2024-12-06
Comparative analysis of nitrogen and carbon isotopic fractionation during diamond formation based on β-factor determination
- Authors:
- Dmitrii P. Krylov
First quantitative estimates are presented for nitrogen isotopic fractionation during diamond crystallization with respect to nitrogen-bearing fluid components using quantum-mechanical (DFT) calculations on the defect (with the substitutional nitrogen) diamond lattice. Provided equilibrium isotopic fractionation, 15N/14N ratio decreases within the sequence of compounds NH4+ > N2 > (diamond, NH3) > CH3N > CN− > NH2. At temperatures of 1,100 to 1,200 °C fractionation among diamond and fluid N-compounds are estimated at –2.23, –0.77, 0.01, 0.44, 1.31 and 2.85 ‰ and substantially (over 1 ‰) exceed the already available estimates based on the modeling diamond C-N bonds by analogy with HCN or CN – molecules. Depending on the dominant nitrogen and carbon substance in the mineral-forming fluid, diamond formation can be accompanied by different isotope compositional trends, as expressed either by zoned patterns within individual diamond grains or by isotopic δ15N vs δ13C covariations during successive crystallization. Provided the dominance of NH3 component (the reduced conditions, high pressures and the cold geotherm) nitrogen isotope fractionation between diamond and fluid does not exceed 0.1-0.2 ‰ and the isotope shifts at temperature ca. 1100 °C Δ15N << Δ13C. In nitrogen depleted reduced mantle fluids possible existence of compounds with low heavy isotope affinity at temperature of diamond formation (especially NH2) implies high isotope fractionation between diamond and the fluid and hence, evolved Δ15N/Δ13C ratios. Oxidized fluids dominated by CO2 or CO3 coupled with N2 component are characterized by close to zero Δ15N/Δ13C ratios as inferred by prevailing carbon isotope fractionation with respect to nitrogen isotopes, the latter change considerably with nitrogen distribution coefficient among diamond and the growth media.
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Date submitted2023-08-31
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Date accepted2023-12-27
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Date published2024-11-12
Geochemical studies of rocks of the Siberian igneous province and their role in the formation theory of unique platinum-copper-nickel deposits
- Authors:
- Nadezhda А. Krivolutskaya
The Norilsk deposits, unique both in their geological structure and reserves of nickel and platinum, have attracted the attention of researchers for several decades. Several hypotheses have been proposed to explain their formation. Two of them are the most widely accepted: the model of ore formation in an intermediate chamber from picritic melt enriched in sulphides and the formation of sulphides in situ through the assimilation of sulphate-bearing sediments by tholeiitic magma as it rises to the surface. The main questions regarding the genesis of these deposits are: the composition of the parental magmas that formed the ore-bearing massifs; the relationship between intrusions and effusive rocks; and the extent and role of assimilation of host rocks by magmas. These issues are discussed in the article using a large amount of analytical data obtained by the author during the study of the magmatic rocks and geological structures in the Norilsk area. Based on these data, it was concluded that none of the proposed models could fully explain all observed geological features of the deposits as well as the appearance of the unique sulphide ores. In order to solve the problem of the genesis of the Norilsk deposits, it is necessary to analyse the evolution of P3-T1 magmatism over time in the Siberian large igneous province, especially in its eastern part, and to determine its association with ore-forming processes; and its investigating it is a priority task for understanding sulphide ore formation. Solving this task should be based not only on geophysical data but also on studies of the geochemistry of igneous rocks within the province.
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Date submitted2024-04-16
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Date accepted2024-09-24
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Date published2024-11-12
Deep-buried Lower Paleozoic oil and gas systems in eastern Siberian Platform: geological and geophysical characteristics, estimation of hydrocarbon resources
The study of deep-buried oil and gas systems is a promising trend in the preparation of hydrocarbon resources. The study of the factors determining oil and gas potential is extremely important. The Lena-Vilyui sedimentary basin in the eastern Siberian Platform has a potential for the discovery of large oil and gas fields in deep-buried Cambrian deposits. The use of original methodological approaches to the analysis of black shale and overlying deposits, generalization of the results of lithological, biostratigraphic and geochemical studies of Cambrian deposits in territories adjoining the study area, modern interpretation of geophysical data showed that siliceous, carbonate, mixed rocks (kerogen-mixtite) of the Kuonamka complex and clastic clinoform-built Mayan deposits are most interesting in terms of oil and gas potential. Oil and gas producing rocks of the Lower and Middle Cambrian Kuonamka complex subsided to the depths of 14 km. The interpretation of modern seismic surveying data confirms the hypothesis of a limited occurrence of the Upper Devonian Vilyui rift system. Based on generalization of geological, geophysical and geochemical archival and new materials on the Lower Paleozoic deposits of the eastern Siberian Platform, a probabilistic estimation of geological hydrocarbon resources of the Cambrian and younger Paleozoic complexes in the Lena-Vilyui sedimentary basin was performed. Based on basin modelling results it was concluded that the resources were mainly represented by gas. It is presumed that oil resources can be discovered in traps of the barrier reef system as well as on the Anabar and Aldan slopes of the Vilyui Hemisyneclise. With a confidence probability of 0.9, it can be stated that total initial resources of oil and gas (within the boundaries of the Vilyui Hemisyneclise) exceed 5 billion t of conventional hydrocarbons. The recommended extremely cautious estimate of resources of the pre-Permian complexes is 2.2 billion t of conventional hydrocarbons. In the study area, it is necessary to implement a program of deep and super-deep parametric drilling without which it is impossible to determine the oil and gas potential of the Lower Paleozoic.
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Date submitted2024-04-10
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Date accepted2024-10-14
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Date published2024-11-12
The influence of ocean anoxia on conditions for the Domanik deposits formation
The article considers one of conditions for the Domanik facies formation on the example of Tatarstan and Bashkortostan. The main emphasis is on the influence of anoxic paleobasin conditions on the high-carbon strata formation. A detailed study of the hydrocarbon composition of Domanik deposits made it possible to find characteristic biomarkers in their composition. They are based on the composition and structure of diagenetic products of biological compounds composing the sulphur bacteria living in anoxic/euxinic paleobasin conditions. Such compounds include C40 diaryl isoprenoids – isorenieratane and paleorenieratane. C10 tetramethylbenzenes also occupy a special place in the Domanik deposits study. Their appearance in the composition of organic matter of these deposits results from the transformation of sulphur bacteria compounds. Diaryl isoprenoids and tetramethylbenzenes are a reliable indicator of anoxic conditions of the Domanik deposits formation. The thermodynamic state of the hydrocarbon environment can be determined from the ratio of tetramethylbenzene isomers.
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Date submitted2024-04-12
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Date accepted2024-09-05
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Date published2024-11-12
Promising reagents for the extraction of strategic metals from difficult-to-enrich mineral raw materials
The need of the mining and processing industry for new types of directional reagents is due to the deterioration of the material composition of the processed ores. Low Au content (less than 0.5-1.0 g/t), finely dispersed Au inclusions (0.1-10.0 microns) in the ore, similar properties of the separated minerals have an extremely negative effect on flotation performance when using traditional reagents, which leads to significant losses of valuable metal with enrichment tailings. Expanding the range of domestic flotation reagents based on the latest achievements of fundamental research and their targeted application at mining and processing companies will compensate for the negative impact of the mineral composition of raw materials and ensure maximum extraction of strategic metals from difficult-to-enrich ores. The use of modern research methods (scanning electron and laser microscopy, UV spectrophotometry, XRF and chemical analysis) made it possible to visualize the adsorption layer of new reagents-collectors of a number of dithiocarbamates with different structures of a hydrocarbon radical and an organic modifier on the surface of gold-containing sulfides. The amount of adsorbed reagents on the surface of minerals has been experimentally determined. The specific features of the fixation of reagents on minerals of various compositions led to optimal correlations of their consumption in the flotation process. Scientifically based reagent regimes ensured an increase in the gold content in the concentrate and a decrease in the loss of gold with tailings by 5-6 % during flotation enrichment of the refractory ore of the Malinovskoe deposit.
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Date submitted2024-04-24
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Date accepted2024-09-24
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Date published2024-11-12
Study and justification of the combination of beneficiation processes for obtaining flake graphite from technogenic carbon-containing dusts
The most important task of modern production development is to provide the mineral and raw materials sector of the economy with resources included in the list of strategic raw materials, including flake graphite. In addition to natural raw materials, the source of its obtaining can be metallurgical production wastes not involved in processing. Development of metallurgical dust beneficiation technology will solve the problem of obtaining high-purity flake graphite with a crystal structure close to ideal and in demand in the production of high-tech materials. It will allow creating a renewable raw material base of graphite and utilising metallurgical production wastes. The research included the study of dust beneficiation by coarseness, magnetic and flotation methods, the influence of dust disintegration processes on beneficiation indicators. Based on the established technological properties of the components of dusts, magnetic, flotation and gravity beneficiation methods can be applied for their separation in different sequence. It is shown that dusts from different sites have different enrichability by these methods, and it should be taken into account when developing a complex technology of their processing. The degree of beneficiation increases in a row of dusts from the blast furnace shop (BF) – electric steel smelting shop (ESS) – oxygen-converter shop (OCS). The method of grinding has a significant influence on the separation indicators – at dry grinding in a centrifugal-impact mill with subsequent pneumatic classification the quality of graphite concentrates increases by 22.7 % of carbon for BF dust and by 13.48 % of carbon for ESS dust. OCS dust beneficiation indicators are high at coarse grinding with steel medium – mass fraction of carbon 96.1 %.
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Date submitted2024-04-25
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Date accepted2024-09-24
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Date published2024-11-12
Specific features of kinetics of thermal transformation of organic matter in Bazhenov and Domanik source rocks based on results of pyrolysis gas chromatography
Pyrolysis of organic matter with subsequent analysis of hydrocarbon composition of the resulting products allows obtaining multicomponent distribution spectra of the generation potential by the activation energies of reactions of kerogen transformation into hydrocarbons. Configuration of the spectra depends on the structure of kerogen and is individual for each type of organic matter. Studies of kerogen kinetics showed that the distribution of activation energies is unique for each oil source rocks. The kinetic model of thermal decomposition of kerogen of the same type, for example, marine planktonic (type II), can differ significantly in different sedimentary basins due to the multivariate relationship of chemical bonds and their reaction energy threshold. The developed method for calculating multicomponent kinetic spectra (four-component models are used) based on results of pyrolysis gas chromatography allows obtaining one of the most important elements of modelling the history of oil and gas generation in geological basins. Kinetic parameters of organic matter of oil and gas source rocks influence the onset time of generation and directly reflect differences in the composition and structure of different types of kerogens. The results of determining the kinetic parameters of two high-carbon source rocks occurring across the territory of three oil and gas basins are shown. Generation and updating of the data of kinetic models of certain oil and gas source rocks will increase the reliability of forecasting oil and gas potential using the basin modelling method.
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Date submitted2024-05-03
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Date accepted2024-10-14
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Date published2024-11-12
Genetic geological model of diamond-bearing fluid magmatic system
The article proposes a genetic geological model of diamond deposit formation associated with kimberlites and lamproites. It is based on the synthesis of published data on diamond-bearing kimberlite systems and an original study of the ontogenetic features of diamond crystals. Deep diamond crystallization, its upward transportation and subsequent concentration in near-surface kimberlite-lamproite bodies and other rocks, including those brought to the surface by high-amplitude uplifts of crystalline basement rocks, are combined in a single system. An assumption is made about the primary sources of the Anabar placer diamonds. The possibility of hydrocarbon generation at mantle levels corresponding to diamond formation areas and their transportation to the upper crustal zones by a mechanism similar to the mantle-crust migration of diamond-bearing fluidized magmas is shown. The high rate of their upward movement allows transportation to the surface without significant loss as a result of dissolution in melts and sorption on the surface of mineral phases. The significant role of fluid dynamics at all stages of this system is noted.
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Date submitted2024-05-17
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Date accepted2024-10-14
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Date published2024-11-12
Black shales – an unconventional source of noble metals and rhenium
The content of noble metals and rhenium in the Lower Paleozoic black shales of the eastern Baltic paleobasin in Russia was estimated. Shales are enriched in platinoids (PGM to 0.12 g/t) and rhenium (to 1.54 g/t). The main accessory elements of noble metals and Re are U, V, Mo, Cu, and Ni. Black shales consist of organic (9-26 rel.%), clay (40-60 rel.%), and silt-sandy (25-50 rel.%) components and a nodule complex (2-5 rel.%) (carbonate, sulfide, phosphate and silicate nodules). Noble metals occur sporadically in the silt-sandy admixture as native forms and intermetallics: Aunat, Au-Ag, Au-Cu, Au-(Cu)-Hg, Au-Hg, Ag-Cu, Pt-Fe. Micromineral phases of noble metals were found in diagenetic sulfides: Aunat, chalcopyrite with Au admixture, pyrite with platinoid admixture. Clay fraction is 10-fold enriched in noble metals as compared to shale – to 0.28 g/t Au, 0.55 g/t Pt, 1.05 g/t Pd, and 1.56 g/t Re. Organic matter sorbs noble metals to a limited extent but accumulates rhenium. Pore space of black shales contains a colloidal salt component (submicron fraction) which is represented by particles smaller than 1,000 nm. The share of submicron fraction in black shales is 0.1-6 wt.%. The submicron fraction contains on average: PGM – 14 g/t, Au – 0.85 g/t, and Re – 4.62 g/t. The geochemical resource of noble metals (Au, Pt, Pd), Re and the accessory elements (U, V, Mo, Cu, and Ni) for black shales as a whole and their submicron fraction was estimated. Black shales are recommended as an integrated source of raw materials.