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Date submitted2024-05-15
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Date accepted2024-11-07
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Date published2025-04-14
Metacarbonate rocks of the Paleoproterozoic Khapchan series (southeastern part of the Anabar Shield): mineral and chemical composition, metamorphic conditions
The mineral composition of metacarbonate rocks (silicate marbles and carbonate-silicate rocks) of the Khapchan series (southeastern part of the Anabar Shield) was studied, and the PT (pressure and temperature)-parameters of their formation were established. Silicate marbles contain calcite, dolomite, forsterite, clinohumite, spinel, enstatite, diopside, pargasite, meionite, phlogopite, and feldspars. Carbonate-silicate rocks are composed of calcite, quartz, feldspars, diopside, grossular, marialite, and vesuvianite. Carbonate-silicate rocks are significantly enriched in SiO 2 , Al 2 O 3 , FeO, Na 2 O, K 2 O, TiO 2 and contain less MgO, CaO than silicate marbles. A difference was revealed in PT-parameters determined for silicate marbles (temperatures 700-900 °C and pressure no more than 8 kbar) and for carbonate-silicate rocks (temperatures 680-820 °C, pressures 8-15 kbar). Silicate marbles have a primary sedimentary nature, as evidenced by their rare-element composition and the presence of fragments of host terrigenous rocks. There is no doubt about the primary sedimentary nature of carbonate-silicate rocks, which are very similar in REE distribution spectra and in rare-element composition to silicate marbles. A number of features indicate that metacarbonate rocks have undergone metasomatic alteration. Thus, in silicate marbles, reaction rims are observed around orthopyroxene, forsterite, potassium feldspar, as well as quartz veins bordered by accumulations of phlogopite, feldspars, and diopside. In carbonate-silicate rocks, the development of secondary marialite on potassium feldspar has been established; the rare-element composition of garnet may indicate its metasomatic origin.
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Date submitted2023-12-07
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Date accepted2024-11-07
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Date published2025-04-07
Determination of the tangential component of cutting resistance during frozen sedimentary rock cutting using blocked, deeply blocked and cell cutting methods
Due to the insufficient accuracy of existing studies of frozen sedimentary rock cutting process for practical calculations, the article solves the problem of determining the tangential component cutting resistance for blocked, deep blocked and cell cutting, which are currently the most commonly used methods in earthmoving equipment. The cutting tool and rock mass force interaction is considered from the point of view of the emerging stresses, which act on the separated chip element. The analytical dependences for determining the tangential component of cutting resistance were obtained. The numerical explanation of the choice of cell cutting in relation to blocked and deeply blocked cutting is given. For all three methods of cutting, under equal geometrical parameters of the cutting tool and the physical and mechanical properties of the frozen rock, the numerical value of the tangential component of cutting resistance is obtained. The comparison of the cutting resistance estimated values has shown that cell cutting requires relatively less energy and is preferred during the process of frozen sedimentary rock excavation. During field and laboratory investigations with the use of a multi-purpose cutting stand, a sufficient convergence of the analytical statements with the physics of frozen sedimentary rock cutting process was established. The results of the research allow a more reasonable approach to the adjustment of existing methods for determining the required tractive force and power for the drive of an excavation machine, and, therefore, to the actual efficiency and profitability of work.
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Date submitted2024-05-17
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Date accepted2025-03-27
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Date published2025-03-27
Determination of impact hazard potential of rocks in the Norilsk Industrial Region
The deeper the mineral deposits developments are, the worse the mining and geological conditions become. Significant growth of stress level in the rock mass contributes to possible manifestation of rock pressure in dynamic form. The resulting task of assessment of rock impact hazard is closely related to the task of obtaining more accurate results of compression tests of samples in rigid or servohydraulic test presses using graphs of their full deformation. This approach requires special expensive equipment, considerable time resources, and sufficient core material. Therefore, it is important to have an approach that allows to assess the propensity of rocks to brittle fracture with research methods simple enough not to result in the loss of quality and reliability of the obtained results. This paper presents the results of laboratory tests of rocks from the Norilsk Industrial Region to determine their tensile and compressive strengths. Test methods involved both domestic and foreign standards for determining the value of the brittleness coefficient. The impact hazard potential of rocks was determined using the Kaiser criterion. It is found that the tested lithological types (rich sulfide ores, hornblende, disseminated ores, and gabbro-dolerite rocks), with the exception of anhydrite, have a low impact hazard potential.
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Date submitted2024-05-11
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Date accepted2025-01-28
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Date published2025-03-21
Research and development of technology for the construction of snow airfields for accommodating wheeled aircraft in Antarctica
- Authors:
- Sergey P. Polyakov
- Sergey V. Popov
Construction of a new wintering complex at the Antarctic Vostok Station required prompt delivery of builders and mechanics to Progress Station to move them further to the work area. To solve this major logistical issue, a new landing site, later named Zenit, certified for accommodating heavy wheeled aircraft, was prepared in the Progress Station area from March to August 2022. Its snow pavement slab with a total area of 350 thousand m2 is from 100 to 120 cm high. It was made by applying snow layers with their subsequent compaction by a specially designed compaction platform for snow airfields suitable for heavy wheeled aircraft. As a result, the pavement has a surface hardness of at least 1 MPa. The layer from 30 to 60 cm has a hardness of at least 0.8 MPa, and the bottom layer at least 0.6 MPa. The first Il-76TD-90VD aircraft of the Russian company Volga-Dnepr was accommodated to the new runway on 7 November 2022. The aircraft landed in normal mode. The depth of the chassis wheels track after landing did not exceed 3 cm. The research provided in-depth understanding of the mechanisms for forming the supporting base of the runway from snow and ice in Antarctica. The experience gained can be used to solve similar issues in the Far North.
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Date submitted2024-03-20
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Date accepted2024-11-07
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Date published2025-02-27
Analysis of the stress state of rocks transformation near a horizontal well during acid treatment based on numerical simulation
The article presents an overview of the assessment and modelling of the stress state of rocks in the near-wellbore zone of horizontal wells during acid stimulation of the formation for improving the efficiency of oil and gas field development. A numerical finite element model of near-wellbore zone of the reservoir drilled by a horizontal section was compiled using one of oil fields in the Perm Territory as an example. The distribution of physical and mechanical properties of the terrigenous reservoir near the well was determined considering transformation under the action of mud acid for different time periods of its injection. Multivariate numerical simulation was performed and the distribution of horizontal and vertical stresses in near-wellbore zone was determined with regard for different values of pressure drawdown and changes in stress-strain properties depending on the area of mud acid infiltration. It was found that a change in elastic modulus and Poisson's ratio under the influence of acid led to a decrease in stresses in near-wellbore zone. Analysis of the stress distribution field based on the Coulomb – Mohr criterion showed that the minimum safety factor of rock even after the effect of mud acid was 1.5; thus, under the considered conditions of horizontal well modelling, the reservoir rock remained stable, and no zones of rock destruction appeared.
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Date submitted2023-06-25
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Date accepted2024-11-07
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Date published2025-02-25
Study of wormhole channel formation resulting from hydrochloric acid treatment in complex-type reservoirs using filtration and X-ray computed tomography methods
- Authors:
- Andrei A. Аbrosimov
The primary function of hydrochloric acid treatment (HAT) is to create the maximum number of high-conductivity channels in the near-wellbore zone of the reservoir to restore its permeability and enhance hydraulic connectivity between the undisturbed part of the formation and the well. The objective of this study is to physically model HAT on core samples from the Orenburg oil and gas condensate field and to research the impact of such treatment on the structure of the pore space of rocks related to complex-type reservoirs. The complexity of the rock's pore space and the low permeability of the formations are distinguishing features of the study object. For this reason, HAT is a widely applied method for production intensification, necessitating the verification of acid injection rates, where the success criterion is the formation of high-conductivity filtration channels (wormholes) in the near-wellbore zone. These channels significantly expand the drainage area of wells, thereby bringing additional reservoir sections into development. The study examined the characteristics of filtration channel development resulting from acid treatment. Their structure was characterized and analyzed using X-ray computed tomography. The complex study confirmed the accuracy of the selected injection rate and provided practical recommendations for enhancing the efficiency of HAT.
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Date submitted2023-12-15
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Date accepted2024-06-13
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Date published2025-02-25
Development of equipment and improvement of technology for inertial thickening of backfill hydraulic mixtures at the final stages of transportation
The results of the study of the functioning of the developed thickening equipment as part of the stowing complex for the formation of a flow of high-concentration hydromixture are presented. To explain the operation of the hydrotransport system of the stowing complex, equipped with a thickener of the developed design, its basic diagram is presented. A mathematical model has been created that describes the mechanism of inertial sedimentation of a solid component of a hydraulic mixture in a working chamber equipped with hydrodynamic profiles. Interaction with the profile leads to flow stratification due to a change in the trajectory of movement and a decrease in speed. The interval of rational velocity of primary pulp entering the input of the working chamber of the inertial thickener is substantiated. The synthesis of solutions of the thickening process model is performed in the COMSOL Multiphysics and Ansys Fluent programs. This made it possible to eliminate physical contradictions in the operation of the equipment and justify the overall dimensions of its main elements, ensuring the implementation of the mechanism of inertial sedimentation of the slurry. It was found that the concentration of the thickened flow at the outlet branch pipe of the thickener working chamber is determined by the level of the primary hydraulic fluid velocity, the characteristic length of the section of interaction with the deflecting profile, and the ratio of the flow and attack angles. A nomogram of the dynamics of the change in the hydraulic fluid concentration in the section of the outlet branch pipe depending on the ratios of the overall dimensions of the deflecting profile of the working chamber was compiled. The results of the study allowed formulating recommendations for selecting the dimensions of the thickener's deflecting hydrodynamic profile to form a flow of hydraulic mixture with a concentration of about 50 % by weight. The developed equipment can be used in a stowage complex and will increase the range of supply of the stowage mixture. This is due to the fact that a flow of primary slurry with a low concentration, due to lower pressure losses, can be moved in a pipeline system over a greater distance than a flow with a high filler content. The use of a thickener at the final stage of transportation is intended to increase the concentration of the hydraulic mixture immediately before production.
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Date submitted2024-03-29
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Date accepted2024-11-07
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Date published2025-02-26
Well killing with absorption control
The development of new fields with low-permeability reservoirs required the introduction of new production technologies, of which the most significant for well killing and underground repair were multi-ton hydraulic fracturing, the simultaneous operation of two or three development sites by one well grid, and an increase in the rate of fluid extraction. These global decisions in field development have led to the need to search for new effective materials and technologies for well killing. The article is devoted to the analysis of problems associated with the process of killing production wells in fields characterized by increased fracturing, both natural and artificial (due to hydraulic fracturing), with reduced reservoir pressure and a high gas factor. The relevance of the analysis is due to the increase in the number of development sites where complications arise when wells are killed. Particular attention is paid to technical solutions aimed at preserving the filtration and capacity properties of the bottomhole formation zone, preventing the absorption of process fluid, and blocking the manifestation of gas. The classification of block-packs used in killing is given, based on the nature of the process fluid. Suspension thickened water-salt solutions are considered, forming a waterproof crust on the surface of the rock, which prevents the penetration of water and aqueous solutions into the formation. This approach ensures the safety and efficiency of killing operations, especially when working with formations in which maintaining water saturation and preventing the ingress of the water phase are of critical importance. Modern trends in the development of technology are revealed, and promising areas for further improvement of well killing with absorption control are outlined.
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Date submitted2023-10-31
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Date accepted2024-11-07
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Date published2025-01-24
Specifics of magnetotelluric studies in Antarctica
One of the priority areas of scientific research in Antarctica is the study of its deep structure. Most of the continent is covered with a thick ice sheet, so the main geoscientific data are acquired using geophysical methods, among which magnetotelluric (MT) ones have the greatest penetration depth and insignificant environmental impact. The possibility of acquiring high-quality MT data in the conditions of the sixth continent has long been questioned. The work is aimed at studying the specifics of magnetotelluric survey in Antarctica. The following tasks were set: to summarize the world experience of studying Antarctica using MT sounding methods; to identify factors that negatively affect the high-quality data acquisition; to determine methods for minimizing the influence of these factors. The article analyses geophysical studies conducted by the magnetotelluric sounding method in the Antarctic region from 1964 to the present. The application of the method is complicated by the following: extremely low temperature affects the drop in the batteries capacity, freezing of the non-polarizing electrodes solution, and changes in the strength properties of materials. Electromagnetic noise occurs during strong winds; proximity to the magnetotelluric field source can violate the plane wave principle on which the method is based. The ice sheet covering most of Antarctica does not allow acquiring optimal values of the contact resistance of the electrode grounding; the extended coastline distorts the acquired data. Studies of the influence of factors complicating the MT sounding method in the coastal and central parts of Antarctica made it possible to formulate recommendations for preparing equipment and adapting the work procedure, modifying the processing flow and a set of measures to ensure safety, the implementation of which will both allow safe performance of geophysical investigations and high-quality data acquisition.
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Date submitted2023-08-31
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Date accepted2023-12-27
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Date published2024-11-12
Geochemical studies of rocks of the Siberian igneous province and their role in the formation theory of unique platinum-copper-nickel deposits
- Authors:
- Nadezhda А. Krivolutskaya
The Norilsk deposits, unique both in their geological structure and reserves of nickel and platinum, have attracted the attention of researchers for several decades. Several hypotheses have been proposed to explain their formation. Two of them are the most widely accepted: the model of ore formation in an intermediate chamber from picritic melt enriched in sulphides and the formation of sulphides in situ through the assimilation of sulphate-bearing sediments by tholeiitic magma as it rises to the surface. The main questions regarding the genesis of these deposits are: the composition of the parental magmas that formed the ore-bearing massifs; the relationship between intrusions and effusive rocks; and the extent and role of assimilation of host rocks by magmas. These issues are discussed in the article using a large amount of analytical data obtained by the author during the study of the magmatic rocks and geological structures in the Norilsk area. Based on these data, it was concluded that none of the proposed models could fully explain all observed geological features of the deposits as well as the appearance of the unique sulphide ores. In order to solve the problem of the genesis of the Norilsk deposits, it is necessary to analyse the evolution of P3-T1 magmatism over time in the Siberian large igneous province, especially in its eastern part, and to determine its association with ore-forming processes; and its investigating it is a priority task for understanding sulphide ore formation. Solving this task should be based not only on geophysical data but also on studies of the geochemistry of igneous rocks within the province.
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Date submitted2024-04-16
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Date accepted2024-09-24
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Date published2024-11-12
Deep-buried Lower Paleozoic oil and gas systems in eastern Siberian Platform: geological and geophysical characteristics, estimation of hydrocarbon resources
The study of deep-buried oil and gas systems is a promising trend in the preparation of hydrocarbon resources. The study of the factors determining oil and gas potential is extremely important. The Lena-Vilyui sedimentary basin in the eastern Siberian Platform has a potential for the discovery of large oil and gas fields in deep-buried Cambrian deposits. The use of original methodological approaches to the analysis of black shale and overlying deposits, generalization of the results of lithological, biostratigraphic and geochemical studies of Cambrian deposits in territories adjoining the study area, modern interpretation of geophysical data showed that siliceous, carbonate, mixed rocks (kerogen-mixtite) of the Kuonamka complex and clastic clinoform-built Mayan deposits are most interesting in terms of oil and gas potential. Oil and gas producing rocks of the Lower and Middle Cambrian Kuonamka complex subsided to the depths of 14 km. The interpretation of modern seismic surveying data confirms the hypothesis of a limited occurrence of the Upper Devonian Vilyui rift system. Based on generalization of geological, geophysical and geochemical archival and new materials on the Lower Paleozoic deposits of the eastern Siberian Platform, a probabilistic estimation of geological hydrocarbon resources of the Cambrian and younger Paleozoic complexes in the Lena-Vilyui sedimentary basin was performed. Based on basin modelling results it was concluded that the resources were mainly represented by gas. It is presumed that oil resources can be discovered in traps of the barrier reef system as well as on the Anabar and Aldan slopes of the Vilyui Hemisyneclise. With a confidence probability of 0.9, it can be stated that total initial resources of oil and gas (within the boundaries of the Vilyui Hemisyneclise) exceed 5 billion t of conventional hydrocarbons. The recommended extremely cautious estimate of resources of the pre-Permian complexes is 2.2 billion t of conventional hydrocarbons. In the study area, it is necessary to implement a program of deep and super-deep parametric drilling without which it is impossible to determine the oil and gas potential of the Lower Paleozoic.
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Date submitted2024-04-22
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Date accepted2024-09-24
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Date published2024-11-12
On peculiarities of composition and properties of ancient hydrocarbon source rocks
Precambrian rocks are widespread within all continents of the Earth; that said, sedimentary associations of these deposits are of special interest in search for oil and gas fields. A wide range of paleontological, lithological and geochemical methods is utilized for conducting integrated geological-geochemical analysis and evaluating the initial hydrocarbon generating potential of organic matter of Precambrian source rocks. Investigated were peculiarities of depositional environments of the organic matter, specific features of its composition in sedimentary rocks and its generation characteristics. Own research efforts were performed in combination with generalization of other authors’ publications focused on Precambrian sequences enriched in organic matter – their occurrence, isotopic and biomarker characteristics and realization schemes of the hydrocarbon generation potential of Precambrian organic matter in the process of catagenesis. Geochemical peculiarities of initial organic matter are illustrated on various examples, type of the organic matter is determined together with the character of evolution of realization of its initial generation potential.
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Date submitted2024-09-09
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Date accepted2024-11-05
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Date published2024-11-12
Acoustic emission criteria for analyzing the process of rock destruction and evaluating the formation of fractured reservoirs at great depths
In order to study the mechanism of destruction of rocks of various genesis and the formation of fractured reservoirs at great depths, laboratory studies of rock samples in the loading conditions of comprehensive pressure with registration of acoustic emission (AE) and parameters of the process of changing the strength and deformation properties of samples were carried out. The spatial distributions of the hypocenters of AE events for each sample were investigated. By the nature of the distributions, the fracture geometry is described, then visually compared with the position of the formed macrofractures in the samples as a result of the tests. The time trends of the amplitude distribution b, set by the Guttenberg – Richter law, were calculated, which were compared with the loading curves and trends of the calculated AE activity. Based on the analysis of the AE process for three types of rocks – igneous (urtites), metamorphic (apatite-nepheline ores), and sedimentary (limestones) – parameterization of acoustic emission was carried out to determine the features of the deformation process and related dilatancy. As a result, three types of destruction of samples were identified, their geometry and changes in strength and seismic criteria were established.
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Date submitted2023-09-29
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Date accepted2023-10-25
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Date published2024-08-26
Laboratory studies of transformation of porosity and permeability and chemical composition of terrigenous reservoir rocks at exposure to hydrogen (using the example of the Bobrikovskii formations in the oil field in the northeast Volga-Ural oil and gas province)
The article describes the methodology for laboratory studies of reservoir rock exposure to hydrogen. The stages of sample research and the instruments used in the experiments are considered. A comparative analysis of the results of studies on porosity and permeability of core samples was performed. It was shown that after exposure to hydrogen, the porosity decreased by 4.6 %, and the permeability by 7.9 %. The analysis of correlation dependencies demonstrated a typical change in the relationship of these characteristics: after the samples exposure to hydrogen the scatter of the values increased and the correlation coefficient decreased, which indicates a change in the structure of the void space. Based on the research results, it was concluded that the decrease in porosity and permeability of the core samples occurred due to their minor compaction under the action of effective stresses. The chemical analysis of the rock showed no major difference in the composition of the basic oxides before and after exposure to hydrogen, which points to the chemical resistance of the studied formation to hydrogen. The experimental results showed that the horizon under consideration can be a storage of the hydrogen-methane mixture.
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Date submitted2022-11-21
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Date accepted2024-05-02
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Date published2024-08-26
M1 formation tectono-structural features and gas-oil potential within Archinskaya area Paleozoic basement (Western Siberia)
- Authors:
- Vladimir B. Belozerov
- Mikhail O. Korovin
Western Siberian Plate basement oil and gas potential evaluation largely depends on structural and stratigraphic complex architecture representation. New modern procedures for seismic data processing, detailed Paleozoic deposits stratigraphic studies and expanded geophysical well logging significantly change the representation of the basement rocks fold-block structure and previously developed hydrocarbon reservoirs models. Detailed studies conducted within the Archinskii uplift showed that Paleozoic sediments form a contrasting folded structure complicated by block tectonics. The significant block displacements amplitude determines the lithological and stratigraphic basement rocks erosional-tectonic surface, while the identified stratigraphic blocks control the oil productivity distribution within the Archinskaya area. The filtration-capacity heterogeneity folded structure of the Paleozoic sediments is reflected in the distribution of hydrocarbon saturation in the well section, forming independent gas, oil, and oil-water zones for the development process. The relationship between anticlinal structural forms of basement rocks to lowered, and synclinal to elevated blocks, determines the necessity to conduct exploration prospecting within younger stratigraphic blocks when assessing the deep Paleozoic oil and gas potential.
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Date submitted2024-03-07
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Date accepted2024-06-14
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Date published2024-07-04
Anomaly detection in wastewater treatment process for cyber resilience risks evaluation
Timely detection and prevention of violations in the technological process of wastewater treatment caused by threats of different nature is a highly relevant research problem. Modern systems are equipped with a large number of technological sensors. Data from these sensors can be used to detect anomalies in the technological process. Their timely detection, prediction and processing ensures the continuity and fault tolerance of the technological process. The aim of the research is to improve the accuracy of detection of such anomalies. We propose a methodology for the identification and subsequent assessment of cyber resilience risks of the wastewater treatment process, which includes the distinctive procedure of training dataset generation and the anomaly detection based on deep learning methods. The availability of training datasets is a necessary condition for the efficient application of the proposed technology. A distinctive feature of the anomaly detection approach is a new method of processing input sensor data, which allows the use of computationally efficient analytical models with high accuracy of anomaly detection, and outperforms the efficiency of previously published methods.
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Date submitted2023-05-19
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Date accepted2024-03-05
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Date published2024-08-26
Development and research of backfill compounds with improved elastic and strength properties for oil and gas well lining
This article describes operations from the well construction cycle where the cement rock behind the casing is subjected to dynamic action (impacts of the drill stem during drilling and normalization of the cement sleeve, secondary drilling operations, hydraulic fracturing, etc.). The developed cement mortar compositions were tested following API 10B-2, API 10B-6, API STD-65-2, and GOST 28985-91 standards. The composition of the cement system without the use of imported components (CM-5) was developed, which improved elastic and strength properties compared to existing industry solutions. An improvement in the elastic and strength features and technological properties of cement rock when using epoxy resins was identified, the optimal composition of the cement-and-epoxy grout was determined, and the internal structure of the formed backfill rock, its permeability, and porosity were studied.
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Date submitted2022-05-20
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Date accepted2023-06-20
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Date published2024-02-29
Increasing the quality of zeolite-bearing rocks from Eastern Transbaikalia by applying directed energy
This paper presents the use of accelerated electrons to treat zeolite-bearing rocks from Eastern Transbaikalia to increase the efficiency of separating zeolites from rock-forming minerals via electromagnetic separation. The effectiveness of the liberation of zeolite minerals using accelerated electrons was analyzed. The results of dry electromagnetic separation of zeolite-bearing rocks are presented. The dependence of the extraction of iron-bearing minerals from zeolite-bearing rocks by electromagnetic separation on the magnetic field intensity for different particle sizes has been established. The main methods of zeolite-bearing rock enrichment and ore preparation were determined. A technological scheme for processing zeolite-bearing rocks, based on the use of accelerated electron treatment at the ore preparation stage, is presented, significantly improving the zeolite production quality.
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Date submitted2021-10-27
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Date accepted2023-06-20
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Date published2023-12-25
Geomechanical analysis of the impact of the new tunnels construction in the vicinity of existing underground subway structures on the state of the soil massif
The specificity of the behavior of the soil massif near the tunnel under construction in difficult mining conditions is considered. It was revealed through the joint interpretation of the results of geophysical measurements in the tunnel and computer simulation. The results of field geophysical studies to identify areas of decompacted soil behind the lining in two existing tunnels during successive drilling of two new tunnels under them are described. A method to analyze the response of the lining to impact was used providing for the calculation of its energy. It has been established that the decompaction zones are mainly located in the lateral lower areas of the tunnel. To substantiate the mechanism of formation of cavities, computer simulations were carried out using the finite element method with the COMSOL Multiphysics software. The finite element model is built on the Drucker – Prager criterion in the variant of a two-dimensional problem statement. It is shown that at the initial position of two old tunnels, the areas of decompaction can develop mainly on the sides. The position of the zones changes significantly when excavating two new tunnels. Soil decompaction zones appear between the tunnels and there is a tendency for the areas to spread to the upper point of the tunnel. According to geophysical data time delays in the impact of new tunnels on the existing line are noted, as well as a decrease in the size of decompacted soil areas over time. There is a satisfactory agreement between the positions of the decompaction areas and voids obtained by the geophysical method and the results of numerical simulation.
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Date submitted2023-02-07
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Date accepted2023-06-20
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Date published2024-02-29
Origin of carbonate-silicate rocks of the Porya Guba (the Lapland-Kolvitsa Granulite Belt) revealed by stable isotope analysis (δ18O, δ13C)
- Authors:
- Dmitrii P. Krylov
- Ekaterina V. Klimova
Carbonate-silicate rocks of unclear origin have been observed in granulites of the Porya Guba of the Lapland-Kolvitsa Belt within the Fennoscandinavian Shield. The present work aims to reconstruct possible protoliths and conditions of metamorphic transformation of these rocks based on oxygen and carbon isotopic ratios combined with phase equilibria modeling. Isotope analysis and lithochemical reconstructions suggest that carbonate-silicate rocks of the Porya Guba represent metamorphosed sediments (possibly marls) with the isotopic composition corresponding to the Precambrian diagenetically transformed carbonates (δ18O ≈ 17.9 ‰, SMOW and δ13C ≈ –3.4 ‰, PDB). The chemical composition varies depending on the balance among the carbonate, clay, and clastic components. Significant changes of the isotopic composition during metamorphism are caused by decomposition reactions of primary carbonates (dolomite, siderite, and ankerite) producing CO2 followed by degassing. These reactions are accompanied by δ18O and δ13C decrease of calcite in isotopic equilibrium with CO2 down to 15 ‰ (SMOW) and –6 ‰ (PDB), respectively. The isotopic composition is buffered by local reactions within individual rock varieties, thus excluding any pronounced influence of magmatic and/or metasomatic processes.
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Date submitted2022-12-01
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Date accepted2023-01-19
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Date published2023-12-25
Inclusions of diamond crystals in the tourmaline of the schorl-uvite series: problems of genesis
The mineralogical and geochemical features of diamond-bearing tourmaline crystals (schorl-uvite series) from garnet-clinopyroxene rocks of the Kumdy-Kol deposit (Northern Kazakhstan) have been studied in detail. The formation of the main rock-forming minerals (garnet + K-bearing clinopyroxene) occurred in the diamond stability field at 4-6 GPa and 950-1000 °C. Crystallization of K-bearing clinopyroxene at these parameters is possible in the presence of an ultra-potassic fluid or melt formed because of crustal material melting in subduction zones. Tourmaline crystals (up to 1 cm) containing diamond inclusions perform veins crosscutting high-pressure associations. The composition of individual zones varies from schorl to uvite within both a single grain and the sample as a whole. The potassium content in this tourmaline does not exceed 0.1 wt.% K2O, and the isotopic composition of boron δ11B varies from –10 to –15.5 ‰, which significantly differs from the previously established isotopic composition of boron in maruyamaite crystals (δ11B 7.7 ‰ in the core and –1.2 ‰ in the rim) of the same deposit. Analysis of the obtained data on δ11B in the tourmalines from the diamond-grade metamorphic rocks within the Kumdy-Kol deposit suggests the existence of two boron sources that resulted in crystallization of K-bearing tourmaline crystals (maruyamaite-dravite series) and potassium-free tourmalines of the schorl-uvite series.
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Date submitted2021-12-15
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Date accepted2022-09-12
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Date published2023-08-28
Substantiation and selection of the design parameters of the hydroficated equipment complex for obtaining backfill mixtures from current enrichment tailings
The issue of the influence of the concentration of the solid phase on the reduction of energy costs and specific energy consumption during pulp transportation is considered. The procedure for preparing slurry from the current enrichment tailings is shown. A scheme is given and the operation of a hydroficated unit for thickening and hydraulic transport of backfill mixtures is described. A diagram of the movement of solid particles in one of the units of the complex – a lamellar thickener is shown. The summary table shows the main design parameters and characteristics of the lamellar thickener. A general view of the laboratory setup used for experimental studies with slurry at various concentrations is given. An example of calculating productivity, density and specific load is presented. The dependence of the shear stress on the velocity gradient was determined for various pulp concentrations. Experimental studies of the process of thickening the production of slurry from the current enrichment tailings have been carried out. It was found that the geometric dimensions of the thickener depend on the concentration of the solid phase in the transported mixture. It is concluded that the flow rate of the slurry and the head loss are functions of the rheological characteristics of the viscoplastic slurry and can be calculated from the derived calculated dependencies.
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Date submitted2021-09-01
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Date accepted2022-10-07
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Date published2022-12-29
Parameter determination of the method of directional unloading of the reservoir based on physical modelling on a true triaxial loading setup
The article presents a theoretical and experimental substantiation of the method of directional unloading of the reservoir in fields with low-permeability reservoirs. The relevance of the article is due to the reduction of hydrocarbon resources in modern conditions and the need to create new efficient environmentally friendly technologies to develop hydrocarbon deposits with hard-to-recover reserves, primarily with low-permeability reservoirs. The results of a theoretical study of the stress-strain state in the vicinity of a well, both cased and open, are presented. They are necessary to develop programs for laboratory testing of core specimens from the studied fields. A technique for physical modelling of deformation processes in the bottomhole zone with a decrease in pressure at the well bottom in a true triaxial loading unit is described in order to determine the parameters of the process impact on the formation reservoir, leading to an increase in well productivity. The method was applied to the conditions of the low-permeability reservoir at the Verkhneviluchanskoye oil and gas condensate field in the southwest of the Republic of Sakha (Yakutia). Expe-rimental studies were carried out on a unique scientific unit for true triaxial loading, created at the IPMech RAS, the Triaxial Independent Loading Test System. The directional unloading method was adapted for the studied field, the process parameters of successful application of the method were determined: the bottomhole design, the drawdown values necessary to increase the permeability of the bottomhole formation zone.
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Date submitted2022-03-25
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Date accepted2022-09-06
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Date published2022-12-29
Autoclave modeling of corrosion processes occurring in a gas pipeline during transportation of an unprepared multiphase medium containing CO2
The problem of selecting a method for ensuring the reliability of the unprepared fluid transport facilities of an unprepared fluid in the presence of carbon dioxide is considered. Carbon dioxide corrosion is one of the dangerous types of damage to field and main pipelines. It has been shown that dynamic autoclave tests should be carried out during staged laboratory tests in order to determine the intensity of carbon dioxide corrosion and to select the optimal method of protection. A hypothesis about the imperfection of the existing generally accepted approaches to dynamic corrosion testing has been put forward and confirmed. A test procedure based on the use of an autoclave with an overhead stirrer, developed using elements of mathematical modeling, is proposed. The flows created in the autoclave provide corrosive wear of the sample surface similar to the internal surfaces elements wear of the pipelines piping of gas condensate wells. The autoclave makes it possible to simulate the effect of the organic phase on the flow rate and the nature of corrosion damage to the metal surface, as well as the effect of the stirrer rotation speed and, accordingly, the shear stress of the cross section on the corrosion rate in the presence/absence of a corrosion inhibitor. The given results of staged tests make it possible to judge the high efficiency of the developed test procedure.
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Date submitted2022-08-20
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Date accepted2022-11-17
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Date published2022-12-29
Comparison of the approaches to assessing the compressibility of the pore space
- Authors:
- Vitaly S. Zhukov
- Yuri O. Kuzmin
Integral and differential approaches to determining the volumetric compression of rocks caused by changes in the stress state are considered. Changes in the volume of the pore space of rocks are analyzed with an increase in its all-round compression. Estimation of changes in the compressibility coefficients of reservoirs due to the development of fields is an urgent problem, since the spread in the values of compressibility factors reduces the adequacy of estimates of changes in the physical properties and subsidence of the earth's surface of developed fields and underground gas storages. This parameter is key in assessing the geodynamic consequences of the long-term development of hydrocarbon deposits and the operation of underground gas storage facilities. Approaches to the assessment differ in the use of cumulative (integral) or local (differential) changes in porosity with a change in effective pressure. It is shown that the coefficient of volumetric compressibility of pores calculated by the integral approach significantly exceeds its value calculated by the differential approach, which is due to the accumulative nature of pore compression with an increase in effective pressure. It is shown that the differential approach more accurately determines the value of the pore compressibility coefficient, since it takes into account in more detail the features of the change in effective pressure.