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Date submitted2024-04-16
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Date accepted2024-06-03
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Date published2024-07-04
Quantitative determination of sulfur forms in bottom sediments for rapid assessment of the industrial facilities impact on aquatic ecosystems
- Authors:
- Ivan P. Sverchkov
- Vladimir G. Povarov
The article describes an X-ray fluorescence method for quantitative analysis of sulfate and total sulfur in bottom sediments of watercourses and reservoirs located in the area of industrial enterprises impact. The quantitative determination of sulfur forms was carried out by analyzing the characteristic curves SKα1,2 and SKβ1,3, as well as the satellite line SKβ′ on X-ray emission spectra measured by an X-ray fluorescence spectrometer with wavelength dispersion. The study shows that these characteristic curves allow not only to determine the predominant form of sulfur, but also to separately conduct quantitative analyses of sulfates and total sulfur after fitting peaks and to separately analyze overlapping spectral lines. The results of quantitative analysis of the chemical state of sulfur by the proposed X-ray fluorescence method were compared with the results of inductively coupled plasma atomic emission spectroscopy and elemental analysis, as well as certified standard samples of soils and sediments. The results are in good agreement with each other.
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Date submitted2024-03-30
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Date accepted2024-06-13
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Date published2024-07-04
Organotin pollutants in emerging coastal-marine sediments of the Kaliningrad shelf, Baltic Sea
Based on two years of monitoring of modern bottom sediments of two sections of the Kaliningrad shelf of the Baltic Sea – “Curonian Spit” and “Northern Sambian” – an assessment of the sources of pollution with organotin compounds (OTs) and heavy metals was carried out. The content of individual organotin compounds and OTCs spectra obtained by gas chromatography with mass spectrometry of relatively coarse-grained bottom sediments indicate the presence of organotins in significant quantities – the total OTs content (ΣOTs) is from 0.6 to 8.3 ng/g. However, the content of tributyltin (TBT), the main component of anti-fouling systems for marine vessels and the most dangerous endocrine-disrupting compound among the hazardous substances for marine ecosystems, is at a low level (0-2.3 ng/g) in all studied samples and has not increased over the two-year observation period (biodegradation index 1.7-12.4). At the same time, the presence of abnormally high concentrations of mono-, triphenyl- and tricyclohexyltin in the sediments of the ”Northern Sambian” site (up to 30, 7 and 6.4 ng/g, respectively) indicates an additional source of pollution of coastal waters and shelf sediments (for example, plastic litter and agricultural runoff). The absence of significant shipping in the study areas ensures a consistently low level of pollution with tributyltin and its derivatives (less than 0.3 and 2.3 ng/g of TBT in 2017 and less than 0.1 and 1.3 ng/g in 2018 for the sites “Curonian Spit” and “Northern Sambian”, respectively), which indicates the activity of the processes of TBT transformation and self-cleaning of sandy sediments. However, the identified trends and their predictive accuracy require long-term observation and monitoring of the sediment environment using data on the deep-water part of the shelf, enriched in clay and humus components.
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Date submitted2024-04-09
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Date accepted2024-06-03
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Date published2024-07-04
Analysis of the geochemical barriers effectiveness as the basis for the use of nature-like water purification technologies
Nature-like technologies are being introduced into many human activities including mining wastewater treatment. This work is based on long-term studies of the Sibay copper-zinc-pyrite deposit development. It is dedicated to assessment of geochemical barriers effectiveness in Cu, Zn, Cd removal from water of the Karagayly River (receiving quarry and dump drainage water). The research is based on the elements’ content and forms in water and bottom sediments, pH values etc. Four types of hydrogeochemical environment (formed due to changes in the water use over the past 20 years) were distinguished using discriminant analysis. The mechanisms of barriers formation and destruction were described. Statistical modeling of the metals’ precipitation was performed by multivariate regression analysis. Cu is adsorbed by recently formed Fe hydroxides, and, to a lesser extent, precipitates with sulfates as water pH increases. Antagonism to Mn hydroxides has been demonstrated, due to different physicochemical conditions for their precipitation. Zn enters solid phase mainly with sulfates, this element also forms its own mineral phases. The second mechanism is adsorption by recently formed Mn hydroxides, which corresponds to the idea of similar conditions for the precipitation of metal hydroxides. Cd behavior reflects conditions intermediate between these of Cu and Zn. Contribution of both mechanisms (related to Fe hydroxides and aqueous sulfates) is equal. Antagonism to Mn is absent. According to the assessment results using of nature-like technologies in situ in watercourses, canals and other water drainage systems is promising. Developed statistical models can be used for needs of experimental studies and artificial geochemical barriers engineering.
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Date submitted2023-04-13
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Date accepted2023-10-25
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Date published2025-02-25
Assessment of the ecological state of aquatic ecosystems by studying lake bottom sediments
- Authors:
- Mariya A. Chukaeva
- Tatyana V. Sapelko
The article presents the results of coupled palynological and geochemical studies of five various genesis lakes, located along the route of the expedition “In the footsteps of Alexander von Humboldt in Siberia, Altai and Eastern Kazakhstan”, dedicated to the double anniversary: the 190th anniversary of the expedition across Russia of the famous scientist and his 250th birthday. A geochemical analysis of water and bottom sediments of Ik Lake (Siberia), Lakes Kolyvanskoe and Beloe (Altai), Lake Bezymyannoe (Kazakhstan) and Nagornyi Pond (Altai) was carried out. Based on their results an assessment of studied lakes ecological state was given through single and integral criteria. A high level of pollution was noted for Nagornyi Pond and Lake Bezymyannoe, which is caused by a significant technogenic load from nearby mines. This is consistent with the data of palynological research. The aquatic ecosystems of Lakes Kolyvanskoe and Beloe are characterized by a satisfactory ecological situation, but they experience an increased recreational load. The results of spore-pollen analysis and analysis of non-pollen palynomorphs showed the low ability of these lakes to self-healing. The most favorable ecological state and high self-cleaning capacity were noted for Lake Ik, which is consistent with the data of palynological studies. It is being confirmed with the results of palynological studies. It was therefore concluded about the ability to make a quick assessment of the aquatic ecosystems’ ecological state by studying lakes using coupled palynological and geochemical analysis.
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Date submitted2022-09-26
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Date accepted2023-03-23
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Date published2023-12-25
A new diamond find and primary diamond potential of the Chetlas uplift (Middle Timan)
In the previously poorly studied southeastern part of the Chetlas uplift in the Middle Timan, a new occurrence of diamond satellite minerals and a diamond grain were found in the modern channel sediments of the Uvuy River basin. In order to assess the prospects of the area under consideration for identification of diamondiferous objects of practical interest, a characteristic of chromium-bearing pyropes and chromospinelides as the main kimberlite of diamond satellite minerals are given and the diamond grain itself is described. The material for the research was 16 schlich samples, each with a volume of 8 to 15 l. The minerals were studied using optical and scanning electron microscopy, Raman spectroscopy, laser luminescence and X-ray diffraction (Debye – Sherrer method). It is shown that among the pyropes, most of which correspond in composition to minerals of the lherzolite paragenesis, there are varieties belonging to the dunite-harzburgite paragenesis, including those belonging to diamond phase stability regions. Among the studied chromospinelides, chrompicotites and aluminochromites similar in composition to those found in rocks such as lherzolites and harzburgites, as well as in kimberlites, were identified. A diamond grain found in one of the samples has the form of a flattened intergrowth with distinct octahedron faces, complicated by co-growth surfaces with other mineral grains that have not been preserved to date. The discovery of the diamond and the established signs the formation of aureoles of the diamond satellites minerals in the channel sediments of the studied area open up the prospects for discovering their primary sources here.
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Date submitted2022-08-10
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Date accepted2023-02-28
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Date published2024-02-29
Selection of the required number of circulating subs in a special assembly and investigation of their performance during drilling of radial branching channels by sectional positive displacement motors
The task of sludge removal to the surface during construction of directional and horizontal wells and strongly curved radial channels is relevant. For stable operation of technical system “Perfobore”, it is proposed to use a circulating sub that ensures efficient cleaning of channel wellbore from the drilled rock. Two schemes of technical system “Perfobore” are considered, consisting of two seven-meter coiled tubing, a positive displacement motor, a bit and one circulating sub in the first scheme and two subs in the second scheme. For each of the schemes CFD modeling was implemented to determine values of pressure and speed. It was found out that the use of two circulating subs in the assembly is more efficient. In order to confirm the numerical experiment, bench tests were carried out. It was determined that the designed circulating sub can eject up to 25 % of pumped drilling fluid. The bench tests of full-size technical system “Perfobore” for drilling 14-meter channels with two circulating subs showed that the axial load on positive displacement motor produced by hydraulic loader was 3000 N and pressure drop depending on flow rate was 1.5-2.0 MPa. This allows the motor to operate at maximum power.
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Date submitted2022-11-02
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Date accepted2023-03-02
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Date published2023-04-25
Environmental damage from the storage of sulfide ore tailings
The mining industry is one of the most challenging in ensuring environmental safety. During the last century, the Karabash Copper Smelting Plant was processing sulfide ores and depositing the tailings into storage facilities that now occupy an area of more than 50 hectares. To date, abandoned tailings are a significant source of natural water, air, and soil pollution in the Karabash city district. The article comprehensively examines the environmental impact of the Karabashmed copper smelter, one of the oldest metallurgical enterprises in Russia. The effects of seepage from the two Karabashmed tailings facilities on water resources were assessed. We revealed that even outside the area of the direct impact of processing waste, the pH of natural water decreases to values 4-5. Further downstream, the infiltration water from the tailings pond No. 4 reduces the pH of river water to 3.0-3.5. The presented results of environmental engineering surveys are derived from sampling water and bottom sediments of the Ryzhiy Stream and the Sak-Elga River, sample preparation, and quantitative chemical analysis. The study revealed significant exceedances of the maximum permissible concentrations for a number of chemical elements in the impact zone of the copper ore processing tailings.
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Date submitted2021-05-27
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Date accepted2022-09-06
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Date published2022-11-10
Application of resonance functions in estimating the parameters of interwell zones
It is shown that the use of force resonance leads to the effect of “shaking” the formation, followed by breaking up the film oil and involving it in the further filtration process. For the first time in oilfield geophysics, the concept of passive noise-metering method is justified for monitoring oil and gas deposit development by measuring the quality factor of the contours in the point areas of formation development channels in interwell zones. It is established that determining the depth of modulation for the reactive substitution parameter of the linear FDC chain is crucial not only for determining the parametric excitation in FDC attenuation systems, but also without attenuation in the metrological support for the analysis of petrophysical properties of rock samples from the wells. It is shown that based on the method of complex amplitudes (for formation pressure current, differential flow rates, impedance), different families of resonance curves can be plotted: displacement amplitudes (for differential flow rates on the piezocapacity of the studied formation section), velocities (amplitudes of formation pressure current) and accelerations (amplitudes of differential flow rates on the linear piezoinductivity of the FDC section). The use of predicted permeability and porosity properties of the reservoir with its continuous regulation leads to increased accuracy of isolation in each subsequent sub-cycle of new segment formation in the FDC trajectories, which contributes to a more complete development of productive hydrocarbon deposits and increases the reliability of prediction for development indicators.
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Date submitted2021-10-19
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Date accepted2021-11-30
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Date published2021-12-27
Potential technological solution for sampling the bottom sediments of the subglacial lake Vostok: relevance and formulation of investigation goals
The subglacial Lake Vostok in Antarctic is a unique natural phenomenon, its comprehensive study involves sampling of water and bottom surface rocks. For further study of the lake, it is necessary to drill a new access well and develop environmentally safe technologies for its exploration. This article discusses existing and potential technologies for sampling bottom surface rocks of subglacial lakes. All these technologies meet environmental safety requirements and are conducive for sampling. The authors have proposed an alternative technology, using a walking device, which, due to its mobility, enables selective sampling of rocks across a large area from a single access well. The principal issues, related to the implementation of the proposed technology, are investigated within this article. This report is prepared by a team of specialists with many years of experience in drilling at the Vostok Station in Antarctic and in experimental work on the design of equipment and non-standard means of mechanization for complicated mining, geological and climatic conditions.
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Date submitted2021-02-20
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Date accepted2021-10-18
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Date published2021-12-16
Thermal protection implementation of the contact overheadline based on bay controllers of electric transport traction substations in the mining industry
The article presents the principle of thermal protection of the contact overheadlineand substantiates the possibility of practical implementation of this principle for rail electric transport in the mining industry. The algorithm for the implementation of modern digital protection of the contact overhead line as one of the functions of the controller is described. A mathematical model of thermal protection is proposed, which follows from the solution of the heat balance equation. The model takes into account the coefficient of the electrical networktopology, as well as the coefficient of consumption of the current-carrying core of the cable, which determines the reduction in the conducting section from contact erosion and the growth of oxide films. Corrections for air flows are introduced when receiving data from an external anemometer, via telemechanics protocol. The mathematical model was tested by writing a real thermal protection program in the C programming language for the bay controller, based on the circuitry of which is the STM32F407IGT6 microcontroller for the microcontroller unit. Verification tests were carried out on a serial bay controller in 2020. The graphs for comparing the calculated and actual values of temperatures, with different flow rates of the current-carrying conductor of the DC cable, are given. To obtain data, telemechanics protocols IEC 60870-104 and Modbus TCP, PLC Segnetics SMH4 were used.
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Date submitted2021-03-16
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Date accepted2021-07-27
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Date published2021-10-21
Allocation of a deep-lying brine aquifer in the rocks of a chemogenic section based on the data of geophysical well logging and 2D seismic exploration
Advancement in the production of potassium fertilizers is an important strategic task of Russian agricultural industry. Given annually growing production rates, the reserves of discovered potassium-magnesium salt deposits are noticeably decreasing, which creates the need to ensure stable replenishment of the resource base through both the discovery of new deposits and the exploitation of deep-lying production horizons of the deposits that are already under development. In most cases, deposits of potassium-magnesium salts are developed by underground mining. The main problem for any salt deposit is water. Dry salt workings do not require any additional reinforcement and can easily withstand rock pressure, but with an inflow of water they begin to collapse intensively – hence, special attention is paid to mine waterproofing. Determination of spatial location, physical and mechanical properties of the aquifer and water-blocking stratum in the geological section represent an important stage in the exploration of a salt deposit. The results of these studies allow to validate an optimal system of deposit development that will minimize environmental and economic risks. On the territory of Russia, there is a deposit of potassium-magnesium salts with a unique geological structure – its production horizon lies at a considerable depth and is capped by a regional aquifer, which imposes significant limitations on the development process. To estimate parameters of the studied object, we analyzed the data from CDP seismic reflection survey and a suite of methods of radioactive and acoustic well logging, supplemented with high-frequency induction logging isoparametric sounding (VIKIZ) data. As a result of performed analysis, we identified location of the water-bearing stratum, estimated average thickness of the aquifers and possible water-blocking strata. Based on research results, we proposed methods for increasing operational reliability of the main shaft in the designed mine that will minimize the risks of water breakthrough into the mine shaft.
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Date submitted2018-11-03
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Date accepted2019-01-16
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Date published2019-04-23
Interpretation of the tracer investigation results considering convective mass transfer
- Authors:
- V. A. Korotenko
- S. I. Grachev
- A. B. Kryakvin
The paper discusses the results of interpreting well tracer studies. It is shown that from the law of mass conservation it follows that when filtering a volume of an indicator, part of the injected tracer flows into the matrix. With the flow of fluid containing the indicator from the low-filtration resistance channel (LFR) into the surrounding matrix, the linear dimensions of the flow area depend on the permeability and porosity properties of the high-permeability channel and the matrix. While another part of the tracer moves toward the production well, its mass is lost due to diffusion processes. From the solution of the diffusion equation, it follows that the initial concentration of the tracer decreases in the course of filtration along the LFR channel. To interpret the results of the tracer studies, different cases of the LFR channels' location in the volume of the productive formation are considered. The varied parameter w allows characterizing the presence of several peaks in the concentration of the indicator and calculation the filtration parameters of the LFR channels. Depending on the known technological indices, several methods for determining pore volumes in the LFR channels have been proposed. To reduce the water cut in producing wells and to apply the technology of changing or aligning the injectivity profiles, calculations of the pore channels' radii in the mass of highly permeable seams are presented. It is shown that the volume of the chemical reagent pumped into the injection well to isolate the LFR channel is affected by the linear dimensions of the drainage area for the aqueous solution of indicator. Examples of the calculation for the permeability and porosity parameters of the LFR, the volume of pore channels necessary to isolate water inflow, and the radii of pore filtration channels, which influence the selection of the size of chemical reagent molecules, are given.
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Date submitted2016-11-21
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Date accepted2017-01-23
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Date published2017-04-14
Prospects of obtaining samples of bottom sediments from subglacial lake Vostok
- Authors:
- N. I. Vasilev
- G. L. Leichenkov
- E. A. Zagrivnyi
The paper proves the timeliness of obtaining and examining bottom sediments from subglacial Lake Vostok. Predictive geological section of Lake Vostok and information value of bottom sediments have been examined. Severe requirements towards environmental security of lake examinations and sampling of bottom sediments rule out the use of conventional drilling technologies, as they would pollute the lake with injection liquid from the borehole. In order to carry out sampling of bottom sediments from the subglacial lake, it is proposed to use a dynamically balanced tool string, which enables rotary drilling without any external support on borehole walls to transmit counter torque. A theoretical analysis has been carried out to assess the operation of the tool string, which is a two-mass oscillatory electromechanical system of reciprocating and rotating motion (RRM) with two degrees of freedom.
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Date submitted2014-11-22
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Date accepted2015-01-01
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Date published2015-10-26
Theoretical and methodological bases of forming a program management system for integrated development of a region
- Authors:
- S. V. Fedoseev
- Sya Chzhan
This article deals with theoretical and methodological bases of forming a program manage-ment system for integrated development of a region. The idea of a program-based management system based on a system of socio-economic transformation is presented. The given bases include monitoring emerging trends in the program management for integrated development of a region of the Russian Federation on basic parameters and involve control of the management process. The concept of forming the mechanism of program management as an integrated system is suggested.
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Date submitted2009-10-02
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Date accepted2009-12-23
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Date published2010-09-22
The problems of efficient use of the tumenian reservoirs at final stage of low-pressure gas production and prospects in their solutions
- Authors:
- O. E. Bugriy
The reserves depletion estimation is presented for main (base) fields in the north part of the Tumenian area. The significance of long time production of base fields is shown. The main problems of efficient use are shown for reservoirs at final stage of low-pressure gas field. The methodology associated with solving the problem is formulated for low profitability in low-pressure gas output. The recommendations for State support of subsurface users are prepared for efficient low-pressure gas production and efficient use of reserves at all.
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Date submitted2009-09-17
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Date accepted2009-11-20
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Date published2010-06-25
Functional and stylistic, national and temporal features of modern scientific english text building
- Authors:
- S. A. Sveshnikova
The paper presents the analysis of the influence of functional and stylistic, national and cultural and time-of-creation factors on the organization of modern scientific texts in English.
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Date submitted2009-09-22
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Date accepted2009-11-23
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Date published2010-06-25
Scientific-technical progress and innovation development in sociological science history
- Authors:
- V. N. Zavrazhin
The paper is dedicated to the consideration of interrelation of scientific-technical progress and social progress as one of the most important subjects of sociological science. Some classical and modern macrosociological theories are in the centre of attention, that develop progressive approach in understanding the place and role of scientific-technical progress and innovation development in the life of society. The emphasis is made on the actualization of macrosociological analysis of the problems stated in the paper in the current global economic crisis context.
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Date submitted2008-11-19
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Date accepted2009-01-04
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Date published2009-12-11
Complex modernisation of manufacture on Open Society «Severstal»
- Authors:
- V. M. Vasiltsova
- O. A. Popova
- S. N. Vinogradov
The metallurgical complex is a part of the manufactures making a basis of industrial and defensive potential of Russia. For increase in volume and production improvement of quality are defined internal possibilities of manufacture on the basis of its modernisation. Attempt of actualisation of the term «modernisation» at the expense of the complex approach to its treatment and workings out of the mechanism of acceptance of corresponding organizational and administrative decisions is undertaken. The technique is specified and the estimation of a technical condition of the equipment is carried out, the technical and economic analysis of modernisation on Open Society «Severstal» is carried out. Ways of perfection of a control system by updating of industrial potential of the metallurgical enterprise taking into account the requirement of the complex approach are defined.