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Date submitted2023-11-02
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Date accepted2024-09-24
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Date published2025-02-12
Mercury contamination of sediments at Indonesia Ciujung watershed: contribution of artisanal small-scale gold mining
Artisanal small-scale gold mining is the largest artificial source of mercury pollution and has been a very common problem recently. This study examined the contribution of Hg release due to artisanal small-scale gold mining in contaminating the sediment of the watershed in Indonesia. Different from other methods, we measured Hg pollution using the stable isotopes of carbon and nitrogen. This report is the first time analytical reports in Indonesia since most papers focus primarily on only detecting heavy metals in river water and sediments, neglecting deep research on Hg pollution and resources. The findings of this study indicate that artisanal and small-scale gold mining activities, located in the upstream areas of the tributaries that act as point sources, are the primary source of mercury in the sediment of the Ciujung watershed. The isotopes δ13C and δ15N successfully trace the Hg-contaminated sediment in the Ciujung watershed derived from the Cisimeut and Ciberang Rivers based on soil organic matter. The biological effect showed the Hg concentration in most of the sampling sites exceeded the Effects-range medium and Probable effect limit values. The Risk quotient values of Hg indicated the Hg pollution had a possibility effect on the benthic organism. Several limitations have also been added in this study and needs for further investigation.
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Date submitted2024-05-03
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Date accepted2024-09-05
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Date published2024-11-12
Platinum group elements as geochemical indicators in the study of oil polygenesis
This study examines elements of the platinum group (PGE), primarily platinum and palladium, as geochemical indicators in the investigation of oil polygenesis. It has been found that, like other trace elements such as nickel, vanadium, and cobalt, platinum group elements and gold can occur in oil fields at both background levels and in elevated or even anomalously high concentrations. The objective of this research is to analyze PGE and trace elements as geochemical markers to identify the geological factors, including endogenous processes, responsible for these unusually high concentrations in oil. A comprehensive review of the literature on this subject was conducted, along with new data on the presence of precious metals in oils from Russia and globally. The study explores the geological mechanisms behind elevated PGE concentrations in oils, utilizing atomic absorption spectroscopy with atomization in the HGA-500 graphite furnace to measure PGE content. Previously, the tellurium co-deposition method (ISO 10478:1994) was used to isolate noble metals from associated elements. Possible geological origins of abnormally high concentrations of platinum metals in oils have been identified. These include endogenous factors such as the spatial proximity of oil fields to ultrabasic rock massifs, the effects of contact-metasomatic processes, and influences from mantle dynamics. Moreover, data concerning mantle elements can serve as indicators of the depth origins of certain hydrocarbon fluids, thus contributing to the study of oil polygenesis.
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Date submitted2024-04-12
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Date accepted2024-09-05
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Date published2024-11-12
Promising reagents for the extraction of strategic metals from difficult-to-enrich mineral raw materials
The need of the mining and processing industry for new types of directional reagents is due to the deterioration of the material composition of the processed ores. Low Au content (less than 0.5-1.0 g/t), finely dispersed Au inclusions (0.1-10.0 microns) in the ore, similar properties of the separated minerals have an extremely negative effect on flotation performance when using traditional reagents, which leads to significant losses of valuable metal with enrichment tailings. Expanding the range of domestic flotation reagents based on the latest achievements of fundamental research and their targeted application at mining and processing companies will compensate for the negative impact of the mineral composition of raw materials and ensure maximum extraction of strategic metals from difficult-to-enrich ores. The use of modern research methods (scanning electron and laser microscopy, UV spectrophotometry, XRF and chemical analysis) made it possible to visualize the adsorption layer of new reagents-collectors of a number of dithiocarbamates with different structures of a hydrocarbon radical and an organic modifier on the surface of gold-containing sulfides. The amount of adsorbed reagents on the surface of minerals has been experimentally determined. The specific features of the fixation of reagents on minerals of various compositions led to optimal correlations of their consumption in the flotation process. Scientifically based reagent regimes ensured an increase in the gold content in the concentrate and a decrease in the loss of gold with tailings by 5-6 % during flotation enrichment of the refractory ore of the Malinovskoe deposit.
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Date submitted2024-10-29
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Date accepted2024-10-29
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Date published2024-11-12
Study of thermodynamic processes of the Earth from the position of the genesis of hydrocarbons at great depths
In the context of significant depletion of traditional proven oil reserves in the Russian Federation and the inevitability of searching for new directions of study and expansion of the raw material base of hydrocarbon raw materials in hard-to-reach regions and on the Arctic shelf, a scientific search is underway for accumulations in complex geological conditions and in manifestations that differ significantly from traditional ones, which include the processes of oil and gas formation and preservation of oil and gas in low-permeability “shale” strata and in heterogeneous reservoirs at great and super-great depths. Within the oil and gas provinces of the world, drilling of a number of deep and super-deep wells has revealed deposits at great depths, established connections between hydrocarbon deposits and “traces” of hydrocarbon migration left in the core of deep wells, which has made it possible to significantly re-evaluate theoretical ideas on the issue of oil and gas formation conditions and the search for technologies aimed at solving applied problems. Modern geochemical, chromatographic, bituminological, coal petrographic and pyrolytic methods of studying oil and bitumoids extracted from the host rocks of deep well cores give a hope for identifying correlations in the oil-source system, revealing processes that determine the possibility of hydrocarbon formation and accumulation, and defining predictive criteria for oil and gas potential at great depths.
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Date submitted2023-07-05
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Date accepted2024-06-03
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Date published2024-12-25
Complete extraction of conditioned ores from complex-structured blocks due to partial admixture of substandard ores
- Authors:
- Bayan R. Rakishev
The paper presents mining-technological substantiation of complete extraction of conditioned ores from complex-structured blocks of benches by mixing a layer of substandard ores of certain sizes. The relevance of the work consists in the development of innovative methods of establishing the parameters of the substandard layer of ores to be added to the conditioned ores. The main problem is to ensure complete extraction of useful components into concentrate from shipped ore with acceptable deviations from the required ones. A new typification of complex-structured ore blocks of the bench has been carried out. Analytical dependences of mining and geological characteristics of complex-structured ore blocks were obtained. Theoretical dependences for determining the main indicators of mineral processing are derived. Analytical dependences for determination of the content of useful component in shipped ore α' – mixture of conditioned ore with the content of useful component α and admixed layer of substandard ore with the content of useful component α'' are offered. For the first time in mining science, a new approach of complete extraction of conditioned ores from complex-structured blocks of benches by grabbing a certain part of substandard ores during excavation, increasing the volume of extracted ore and expanding the extraction of useful components in the concentrate has been substantiated. The increment of useful components can reach 10-15 % of the total volume of extraction, which allows predicting a significant increase in the completeness of mineral extraction from the Earth's interior.
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Date submitted2023-03-01
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Date accepted2024-06-03
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Date published2025-02-25
Lamprophyres of the Peshchernoe gold deposit, their geological position, material composition, and metasomatic alterations (Northern Urals)
The article presents the first data on biotite-hornblende lamprophyres discovered at the Peshchernoe gold deposit. We consider the geological position of lamprophyre dikes in the deposit structure and the relationship of these rocks with tectonically weakened and mineralized zones. The data on the structural position of mineralized zones, faults, dike bodies, metasomatic halos, and host volcanogenic-sedimentary rocks confirm the tectonic nature of the Peshchernoe deposit alteration system. Lamprophyre dikes are pre-ore, as evidenced by the superimposed metasomatic mineral associations. We assume that dikes of andesitic rocks, lamprophyres, and subsequently hydrothermal fluids, including ore-bearing ones, were intruded along the fault zone of northeastern strike at different geological times. The description of mineralogical and chemical transformations of lamprophyres, which occurred as a result of alteration, is given. Two stages of metasomatism are distinguished: carbon dioxide (beresitization-listvenitization) and subsequent alkaline (sodic metasomatism). During carbon dioxide metasomatism, dark-coloured minerals are replaced by chlorite, albitization and sericitization of plagioclase occur, and ferruginous dolomite is formed under the influence of a significant supply of CO2. Alkaline (sodic) metasomatism is superimposed on the mineral metasomatic paragenesis of the first stage. We consider metasomatic zoning during sodic metasomatism, manifested in one of the spessartite dikes. Chlorite and relics of magmatic dark-coloured minerals are replaced by magnesite, the supply of Na leads to the appearance of newly formed albite, and the supply of S leads to the formation of pyrite, which concentrates iron from other minerals. As a result of the sodic metasomatism, iron content in carbonates decreases in the direction from the outer metasomatic zone to the inner one. We conclude that it was the alkaline-sulphide sodium solutions that performed the ore-bearing function, and beresitization and listvenitization prepared a favourable environment for ore deposition.
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Date submitted2023-07-07
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Date accepted2023-09-20
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Date published2024-02-29
Isotherm and kinetic adsorption of rice husk particles as a model adsorbent for solving issues in the sustainable gold mining environment from mercury leaching
One of the techniques used in extracting gold in small-scale gold mining is mercury amalgamation. However, the use of mercury presents significant health and environmental hazards, as well as suboptimal efficiency in gold extraction. This study explores the possibility of the use of rice husk as a prototype adsorbent for mercury removal from its leaching in mining environments. To support the analysis, the rice husk adsorbent was characterized by Fourier-transform infrared spectroscopy, scanning electron microscopy, electron dispersive X-ray spectroscopy, atomic absorption spectrophotometers and Brunauer − Emmett − Teller analysis. To investigate the removal of Hg from aqueous solutions, batch adsorption experiments were conducted, and the efficiency was optimized under various parameters such as contact time, rice husk dosage, and initial concentration of mercury. Kinetic and isotherm investigations were also carried out to gain a better understanding of the adsorption properties. The kinetic adsorption was analyzed using the pseudo-first-order and pseudo-second-order. Furthermore, the isotherm adsorption was analyzed using ten adsorption isotherm models (i.e., Langmuir, Freundlich, Temkin, Dubinin – Radushkevich, Flory – Huggins, Fowler – Guggenheim, Hill – de Boer, Jovanovic, Harkin – Jura, and Halsey). The amount of mercury absorption increased with increasing contact time, adsorbent mass, and initial concentration of mercury. The pseudo-second-order kinetic model is the best model that can be applied to describe the adsorption process. Analysis of the adsorption results obtained shows that the adsorption pattern is explained through the formation of a monolayer without any lateral interaction between the adsorbate and adsorbent. In addition, the formation of multilayers due to inhomogeneous pore distribution also occurs which causes a pore filling mechanism. We found that the isotherm phenomena are near the Jovanovic models with the maximum adsorption capacity) of rice husk found to be 107.299 mg/g. As a result, rice husk could be a promising option for wastewater treatment due to its fast and efficient removal capacity, as well as its affordability and eco-friendliness. The predicted thermodynamic studies using the Flory – Huggins isotherm model show that the adsorption process is endothermic, spontaneous, and physisorption. The impact shows that the utilization of rice husk can be used and fit for the current issues in the sustainable development goals (SDGs).
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Date submitted2021-04-15
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Date accepted2022-09-06
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Date published2023-10-27
Gold-rare metal and associated mineralization in the western part of Bolshevik Island, Severnaya Zemlya archipelago
The presented studies are aimed to determine the formation patterns of the gold-rare metal mineralization within one of the most inaccessible Arctic islands of the Russian Federation, Bolshevik Island of the Severnaya Zemlya archipela-go. The relevance of the work is determined by the high probability of discovering a significant in terms of metal reserves deposit, which is proved by many researchers on the example of known large deposits to be a typical feature of sites with gold-rare metal formation. Obviously, only the possibility of discovering and subsequent development of a deposit of a highly liquid type of mineral, gold, can ensure the profitability of mining production on Severnaya Zemlya. It is established that the main geological, mineralogical, and geochemical features of the gold-rare metal mineralization in the Kropotkinsko-Nikitinskaya metallogenic zone of Bolshevik Island correspond to that of similar ore sites in Russia and the world. The occurrences of other formation types revealed in this metallogenic zone suggest a certain zoning in their distribution: mineralization is located in the apical parts of granitoids and in the nearest halo of hornfelses. At a distance, with an exit from the hornfelsed zone, there are occurrences of a cassiterite-sulphide formation with elevated gold and silver content at the top of the ore column, together with an increased amount of polymetallic ores. Occurrences of gold-quartz and gold-sulphide-quartz formations are localized in fault zones, as a rule, farther from granitoids. The total vertical range of gold mineralization exceeds 300 m. The assignment of all types of mineralization in the Kropotkinsko-Nikitinskaya metallogenic zone of Bolshevik Island to a single hydrothermal process is emphasized by the similar isotope composition of lead galena from heterogeneous occurrences, which determines the age of all mineralization at 200-300 Ma.
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Date submitted2022-05-17
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Date accepted2023-04-03
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Date published2024-02-29
Improvement of concentrate quality in flotation of low-rank coal
- Authors:
- Sergei A. Kondratev
- Tatyana A. Khamzina
Percentage of high-rank coal with low content of ash, moisture, and sulfur in total coal production output is low. Most of the produced coal has a low quality (lignite, bituminous coal: long-flame and fiery). Under increasing requirements for ecological cleanness of coal, the efficient use of coal products is only possible after improvement of their processing properties. The authors discuss the enhancement of flotation efficiency of low-rank coal using the mechanism of physisorption of a collecting agent in particle – bubble attachment. It is explained why the yield of concentrate with low ash content increases as a result of combination of collectors having different physical properties. It is shown that the surface activity of a heteropolar agent relative to the gas – liquid interface and the adsorption density of the agent govern its collecting properties. Based on the recovery – surface activity relationship, the correlation is found between the collecting activity of a chemical compound and the structure of its molecules. The combination of the collectors with different surface activity enables adjusting collectability and selectivity of the blend. The physisorption mechanism of collectors can be a framework for developing recommendations on modification of concentrate yield and ash content, and on selection of optimized ratios of surface activities of miscible collectors relative to the gas – liquid interface.
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Date submitted2022-10-28
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Date accepted2023-03-02
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Date published2023-04-25
Assessment of the possibility of using iron-magnesium production waste for wastewater treatment from heavy metals (Cd2+, Zn2+, Co2+, Cu2+)
Relevant problems associated with treatment of industrial wastewater from heavy metal ions are considered. Due to industrial development, the amount of wastewater increases as well as the risks of heavy metals getting into surface and groundwater, accumulating in water bodies and becoming aggressive environmental pollutants, which affect the animal and human organisms. To assess the possibility of extracting metal ions (Cd 2+ , Zn 2+ , Co 2+ , Cu 2+ ) from industrial wastewater and their further treatment, studies were carried out on redistribution of heavy metals in the “wastewater – waste” system using iron-magnesium production waste. Samples of the investigated waste weighing 0.1; 0.2; 0.5; 1; 1.5; 2 g were taken for wastewater volume of 50 ml per each subsample. Contact time varied from 5 to 180 min, waste fraction was 1 mm. The interaction process showed that the waste efficiently removes metal ions (Cd 2+ , Zn 2+ , Co 2+ , Cu 2+ ) from industrial wastewater. The efficiency of removing a pollutant from the solution depends on the weight of the waste subsample, initial concentration of metal ions, and contact time.
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Date submitted2022-06-20
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Date accepted2022-09-06
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Date published2022-11-03
Adaptive approach formation using machine vision technology to determine the parameters of enrichment products deposition
In this paper, an adaptive approach has been developed for automatic initialization of the thickening curve using machine vision technology, which makes it possible to determine with high accuracy the material parameters necessary for the design of thickening and clarification apparatuses. Software has been developed that made it possible to search for the coordinates of the condensation critical point in automatic mode. Studies on two samples of materials (tailings of apatite-containing ores and gold-bearing concentrate) were carried out and made it possible to statistically prove the reproducibility of the results obtained using the parametric criteria of Fisher and Bartlett. It has been established that the deposition curves are approximated with high accuracy by the Weibull model, which, together with the piecewise linear approximation, makes it possible to formalize the method for determining the critical point coordinates. The empirical coefficients of the Weibull model for two samples are found, and the final liquefaction and settling rates of the studied materials are determined.
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Date submitted2022-02-22
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Date accepted2022-05-11
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Date published2022-11-03
Scientific substantiation and development of innovative processes for the extraction of zirconium and rare earth elements in the deep and comprehensive treatment of eudialyte concentrate
- Authors:
- Valentin A. Chanturiya
Based on a package of modern analysis methods, the influence of various acids and energy effects on the morphology, elemental composition, structural and chemical transformations of the mineral surface, and the efficiency of eudialyte concentrate leaching was studied. The mechanism and the optimal conditions and specific features of the destruction of eudialyte and rock minerals and the extraction of zirconium and REE under the influence of various acids, powerful nanosecond pulses, dielectric barrier discharge, electrochemical processing, mechanochemical activation and ultrasound were revealed. The mechanism of formation and the optimal conditions for the dispersion of silica gel, depending on the methods and parameters of energy effects, was theoretically and experimentally substantiated. A combined three-stage circuit of nitric acid leaching of eudialyte concentrate with ultrasonic treatment of the suspension, providing 97.1 % extraction of zirconium and 94.5 % REE, were scientifically substantiated and tested. The conditions for the selective deposition of zirconium and REE were theoretically and experimentally substantiated.
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Date submitted2022-04-06
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Date accepted2022-06-15
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Date published2022-07-26
Geological and structural position of the Svetlinsky gold deposit (Southern Urals)
The paper presents the geological and structural position of the large Svetlinsky gold deposit in the Kochkar anticline (Southern Urals), localized in the zone of the Late Paleozoic (D 3 ) deep thrust of the western dip. The study confirms and clarifies the notion of its multiphase and polychronism. The thrust caused bending moments in its wings, subsidence of the lying crust, emergence of a shallow marine basin with rapid accumulation of terrigenous carbonate sediments (C 1 v), and formation of numerous landslide structures. The heating of rocks in the anticline core was accompanied by granitization and dome formation. A small Svetlinsky dome formed in the immediate vicinity of the thrust, creating a thermobaric gradient field (С 2 ). The zone of dome dynamic influence also includes the adjoining thrust area, complicated by a series of sub-vertical thrusts of sub meridional strike and numerous steeply dipping subparallel cracks of the latitudinal strike, synchronously filled with vein quartz and accompanied by hydrothermal metasomatic rock transformations. The formation of the gold deposit occurred during the post-collisional relaxation stage (from P 1 to, probably, the Early Jurassic). The association of gold mineralization with the Svetlinsky dome is indicated by the presence of native gold in Neogene ravine placers in the dome area and marbles of the Svetlinsky deposit, in association with fluorite, F-phlogopite, Cr-muscovite, pink topaz, pure quartz, and native sulphur. The presence of native gold in Neogene ravine placers in the dome area and marbles of the Svetlinsky deposit, in association with fluorite, F-phlogopite, Cr-muscovite, pink topaz, pure quartz, and native sulphur, indicates the association of gold mineralization with the Svetlinsky dome.
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Date submitted2022-03-22
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Date accepted2022-06-15
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Date published2022-07-26
Gold in biogenic apatites of the Baltic-Ladoga phosphorite basin
- Authors:
- Sergey B. Felitsyn
- Nadezhda A. Alfimova
The distribution of gold in biogenic apatites from the Ordovician deposits in the northwest of the East European Platform shows that the maximum concentration of gold in apatites is found within the Ladoga-Baltic suture zone. Gold mineralization has a superimposed character, which is confirmed by the dependence of the gold content on the size of apatite particles and a number of isotope geochemical systematics in biogenic apatites. Gold is present in the form of high fineness particles to 20 µm in size on the surface of biogenic apatite fragments (phosphate brachiopod shells and conodont elements) and is easily extracted. In 10 % of samples of biogenic apatites, the total content of rare earth elements is more than 1 wt.%.
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Date submitted2021-06-08
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Date accepted2021-11-30
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Date published2021-12-27
Management of groundwater resources in transboundary territories (on the example of the Russian Federation and the Republic of Estonia)
Groundwater, as a source of water supply, the most important mineral and geopolitical resource, , is often the only source of high-quality drinking water that is protected from pollution under conditions of increasing deterioration of surface water quality. Transboundary groundwaters are the focus of hydrogeological researchers for a number of reasons, including the reduction and pollution of water resources as a result of economic activities. The increased controversy between states over transboundary water issues has necessitated the development of international legal documents on issues related to water conflict prevention and the sustainable use of fresh water. As part of the analysis of the problem of legal regulation of groundwater extraction from transboundary aquifers and complexes, it is proposed to consider this aspect on the example of Russia. The problems of regulation of rational use and protection of fresh water in the bilateral treaties of the Russian Federation were revealed; a methodology for the management of groundwater extraction in the territory of the transboundary aquifer was developed, the size, parameters, and factors influencing the formation of the transboundary zone have been determined (based on research and analysis of water intake activities in the border areas of the Russian Federation and the Republic of Estonia) were determined.
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Date submitted2021-06-24
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Date accepted2021-11-30
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Date published2021-12-27
Development of a methodology to assess the hydrocyclone process with account of the rheological properties of the mineral slurry
- Authors:
- Tatiana N. Aleksandrova
- Vadim A. Potemkin
The paper studies the possibility of assessing the separation of mineral raw materials, taking into account the rheology of the mineral slurry. The ores of the Mayskoye deposit were chosen as the object of the study, characterized by a thin impregnation of the valuable component – gold in the host minerals, which determines the use of fine and ultrafine milling. This fact is essential because the presence of a fine grade seriously affects the rheology of the mineral slurry used in subsequent mineral processing stages. This predetermines the necessity to take into account rheological parameters. The research performed provides the development of a methodology for assessing the separation of minerals in the hydrocyclone based on the interpretation of numerical and mathematical modeling data. using the object-oriented programming language Python, a program for calculating empirical coefficients of the rheological equation, theoretically describing the dynamics of internal transformations of the mineral slurry, was developed. Taking into account the process parameters of the laboratory unit with hydrocyclone and ore properties, three concentrations of solids in the mineral slurry were selected, conditionally corresponding to the minimum, average and maximum values. Rheological equations successively composed for three concentrations, i.e., 400, 500, and 700 g/l, made it possible to calculate the critical shear rates corresponding to the maximum dispersion of the mineral slurry in the hydrocyclone flow. Subsequent numerical simulation using Ansys Fluent software, as well as statistical evaluation of the shear rates at different levels of solids content showed that the shear rate profile in the cross-section of the hydrocyclone corresponding to the maximum dispersion of the mineral slurry is obtained at the content of 400 g/l.
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Date submitted2020-09-15
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Date accepted2021-11-30
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Date published2021-12-27
Evaluating the effectiveness of fine gold extraction technologies on the example of titanomagnetite beach placers of the western coast of Kamchatka
- Authors:
- Valentina E. Kungurova
The material on the gold content of coastal-marine deposits of the western coast of Kamchatka is analyzed and the resource potential is briefly characterized. A review of gold technological estimates obtained from the study of gold-bearing samples taken in promising areas of the coastal-marine strip, from the Bolshaya Vorovskaya River in the north to Cape Levashova in the south, is presented. Stock materials supplemented by our studies were used. Gold-bearing deposits with very fine (0.05-0.1 mm) and fine (0.1-1.0 mm) gold amounting to 94.6 % were tested, as well as samples with gold up to 2 mm and more in addition to fine gold The content of freely recoverable gold reached 91.9 %. In the case of significant gold reserves in placers, prospects for their commercial development open up. experiments on the enrichment of gold-bearing coastal-marine deposits of Western Kamchatka indicate the possibility of extraction of free gold and other valuable components from them. Gravity technologies and modern equipment developed by ОАО Irgiredmet and JSC ITOMAK are the most effective for their extraction. enrichment of gold-bearing formations with simultaneous extraction of several useful components from them, which is possible with the use of fluoride technology, can also become economically advantageous.
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Date submitted2021-06-15
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Date accepted2021-10-18
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Date published2021-12-16
Study on hydrometallurgical recovery of copper and rhenium in processing of substandard copper concentrates
- Authors:
- Denis S. Lutskiy
- Aleksander S. Ignatovich
Over the past decade, there has been a steady growth in demand for rare metals, with rhenium being one of the most highly demanded, but also one of the most expensive and difficult to obtain. The high demand for rhenium is due to its use as a key component of metallurgical alloys or as a component of catalysts used in the oil refining industry. The aggregate of facts causes profitability of processing of the rhenium-containing mineral resources, which also are the copper substandard concentrates obtained at processing of the Zhezkazgan sandstones. The study focuses on the processes of extraction of copper and sorption recovery of rhenium from solutions of ammonia leaching of copper substandard concentrates. Model solutions similar in the elemental composition to solutions of ammonia leaching solutions of copper substandard concentrates obtained during the processing of Zhezkazgan sandstones were used as an object of the study. The paper estimates extraction characteristics of copper recovery using LIX 84-I solution in kerosene, as well as sorption characteristics of the rhenium recovery process using the Purolite PPA100 anion exchanger. Based on the obtained characteristics the possibility of hydrometallurgical processing of ammonia leaching solutions of substandard copper-sulfide concentrates, and recovery of the obtained commercial products is shown.
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Date submitted2020-09-10
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Date accepted2020-11-25
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Date published2021-06-24
Formation conditions of noble metal mineralization in sulfide cobalt-copper-nickel ores of Kamchatka (on the example of Annabergitovaya Schel ore occurrence)
The authors present research results, the purpose of which is to study the specifics of noble metal mineralization and its genesis in sulfide cobalt-copper-nickel ores of the Kamchatka nickel-bearing province. The paper is dedicated to one of its many ore occurrences called Annabergitovaya Schel (Annabergite Gap). The material composition of platinoid, silver, gold, bismuth and tellurium minerals, as well as sulfarsenides in the ores of this occurrence was investigated. Based on the data of mineral formation sequence and the use of geosensors, conclusions were drawn regarding the genesis of noble metal mineralization. Formation of platinoid minerals, silver and gold at the Annabergitovaya Schel ore occurrence is mainly associated with the epigenetic effect of post-ore granitoids on ore-bearing intrusion rocks of the Dukuk complex of the cortlandite-norite formation and on syngenetic ores. An early association of noble metal minerals is represented by sperrylite, irarsite, and rare unnamed phases of Pt + Ir + Te. Irarsite and Pt + Ir + Te phases were formed at the contact-metasomatic stage. Sperrylite can be assumed to be of magmatic origin. Silver sulfides and tellurides, silver and palladium bismuth tellurides, and native gold were formed at the late, hydrothermal-metasomatic, stage. The occurrence conditions of mineral parageneses, associated with noble metal mineralization, correspond to the formation of shallow-depth metasomatic rocks (≤5 km). Sub-developed quartz-feldspar metasomatites, associated with the formation of early platinoid arsenides and sulfarsenides, are in equilibrium with circumneutral solutions (pH of 4.5-6.5) at temperatures of 350-600 °C. Late hydrothermal association with Pd, Ag and Au minerals is close to propylites and was formed at pH values of 4.5-6.5 and temperature of 150-350 °C.
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Date submitted2020-02-19
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Date accepted2020-04-17
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Date published2020-10-08
Decrease in coal losses during mining of contiguous seams in the near-bottom part at Vorkuta deposit
- Authors:
- Oleg I. Kazanin
- Valeriy V. Yaroshenko
The problem of formation of extended zones with high rock pressure (HRP) from safety pillars at the boundaries of extraction pillars formed due to the mine layout of complex geometry is considered at the example of JSC Vorkutaugol mines. A detailed analysis of the remaining reserves of the near-bottom part of the deposit was carried out to estimate losses and the impact of HRP zones from the Chetvertyi protective seam to mining operations on the Troinoi upper seam along with the possibilities for the reduction of sizes of HRP zones at the account of expanding the underworked space. Due to research on the near-bottom part of the Vorkuta deposit, within the framework of the accepted layout, a zone at the Komsomolskaya mine and two zones at the Zapolyarnaya-2 mine were singled out, at which losses at the boundaries of the extraction pillars amount up to 13-22 % of the total resources of the mine field. The high volume of losses in these pillars indicates the relevance of research on the priority extraction impact of protective seams on the efficiency and safety of mining operations in the working area of underworked and HRP zones. Based on the analysis of foreign and Russian experience in the pillar cleaning-up at the boundaries of working areas and the methodical guidelines and instructions, a technological scheme was developed that allows increasing the coal mining recovery factor in the near-bottom part of the Vorkuta deposit from 0.75 to 0.9 without fundamental changing of the ventilation and transport networks and also without purchasing any additional mining equipment. The conducted economic calculations confirmed the effectiveness of implementing the new technological scheme for cleaning-up reserves at the boundaries of extraction districts. The economic effect is from 0.079 to1.381 billion rubles of additional profit from coaxial extraction pillars, depending on the mining and geological conditions and the size of the pillars.
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Date submitted2019-06-06
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Date accepted2019-08-09
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Date published2020-04-24
Studies of enrichment of sulfide and oxidized ores of gold deposits of the Aldan shield
The paper presents the analysis of studies of the enrichment of sulfide and oxidized ores in Yakutia deposits. The ore of the deposit is a mixture of primary, mixed and oxidized ores. The main useful component of the studied ore samples is gold with a content of 1.5 to 2.8 g/t, the silver content is low – 5-17 g/t. Ore minerals are represented by sulfides, among which pyrite predominates. The total sulfide content does not exceed 3-5 %. The presence in the ore of free and associated gold with a grain size from fractions of a micron to 1.5 mm. Gold is represented by nuggets in intergrowth with sulfides and also forms independent inclusions. Ores are classified as easily cyanidable. It was found that the content of amalgamable gold is 10-49, the share of cyanidable gold ranges from 66.67-91, the share of refractory gold is 9.0-33.33 %, which in absolute amount equals to 0.24-0.8 g/t. The extraction of gold in gravitation concentrate varies depending on the gold content in the ore and the yield of concentrate and for ores with a gold content of 1.5-2.8 g/t from 40 to 60 %. The direct cyanidation of all studied ore samples established the possibility of extracting gold into solution up to 86.7-92.9 %, the gold content in cyanidation cakes is 0.2-0.3 g/t. Investigations of the gravitation concentrate by the method of intensive cyanidation showed that with an initial gold content of ~ 500 g/t, up to 98.9 % is extracted into the solution. The gold content in intensive cyanide cakes will be 6-15 g/t. A set of studies carried out by the authors of the article at various institutes showed that it is advisable to process ore from the deposit using cyanidation technology with preliminary gravitational extraction of gold.
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Date submitted2019-07-11
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Date accepted2019-09-11
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Date published2020-04-24
Research of lithium sorption by KU-2-8 cation exchanger from model solutions simulating geothermal fluids in the dynamic mode
- Authors:
- Tatiana P. Belova
- Tatiana I. Ratchina
The extraction of chemical compounds from hydromineral raw materials is currently a promising objective. The geothermal deposits in the Kamchatka Territory should be considered as possible sources of lithium, boron and other chemical compounds. Their economic efficiency is justified by the complexity of the use of resources of geothermal fluids. The article presents data obtained as a result of experimental studies of lithium sorption by KU-2-8 cation exchanger from model solutions that simulate geothermal fluids in the dynamic mode. It was shown that in the first phase of sorption, ion exchange results in the absorption of lithium and sodium ions by the hydrogen form of cation exchanger up to the degree of cation exchanger saturation by 78 %. After that, the displacement of lithium ions by sodium ions is observed. The intermediate solutions were obtained in which the molar ratio of Li/Na is 80 times higher than in the initial solution. To separate sodium and lithium, it is proposed to use the lithium form of cation exchanger obtained using a portion of lithium chloride concentrate. The separation occurs due to the displacement of lithium ions by sodium ions. The effluent has a molar ratio of Li/Na = 10.4. The regeneration is carried out with 1 n hydrochloric acid, while the concentration coefficient of sodium chloride equals three.
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Date submitted2018-09-12
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Date accepted2019-01-05
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Date published2020-04-24
Flotation extraction of elemental sulfur from gold-bearing cakes
- Authors:
- Svetlana A. Ivanik
- Dmitrii A. Ilyukhin
Currently, in the development of the raw materials base of the gold mining industry, there is a tendency to reduce the quality of the initial mineral raw materials due to the depletion of reserves of rich gold-bearing ores. The article discusses the technology of extraction of refractory gold-bearing concentrates based on low-temperature leaching of pyrite concentrate. A decrease in the parameters of the autoclave oxidation of sulfide minerals, such as pyrite and arsenopyrite, leads to the incomplete extraction of gold into the solution and, consequently, its losses during subsequent cyanidation. As a possible option for a more complete extraction of gold using low-temperature oxidation technology, a method of flotation separation of elemental sulfur from leaching cakes is proposed. According to the basic process flow chart, the flotation process designed for gold extraction is carried out after autoclave oxidation, but before cyanidation. A series of experiments were carried out with varying reagent conditions and the dependence of gold losses on the extraction of elemental sulfur in the flotation tailings was established. As determining factors, pH and solid content in the initial pulp were considered. The paper justifies the separation of elemental sulfur from autoclave cake to enriched sulfur concentrate. The cake flotation modes after autoclave oxidative leaching of pyrite concentrate are investigated. The distribution of elemental sulfur and gold by flotation products makes it possible to conduct the tailings cyanidation process with acceptable indicators.
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Date submitted2019-05-26
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Date accepted2019-07-23
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Date published2019-10-23
Ensuring Stability of Undermining Inclined Drainage Holes During Intensive Development of Multiple Gas-Bearing Coal Layers
At high rates of production face advance, requirements towards reliable operation of undermining drainage holes get raised. The issue of maintaining high intensity of gaseous seams development under naturally increasing gas content, mining depth and capacity of production equipment poses a problem. The greatest threat comes from the loss of hole stability in the bearing pressure affected zone (in front of the face) and in the intensive shift area of overhanging rock corbels (behind the face). Intensification of air leaks due to deformation of borehole channel leads to impoverishment of removed methane-air mixture and an increasing risk to disturb safe aerogas regime in the mining area. The paper describes a mechanism of how coal-face operations affect the state of underground holes and formation of overhanging rock corbels. A typification of basic kinds of borehole deformations is presented. Authors point out critical disadvantages of the most widely-used technological schemes of gaseous seams development under high load on the production face, which hinder normal operation of a gas drainage system. As a result of research, a dependency of shot hole number, as well as the distance between shot hole axes and the borehole, on the stress state of the borehole outline has been defined more precisely. Basing on that, a formula to calculate drilling parameters of the discharge hole system has been suggested. Implementation of these measures will allow to increase the efficiency of underground gas drainage and to maintain growing intensity of gaseous coal seam development.
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Date submitted2018-11-10
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Date accepted2019-01-17
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Date published2019-04-23
AMT soundings in the dead band within the Chukotka region (Russian Far East)
The article analyzes the amplitude spectra of audio magnetotelluric sounding (AMTs) data. Particular attention is focused on the frequency range from 1 to 5 kHz, which is called dead band. We analyzed the data of base stations used in the fieldwork during the summer and autumn seasons in 2013, 2014, and 2017. The area of work is located in the Chukotka Autonomous Area beyond the Arctic Circle. Previous researchers noted that a reliable signal in the dead band can only be obtained at nighttime. The authors of the article found that in Chukotka region in the daytime against the minimum signal within the dead band there is a local maximum at a frequency of 2.4 kHz. When registering a field for more than 3 hours during daytime, in most cases, it is possible to restore the frequencies of 2.2 and 2.6 kHz. These frequencies are reliable benchmarks, allowing in some cases to restore the AMT curve using the correlation between amplitude and phase. We have proposed ways to improve data quality in the dead band when measured during the daytime.