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Date submitted2024-03-11
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Date accepted2024-11-07
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Date published2025-03-06
Geochemical characteristics of weathering crusts on the Dzhezhimparma Ridge and the Nemskaya Upland (South Timan)
Numerous local varieties of weathering crusts are known in the South Timan. They differ in their position in the section, type of weathering products, substrates, and occurrence. The aim of the research is to identify patterns in the distribution of rock-forming, rare and rare earth elements and the composition of clay minerals in clay formations of the weathering crusts. The main task is to describe the occurrence and geochemical features that enable determining the genetic type and formation conditions of weathering crusts. The paper presents the results of a study of the distribution of petrogenic, rare earth, rare elements, and clay minerals in weathering crust of different ages, genetic types and occurrence conditions on the Dzhezhimparma Ridge and the Nemskaya Upland in the South Timan. We found that hydromica-kaolinite-type weathering crust is developed after the Late Riphean Dzhezhim Fm. rocks in the basement-cover contact zone on the Dzhezhimparma Upland, and the layer of fine-grained rock at the base of the Devonian section previously considered a weathering crust was formed as a result of mechanical destruction of the Devonian sandstones during movement in the thrust zone. In the Vadyavozh quarry located on the Nemskaya Upland, we studied and described the formations of Mesozoic-Cenozoic areal and linear weathering crusts after the Late Riphean Dzhezhim Fm. rocks. We found that micaceous siltstones in the siltstone-sandstone strata of the Dzhezhim Fm. are associated with the Riphean stage of crust formation and are composed of weathering crust material redeposited in the epicontinental basin.
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Date submitted2024-04-24
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Date accepted2024-09-24
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Date published2024-11-12
Study and justification of the combination of beneficiation processes for obtaining flake graphite from technogenic carbon-containing dusts
The most important task of modern production development is to provide the mineral and raw materials sector of the economy with resources included in the list of strategic raw materials, including flake graphite. In addition to natural raw materials, the source of its obtaining can be metallurgical production wastes not involved in processing. Development of metallurgical dust beneficiation technology will solve the problem of obtaining high-purity flake graphite with a crystal structure close to ideal and in demand in the production of high-tech materials. It will allow creating a renewable raw material base of graphite and utilising metallurgical production wastes. The research included the study of dust beneficiation by coarseness, magnetic and flotation methods, the influence of dust disintegration processes on beneficiation indicators. Based on the established technological properties of the components of dusts, magnetic, flotation and gravity beneficiation methods can be applied for their separation in different sequence. It is shown that dusts from different sites have different enrichability by these methods, and it should be taken into account when developing a complex technology of their processing. The degree of beneficiation increases in a row of dusts from the blast furnace shop (BF) – electric steel smelting shop (ESS) – oxygen-converter shop (OCS). The method of grinding has a significant influence on the separation indicators – at dry grinding in a centrifugal-impact mill with subsequent pneumatic classification the quality of graphite concentrates increases by 22.7 % of carbon for BF dust and by 13.48 % of carbon for ESS dust. OCS dust beneficiation indicators are high at coarse grinding with steel medium – mass fraction of carbon 96.1 %.
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Date submitted2023-09-29
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Date accepted2023-10-25
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Date published2024-08-26
Laboratory studies of transformation of porosity and permeability and chemical composition of terrigenous reservoir rocks at exposure to hydrogen (using the example of the Bobrikovskii formations in the oil field in the northeast Volga-Ural oil and gas province)
The article describes the methodology for laboratory studies of reservoir rock exposure to hydrogen. The stages of sample research and the instruments used in the experiments are considered. A comparative analysis of the results of studies on porosity and permeability of core samples was performed. It was shown that after exposure to hydrogen, the porosity decreased by 4.6 %, and the permeability by 7.9 %. The analysis of correlation dependencies demonstrated a typical change in the relationship of these characteristics: after the samples exposure to hydrogen the scatter of the values increased and the correlation coefficient decreased, which indicates a change in the structure of the void space. Based on the research results, it was concluded that the decrease in porosity and permeability of the core samples occurred due to their minor compaction under the action of effective stresses. The chemical analysis of the rock showed no major difference in the composition of the basic oxides before and after exposure to hydrogen, which points to the chemical resistance of the studied formation to hydrogen. The experimental results showed that the horizon under consideration can be a storage of the hydrogen-methane mixture.
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Date submitted2023-08-14
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Date accepted2023-12-27
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Date published2024-12-25
Modelling of compositional gradient for reservoir fluid in a gas condensate deposit with account for scattered liquid hydrocarbons
In oil and gas reservoirs with significant hydrocarbon columns the dependency of the initial hydrocarbon composition on depth – the compositional gradient – is an important factor in assessing the initial amounts of components in place, the position of the gas-oil contact, and variations of fluid properties throughout the reservoir volume. Known models of the compositional gradient are based on thermodynamic relations assuming a quasi-equilibrium state of a multi-component hydrodynamically connected hydrocarbon system in the gravity field, taking into account the influence of the natural geothermal gradient. The corresponding algorithms allow for calculation of changes in pressure and hydrocarbon fluid composition with depth, including determination of the gas-oil contact (GOC) position. Above and below the GOC, the fluid state is considered single-phase. Many oil-gas-condensate reservoirs typically have a small initial fraction of the liquid hydrocarbon phase (LHC) – scattered oil – within the gas-saturated part of the reservoir. To account for this phenomenon, a special modification of the thermodynamic model has been proposed, and an algorithm for calculating the compositional gradient in a gas condensate reservoir with the presence of LHC has been implemented. Simulation cases modelling the characteristic compositions and conditions of three real oil-gas-condensate fields are considered. The results of the calculations using the proposed algorithm show peculiarities of variations of the LHC content and its impact on the distribution of gas condensate mixture composition with depth. The presence of LHC leads to an increase in the level and possible change in the type of the fluid contact. The character of the LHC fraction dependency on depth can be different and is governed by the dissolution of light components in the saturated liquid phase. The composition of the LHC in the gas condensate part of the reservoir changes with depth differently than in the oil zone, where the liquid phase is undersaturated with light hydrocarbons. The results of the study are significant for assessing initial amounts of hydrocarbon components and potential efficiency of their recovery in gas condensate and oil-gas-condensate reservoirs with large hydrocarbon columns.
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Date submitted2022-09-26
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Date accepted2023-09-20
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Date published2024-04-25
Technology of absorption elimination with cross-linking plugging material based on cement and cross-linked polymer
The peculiarity of the geological structure of carbonate reservoirs is their complex permeability and porosity characteristics, reflecting the simultaneous presence of cavities variety (fractures, caverns, pores). Loss of circulation during penetration of fractured rock intervals significantly increases well construction time due to lack of efficient plugging isolation compositions. The main disadvantages of traditional compositions are high sensitivity to dilution in the process of their injection into the absorption zone, as well as insufficient structural strength to prevent the isolation composition from spreading during the induction period. For efficient isolation of catastrophic absorption zones in conditions of high opening of absorption channels a new cross-linking plugging isolation composition has been developed, which allows to exclude disadvantages of traditional isolation compositions. Application of the composition will allow to reduce the injection volume of the isolation composition and the time of isolation works due to its resistance to dilution and movement of formation water in the absorption interval.
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Date submitted2022-12-01
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Date accepted2023-01-19
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Date published2023-12-25
Inclusions of diamond crystals in the tourmaline of the schorl-uvite series: problems of genesis
The mineralogical and geochemical features of diamond-bearing tourmaline crystals (schorl-uvite series) from garnet-clinopyroxene rocks of the Kumdy-Kol deposit (Northern Kazakhstan) have been studied in detail. The formation of the main rock-forming minerals (garnet + K-bearing clinopyroxene) occurred in the diamond stability field at 4-6 GPa and 950-1000 °C. Crystallization of K-bearing clinopyroxene at these parameters is possible in the presence of an ultra-potassic fluid or melt formed because of crustal material melting in subduction zones. Tourmaline crystals (up to 1 cm) containing diamond inclusions perform veins crosscutting high-pressure associations. The composition of individual zones varies from schorl to uvite within both a single grain and the sample as a whole. The potassium content in this tourmaline does not exceed 0.1 wt.% K2O, and the isotopic composition of boron δ11B varies from –10 to –15.5 ‰, which significantly differs from the previously established isotopic composition of boron in maruyamaite crystals (δ11B 7.7 ‰ in the core and –1.2 ‰ in the rim) of the same deposit. Analysis of the obtained data on δ11B in the tourmalines from the diamond-grade metamorphic rocks within the Kumdy-Kol deposit suggests the existence of two boron sources that resulted in crystallization of K-bearing tourmaline crystals (maruyamaite-dravite series) and potassium-free tourmalines of the schorl-uvite series.
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Date submitted2021-02-12
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Date accepted2022-07-26
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Date published2022-11-10
Manifestation of incompatibility of marine residual fuels: a method for determining compatibility, studying composition of fuels and sediment
- Authors:
- Radel R. Sultanbekov
- Andrey M. Schipachev
The results of studying the problem of active sediment formation when mixing residual fuels, caused by manifestation of incompatibility, are presented. A laboratory method has been developed for determining the compatibility and stability of fuels allowing identification of a quantitative characteristic of sediment formation activity. Laboratory studies were performed, and incompatible fuel components were identified. Tests were made to determine the quality indicators of samples and group individual composition of fuels. Results on the content of total and inorganic carbon in the obtained sediments were determined using Shimadzu TOC-V SSM 5000A. Chemical composition was determined and calculated on LECO CHN-628 analyser. Group composition of hydrocarbon fuels contained in the sediment was studied by gas chromato-mass spectrometry on GCMS-QP2010 Ultra Shimadzu. To obtain additional information on the structural group composition of fuel sediment, IR spectrometry was performed on IR-Fourier spectrometer IRAffinity-1. X-ray diffraction analysis of sediment samples was made using X-ray diffractometer XRD-7000 Shimadzu; interplanar distances d002 and d100 as well as Lс and Lа crystallite sizes served as the evaluation criteria. Microstructural analysis of total sediment was performed by scanning electron microscopy. The results of the research confirmed that the content of normal alkanes in the fuel mixture mainly affects sediment formation. Recommendations were drawn on preserving the quality of fuels and reducing sediment formation during storage and transportation.
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Date submitted2021-09-17
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Date accepted2022-04-07
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Date published2022-12-29
Technique for calculating technological parameters of non-Newtonian liquids injection into oil well during workover
Technique for automated calculation of technological parameters for non-Newtonian liquids injection into a well during workover is presented. At the first stage the algorithm processes initial flow or viscosity curve in order to determine rheological parameters and coefficients included in equations of rheological models of non-Newtonian fluids. At the second stage, based on data from the previous stage, the program calculates well design and pump operation modes, permissible values of liquid flow rate and viscosity, to prevent possible hydraulic fracturing. Based on the results of calculations and dependencies, a decision is made on the necessity of changing the technological parameters of non-Newtonian liquid injection and/or its composition (components content, chemical base) in order to prevent the violation of the technological operation, such as unintentional formation of fractures due to hydraulic fracturing. Fracturing can lead to catastrophic absorptions and, consequently, to increased consumption of technological liquids pumped into the well during workover. Furthermore, there is an increased risk of uncontrolled gas breakthrough through highly conductive channels.
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Date submitted2021-08-05
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Date accepted2021-11-30
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Date published2021-12-27
Morozkinskoye gold deposit (southern Yakutia): age and ore sources
The paper presents the results of the comprehensive isotope geochemical (Re-Os, Pb and δ 34 S) study of sulfide mineralization of the Morozkinskoye deposit. The ore zones of the deposit are localized in the syenite massif of Mount Rudnaya, which is located within the Central Aldan ore region (southern Yakutia). Gold mineralization is represented by vein-disseminated or vein type mineralization and is manifested in acidic low-temperature metasomatites – beresites (Qz-Ser-Ank-Py). For the first time we obtained an age estimate of the gold mineralization ~ 129 ± 3 Ma, which the synchronism of the hydrothermal ore process in the beresites, which formed the Morozkinskoye deposit, and magmatic crystallization of the syenites of Mount Rudnaya (~130 Ma). The osmium initial isotopic composition of the studied sulfides indicates a mixed mantle-crustal source of sulfide mineralization. New lead isotopic data of syenites indicate the predominance of mantle lead and an insignificant role of the lower – crust lead, while the isotopic composition of pyrite denotes the presence of the upper crustal material in the ore genesis. The sulfide δ 34 S values vary from –2.3 to +0.6 ‰ and indicate a predominantly magmatic source of sulfur in the ores.
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Date submitted2021-03-11
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Date accepted2021-07-27
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Date published2021-10-21
Justification of a comprehensive technology for preventing the formation of asphalt-resin-paraffin deposits during the production of highlyparaffinic oil by electric submersible pumps from multiformation deposits
Production of highly solidifying abnormal oils (with a paraffin content of over 30 % by mass) in the Far North is complicated by the intensive formation of asphalt-resin-paraffin deposits (ARPD) in the bottomhole zone of the productive formation, well and surface equipment. Existing methods and technologies for countering the formation of organic deposits in well equipment have many advantages. However, their application in the production of highly paraffinic oil does not fully prevent the formation of ARPD in the tubing string. This leads to a significant reduction in oil production, reduction of turnaround and intertreatment periods of production wells operation, an increase in specific operating expenses for paraffin removal. Results of theoretical and laboratory investigations presented in the article show that one of the promising ways to improve the operational efficiency of wells equipped with electric submersible pumps during extraction of highly paraffinic oil from multiformation deposits is the application of a new integrated technology based on the joint production of highly solidifying abnormal oil with oil, characterized by a lower paraffin content and manifestation of structural and mechanical properties, in conjunction with the regulation of the parameters for the electric submersible pump. Results of numerical modeling using the PIPESIM steady-state multiphase flow simulator, physical, chemical and rheological investigations show that with a decrease of highly paraffinic oil from the productive formation D2ef in a blend with Stary Oskol oil from the Kyrtaelskoye field, a decrease in the mass content of paraffin in the blend and the temperature of its saturation with paraffin, depth and intensity of the organic deposits formation in the tubing string, pour point, as well as the improvement of the rheological properties of the investigated structured dispersed systems is observed. Article describes a promising assembly of well equipment for the single tubing separate production of highly paraffinic oil from multiformation deposits of the Timan-Pechora province, providing separation of the perforation zones in two productive formations using a packer-anchor system at simultaneous-separate operation of the formations by a double electric submersible pump unit.
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Date submitted2021-02-09
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Date accepted2021-07-27
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Date published2021-10-21
Development of an algorithm for determining the technological parameters of acid composition injection during treatment of the near-bottomhole zone, taking into account economic efficiency
Relevance of the research is due to the low proportion of successful hydrochloric acid treatments of near-bottomhole zones of carbonate reservoirs in the Perm region caused by insufficiently careful design and implementation of measures to stimulate oil production. Within the framework of this article, the development of a program is presented, which is based on an algorithm that allows determining the volume and rate of injection for an acid composition into a productive formation corresponding to the maximum economic efficiency during hydrochloric acid treatment. Essence of the proposed algorithm is to find the greatest profit from measures to increase oil recovery, depending on the cost of its implementation and income from additionally produced oil. Operation of the algorithm is carried out on the principle of enumerating the values of the volume and rate of injection for the acid composition and their fixation when the maximum difference between income and costs, corresponding to the given technological parameters of injection, is reached. The methodology is based on Dupuis's investigations on the filtration of fluids in the formation and the results of the experiments by Duckord and Lenormand on the study of changes in the additional filtration resistance in the near-well zone of the formation when it is treated with an acid composition. When analyzing and including these investigations into the algorithm, it is noted that the developed technique takes into account a large number of factors, including the lithological and mineralogical composition of rocks, technological parameters of the injection of a working agent and its properties, well design, filtration properties of the formation, properties of well products. The article provides an algorithm that can be implemented without difficulty using any programming language, for example, Pascal. Selection of the optimal values for the volume and rate of injection is presented in this paper, using the example of a production well at the Chaikinskoye oil field, located within the Perm region. Introduction of the developed algorithm into the practice of petroleum engineering will allow competent and effective approach to the design of hydrochloric acid treatments in carbonate reservoirs without a significant investment of time and additional funds.
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Date submitted2020-06-16
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Date accepted2021-03-29
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Date published2021-09-20
Empirical regularities investigation of rock mass discharge by explosion on the free surface of a pit bench
- Authors:
- Igor A. Alenichev
- Ruslan A. Rakhmanov
Minimizing the discharge of blasted rock mass into the developed space of the pit is a very relevant area for study, as it allows to increase the processability of work and reduce the cost of mining. The article presents the results of experimental industrial explosions, during which the study of this issue was conducted. The main purpose of the work was to establish the key factors affecting the volume of rock mass discharge to the pit haulage berm. During the analysis of the world experience of research on this topic, the key factors affecting the formation of collapse and discharge – natural and technological – are identified. The method of conducting experiments and collecting data for analyzing the influence of technological parameters of location, charging and initiation of wells on the volume of rock mass discharge is described. It is established that the main discharge to the pit haulage berm is formed by the volume of rock mass limited by the prism of the slope angle. With a sufficient rock mass displacement from the edge of the bench crest towards the center of the block, only the wells of the 1st and 2nd rows participate in the discharge formation. Empirical dependences of the total volume of rock mass discharge on the length of the block along the bench crest, the specific consumption of explosives, the size of a rock piece P 50 and the rate of rock breaking are obtained. The obtained results can be used to design the parameters of the drilling and blasting operations (DBO), as well as to predict and evaluate the possible consequences of a mass explosion in similar mining and geological conditions.
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Date submitted2019-06-06
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Date accepted2019-08-09
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Date published2020-04-24
Studies of enrichment of sulfide and oxidized ores of gold deposits of the Aldan shield
The paper presents the analysis of studies of the enrichment of sulfide and oxidized ores in Yakutia deposits. The ore of the deposit is a mixture of primary, mixed and oxidized ores. The main useful component of the studied ore samples is gold with a content of 1.5 to 2.8 g/t, the silver content is low – 5-17 g/t. Ore minerals are represented by sulfides, among which pyrite predominates. The total sulfide content does not exceed 3-5 %. The presence in the ore of free and associated gold with a grain size from fractions of a micron to 1.5 mm. Gold is represented by nuggets in intergrowth with sulfides and also forms independent inclusions. Ores are classified as easily cyanidable. It was found that the content of amalgamable gold is 10-49, the share of cyanidable gold ranges from 66.67-91, the share of refractory gold is 9.0-33.33 %, which in absolute amount equals to 0.24-0.8 g/t. The extraction of gold in gravitation concentrate varies depending on the gold content in the ore and the yield of concentrate and for ores with a gold content of 1.5-2.8 g/t from 40 to 60 %. The direct cyanidation of all studied ore samples established the possibility of extracting gold into solution up to 86.7-92.9 %, the gold content in cyanidation cakes is 0.2-0.3 g/t. Investigations of the gravitation concentrate by the method of intensive cyanidation showed that with an initial gold content of ~ 500 g/t, up to 98.9 % is extracted into the solution. The gold content in intensive cyanide cakes will be 6-15 g/t. A set of studies carried out by the authors of the article at various institutes showed that it is advisable to process ore from the deposit using cyanidation technology with preliminary gravitational extraction of gold.
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Date submitted2018-12-28
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Date accepted2019-03-24
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Date published2019-06-25
Modern physicochemical equilibrium description in Na2O–Al2O3–H2O system and its analogues
Equilibrium and non-equilibrium states of systems Na 2 O–Al 2 O 3 –H 2 O and K 2 O–Al 2 O 3 –H 2 O are crucial for establishing key technological parameters in alumina production and their optimization. Due to a noticeable discrepancy between experimental results and thermodynamic calculations based on materials of individual researchers the necessity of systematization and statistical processing of equilibrium data in these systems to create a reliable base of their physicochemical state, analysis and mathematical modeling of phase equilibria is substantiated. The tendency to a decrease of the hydration degree of solid sodium aluminates with increasing temperature and the transition of systems from the steady state of gibbsite to equilibrium with boehmite is revealed. The paper contains approximating functions that provide high-precision description of equilibrium isotherms in technologically significant area of Na 2 O–Al 2 O 3 –H 2 O and K 2 O–Al 2 O 3 –H 2 O concentrations. Approximating function can be simplified by dividing the isotherm into two sections with the intervals of alkaline content 0-0.25 and 0.25-0.4 mole/100 g of solution. The differences in solubility isotherms for Na 2 O–Al 2 O 3 –H 2 O and K 2 O–Al 2 O 3 –H 2 O systems provide are associated with changes in the ionic composition solutions that depends on concentration and temperature, as well as differences connecting with alkali cation hydration, which is crucially important for thermodynamic modeling of equilibria under consideration.
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Date submitted2018-12-25
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Date accepted2019-03-22
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Date published2019-06-25
Technology of blasting of strong valuable ores with ring borehole pattern
- Authors:
- I. V. Sokolov
- A. A. Smirnov
- A. A. Rozhkov
The ores of non-ferrous and precious metals, represented by hard rocks, has a peculiar feature, that is the effect of segregation, that is the tendency of ore minerals to break down into small size classes, which in the underground mining method accumulate in significant quantities on uneven surface of bottom layers and subsequently are lost. When mining valuable non-metallic materials, there is an acute problem of overgrinding, when fines do not meet the requirements for the quality of the final product. It is well known that the granulometric composition of the ore depends mainly on the technology and parameters of drilling and blasting operations. In underground mining of ore deposits, the main method of drilling and blasting is the borehole blasting with continuous construction charges with the ring pattern. The main drawbacks of the method are: uneven distribution of the explosive along the plane of the broken layer and the expenditure of a significant part of the blast energy of the charges of the continuous structure on the blasting effect, necessarily associated with over-grinding the ore. To solve these problems, the authors proposed a blasting technology, the essence of which lies in the fact that the uniform distribution of the energy concentration of explosives in the broken layer is ensured by the dispersion of charges by air gaps and a certain order of their placement in the ring plane. For the practical implementation of the technology, a method has been developed to form dispersed charges in deep boreholes that do not require a significant increase in labor costs and additional special means. A special technique has been created that allows defining the dispersion parameters, ensuring the sustained specific consumption of explosives over the entire plane of the broken layer. Experimental studies of the proposed technology in the natural conditions of an underground mine for the extraction of valuable granulated quartz were carried out. As a result, the possibility of a significant reduction in the specific consumption of explosives (by 42 %) has been established. At the same time, the yield of the commercial product increased by 10.7 % in total, and the yield of the fraction most favorable for further processing increased by 33.7 %.
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Date submitted2018-09-04
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Date accepted2018-11-16
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Date published2019-02-22
Development of an occupational safety management system based on the process approach
- Authors:
- V. A. Filimonov
- L. N. Gorina
The article discusses the relevance and possibility of using the process approach in the development and implementation of occupational safety management systems based on GOST 12.0.230-2007, which is the main document in this area for all industrial enterprises and organisations of the Russian Federation. The system of occupational safety management in the organisation is considered taking into account all its internal communications and input-output parameters. It is shown that the process approach used in the design of the occupational safety management system in the organisation, allows categorising the list of works (processes), participants, resources (responsible, performers, documents, etc.), the control and correction processes. The methodological substantiation of the process approach to the design of the occupational safety management system in the organisation is given, the basic issues of its applicability are considered. A context diagram of the process of an occupational safety management system is drawn in the IDEF0 graphical notation by means of the SADT structural analysis technology. The decomposition of the context diagram to the required levels of detail is presented and the balance factor of the models is calculated.
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Date submitted2018-08-30
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Date accepted2018-10-26
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Date published2019-02-22
Study of bearing units wear resistance of engines career dump trucks, working in fretting corrosion conditions
- Authors:
- Ju. Olt
- V. V. Maksarov
- V. A. Krasnyy
The occurrence of fretting corrosion on nominally fixed surfaces of high-loaded parts of mining machines and mechanisms is considered. Examples of wear and damage of critical parts, bearing assemblies of engines of dump trucks in fretting conditions are given. The mechanisms of fretting corrosion when using wear-resistant coatings are considered. It is noted that when choosing protective thin-layer coatings that provide an increase in the fretting-resistance of surfaces of tightly contacting parts, it is necessary to take into account both their wear resistance and the ability to resist shear. At the same time, the thickness of such coatings allows preserving, during operation, those provided during the assembly of the tension, without disturbing the maintainability of the nodes. The results of research of fretting wear of a number of coatings on a special installation are given. The mechanisms of wear of a number of thin-layer coatings based on friction-mechanical brazing, polymer fluorocarbon composition, solid lubricant coating using scanning electron microscopy were studied. Recommendations on the use of the studied thin-layer coatings for high-loaded parts of mining machines operating in fretting corrosion conditions have been developed. The aim of the work was to study the effect of a number of thin-layer coatings on the wear of highly loaded connections of the mechanisms of mining machines, in particular bearing assemblies of quarry dump trucks operating under fretting corrosion conditions.
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Date submitted2015-12-08
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Date accepted2016-02-02
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Date published2016-12-23
Effect of chemical composition and quality of heavy Yarega oil on selection of appropriate processing technology
- Authors:
- N. K. Kondrasheva
- Anchita Khorkhe
The paper explores physical and chemical properties and composition of heavy oil from Yarega field and its vacuum residue, i.e. the tar. The capillary chromatography and gas chromatography-mass spectrometry were used to identify specific group hydrocarbon composition of heavy Yarega oil and components extracted therefrom, which has proven its belonging to highly resinous sulfurous naphthenic and aromatic oils. Based on the comparative analysis of composition and quality of feedstock a possibility has been assessed to produce a high-quality needle coke with low content of sulphur and metals from the heavy oil of Yarega field and its vacuum residue. An integrated process flow diagram for heavy Yarega oil refinement has been proposed, including preliminary deasphalting and demetallization, hydrotreatment, delayed coking and thermodestructive processes or gasification.
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Date submitted2015-12-17
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Date accepted2016-03-01
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Date published2016-12-23
Anomalous geochemistry of zircon from the Yastrebetskoe rare metal deposit (SIMS- and TOF-study)
- Authors:
- S. G. Skublov
- S.-Kh. Li
A detailed isotopic geochemical study (secondary ions mass-spectrometry – SIMS, time-of-flight mass-spectrometry – TOF) of zircon from ore-bearing syenites of the Yastrebetskoe rare metal-rare earth deposit (the Ukrainian Shield) has yielded proofs of magmatic genesis of the deposit: unaltered central parts of zircon grains typically feature characteristic magmatic spectra of REE distribution, their values of δ 18 O staying somewhat higher than the mantle value (6.5 ‰, on the average). During the final stage of forming the deposit the role of fluorine-water-bearing fluids enriched with Y, REE, Nb, Ве and heavy oxygen had increased, as directly reflected in the anomalous isotopic-geochemical characteristics of zircon rims and zones of zircon alteration (the contents of Y reaches 61874 ppm, that of Nb – 7976 ppm, Be – 1350 ppm, δ 18 O reaches 12.42‰, F – 0.7 % mass, H 2 O – 4% mass).
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Date submitted2015-10-06
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Date accepted2015-12-18
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Date published2016-08-22
New technology of dry benefication of fly ash from coal power plants using applied mineralogy techniques
- Authors:
- V. A. Arsentev
- E. L. Kotova
The existence of environmental and strategic need to process dumps and slagheaps of coal mining enterprises of Russia and foreign countries results in reviewing the potential of using fly ash as a technogenic mineral resource. Comprehensive studies of substance composition of fly ash from coal power plants make it possible to define rational further ways of utilizing that mineral resource substantiating the scheme of its technological secondary processing. In view of the numerous environmental problems stemming from the techniques of wet benefication and processing of that mineral resource, a technology is suggested of dry cleaning of fly ash from thermal coal power plants. Studies were carried out using a number of samples of fly ash from various power plants. The suggested criteria are used to discriminate the compounds of fly ash and quantitative and qualitative composition of particulate matter is assessed. Studies of substance composition of fly ash samples has demonstrated that the concentration of non-combusted carbon in them varies from 5 to 20 %. The principal technological procedure of cleansing in our studies was a combination of magnetic and electric separation of ash in the state of vibrational pseudo-liquefaction. It enables one to increase the throughput capacity and selectivity of the cleansing process significantly. In the result of such cleansing a stable mineral fraction is produced that contains 0.5-2.5 % of carbon, so that the purified mineral fraction can be used as a construction binding agent.
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Date submitted2015-08-02
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Date accepted2015-10-04
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Date published2016-04-22
Development of innovative technologies of dedusting in mining and advance coal mine faces
- Authors:
- G. I. Korshunov
- S. B. Romanchenko
The article describes the results of the implementation of investment projects in the field of complex dedusting implemented in major coal producing companies in Russia. Experimental study of the processes reduce the levels of dust in the workplace in the application of modern systems of irrigation and aspiration systems. The factors that determine the mass and composition of particulate airborne dust at various ways of dust suppression. The results of the analysis of the laser dispersed composition of particles removed from the air of the working area
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Date submitted2015-07-16
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Date accepted2015-09-28
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Date published2016-02-24
Examination of the raw materials and the products of the combustible shales processing
- Authors:
- N. K. Kondrasheva
- S. N. Saltykova
The reserves of combustible slates of Russia in shale oil and gas equivalent are more than the reserves of oil and natural gas. The formation of a large volume of ash is a major problem connected to the processing and the usage of the combustible slates. It is possible to look at this problem from a different angle of vision if a mineral part of slates is considered as a complex organo-mineral raw material where a mineral substance of the slates is the same raw material as the organic one. For this purpose, it is required to study in detail the physicochemical characteristics of the combustible slates and the behavior of the organic and the mineral parts of the slates during the heat treatment. This research focuses on the phase composition of Leningrad fuel shale and its changes on pyrolysis. They were studying the phase composition, the gas phase outlet, pyrolysis mass balance of combustible slates in the nitrogen atmosphere in the temperature range of 200-1000 °С, the porosity changes of combustible slate in the nitrogen atmosphere in the temperature range of 25-900 °С. It is determined that the main minerals of combustible slates are calcite (28 %), quartz (25 %), illite (17 %), and microcline (11 %). The temperature dependence of the shale porosity is studied in a nitrogen atmosphere and in air. The porosity changes in four stages: (I) 25-200 °C; (II) 200-400 °C; (III) 400-600 °C; (IV) 600-900 °C. The mass balance pyrolysis of combustible slates in a PTK_1.2_40 tube furnace is made up, in the nitrogen atmosphere of 200, 400, 600, 800 and 1000 °C.
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Date submitted2015-07-07
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Date accepted2015-09-16
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Date published2016-02-24
Activation of heap leaching of low-sulfide ores the invisible gold
- Authors:
- A. G. Sekisov
- Yu. I. Rubtsov
- A. Yu. Lavrov
This article deals with a physical-chemical model of heap leaching processes justifying new technological approaches to recovering dispersed forms of gold from ores, placer sands and deute-rogene mineral raw materials. The key process of this model includes lattice diffusion of high-energy hydrion minerals and hydroxyl-radicals formed as a result of photochemical and electro-chemical processing of initial reagent aqueous solutions. Active components of gas-water emulsions obtained while processing initial reagent solutions provide a structural and material trans-formation of a mineral lattice which concentrates clusters of dispersed gold creating conditions for its interacting with complexing compounds of process solutions. The article also considers the technological processes of activation heap leaching of dispersed gold from the Pogromnoe ore field and the results of the experiments conducted in percolators with their charge ranged from 3 to 100 kg. The results have proved the efficiency of using gas-water suspensions prepared in the pho-toelectrochemical reactor with active ion-radical oxidizing agents.
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Date submitted2010-07-14
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Date accepted2010-09-07
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Date published2011-03-21
Substantiation of pumped volumes of flow angularity compositions in injection wells
- Authors:
- A. R. Mavliev
- M. K. Rogachev
- D. V. Mardashov
The method of calculation pumped volumes of flow angularity compositions in injection wells, which based on combination of the seepage theory, laboratory investigation and field experience is developed.
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Date submitted2010-07-06
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Date accepted2010-09-06
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Date published2011-03-21
Distribution of products of destruction of granite files
The article considers the problem of size distribution of grain-size composition of the blasted rock mass, rock fragments blasted rock mass and rock blockiness. The logarithmic-normal distribution law is laid down for all blasted granite mass products. It was proved, that logarithmic variance of logarithmic normal distribution law of the fractured rock mass fragments’ distribution is a structural invariant on the level of statistical universe of the block and fragments.