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Date submitted2024-03-20
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Date accepted2024-11-07
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Date published2025-02-27
Analysis of the stress state of rocks transformation near a horizontal well during acid treatment based on numerical simulation
The article presents an overview of the assessment and modelling of the stress state of rocks in the near-wellbore zone of horizontal wells during acid stimulation of the formation for improving the efficiency of oil and gas field development. A numerical finite element model of near-wellbore zone of the reservoir drilled by a horizontal section was compiled using one of oil fields in the Perm Territory as an example. The distribution of physical and mechanical properties of the terrigenous reservoir near the well was determined considering transformation under the action of mud acid for different time periods of its injection. Multivariate numerical simulation was performed and the distribution of horizontal and vertical stresses in near-wellbore zone was determined with regard for different values of pressure drawdown and changes in stress-strain properties depending on the area of mud acid infiltration. It was found that a change in elastic modulus and Poisson's ratio under the influence of acid led to a decrease in stresses in near-wellbore zone. Analysis of the stress distribution field based on the Coulomb – Mohr criterion showed that the minimum safety factor of rock even after the effect of mud acid was 1.5; thus, under the considered conditions of horizontal well modelling, the reservoir rock remained stable, and no zones of rock destruction appeared.
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Date submitted2023-06-25
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Date accepted2024-11-07
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Date published2025-02-25
Study of wormhole channel formation resulting from hydrochloric acid treatment in complex-type reservoirs using filtration and X-ray computed tomography methods
- Authors:
- Andrei A. Аbrosimov
The primary function of hydrochloric acid treatment (HAT) is to create the maximum number of high-conductivity channels in the near-wellbore zone of the reservoir to restore its permeability and enhance hydraulic connectivity between the undisturbed part of the formation and the well. The objective of this study is to physically model HAT on core samples from the Orenburg oil and gas condensate field and to research the impact of such treatment on the structure of the pore space of rocks related to complex-type reservoirs. The complexity of the rock's pore space and the low permeability of the formations are distinguishing features of the study object. For this reason, HAT is a widely applied method for production intensification, necessitating the verification of acid injection rates, where the success criterion is the formation of high-conductivity filtration channels (wormholes) in the near-wellbore zone. These channels significantly expand the drainage area of wells, thereby bringing additional reservoir sections into development. The study examined the characteristics of filtration channel development resulting from acid treatment. Their structure was characterized and analyzed using X-ray computed tomography. The complex study confirmed the accuracy of the selected injection rate and provided practical recommendations for enhancing the efficiency of HAT.
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Date submitted2024-05-02
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Date accepted2024-06-03
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Date published2024-07-04
Iron ore tailings as a raw material for Fe-Al coagulant production
The paper presents the results of experimental research into the recovery of Fe-Al coagulant from iron ore tailings (IOTs). The variables investigated in the laboratory tests included sulphuric acid concentration, temperature, leaching time, solid/liquid phase ratio (S:L) and the presence of stirring. The experiment determined the composition of the coagulant and the solid residue after leaching. The maximum iron content in the solution after leaching was obtained using 40 % H2SO4 at a temperature of 100 °C (or with stirring at 75 °C) and a contact time of 60 minutes. In this case, the iron yield was at the level of 25 % of the total content in the iron ore tailings. Chemical analysis of the solution obtained after leaching showed Fe and Al sulphate contents of 11 and 2 % respectively. In the next step, the efficiency of the coagulant was evaluated on model solutions of colour. The experimental results showed that the coagulant obtained from the iron ore tailings can be used for wastewater treatment in a wide pH range from 4 to 12 pH units. The solid residue after leaching is a fine-grained powder rich in silica, which can potentially be used as an artificial raw material in the construction industry. The research carried out in this thesis has shown that the extraction of coagulants from iron ore tailings can be considered as a way to extend the production chain of iron ore mining and to minimise the amount of tailings to be stored in tailing ponds. The technical solution presented in this work allows to comprehensively solve the problem of environmental protection by creating new target products for wastewater treatment from IOTs.
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Date submitted2024-07-04
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Date accepted2024-07-04
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Date published2024-07-04
Environmental safety and sustainable development: new approaches to wastewater treatment
In 2015, the UN member states adopted the 2030 Agenda for Sustainable Development. Despite significant progress, billions of people – one in three people – do not have access to safe, clean drinking water. Modern wastewater treatment methods include a wide range of biological, chemical and physical processes, each having its own advantages and applications. This thematic volume considers the latest achievements in wastewater treatment technologies, wastewater purification and treatment as well as their potential applications at the local level. The problem of surface water pollution is relevant for all regions of the world. One of the largest sources of pollutants is mining and processing industry. The first stage in the development of wastewater treatment technologies is monitoring of anthropogenically modified water bodies.
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Date submitted2024-04-22
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Date accepted2024-06-13
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Date published2024-07-04
Comprehensive utilization of urban wastewater sludge with production of technogenic soil
The article presents the analysis of the existing approach to wastewater sludge treatment and justifies the selection of the most promising management technology that allows maximum use of wastewater sludge resource po-tential. To obtain a useful product (biocompost) suitable for use as part of technogenic soil, experimental studies of aerobic stabilization of organic matter of dehydrated urban wastewater sludge with the addition of other waste by using passive composting technology were carried out. The technology is included in the list of best available technologies (BAT). The selection of the most optimal components for the mixture was based on the results of determining the C and N content, humidity and pH of the components used that ensured the composting of organic waste. The results of laboratory studies of the obtained biocompost according to the main agrochemical and sanitary-epidemiological indicators are presented. Testing was carried out according to the criterion of toxicity of the biocompost’s aqueous extract. The assessment of the technogenic soil was performed when using biocompost in its composition for compliance with existing hygienic requirements for soil quality in the Russian Federation. Based on the results of the vegetation experiment, optimal formulations of the technogenic soil were determined, i.e., the ratio of biocompost and sand, under which the most favorable conditions for plant growth are observed according to a combination of factors such as the number of germinated seeds, the maximum height of plants and the amount of biomass. The conducted research makes it possible to increase the proportion of recycled urban wastewater sludge in the future to obtain soils characterized by a high degree of nutrient availability for plants and potentially suitable for use in landscaping, the biological stage of reclamation of technogenically disturbed lands, as well as for growing herbaceous plants in open and protected soil.
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Date submitted2024-03-29
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Date accepted2024-06-03
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Date published2024-07-04
Potential use of water treatment sludge for the reclamation of small-capacity sludge collectors
- Authors:
- Olga M. Guman
- Irina A. Antonova
In small settlements, collectors for the sludge produced during water treatment processes are small-sized and located in the vicinity of drinking water storage reservoirs or in coastal areas. Sludge removal is not economical. Besides, the relief depressions formed after sludge disposal are required to be reclaimed. In ore mining regions, where the main settlements of the Urals are located, sludge produced in water treatment has high contents of heavy metals typical of ore mining provinces. Consequently, places of sludge accumulation are potential sources of water pollution. The article discusses the possibility to mix sludge with slaked lime and local overburden with the help of special equipment. So far water treatment sludge in the region has been used to reclaim the surface of solid waste landfills by creating anaerobic conditions for waste decomposition. When placed inside the embankment dams as an independent object, sludge needs to be improved for the increase of its bearing capacity and the ability to bind heavy metals. The article aims at the substantiation of the composition and properties of the reclamation material made of the water treatment sludge mixed with local overburden and slaked lime (technosoil). For this reason the paper describes the composition of the sludge in a sludge collector, the composition and properties of the overburden rocks as a component of the mixtures with water treatment sludge, the composition and properties of the mixtures of water treatment sludge with overburden rocks and Ca(OH)2 as a component dewatering sludge and neutralizing toxicants. Furthermore, the research work provides the technology created for the optimal processing of the water treatment sludge in the process of the reclamation of a sludge collector. The research results and the experience obtained in reclamation of disturbed lands in the region have confirmed the possible use of technosoil for the reclamation of small-capacity sludge collectors. The analysis of the chemical composition and physical and mechanical properties of the mixtures under study has shown that the most economical and environmentally sound reclamation material is a mixture of water treatment sludge, loose overburden dump soils and Ca(OH)2 in a ratio of 60 : 30 : 10 %.
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Date submitted2024-03-07
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Date accepted2024-06-14
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Date published2024-07-04
Anomaly detection in wastewater treatment process for cyber resilience risks evaluation
Timely detection and prevention of violations in the technological process of wastewater treatment caused by threats of different nature is a highly relevant research problem. Modern systems are equipped with a large number of technological sensors. Data from these sensors can be used to detect anomalies in the technological process. Their timely detection, prediction and processing ensures the continuity and fault tolerance of the technological process. The aim of the research is to improve the accuracy of detection of such anomalies. We propose a methodology for the identification and subsequent assessment of cyber resilience risks of the wastewater treatment process, which includes the distinctive procedure of training dataset generation and the anomaly detection based on deep learning methods. The availability of training datasets is a necessary condition for the efficient application of the proposed technology. A distinctive feature of the anomaly detection approach is a new method of processing input sensor data, which allows the use of computationally efficient analytical models with high accuracy of anomaly detection, and outperforms the efficiency of previously published methods.
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Date submitted2023-04-11
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Date accepted2023-10-25
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Date published2024-07-04
Acid mine water treatment using neutralizer with adsorbent material
One of the biggest issues in the mining sector is due to acid mine drainage, especially in those abandoned mining operations and active ones that fail to adequately control the quality of their water discharge. The removal degree of copper, iron, lead, and zinc dissolved metals in acid mine drainage was investigated by applying different proportions of mixtures based on neutralizing reagent hydrated lime at 67 % calcium oxide (CaO), with adsorbent material – natural sodium bentonite, compared to the application of neutralizing reagent without mixing, commonly used in the neutralization of acid mining drainage. The obtained results show that the removal degree of dissolved metals in acid mine drainage when treated with a mixture of neutralizing reagent and adsorbent material in a certain proportion, reaches discharge quality, complying with the environmental standard (Maximum Permissible Limit), at a lower pH than when neutralizing material is applied without mixing, registering a net decrease in the consumption unit of neutralizing agent express on 1 kg/m3 of acid mine drainage. Furthermore, the sludge produced in the treatment with a mixture of the neutralizing reagent with adsorbent material has better characteristics than common sludge without bentonite, since it is more suitable for use as cover material, reducing the surface infiltration degree of water into the applied deposit.
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Date submitted2023-03-20
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Date accepted2023-09-20
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Date published2023-10-27
Experimental simulation of a system of swamp biogeocenoses to improve the efficiency of quarry water treatment
Mining activities were producing large quantities of wastewater contaminated with nitrogen compounds and metals. With insufficient treatment, these pollutants are released into the environment and have a toxic effect on living organisms. Constructed wetlands are now widely adopted as wastewater treatment systems because of the combination of physical, chemical and biological processes for the removal of contaminants. In this study, an experimental system was modeled to improve the efficiency of the quarry wastewater treatment of a mining enterprise by sharing the higher aquatic vegetation: broad-leaved cattail (Typha latifolia L.), common water-plantain (Alisma plantago-aquatica L.), jointed rush (Juncus articulatus L.) and lower aquatic vegetation (Chlorella sp.). Concentrations of nitrogen compounds and metal were analyzed both in the model and in the treated solution of quarry wastewater for calculation of treatment efficiency. Concentrations of the pollutants in the tissues of the higher aquatic vegetation were analyzed to assess the accumulation capacity and efficiency of translocation of the pollutants. The results of the experimental study showed the practical applicability of the constructed integrated treatment system to reduce the concentration of pollutants in quarry wastewater, as well as increasing the efficiency of treatment by introducing lower aquatic vegetation into the system
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Date submitted2022-10-31
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Date accepted2023-03-02
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Date published2023-12-25
Lightweight ash-based concrete production as a promising way of technogenic product utilization (on the example of sewage treatment waste)
- Authors:
- Tatyana E. Litvinova
- Denis V. Suchkov
The study is devoted to the development of a method for the technogenic raw materials utilization. Special attention is paid to the prospect of involving products based on them in the production of new building materials. The results of Russian and foreign studies on the reuse of wastes, such as phosphogypsum, metallurgical slag, waste from municipal and industrial wastewater treatment, etc., in the building materials industry are considered. It has been established that the use of incinerated sewage sludge ash in construction is a promising direction in terms of environmental and economic efficiency. The research confirmed the compliance of the lightweight ash-based concrete components to the regulatory documentation requirements for a number of indicators. As a result of the research, the composition of the raw mixture for the lightweight concrete production with incinerated sewage sludge ash as a replacement for a part of the cement has been developed. In terms of parameters, the developed concrete corresponds to standard lightweight concrete, marked in accordance with the regulatory documents of the Russian Federation as D1300 (density not less than 1.3 g/cm3), Btb2 (flexural strength not less than 2 MPa), M200/B15 (compressive strength not less than 15 MPa). Lightweight ash-based concrete is suitable for use in construction, repair of roads and improvement of urban areas.
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Date submitted2022-06-20
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Date accepted2023-01-10
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Date published2023-08-28
Laboratory, numerical and field assessment of the effectiveness of cyclic geomechanical treatment on a tournaisian carbonate reservoir
Results are discussed for evaluation of effectiveness of the cyclic geomechanical treatment (CGT) on a Tournaisian carbonate reservoir. Analysis of laboratory experiments performed according to a special program to assess permeability changes for Tournaisian samples under cyclic changes in pore pressure is presented. The main conclusion is the positive selectivity of the CGT: an increase in permeability is observed for samples saturated with hydrocarbons (kerosene) with connate water, and maximal effect is related to the tightest samples. For water-saturated samples, the permeability decreases after the CGT. Thus, the CGT improves the drainage conditions for tight oil-saturated intervals. It is also confirmed that the CGT reduces the fracturing pressure in carbonate reservoirs. Using flow simulations on detailed sector models taking into account the results of laboratory experiments, a possible increase in well productivity index after CGT with different amplitudes of pressure variation was estimated. Results of a pilot CGT study on a well operating a Tournaisian carbonate reservoir are presented, including the interpretation of production logging and well testing. The increase in the well productivity index is estimated at 44-49 % for liquid and at 21-26 % for oil, with a more uniform inflow profile after the treatment. The results of the field experiment confirm the conclusions about the mechanisms and features of the CGT obtained from laboratory studies and flow simulations.
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Date submitted2023-04-25
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Date accepted2023-04-25
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Date published2023-04-25
Ecological security and sustainability
- Authors:
- Mariya A. Pashkevich
- Alexandr S. Danilov
In 2015, UN Member States adopted the 2030 Agenda for Sustainable Development, aimed at balancing initiatives by the world community and individual countries in the environmental, social, and economic spheres. The global sustainable development goals are to promote the well-being of the world population, preserve the planet’s resources, and maintain ecological security, which is vital in the age of the rapid industrial growth and ever-increasing anthropogenic pressure on the environment. For the successful achievement of sustainability goals in the manufacturing sector, integrated measures should be undertaken for monitoring and assessing the technogenic impact of industrial facilities. Additionally, it is necessary to develop environmentally-friendly technologies in the fields of gas and water treatment, land reclamation, and waste disposal. Therefore, fundamental and applied research in these related spheres is of particular importance. Currently, environmental monitoring of all components of the environment, along with anthropogenic objects and processes, receives considerable attention, which is determined by the vector of development in science and technology. In this regard, the latest innovations in green technology in this area are becoming increasingly significant.
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Date submitted2022-10-24
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Date accepted2023-03-03
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Date published2023-04-25
Use of clay-containing waste as pozzolanic additives
Growing productivity of mining and processing enterprises entails an increase in the volumes of liquid tailings impoundments and upstream impoundments of ore processing waste. Enterprises face the challenge of minimizing the environmental impact of waste and guaranteeing the sanitary and epidemiological safety of population. The article presents a possibility of recycling one type of such waste (clay-containing concentration tailings of apatite-nepheline and sylvinite ores, coal beneficiation tailings) by using them after preliminary thermochemical treatment as pozzolanic additives to cements and concretes, including concrete mixtures used for soil stabilization, development of territories, reclamation of mine workings, as a component of the insulating layer of landfills for the disposal of municipal solid waste. An analysis of the phase changes of kaolinite, one of the main minerals that make up clay-containing waste, in the temperature range of 200-1,000 °С showed that a change in its mineral form during heat treatment is the main factor in changing its pozzolanic activity. The effect of heat treatment of clay minerals at temperature of 700-800 °C on their pozzolanic activity, estimated by the ability to absorb calcium hydroxide (0.7 g Ca(OH) 2 per 1 g of modified kaolinite), is considered. It is shown that the addition of heat-treated samples (20 % by weight) improves the quality of cement increasing its activity by 15 %, in comparison with the use of unmodified clay minerals. It was proved experimentally that partial replacement of Portland cement with thermally modified kaolinite increases the strength of consolidating stowing mixture by up to 15 %. This approach to processing of ores containing layered silicates, which provides for thermochemical modification of run-of-mine ore, intensifies the processes of tailings thickening and filtering.
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Date submitted2022-10-19
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Date accepted2023-02-14
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Date published2023-04-25
Electric steelmaking dust as a raw material for coagulant production
The paper describes the issues associated with waste generated during steel production and processing, in particular the dust from electric arc furnaces (EAF). An effective solution for the disposal of such waste is its involvement in processing to obtain valuable products. This paper studies the physical and chemical properties of EAF dust produced during the smelting of metallized pellets and captured by the dust and gas cleaning system of the steel-smelting shop at the Oskol Electrometallurgical Combine, Belgorod Region. The results obtained in the study of the chemical and disperse compositions of dust, the microstructure of the surface made it possible to propose the use of dust as a raw material for coagulant production. The conditions of acid-thermal treatment of dust are determined, contributing to the partial dissolution of iron (II), (III), and aluminium compounds, which ensure the coagulation processes during wastewater treatment. Model solutions show high efficiency (> 95 %) of water treatment from heavy metal ions by modified EAF dust.
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Date submitted2021-10-08
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Date accepted2022-01-24
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Date published2022-04-29
Methodology for thermal desorption treatment of local soil pollution by oil products at the facilities of the mineral resource industry
- Authors:
- Mariya A. Pashkevich
- Marina V. Bykova
The analysis of the main environmental consequences of leaks and local spills of petroleum products at the enterprises of the mineral resource complex is presented. It is established that the problem of soil contamination with petroleum products at the facilities of the mineral resource complex and enterprises of other industries is caused by significant volumes of consumption of the main types of oil products. Based on the results of the author's previous field research, a series of experiments was carried out, consisting in modeling artificial soil pollution with petroleum products such as gasoline, diesel fuel, highly refined oil, motor oil, and transmission oil, followed by their purification by heat treatment at temperatures of 150, 200, and 250 °C. The 250 °C limit of the heating temperature was set due to the need to partially preserve the structure and quality of the soil after heat treatment to preserve its fertility. When the processing temperature rises to 450 °C, all humates are completely burned out and, as a result, productivity is lost. Confirmation is provided by the results of experiments to determine the humus content in uncontaminated soil and soil treated at different temperatures. It was found that at a maximum processing temperature of 250 °C, about 50 % of the initial organic carbon content is preserved. According to the results of the conducted experimental studies, the dependences of the required processing temperature on the concentration of petroleum products to reduce the concentration of petroleum products to an acceptable level have been established. The methodology of thermal desorption cleaning of soils with varying degrees of contamination at enterprises of the mineral resource complex is presented.
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Date submitted2021-06-24
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Date accepted2021-10-18
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Date published2021-12-16
Modeling the acid treatment of a polymictic reservoir
- Authors:
- Mars M. Khasanov
- Andrey А. Maltcev
Acid treatment of wells program is directly related to oil production efficiency. Investigations aimed at improving the efficiency of acid treatment in a terrigenous reservoir have mainly reviewed the changing and adapting the reagents to minimize bridging caused by acid-rock interaction. Under real conditions, application of new and unique acid compositions is a complex process from an organizational point of view and is therefore not widely used as compared with conventional compositions based on a mixture of hydrochloric and hydrofluoric acids. The paper is based on an approach to improve acid treatment efficiency through optimal design based on near-bottomhole zone treatment simulation. The aspects for practical application of the developed acid treatment simulator for terrigenous reservoirs based on a numerical model of hydrodynamic, physical and chemical processes in a porous medium on an unstructured PEBI-grid are described. The basic uncertainties of the model are identified and analyzed. Influence of empirical parameters within the system of equations on the calculation results and modeling of the mineralogical composition of rocks are considered. Algorithm for static modelling of near-bottomhole zone for acid treatment modelling is described, as well as an approach to optimizing the design of near-bottomhole zone treatment based on adapting the results of rock tests in the model. Using experimental data, the necessity of accounting for influence of secondary and tertiary reactions on the results of modeling physical and chemical processes during acid treatment of terrigenous reservoirs was proved. The distinctive features of West Siberian objects (polymictic reservoirs) with respect to the efficiency of near-bottomhole zone treatment with clay acid have been investigated. Series of calculations to determine the optimum volume of acid injection has been carried out. Experience of previously conducted measures under the considered conditions has been analyzed and recommendations to improve the efficiency of acid treatment have been given.
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Date submitted2021-02-09
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Date accepted2021-07-27
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Date published2021-10-21
Development of an algorithm for determining the technological parameters of acid composition injection during treatment of the near-bottomhole zone, taking into account economic efficiency
Relevance of the research is due to the low proportion of successful hydrochloric acid treatments of near-bottomhole zones of carbonate reservoirs in the Perm region caused by insufficiently careful design and implementation of measures to stimulate oil production. Within the framework of this article, the development of a program is presented, which is based on an algorithm that allows determining the volume and rate of injection for an acid composition into a productive formation corresponding to the maximum economic efficiency during hydrochloric acid treatment. Essence of the proposed algorithm is to find the greatest profit from measures to increase oil recovery, depending on the cost of its implementation and income from additionally produced oil. Operation of the algorithm is carried out on the principle of enumerating the values of the volume and rate of injection for the acid composition and their fixation when the maximum difference between income and costs, corresponding to the given technological parameters of injection, is reached. The methodology is based on Dupuis's investigations on the filtration of fluids in the formation and the results of the experiments by Duckord and Lenormand on the study of changes in the additional filtration resistance in the near-well zone of the formation when it is treated with an acid composition. When analyzing and including these investigations into the algorithm, it is noted that the developed technique takes into account a large number of factors, including the lithological and mineralogical composition of rocks, technological parameters of the injection of a working agent and its properties, well design, filtration properties of the formation, properties of well products. The article provides an algorithm that can be implemented without difficulty using any programming language, for example, Pascal. Selection of the optimal values for the volume and rate of injection is presented in this paper, using the example of a production well at the Chaikinskoye oil field, located within the Perm region. Introduction of the developed algorithm into the practice of petroleum engineering will allow competent and effective approach to the design of hydrochloric acid treatments in carbonate reservoirs without a significant investment of time and additional funds.
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Date submitted2021-03-10
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Date accepted2021-05-21
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Date published2021-09-20
Influence of heat treatment on the microstructure of steel coils of a heating tube furnace
- Authors:
- Vladimir Yu. Bazhin
- Bashar Issa
Transportation and refining of heavy metal-bearing oil are associated with the problems of localized destruction of metal structures and elements due to corrosion. In the process of equipment operation, it was revealed that premature failure of steel coils of heating tube furnaces at oil refineries and petrochemical plants was associated with insufficient strength and corrosion resistance of the steelwork. The study of the effect that structure and phase composition of 15KH5M-alloy steel elements of heating furnaces at oil refineries have on the corrosion properties, associated with mass loss and localized destructions in the process of heat treatment, allows to develop protective measures and determine heating modes with a rate-limiting step of oxidation. The rate of various corrosion types of 15KH5M steel is used as an indicator to assess the effectiveness of the applied modes of coil heat treatment in order to increase their corrosion resistance and improve their operational characteristics. Conducted experiments on heat treatment of certain steel coil sections allowed to determine rational heating modes for the studied coils, which made it possible to reduce their mass loss and increase corrosion resistance of working surfaces in the process of operation. Proposed heat treatment of steel coils at specified intervals of their operation in the tube furnaces creates conditions for their stable performance and affects the degree of industrial and environmental safety, as well as reduces material costs associated with the repair and replacement of individual assemblies and parts of tube furnaces.
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Date submitted2020-06-19
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Date accepted2020-10-06
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Date published2020-11-24
Practice of using the magnetic treatment devices to intensify the processes of primary oil treating
During the primary treatment of oil, gas and water, complications arise associated with the presence of hard water-oil emulsions, which cause an increase in fluid pressure in the gathering systems, pipeline damage, as well as difficulties in gas separation and preliminary water discharge at the preliminary discharge unit (PRU). Additional problems arise during transportation of highly paraffinic oils associated with the crystallization of paraffin in the flow path of the oilfield equipment and on the inner surface of pipes, leading to a drop in the productivity of pipelines. Article discusses the technology of magnetic-reagent treatment of water-oil media, which allows intensifying the processes of primary oil treatment at the facilities of its production. Bench and pilot tests have shown the ability of the magnetic field to accelerate oil demulsification processes, increasing the percentage of separated water during subsequent settling, and to reduce asphalt-resin-paraffin deposits (ARPD) on the inner surface of oil and gas field equipment. Mechanism of the magnetic field effect on water-oil media is described. Effect of treatment on the integrity of the armour shells of oil-water emulsions was studied. Various modes of magnetic treatment have been investigated with evaluation of its effectiveness. It is shown that the best effect is achieved with the combined use of reagents and a magnetic field. Synergistic effect is observed, which consists in increasing their effectiveness. This made it possible to conclude that this method can be applied to reduce the consumption of reagents used in oil production while maintaining the treatment efficiency.
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Date submitted2020-04-15
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Date accepted2020-05-13
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Date published2020-10-08
Processing of platinum group metal ores in Russia and South Africa: current state and prospects
- Authors:
- Tatyana N. Aleksandrova
- Cyril О’Connor
The presented study is devoted to a comparative review of the mineral raw material base of platinum group metals (PGMs) and technologies of their processing in South Africa and Russia, the largest PGM producers. Mineralogical and geochemical classification and industrial value of iron-platinum and platinum-bearing deposits are presented in this work. The paper also reviews types of PGM ore body occurrences, ore processing methods (with a special focus on flotation processes), as well as difficulties encountered by enterprises at the processing stage, as they increase recovery of the valuable components. Data on mineralogical features of PGM deposits, including the distribution of elements in the ores, are provided. The main lines of research on mineralogical features and processing of raw materials of various genesis are identified and validated. Sulfide deposits are found to be of the highest industrial value in both countries. Such unconventional PGM sources, as black shale, dunites, chromite, low-sulfide, chromium and titanomagnetite ores, anthropogenic raw materials, etc. are considered. The main lines of research that would bring into processing non-conventional metal sources are substantiated. Analysis of new processing and metallurgical methods of PGM recovery from non-conventional and industrial raw materials is conducted; the review of existing processing technologies for platinum-bearing raw materials is carried out. Technologies that utilize modern equipment for ultrafine grinding are considered, as well as existing reagents for flotation recovery; evaluation of their selectivity in relation to platinum minerals is presented. Basing on the analysis of main technological processes of PGM ore treatment, the most efficient schemes are identified, i.e.,gravity and flotation treatment with subsequent metallurgical processing.
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Date submitted2019-06-02
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Date accepted2019-09-02
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Date published2020-04-24
Sorption of nickel (II) and manganese (II) ions from aqueous solutions
Mine water from non-ferrous metal deposits is often contaminated with nickel and manganese ions. The entry of these ions, especially nickel, into surface waters and underground aquifers is undesirable since it has a negative effect on living organisms and worsens the condition of drinking water sources. One of the promising methods for selectively extracting nickel ions and obtaining an eluate suitable for further use is sorption by weakly acid cation exchangers with chelate groups of iminodiacetic acid. As part of the study, sorption isotherms of nickel and manganese ions by Lewatit MonoPlus TP 207 cation exchanger in mono- and bicomponent systems were obtained. In monocomponent systems, the maximum static exchange capacity (SEC) of the cation exchanger for nickel ions is 952 mmol/dm 3 , and in bicomponent systems – 741 mmol/dm 3 ; for manganese ions– 71 mmol/dm 3 and 49 mmol/dm 3 , respectively. It is obvious that the studied cation exchanger has a greater capacity for nickel ions than for manganese ions. The influence of a temperature increase from 300 to 330 K on the sorption of nickel and manganese ions was established: in monocomponent systems, the maximum degree of extraction of the former increases from 65 to 77 % (SEC from 337 to 399 mmol/dm 3 ), and the latter from 21 to 35 % (SEC – from 140 to 229 mmol/dm 3 ); in bicomponent systems, the extraction of nickel ions increases from 59 to 78 % (SEC – from 307 to 429 mmol/dm 3 ), and manganese ions decreases from 20 to 17 % (SEC – from 164 to 131 mmol/dm 3 ). The predominant increase in the indicators is due to the filling of the sorption centers of the ion-exchange resins, which are energetically unfavorable for the exchange of counterions at a lower temperature. The influence of the pH of the solution on sorption was determined: the intensification of the process for nickel ions is observed in the pH range of 8.0-8.5 in a monocomponent solution and 8.0-9.0 in a bicomponent solution, for manganese ions in the range of 8.0-9.5 in both cases. The increase in the degree of extraction of ions and the exchange capacity of the ion exchanger with increasing pH is associated with the appearance of singly charged hydroxocations, dissociation of the functional groups of the sorbent and, to some extent, with the subsequent formation of insoluble forms of nickel and manganese. However, with increasing pH, a decrease in the selectivity of nickel extraction is observed: the ion separation coefficient decreases from 14.0 to 6.0 in the pH range of 6.0-11.0.
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Date submitted2019-05-20
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Date accepted2019-07-12
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Date published2019-10-23
Development of Manufacturing Technology for High-Strength Hull Steel Reducing Production Cycle and Providing High-Quality Sheets
The article presents the results of scientific research and industrial experiments aimed at the development of technology to reduce the production cycle of high-strength hull steel. The technology includes an improved reduced heat treatment of ingots made using rare-earth metals and uphill teeming of large sheet ingots. The proposed technology for the preliminary heat treatment of ingots eliminates the high-temperature phase re- crystallization operation, which is unnecessary, according to the authors, since it does not allow partial crushing (grinding) of the metal dendritic structure and homogenization. When using the proposed technology of reduced pre- treatment, phase and structural stresses are sharply reduced. Experiments have shown that the modification of steel with rare-earth metals has a positive effect on the crystallization of ingots, changing the macro- and microstructure of alloy steel. The developed manufacturing technology of high-strength hull steel provides a high level of sheet quality and a reduction in the production cycle time by 10-12 %.
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Date submitted2019-03-11
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Date accepted2019-05-11
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Date published2019-08-23
Estimate of Radial Drilling Technology Efficiency for the Bashkir Operational Oilfields Objects of Perm Krai
- Authors:
- S. V. Galkin
- A. A. Kochnev
- V. I. Zotikov
The radial drilling technology efficiency for carbonate bashkir deposits of Perm Krai is considered. The geological structure of a productive part of bashkir layer is characterized by high degree of heterogeneity that promotes while drilling radial channels involvement in development additional interlayers that earlier was not drained. During the analysis the main geological process parameters affecting drilling technology efficiency were revealed. According to the dynamics of average daily oil production growth, palettes were built to forecast additional oil production as a result of radial drilling activities. Using the pallets, it is possible to predict the total additional oil production, well operating time with the effect of radial drilling and average daily oil production growth for each year. It was found that hydrochloric acid treatments performed on wells prior to radial drilling significantly reduce the effectiveness of radial drilling technology. For such wells, the value of the correction is statistically substantiated, which reduces the predictive estimate of the increase in oil production. A model was built to assess the increase in oil production in the first year after the event and an algorithm for calculating the total additional oil production was developed using linear discriminant analysis. For the resulting model, errors are calculated that are compared with the forecast efficiency of standard methods for oil-producing enterprises. This model shows a much more accurate correspondence of forecast results to actual technology application results. The probability of the event high efficiency increases significantly with a more detailed approach to the selection of wells for radial drilling. According to the forecast methodology, the technology’s efficiency was calculated and recommendations for its implementation for the wells of the Bashkir production objects were made in the interests of an oil-producing enterprise.
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Date submitted2018-10-28
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Date accepted2018-12-30
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Date published2019-04-23
Development and research of formation technologies on specialized presses with subsequent sintering of high-density details from iron-based powders
- Authors:
- A. M. Dmitriev
- N. V. Korobov
- A. Zh. Badalyan
Creating shifts of the lyaers in a deforming workpieces improves the quality of the product produced by pressure treatment. qual-channel angular pressing and precipitations of a cylindrical billet with a rotating turnaround were developed by specialists earlier and became basic for scientists engaged in nanotechnology. One of the most modern schemes for creating nanostructures by processing on presses is the «Cyclic Extrusion Compression» scheme (in Russia – «Hourglass»), which has significant drawbacks. To date, research on the creation of layer shifts in compacted metal powders is substantially less than in compaction of compact blanks. The article developed compaction schemes for presses of blanks from iron-based powders that have a certain analogy with the «Hourglass», while lacking the disadvantages inherent in the named scheme and implemented on the created samples of specialized hydraulic presses. The results of the studies of density, strength and microhardness before sintering the samples molded from a number of domestic and imported powders on iron base, including those doped with carbon and other alloying components, are described. It has been established that with the use of the formation schemes for powders providing large shifts between particles, the density of the preforms increases on average by 10-12 %. With an average stress (16.32 MPa) of the transverse section of the molded specimen prior to its sintering, molding with shifts between particles increases this stress by 78 %. The strength after sintering of samples made using the compaction schemes developed by the authors of the article increases approximately by 2 times. Magnetic pulse treatment (MPT) of a molded sample prior to its sintering increases its resistance to shearing before sintering, regardless of the molding pattern. When MPT of both the powder and the molded sample is executed, the most uniform distribution of microhardness in the sample is achieved, and after subsequent sintering, the most uniform distribution of the mechanical characteristics of the product. The results of all studies are described by regression equations.
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Date submitted2018-06-27
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Date accepted2018-08-31
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Date published2018-12-21
Numerical modeling of a stress-strain state of a gas pipeline with cold bending offsets according to in-line inspection
Knowledge of the current stress-strain state of any section of the pipeline allows you to make informed decisions on its operation, maintenance and repair, as well as on the prediction of the technical condition. The task of determining the characteristics of the stress-strain state of a gas pipeline section that has cold bend offsets (CBO) according to in-line inspection (ILI) is considered. The bent part of CBO is characterized by the presence of residual stresses and deformations in the wall of the offset, which contribute to the overall level of the stress-strain state of the gas pipeline operating under external and internal loads. Using the results of in-line diagnostics, numerical modeling and a solution, the change in the values of longitudinal stresses, is determined and the need to take into account residual stresses in the zone of elastic-plastic deformations of cold bend offsets is shown.