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Date submitted2022-03-01
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Date accepted2024-06-03
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Date published2024-12-25
Study of the possibility of using high mineralization water for hydraulic fracturing
The results of laboratory studies aimed at developing hydraulic fracturing fluid based on alternative sources of high mineralization water are presented. It is shown that Cenomanian sources have the most stable mineralization parameters, while bottom water and mixed waters collected from pressure maintenance systems differ significantly in their properties, with iron content varying several times, and hardness and mineralization undergoing substantial changes. The quality of the examined hydraulic fracturing fluids based on alternative water sources is confirmed by their impact on residual permeability, as well as residual proppant pack conductivity and permeability. The experimental results show similar values for these parameters. The comprehensive laboratory studies confirm the potential for industrial use of high mineralization water in hydraulic fracturing operations.
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Date submitted2024-04-16
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Date accepted2024-06-03
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Date published2024-07-04
Quantitative determination of sulfur forms in bottom sediments for rapid assessment of the industrial facilities impact on aquatic ecosystems
- Authors:
- Ivan P. Sverchkov
- Vladimir G. Povarov
The article describes an X-ray fluorescence method for quantitative analysis of sulfate and total sulfur in bottom sediments of watercourses and reservoirs located in the area of industrial enterprises impact. The quantitative determination of sulfur forms was carried out by analyzing the characteristic curves SKα1,2 and SKβ1,3, as well as the satellite line SKβ′ on X-ray emission spectra measured by an X-ray fluorescence spectrometer with wavelength dispersion. The study shows that these characteristic curves allow not only to determine the predominant form of sulfur, but also to separately conduct quantitative analyses of sulfates and total sulfur after fitting peaks and to separately analyze overlapping spectral lines. The results of quantitative analysis of the chemical state of sulfur by the proposed X-ray fluorescence method were compared with the results of inductively coupled plasma atomic emission spectroscopy and elemental analysis, as well as certified standard samples of soils and sediments. The results are in good agreement with each other.
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Date submitted2024-03-30
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Date accepted2024-06-13
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Date published2024-07-04
Organotin pollutants in emerging coastal-marine sediments of the Kaliningrad shelf, Baltic Sea
Based on two years of monitoring of modern bottom sediments of two sections of the Kaliningrad shelf of the Baltic Sea – “Curonian Spit” and “Northern Sambian” – an assessment of the sources of pollution with organotin compounds (OTs) and heavy metals was carried out. The content of individual organotin compounds and OTCs spectra obtained by gas chromatography with mass spectrometry of relatively coarse-grained bottom sediments indicate the presence of organotins in significant quantities – the total OTs content (ΣOTs) is from 0.6 to 8.3 ng/g. However, the content of tributyltin (TBT), the main component of anti-fouling systems for marine vessels and the most dangerous endocrine-disrupting compound among the hazardous substances for marine ecosystems, is at a low level (0-2.3 ng/g) in all studied samples and has not increased over the two-year observation period (biodegradation index 1.7-12.4). At the same time, the presence of abnormally high concentrations of mono-, triphenyl- and tricyclohexyltin in the sediments of the ”Northern Sambian” site (up to 30, 7 and 6.4 ng/g, respectively) indicates an additional source of pollution of coastal waters and shelf sediments (for example, plastic litter and agricultural runoff). The absence of significant shipping in the study areas ensures a consistently low level of pollution with tributyltin and its derivatives (less than 0.3 and 2.3 ng/g of TBT in 2017 and less than 0.1 and 1.3 ng/g in 2018 for the sites “Curonian Spit” and “Northern Sambian”, respectively), which indicates the activity of the processes of TBT transformation and self-cleaning of sandy sediments. However, the identified trends and their predictive accuracy require long-term observation and monitoring of the sediment environment using data on the deep-water part of the shelf, enriched in clay and humus components.
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Date submitted2024-04-09
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Date accepted2024-06-03
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Date published2024-07-04
Analysis of the geochemical barriers effectiveness as the basis for the use of nature-like water purification technologies
Nature-like technologies are being introduced into many human activities including mining wastewater treatment. This work is based on long-term studies of the Sibay copper-zinc-pyrite deposit development. It is dedicated to assessment of geochemical barriers effectiveness in Cu, Zn, Cd removal from water of the Karagayly River (receiving quarry and dump drainage water). The research is based on the elements’ content and forms in water and bottom sediments, pH values etc. Four types of hydrogeochemical environment (formed due to changes in the water use over the past 20 years) were distinguished using discriminant analysis. The mechanisms of barriers formation and destruction were described. Statistical modeling of the metals’ precipitation was performed by multivariate regression analysis. Cu is adsorbed by recently formed Fe hydroxides, and, to a lesser extent, precipitates with sulfates as water pH increases. Antagonism to Mn hydroxides has been demonstrated, due to different physicochemical conditions for their precipitation. Zn enters solid phase mainly with sulfates, this element also forms its own mineral phases. The second mechanism is adsorption by recently formed Mn hydroxides, which corresponds to the idea of similar conditions for the precipitation of metal hydroxides. Cd behavior reflects conditions intermediate between these of Cu and Zn. Contribution of both mechanisms (related to Fe hydroxides and aqueous sulfates) is equal. Antagonism to Mn is absent. According to the assessment results using of nature-like technologies in situ in watercourses, canals and other water drainage systems is promising. Developed statistical models can be used for needs of experimental studies and artificial geochemical barriers engineering.
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Date submitted2023-04-13
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Date accepted2023-10-25
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Date published2025-02-25
Assessment of the ecological state of aquatic ecosystems by studying lake bottom sediments
- Authors:
- Mariya A. Chukaeva
- Tatyana V. Sapelko
The article presents the results of coupled palynological and geochemical studies of five various genesis lakes, located along the route of the expedition “In the footsteps of Alexander von Humboldt in Siberia, Altai and Eastern Kazakhstan”, dedicated to the double anniversary: the 190th anniversary of the expedition across Russia of the famous scientist and his 250th birthday. A geochemical analysis of water and bottom sediments of Ik Lake (Siberia), Lakes Kolyvanskoe and Beloe (Altai), Lake Bezymyannoe (Kazakhstan) and Nagornyi Pond (Altai) was carried out. Based on their results an assessment of studied lakes ecological state was given through single and integral criteria. A high level of pollution was noted for Nagornyi Pond and Lake Bezymyannoe, which is caused by a significant technogenic load from nearby mines. This is consistent with the data of palynological research. The aquatic ecosystems of Lakes Kolyvanskoe and Beloe are characterized by a satisfactory ecological situation, but they experience an increased recreational load. The results of spore-pollen analysis and analysis of non-pollen palynomorphs showed the low ability of these lakes to self-healing. The most favorable ecological state and high self-cleaning capacity were noted for Lake Ik, which is consistent with the data of palynological studies. It is being confirmed with the results of palynological studies. It was therefore concluded about the ability to make a quick assessment of the aquatic ecosystems’ ecological state by studying lakes using coupled palynological and geochemical analysis.
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Date submitted2022-09-30
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Date accepted2023-04-03
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Date published2024-02-29
Optimization of the location of a multilateral well in a thin oil rim, complicated by the presence of an extensive gas cap
- Authors:
- Кirill О. Тomskii
- Mariya S. Ivanova
The specific share of the reserves of hard-to-recover hydrocarbon raw materials is steadily growing. The search for technologies to increase the hydrocarbon recovery factor is one of the most urgent tasks facing the oil and gas industry. One of the methods to expand the coverage of oil reserves and increase oil recovery is to use the technology of drilling multilateral wells with a fishbone trajectory. In the Russian Federation, the most branched well was drilled in the Republic of Sakha (Yakutia) at the Srednebotuobinskoye oil and gas condensate field. The main object of development is the Botuobinsky horizon (Bt reservoir). About 75 % of the geological reserves of the reservoir are concentrated in a thin oil rim with an average oil-saturated layer thickness of 10 m with an extensive gas cap. This circumstance is one of the main complicating factors in the development of the Srednebotuobinskoye oil and gas condensate field. For such complex wells, one of the most important design stages is to determine the optimal location of the fishbone well in an oil-saturated reservoir. The article shows the results of sector modeling in the conditions of the Srednebotuobinskoye field to determine the optimal location of multilateral wells using Tempest simulator.
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Date submitted2022-09-26
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Date accepted2023-03-23
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Date published2023-12-25
A new diamond find and primary diamond potential of the Chetlas uplift (Middle Timan)
In the previously poorly studied southeastern part of the Chetlas uplift in the Middle Timan, a new occurrence of diamond satellite minerals and a diamond grain were found in the modern channel sediments of the Uvuy River basin. In order to assess the prospects of the area under consideration for identification of diamondiferous objects of practical interest, a characteristic of chromium-bearing pyropes and chromospinelides as the main kimberlite of diamond satellite minerals are given and the diamond grain itself is described. The material for the research was 16 schlich samples, each with a volume of 8 to 15 l. The minerals were studied using optical and scanning electron microscopy, Raman spectroscopy, laser luminescence and X-ray diffraction (Debye – Sherrer method). It is shown that among the pyropes, most of which correspond in composition to minerals of the lherzolite paragenesis, there are varieties belonging to the dunite-harzburgite paragenesis, including those belonging to diamond phase stability regions. Among the studied chromospinelides, chrompicotites and aluminochromites similar in composition to those found in rocks such as lherzolites and harzburgites, as well as in kimberlites, were identified. A diamond grain found in one of the samples has the form of a flattened intergrowth with distinct octahedron faces, complicated by co-growth surfaces with other mineral grains that have not been preserved to date. The discovery of the diamond and the established signs the formation of aureoles of the diamond satellites minerals in the channel sediments of the studied area open up the prospects for discovering their primary sources here.
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Date submitted2022-11-02
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Date accepted2023-03-02
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Date published2023-04-25
Environmental damage from the storage of sulfide ore tailings
The mining industry is one of the most challenging in ensuring environmental safety. During the last century, the Karabash Copper Smelting Plant was processing sulfide ores and depositing the tailings into storage facilities that now occupy an area of more than 50 hectares. To date, abandoned tailings are a significant source of natural water, air, and soil pollution in the Karabash city district. The article comprehensively examines the environmental impact of the Karabashmed copper smelter, one of the oldest metallurgical enterprises in Russia. The effects of seepage from the two Karabashmed tailings facilities on water resources were assessed. We revealed that even outside the area of the direct impact of processing waste, the pH of natural water decreases to values 4-5. Further downstream, the infiltration water from the tailings pond No. 4 reduces the pH of river water to 3.0-3.5. The presented results of environmental engineering surveys are derived from sampling water and bottom sediments of the Ryzhiy Stream and the Sak-Elga River, sample preparation, and quantitative chemical analysis. The study revealed significant exceedances of the maximum permissible concentrations for a number of chemical elements in the impact zone of the copper ore processing tailings.
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Date submitted2022-05-26
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Date accepted2022-11-17
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Date published2022-12-29
Renovation method of restoring well productivity using wavefields
A stagewise theoretical substantiation of the renovation vibrowave method of influencing the near-wellbore zone of reservoir for restoring well productivity is presented. The area of treatment by the proposed method covers the reservoir with a heterogeneous permeability with fractures formed by fracking. In this method a decrease in concentration of colmatants occurs due to a change in direction of contaminants migration. Under the influence of pressure pulses, they move deep into the reservoir and disperse through the proppant pack. The results of mathematical modelling of the propagation of pressure wave and velocity wave and the calculations of particles entrainment in wave motion are presented.
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Date submitted2022-03-14
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Date accepted2022-06-20
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Date published2022-11-10
Model of a walking sampler for research of the bottom surface in the subglacial lake Vostok
Technologies and technical means for investigation of subglacial lakes in Antarctic is a new developing scientific and technical direction, which today has no clearly established methodology. Based on the developed technology of drilling a new access well to lake Vostok and its penetration as well as analysis of existing methods and devices for bottom sediment sampling, a basic model of a sampler with a walking-type mover, capable of moving along different trajectories and operating in a wide technological range, is proposed. The proposed device model is equipped with different actuators for sampling the bottom surface with different physical and mechanical properties. Based on the presented basic model of the walking sampler, a mathematical model of the device was developed, which was based on the theoretical mechanics methods. As a result of conducted research the dependencies were obtained, which allow making a scientifically justified choice of optimal values for geometric and force parameters of the walking sampler. A conceptual design of the walking sampler has been developed, taking into account the mutual location and coupling of its main components, the overall dimensions of the delivery tool, as well as the esthetic component of the device.
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Date submitted2021-10-19
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Date accepted2021-11-30
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Date published2021-12-27
Potential technological solution for sampling the bottom sediments of the subglacial lake Vostok: relevance and formulation of investigation goals
The subglacial Lake Vostok in Antarctic is a unique natural phenomenon, its comprehensive study involves sampling of water and bottom surface rocks. For further study of the lake, it is necessary to drill a new access well and develop environmentally safe technologies for its exploration. This article discusses existing and potential technologies for sampling bottom surface rocks of subglacial lakes. All these technologies meet environmental safety requirements and are conducive for sampling. The authors have proposed an alternative technology, using a walking device, which, due to its mobility, enables selective sampling of rocks across a large area from a single access well. The principal issues, related to the implementation of the proposed technology, are investigated within this article. This report is prepared by a team of specialists with many years of experience in drilling at the Vostok Station in Antarctic and in experimental work on the design of equipment and non-standard means of mechanization for complicated mining, geological and climatic conditions.
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Date submitted2021-06-24
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Date accepted2021-10-18
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Date published2021-12-16
Modeling the acid treatment of a polymictic reservoir
- Authors:
- Mars M. Khasanov
- Andrey А. Maltcev
Acid treatment of wells program is directly related to oil production efficiency. Investigations aimed at improving the efficiency of acid treatment in a terrigenous reservoir have mainly reviewed the changing and adapting the reagents to minimize bridging caused by acid-rock interaction. Under real conditions, application of new and unique acid compositions is a complex process from an organizational point of view and is therefore not widely used as compared with conventional compositions based on a mixture of hydrochloric and hydrofluoric acids. The paper is based on an approach to improve acid treatment efficiency through optimal design based on near-bottomhole zone treatment simulation. The aspects for practical application of the developed acid treatment simulator for terrigenous reservoirs based on a numerical model of hydrodynamic, physical and chemical processes in a porous medium on an unstructured PEBI-grid are described. The basic uncertainties of the model are identified and analyzed. Influence of empirical parameters within the system of equations on the calculation results and modeling of the mineralogical composition of rocks are considered. Algorithm for static modelling of near-bottomhole zone for acid treatment modelling is described, as well as an approach to optimizing the design of near-bottomhole zone treatment based on adapting the results of rock tests in the model. Using experimental data, the necessity of accounting for influence of secondary and tertiary reactions on the results of modeling physical and chemical processes during acid treatment of terrigenous reservoirs was proved. The distinctive features of West Siberian objects (polymictic reservoirs) with respect to the efficiency of near-bottomhole zone treatment with clay acid have been investigated. Series of calculations to determine the optimum volume of acid injection has been carried out. Experience of previously conducted measures under the considered conditions has been analyzed and recommendations to improve the efficiency of acid treatment have been given.
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Date submitted2021-03-16
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Date accepted2021-07-27
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Date published2021-10-21
Allocation of a deep-lying brine aquifer in the rocks of a chemogenic section based on the data of geophysical well logging and 2D seismic exploration
Advancement in the production of potassium fertilizers is an important strategic task of Russian agricultural industry. Given annually growing production rates, the reserves of discovered potassium-magnesium salt deposits are noticeably decreasing, which creates the need to ensure stable replenishment of the resource base through both the discovery of new deposits and the exploitation of deep-lying production horizons of the deposits that are already under development. In most cases, deposits of potassium-magnesium salts are developed by underground mining. The main problem for any salt deposit is water. Dry salt workings do not require any additional reinforcement and can easily withstand rock pressure, but with an inflow of water they begin to collapse intensively – hence, special attention is paid to mine waterproofing. Determination of spatial location, physical and mechanical properties of the aquifer and water-blocking stratum in the geological section represent an important stage in the exploration of a salt deposit. The results of these studies allow to validate an optimal system of deposit development that will minimize environmental and economic risks. On the territory of Russia, there is a deposit of potassium-magnesium salts with a unique geological structure – its production horizon lies at a considerable depth and is capped by a regional aquifer, which imposes significant limitations on the development process. To estimate parameters of the studied object, we analyzed the data from CDP seismic reflection survey and a suite of methods of radioactive and acoustic well logging, supplemented with high-frequency induction logging isoparametric sounding (VIKIZ) data. As a result of performed analysis, we identified location of the water-bearing stratum, estimated average thickness of the aquifers and possible water-blocking strata. Based on research results, we proposed methods for increasing operational reliability of the main shaft in the designed mine that will minimize the risks of water breakthrough into the mine shaft.
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Date submitted2020-09-09
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Date accepted2021-03-29
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Date published2021-09-20
Developing features of the near-bottomhole zones in productive formations at fields with high gas saturation of formation oil
The article studies the formation features of the bottomhole zones in productive formations during operation of production wells in the north of the Perm Territory. Their distinctive feature is the high gas saturation of formation oil. The most widely used parameter in Russian and world practice – the skin factor was used as a criterion characterizing the state of the bottomhole zone. Analysis of scientific publications has shown that one of the main problems of applying the skin factor to assess the state of bottomhole zones is the ambiguity of interpretations of its physical meaning and the impossibility of identifying the prevailing factors that form its value. The paper proposes an approach to identifying such factors in the conditions of the fields under consideration, based on multivariate correlation-regression analysis. Choice of this tool is due to the complexity of the processes occurring in the “formation – bottomhole zone – well” system. When describing complex multifactorial processes, the chosen method demonstrates a high degree of reliability. For a large number of wells in the region, significant material was collected and summarized, including the results of determining the skin factor (1102 values) during hydrodynamic investigations, as well as data on the values of various geological and technological indicators, which can probably be statistically related to the value of the skin factor. A series of multidimensional mathematical models has been built; the skin factor was used as a predicted parameter, and data on the values of geological and technological indicators were used as independent indicators. Analysis of the constructed models is a key stage of this study. Set of parameters included in the multidimensional models, sequence of their inclusion and contribution to the total value of the achieved determination coefficient as the main indicator for the performance of the constructed models were studied. It has been established that the main factor influencing the state of the bottomhole zone is oil degassing. Significant differences in the formation features of the skin factor in the terrigenous and carbonate sediments at the fields under consideration have been determined.
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Date submitted2019-09-25
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Date accepted2019-12-20
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Date published2020-04-24
Study of the well near-bottomhole zone permeability during treatment by process fluids
- Authors:
- Evgenii A. Rogov
In the process of drilling-in productive horizons, several irreversible physical and chemical processes take place in the near-wellbore zone of the formation: stress state of the rocks changes, penetration of the filtrate and solid phase, as well as drilling mud into the reservoir, and swelling of clay particles of intergranular cementing material are observed. As a result, permeability of productive horizon is significantly reduced and, consequently, potential inflow of oil or gas from formation is excluded. An equally serious problem exists during well servicing and workover, when the use of irrational fluids of well killing causes negative consequences associated with deterioration of reservoir properties of formations in the wells being repaired. Article presents the results of the experiments on permeability of clayed porous samples after exposure to various compositions of liquids. In order to increase permeability of near-borehole zone of the formation and increase productivity of wells completed by drilling, and after well servicing and workover, a composition of the process fluid containing a 15 % aqueous solution of oxyethylene diphosphonic acid (OEDA) with addition of a surfactant is proposed.
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Date submitted2018-09-21
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Date accepted2018-11-19
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Date published2019-02-22
Feasibility of type of deep-water technologies for the extraction of marine ferro-manganese nodules
- Authors:
- D. A. Yungmeister
- S. M. Sudarikov
- K. A. Kireev
The conditions for the occurrence of near bottom minerals presented in the form of sulphides (the Logachev deposit) and ferro-manganese nodules (The conditions for the occurrence of benthic minerals presented in the form of sulphides (the Logachev deposit) and ferro-manganese nodules (FMN) are considered. An analysis of the structures and parameters of various means of collecting and transporting sulphides and iron ore from the bottom to the surface is given, and the possibility of effectively using vessel lifting on a cable-rope is indicated. Structural schemes for collecting FMN and sulphides in the form of containers on a cable, equipped with manipulators with gripping devices of a disc, drum or clamshell type, are proposed. In them, the capture of rock pieces or FMN is carried out by creating a vacuum in the collectors of the executive bodies and attracting to them pieces of rock or FMN by a pressure drop of water inside and outside the reservoir. It was given the approximate parameters of the mining system. So, for a cable-rope made of kevlar with a diameter of 50 mm, the capacity can be 200-400 thousand tons per year for one installation with different specific mass concentration of FMN per 1 m 2 ) are considered.
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Date submitted2018-01-17
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Date accepted2018-03-09
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Date published2018-06-22
Control and regulation of the hydrochloric acid treatment of the bottomhole zone based on field-geological data
- Authors:
- M. K. Rogachev
- V. V. Mukhametshin
The analysis results of the hydrochloric acid treatment of the bottomhole zone efficiency along the deposits of high-viscosity oil in the carbonate reservoirs of the Tournaisian stage are presented in the paper. Based on the use of the non-parametric Kulbak criterion, the most informative geological and technological parameters, which affect most the success of hydrochloric acid treatments, assessed by the criteria of increased oil production and reduced water cut, are revealed. The generalization of the hydrochloric acid treatments experience in the conditions of the high-viscosity oil reservoirs of the Tournaisian Stage allows for efficient forecasting, selection of wells, control and regulation of the treatment process to reduce the number of inefficient operations and improve the technical and economic parameters of fuel and energy enterprises at the investigated sites and the ones with similar field-geological characteristics.
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Date submitted2016-11-21
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Date accepted2017-01-23
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Date published2017-04-14
Prospects of obtaining samples of bottom sediments from subglacial lake Vostok
- Authors:
- N. I. Vasilev
- G. L. Leichenkov
- E. A. Zagrivnyi
The paper proves the timeliness of obtaining and examining bottom sediments from subglacial Lake Vostok. Predictive geological section of Lake Vostok and information value of bottom sediments have been examined. Severe requirements towards environmental security of lake examinations and sampling of bottom sediments rule out the use of conventional drilling technologies, as they would pollute the lake with injection liquid from the borehole. In order to carry out sampling of bottom sediments from the subglacial lake, it is proposed to use a dynamically balanced tool string, which enables rotary drilling without any external support on borehole walls to transmit counter torque. A theoretical analysis has been carried out to assess the operation of the tool string, which is a two-mass oscillatory electromechanical system of reciprocating and rotating motion (RRM) with two degrees of freedom.
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Date submitted2014-11-04
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Date accepted2015-01-20
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Date published2015-10-26
Stability of productive well operation in a steam hydrothermal field
- Authors:
- A. N. Shulyupin
A condition of well operation stability based on agreement of indicator characteristics of well and aquifer throughput capacity is considered. Two hypotheses of the stability state are examined: with one and two possible combinations of characteristics. It is shown that taking into account resistance between the wellhead and the environment with constant pressure helps explain all the features of wellhead pressure and flow-rate relationship of steam-water wells based on the hypothesis with one combination (when the operating point is located on the ascending branch of a well characteristic). The throttling effect on the wellhead which was used in the development of the Mutnovka steam hydrothermal field in order to stabilize the well operation is explained.
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Date submitted2009-08-19
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Date accepted2009-10-02
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Date published2010-02-01
The estimation features of vulnerability and desintegration оf subway construction materials in Saint Petersburg
- Authors:
- P. V. Kotyukov
In this paper the features of subway construction materials degradation depending on engineering-geological, hydro-geological and geoecological conditions of Saint Petersburg underground space are considered. The basic types of subway construction placing and their destruction specificity depending on influence of water-bearing horizons hydrodynamic and hydro chemical conditions, natural and natural-technogenic gas bio-production and microbial activity are analyzed. The examples of the disintegrated materials and new growths (salt efflorescence, stalactites and others) chemical compound features depending on the content of ground waters basic components affecting on tunnels lining are resulted.