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Date submitted2024-04-09
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Date accepted2024-06-03
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Date published2024-07-04
Analysis of the geochemical barriers effectiveness as the basis for the use of nature-like water purification technologies
Nature-like technologies are being introduced into many human activities including mining wastewater treatment. This work is based on long-term studies of the Sibay copper-zinc-pyrite deposit development. It is dedicated to assessment of geochemical barriers effectiveness in Cu, Zn, Cd removal from water of the Karagayly River (receiving quarry and dump drainage water). The research is based on the elements’ content and forms in water and bottom sediments, pH values etc. Four types of hydrogeochemical environment (formed due to changes in the water use over the past 20 years) were distinguished using discriminant analysis. The mechanisms of barriers formation and destruction were described. Statistical modeling of the metals’ precipitation was performed by multivariate regression analysis. Cu is adsorbed by recently formed Fe hydroxides, and, to a lesser extent, precipitates with sulfates as water pH increases. Antagonism to Mn hydroxides has been demonstrated, due to different physicochemical conditions for their precipitation. Zn enters solid phase mainly with sulfates, this element also forms its own mineral phases. The second mechanism is adsorption by recently formed Mn hydroxides, which corresponds to the idea of similar conditions for the precipitation of metal hydroxides. Cd behavior reflects conditions intermediate between these of Cu and Zn. Contribution of both mechanisms (related to Fe hydroxides and aqueous sulfates) is equal. Antagonism to Mn is absent. According to the assessment results using of nature-like technologies in situ in watercourses, canals and other water drainage systems is promising. Developed statistical models can be used for needs of experimental studies and artificial geochemical barriers engineering.
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Date submitted2023-04-11
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Date accepted2023-10-25
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Date published2024-07-04
Acid mine water treatment using neutralizer with adsorbent material
One of the biggest issues in the mining sector is due to acid mine drainage, especially in those abandoned mining operations and active ones that fail to adequately control the quality of their water discharge. The removal degree of copper, iron, lead, and zinc dissolved metals in acid mine drainage was investigated by applying different proportions of mixtures based on neutralizing reagent hydrated lime at 67 % calcium oxide (CaO), with adsorbent material – natural sodium bentonite, compared to the application of neutralizing reagent without mixing, commonly used in the neutralization of acid mining drainage. The obtained results show that the removal degree of dissolved metals in acid mine drainage when treated with a mixture of neutralizing reagent and adsorbent material in a certain proportion, reaches discharge quality, complying with the environmental standard (Maximum Permissible Limit), at a lower pH than when neutralizing material is applied without mixing, registering a net decrease in the consumption unit of neutralizing agent express on 1 kg/m3 of acid mine drainage. Furthermore, the sludge produced in the treatment with a mixture of the neutralizing reagent with adsorbent material has better characteristics than common sludge without bentonite, since it is more suitable for use as cover material, reducing the surface infiltration degree of water into the applied deposit.
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Date submitted2022-07-15
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Date accepted2022-12-13
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Date published2023-02-27
Mathematical modelling of displacement during the potash ores mining by longwall faces
In favourable mining conditions, in particular at the Starobinskoye potash deposit (Belarus), longwall mining systems are used. They cause a high human-induced load on the subsoil, including intense deformation of the ground surface. The presented investigations are aimed at studying the dynamics of the ground surface displacement during the longwall face advance. Mathematical modelling was carried out in an elastic-plastic formulation with numerical implementation by the finite element method. The condition for the roof rocks collapse was opening of the contact between the seams when its boundaries were reached by shear fractures or formation of the tensile stresses area at the outcrop. With the working front advance, an increase in subsidence is observed, followed by its stabilization to a value determined by the process parameters of mining operations and the physical and mechanical properties of collapsed rocks. In this case, each point of the ground surface experiences sign-alternating horizontal deformations: when the front approaches, it causes tension, and when it moves away, compression. The obtained results of mathematical modelling are in good agreement with the data of instrumental measurements of the ground surface displacements, which indicates the adequate description of the rock mass deformation during the slice excavation of sylvinite seams by longwall faces.
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Date submitted2021-03-31
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Date accepted2022-04-26
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Date published2022-11-03
Features of obtaining metallurgical products in the solid-state hydride synthesis conditions
- Authors:
- Andrey G. Syrkov
- Lyudmila A. Yachmenova
A scientific substantiation of solid-phase feedstock choice and preparation has been carried out, and the thermodynamic and kinetic aspects of solid-state hydride synthesis (SHS) of metal products have been analyzed using the nickel dichloride reduction as an example. The preliminary dehydration modes and methods for controlling the complete removal of crystalline water from chloride raw materials and Olenegorsk superconcentrate, which is natural oxide raw material, are described. Conditions, including initial solid chloride particle sizes, are established under which diffusion complications of reduction to metal in methyldichlorosilane vapor are minimized. Thermodynamic estimates of nickel chlorides and oxides reduction possibility, iron and copper with ammonia and methane at temperatures of 400-1000 K in equilibrium conditions have been carried out. It has been shown that the stoichiometric coefficients of the nickel dichloride in ammonia overall reduction reaction calculated by thermodynamic modeling are in agreement with experimental data. In contrast to the copper dichloride reduction, for nickel dichloride the formation of metal monochloride at the intermediate stage is uncharacteristic, which is associated with a higher thermal stability of nickel dichloride. The main kinetic regularities of the reduction of nickel, copper, and iron to metal under SHS conditions in ammonia, monosilane, and methane, as well as the nickel dichloride with methyldichlorosilane vapor and methane successive reduction, are considered. Approximation of experimental data by topochemical equations in a linear form showed that for reduction degrees a up to 0.7-0.8, these data are satisfactorily described by the Roginsky – Schultz equation. For a > 0,8 the “shrinking sphere” model works better, which confirms the localization of the solid-state reduction reaction at the interface, moves deep into the crystal with the formation of a of interlocked metal germs. The importance and prospects of the results obtained for the theory development of metallurgical processes, deep complex processing of natural iron oxide raw materials, metal products and new generation materials production, including superhydrophobic ones, are discussed. The relevance of the study from the point of view of applying the method of physical and chemical analysis to the study of complex heterogeneous metallurgical processes is noted.
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Date submitted2022-04-12
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Date accepted2022-05-25
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Date published2022-07-26
Rare minerals of noble metals in the collection of the Mining Museum: new data
Modern analytical methods (optical and electron microscopy, X-ray microanalysis) were used to study the unique samples of sulfide ores from the Norilsk ore field from the Mining Museum collections of Saint Petersburg Mining University. Samples containing rare minerals of silver and platinum-group metals (sobolevskite, urvantsevite, sperrylite, argentopentlandite, froodite, kotulskite, and others) were studied. The chemical composition, grain sizes, aggregates, and mineral associations of more than ten noble metal minerals have been refined. The efficiency of combining various methods of electron microscopy and X-ray microanalysis for studying samples of this type is shown. The results of the work made it possible to obtain high-quality images of rare minerals, to detail information on museum objects, and to compile their scientific description. The conducted research showed the relevance of studying museum objects from known deposits of complex genesis and mineral composition in order to find and describe the samples with rare minerals.
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Date submitted2021-03-18
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Date accepted2021-11-30
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Date published2021-12-27
Deformations assessment during subway escalator tunnels construction by the method of artificial freezing of soil for the stage of ice wall formation
- Authors:
- Evgenii M. Volokhov
- Diana Z. Mukminova
The work is devoted to the study of the processes of displacement and deformation of the surface during the escalator tunnels construction of the subway by the method of artificial freezing of soils. The features of the construction and freezing technology, the rocks characteristics in which the escalator tunnels made are considered. The data of specially organized, full-scale surveying observations of deformations on the earth surface are presented. The main factors influencing deformation processes in the frozen strata of a layered inhomogeneous rock mass with inclined tunneling are determined, the complexity of the predictive task and the need to simplify the design scheme are shown. The work is focused on the assessment of the least studied geomechanical processes of soil heaving-uplifts and deformations during the periods of active and passive freezing stages. When studying the displacements processes of the earth surface and rock mass, the finite element method and analysis of the obtained data using field observations of displacements were used. A simplified calculation scheme is proposed for modeling, which allows taking into account the uneven influence of frozen rocks of an inhomogeneous layered rock mass with a large inclined tunneling. The satisfactory convergence of the data of field surveying observations on the earth surface and the results of modeling geomechanical processes for the period of active and passive freezing stages is shown. The proposed calculation scheme is recommended for the prediction of deformation at the stages of underground construction, characterized by the development of the most dangerous tensile deformations of buildings and structures on the surface.
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Date submitted2020-06-29
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Date accepted2021-05-21
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Date published2021-09-20
Transformation of grains of technological raw materials in the process of obtaining fine powders
Crushing and grinding of materials are the most common processes of sample preparation for subsequent analysis and industrial application. Recently, grinding has become one of the most popular methods for producing nano-sized powders. This study investigates certain features of grain transformation in the process of grinding ores with finely dispersed valuable components in order to liberate them, as well as specifics of grinding metallurgical raw materials, metals and their mixtures for using them as initial components in metallurgical and other technological processes. We identified and examined structural and morphological changes of various powders after ultrafine grinding using the methods of scanning electron microscopy and X-ray microanalysis. It was proved that in order to take into account sample preparation artifacts during analytic studies of solid samples and development of technological processes, fine grinding of heterogeneous materials, especially if they contain metals, requires monitoring of the ground product by methods of scanning electron microscopy and X-ray microanalysis.
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Date submitted2020-06-16
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Date accepted2020-07-13
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Date published2020-11-24
Study of Aluminum Influence on the Adhesion of Stainless Steel in Flame Spraying
This paper is dedicated to a study of aluminum influence on the improvement of surface adhesion strength. The main purpose of this work is to investigate the strength of adhesion to the substrate by mixing flame spray powder with aluminum, which not only possesses high corrosion resistance and conductivity, but also provides additional strength, as it combines and reacts with other components of the powder. Research results of sandblasting dependence on surface roughness parameter Ra are demonstrated. The paper describes authors’ original device for a measuring instrument “Profilometer”, which was also used for measuring roughness parameter in order to obtain comparative results. Authors present results of adhesion measurements given obtained values of surface roughness by mixing nominal chemical composition of PR-30X13 powder, used as a testing material, with aluminum, which reacts with oxides on the surface of steel substrates, imparts strength to the bonding between the coating and the substrate, protects the base metal due to a combination of chemical components of the powder and creates a layer of dense surface coating. These dependencies are analyzed and parameters, exerting the greatest influence on their values, are identified. Taking into account the results obtained through numerical modeling, authors propose a mathematical model of a dependency between adhesion strength and certain values of surface roughness for different chemical compositions of flame spray powder. These studies will help in the development of certain material types for spraying and hardening of steel parts and products in order to improve their durability.
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Date submitted2019-05-02
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Date accepted2019-07-09
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Date published2019-10-23
Effect of Temperature on Solid-state Hydride Metal Synthesis According to Thermodynamic Modeling
Thermodynamic modeling of the reduction of copper dichloride in the media of various gaseous hydrides (ammonia, monosilane, methane) in the temperature range 273-1000 K was carried out. Calculations show that in narrower temperature ranges corresponding to the reactions of solid-state hydride synthesis (SHS) of metal sub- stances metal formation is usually supported by theoretical propositions. As a result of thermodynamic modeling, a principal result was obtained on the suppression of competing processes of nitriding, siliconizing and carbonization of metal under SHS conditions, which is important for metallurgical production. This additionally substantiates the correctness of previous experimental studies of SHS metals with modified surface and improved properties. By mod- eling, it was found that the reduction of solid copper dichloride to metal in ammonia or methane occurs stepwise (se- quentially, according to the Baykov rule) through the intermediate stages of the formation of a compound of low- valent copper – copper (I)chloride.
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Date submitted2019-01-10
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Date accepted2019-03-02
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Date published2019-06-25
Modeling of the welding process of flat sheet parts by an explosion
- Authors:
- M. A. Marinin
- S. V. Khokhlov
- V. A. Isheyskiy
The list of materials subject to explosive welding is very extensive and amounts to several hundred combinations of various alloys and metals, and the variety of explosive welding schemes has more than a thousand options. In almost all technical solutions, the process involves the sequential creation of physical contact of the materials to be welded and their connection due to plastic deformation of the contacting surfaces. The strength of such a connection depends on the mode of the welding process. With the correct selection of the parameters of the mode, it is possible to obtain a high-quality connection of the required strength. However, the experimental selection of such options is a very laborious and costly process. Computer simulation and application of mathematical models for solving dynamic problems of explosion mechanics simplifies the search for optimal parameters and allows to predict the expected result in the shortest possible time. The article discusses the issues of modeling of explosive welding of metals, calculations related to the parameters of the process of formation of the weld using the Ansys Autodyn software package. A model is presented for analyzing the deformation process of explosion welding of a plate and its connection with a matrix. The main parameters of explosion welding (velocity, pressure, time) are determined. The adequacy of the obtained values was evaluated in the systems aluminum – copper and copper – steel. It also provides a comparative analysis of simulation results and field experiments. Based on numerical calculations, a conclusion was substantiated on the suitability of the model obtained for a preliminary analysis of the main welding parameters at the preparatory stage.
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Date submitted2018-09-10
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Date accepted2018-11-06
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Date published2019-02-22
Comparative analysis of zincand tin oxidation with acids at room temperatures
- Authors:
- S. D. Pozhidaeva
- L. S. Ageeva
- A. M. Ivanov
The paper analyses the parameters of deep oxidation of zinc and tin by copper (II) compounds and molecular iodine in the presence of molecular oxygen and hydrogen peroxide, as second oxidizers working synchronously with them in various media (aqueous, aqueous-organic and organic) with the participation of mineral and carboxylic acids close to room temperature. The contribution of the reactivity of the metal to its rate of consumption, especially the average, is often much less than the contribution associated with the release characteristics of the working surface, determined by the rates of accumulation of surface deposits of metal oxidation products, their strength and adhesion characteristics their destruction and shifting into the bulk phase.
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Date submitted2018-01-14
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Date accepted2018-03-08
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Date published2018-06-22
Development of research of low-dimension metal-containing systems from P.P. Weymarn to our days
- Authors:
- I. V. Pleskunov
- A. G. Syrkov
The article analyzes main laws discovered by P.P.Weymarn (1879-1935) during his work at the Saint-Petersburg Mining University, they are connected with obtaining metal-containing disperse substances with nanometer particle size. It enlists priority papers in this field (1906-1915) and describes peculiarities of P.P.Weymarn scientific school which has several connections to modern research being conducted at the Saint-Petersburg Mining University in the field of «nanotechnology» as well as by foreign scientists. The paper reveals continuity in the field of several objects (disperse metals) and the methodology of studying the properties and stoichiometry of substances depending on dispersity. It provides information on achievements in synthesis of surface nanostructured metals and low-dimension forms of substances in various porous matrixes. Among the studies of the XXI century developing Weymarn’s ideas there can be noted solid-state hydride synthesis of metals, layering of different-sized molecules of ammonium compounds on metals (Al, Cu, Ni, Fe), as well as synthesis of metal nanostructures (Ag, Cu, Bi) using porous glass as a particle size stabilizing matrix. In the latter case, the dispersity of the metal increases while its melting point decreases.
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Date submitted2017-09-11
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Date accepted2017-10-30
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Date published2018-02-22
Provision of adhesion strength of gas-thermal coatings on piston rings of quarry transport engines
- Authors:
- Yu. Olt
- V. V. Maksarov
- V. A. Krasnyi
The main trend in the development of modern diesel engine manufacturign is the creation of high-powered, reliable and economical internal combustion engines (ICE), which are widely used in various industries, including mining machinery. The application of the methods of gas-thermal and gas-plasma coating for obtaining wear-resistant layers on piston rings for large internal combustion engines of quarry transport – diesel locomotives and dump trucks- is considered. It is shown that the abrasive-jet machining of base coat is widely used as a preparatory operation before coating process, and the roughness of the working surface of the rings after abrasive-jet machining has a significant impact on the adhesion strength of the coating with the base material. The selection of the surface roughness and the conditions of abrasive-jet machining for increasing the coating adhesion strength to the base coat significantly determines both the thickness of the coating and the reliability of the part itself. The aim of the paper is to investigate the dependence of the adhesion strength of a gas-thermal wear-resistant coating of piston rings of large engines of quarry transport, including dump trucks and diesel locomotives, from the roughness of the working surface after abrasive-jet machining, which in turn depends on its modes (distance to the nozzle exit section, the number of passes, the working air pressure, the shot change rate). The working surface adhesion strength of piston rings with diameter of 210 mm coated with molybdenum and steel wire composition was investigated by the twisting angle at which the coating peeled. It is shown that the roughness providing a twist angle greater than 35° should be more than 22 μm, which does not cause coating peeling off. Modes of abrasive-jet machining providing the specified values of roughness: working air pressure is 0.4 MPa, distance to the nozzle exit section is 110 mm, the number of passes is 2, and the shot changes after processing 40 mandrels.
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Date submitted2016-09-16
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Date accepted2016-11-12
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Date published2017-02-22
Possibilities of seismic exploration for crystalline basement study
- Authors:
- A. N. Telegin
Possibilities of seismic methods of reflected and refracted waves have been examined for the purposes of detailed study on crystalline basement structure. Investigation of depth and structure of the basement plays an important role in the exploration of various deposits. Sedimentary cover is usually associated with oil and gas reserves. Ore deposits are formed in the basement rocks, basement splits and structure of its surface have a genetic relation not only to ore minerals, but also to oil resources. Reflection seismology is one of the main seismic methods of investigating structural geometry of the sedimentation mass, forecasting its material composition and possible hydrocarbon reserves. However, its possibilities for investigating crystalline basement are limited. Basing on many years’ experience of reflection seismology and physical modeling it has been identified that actual roughness of basement surface limits the obtainable amount of waves reflected from it. Possibilities of reflection seismology for basement structure study are mostly related to investigation of discontinuous faults as diffraction objects using diffracted waves. Method of refracted waves combined with modern procedures and material processing aimed at getting dynamic seismic sections holds much significance for the basement study, especially in the process of surface mapping and, to a lesser extent, in investigating discontinuous faults.
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Date submitted2015-10-07
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Date accepted2015-12-01
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Date published2016-08-22
Evaluating possible industrial applications of combustible shales and shale ash wastes
- Authors:
- N. K. Kondrasheva
- S. N. Saltykova
Today energy consumption is constantly growing while explored reserves of easily accessible oil are depleting, which is a reason why most countries tend to diversify their energy mix, develop non-hydrocarbon energy sources and use domestic types of fuel, including the low grade ones. Thereby interest is raised to such a source of hydrocarbons as combustible shales. Combustible shales appear to be one of the highest-potential types of organic raw materials, which may offset and in future even substitute oil products and gas. The paper is investigating behavior and structure of combustible shales during heat treatment in order to identify their possible industrial applications. A synchronous thermal analysis has been held, chemical composition of combustible shales’ mineral fraction and optimal conditions for shale fines briquetting have been determined.
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Date submitted2014-12-20
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Date accepted2015-02-05
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Date published2015-12-25
Synergetic changes of tribochemical properties in the heterogeneous systems containing surface modified metals
- Authors:
- A. G. Syrkov
In the article tribochemical properties and synergetic effects in lubricants with metal addi-tives, characterized by surface modifcations, have been analysed. The priority results of measur-ings friction coefficient (f) and friction force (F fr) are given for heterogeneous systems in the form of И-20 oil with solid Al-additives, contatiing dispersed aluminium, with surface-modified triamon (Т), alkamon (A) and ethylhydridsiloxane according to various programs. It has been educed that with all other things being equal, triamon underlayers introduction into Al-additives with the external chemisorpted ethylhydridsiloxane layer results in the decrease of F fr and f in the system in proportion to the Т-underlayer number reduction from three to one. It has been discovered that the use of low-molecular Т-underlayer in Al-additives is a delicate method of summand value regulation (from 10,8 to 13,2 Н), accountable for intermolecular forces in the boundary fritction equation in the tribological pair applied.
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Date submitted2009-10-20
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Date accepted2009-12-11
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Date published2010-09-22
Monitoring of deformation processes of the earth surface with methods of differential interferometric treatment of radar data
- Authors:
- A. A. Krivenko
- Yu. A. Kashnikov
The Differential Interferometry SAR (DInSAR) has recently become one of the most popular methods to reveal and analyze the subsidence of the ground. This method is considered by researchers to be well suited to solve a problem of small relative ground shifts survey applying the short (centimeter) radio waves.
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Date submitted2009-10-13
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Date accepted2009-12-14
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Date published2010-09-22
The evaluation of geodynamic consequences оf long-term exploration of lower cretaceous sediments at the Yamburg oil-gas condensate field with join of additional wells
Within the framework of the engineering design of the join up of additional wells of Lower Cretaceous sediments at the Yamburg oil-gas condensate field the evaluation of geodynamic consequences of long-term exploitation of the mentioned field was performed, as well as the hazardous geodynamic process permanent survey program was developed.
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Date submitted2009-10-10
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Date accepted2009-12-02
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Date published2010-09-22
Deformational precursors of technogenic earthquakes in mining the hydrocarbon deposits
During monitoring since 2005 to 2008 at the Astrakhan gas-field it has been recorded three technogenic earthquakes. Results of geodetic levelling for the given period allow to approve that seismic event is preceded by raisings of a surface and its subsequent subsidence as a its result of unloading. That allows to use geodetic levelling for the forecast of technogenic seismic phenomena for oil and gas fields.
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Date submitted2009-09-22
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Date accepted2009-11-17
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Date published2010-06-25
Linear ccd-sensors based multiprocessor photometer system for spectral analysis
- Authors:
- A. S. Mustafaev
- A. B. Tsyganov
- B. V. Dobrolezh
There is presented a multiprocessor photometric CCD-system for a wide range of spectrometers and for various spectral analysis methods implementation.
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Date submitted2009-08-27
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Date accepted2009-10-25
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Date published2010-02-01
Regularities of change of water-repellent properties of the nanostructured metal powders on the base of aluminium
Regularities of change of water-repellent properties of metal powders on the basis of aluminium depending on the program of nano-structural surface modifying are studyed. The rows of increase of water-repellent properties of modified aluminium on the base of coarse-dispersed and high-dispersed (PAP-2) powders are obtained. Several specimens excelling initial hydrohobic PAP-2 inits water-repellent capacity are found out. The research uses the methods of XP-, EDX- spectroscopy and gravimetry.
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Date submitted2009-07-17
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Date accepted2009-09-06
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Date published2010-04-22
Hydrogeomechanical processes in flooding of mines
- Authors:
- Yu. A. Norvatov
- I. B. Petrova
Hydrodynamic and hydrogeomechanical processes which may occur during flooding of coal mines are considered. Original scheme – model of strain state of waterbearing undermined massif for estimation of uplift of earth surface was suggested.