The paper analyses the parameters of deep oxidation of zinc and tin by copper (II) compounds and molecular iodine in the presence of molecular oxygen and hydrogen peroxide, as second oxidizers working synchronously with them in various media (aqueous, aqueous-organic and organic) with the participation of mineral and carboxylic acids close to room temperature. The contribution of the reactivity of the metal to its rate of consumption, especially the average, is often much less than the contribution associated with the release characteristics of the working surface, determined by the rates of accumulation of surface deposits of metal oxidation products, their strength and adhesion characteristics their destruction and shifting into the bulk phase.