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Date submitted2024-04-10
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Date accepted2024-06-03
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Date published2024-07-19
Combined method for processing spent acid etching solution obtained during manufacturing of titanium products
Possessing high strength, low density and significant chemical resistance, titanium has found wide application in various fields of the national economy – the chemical industry, aviation and rocket technology, mechanical engineering, medicine, etc. The production of titanium products is hampered by a fairly strong oxide film covering its surface. Removal of the oxide film from the surface of titanium workpieces is carried out by etching in solutions of mineral acids of various compositions. A spent acid etching solution (SAES) is formed, containing titanium salt and the remainder of unreacted acids. Almost all etching solutions contain HF and one of the strong acids. This is H2SO4, HCl or HNO3. Thus, the SAES includes ions of titanium, fluorine or chlorine, orsulfate, or nitrate. SAES is quite toxic and must be diluted or cleaned several times before being discharged into a reservoir. Most of the methods used to extract impurities contained in SAES lead to a decrease in their content. As a result of such purification, there is a loss of substances contained in SAES in significant quantities and of interest for further use. The work presents experimental results obtained from the combined processing of SAES containing titanium fluoride, hydrofluoric and hydrochloric acids. At the first stage, SAES is treated with sodium hydroxide. The resulting titanium hydroxide precipitate is filtered off. At the second stage, the filtrate containing sodium fluoride and chloride is processed in a membrane electrolyzer. In this case, not only the extraction of sodium salts from the filtrate occurs, but also the production of sodium hydroxide and a mixture of hydrofluoric and hydrochloric acids. Sodium hydroxide can be used for processing SAES, and a mixture of acids for etching titanium workpieces.
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Date submitted2023-04-11
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Date accepted2023-09-20
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Date published2023-10-27
Current state of above-ground and underground structures of the Alexander Column: an integral basis for its stability
- Authors:
- Regina E. Dashko
- Angelina G. Karpenko
The Alexander Column as a compositional center of the architectural ensemble of Palace Square in Saint Petersburg, Russia, has always been a matter of concern for both the public and specialists due to progressive deterioration of its granite shaft caused by crack formation. The article examines previous studies related to the inspection and restoration of the column's shaft and other parts above ground level, as well as reasons for crack initiation and propagation in the column. An analysis was performed on the anomalies in the Fennoscandian Shield and the structural-tectonic conditions at the Montferrand quarry site, revealing the presence of faults and circular features within the studied area. The research considers N.Hast's measurements of excess tectonic stresses in anomaly zones (southeastern Finland), which acted horizontally and resulted in the development of tensile cracks within the granite massif and later in the column’s shaft after its installation. The most dangerous type of deformation for the Alexander Column is its tilt in the northeast direction, recorded in 1937 and 2000. The article analyzes the construction features of the column's foundations and additional underground elements, as well as soil and groundwater characteristics based on archival data. The contamination history of the underground space is taken into account, and an analogy-based method is used to assess the engineering-geological and hydrogeological conditions of the underground load-bearing structures within the placement zone of the Alexander Column and the New Hermitage buildings. The results of visual observations on the nature of deterioration and deformation of the pavement around the monument, as well as its pedestal, indicating the development of uneven settlement of the foundation, are presented. The article concludes with general recommendations for organizing and implementing comprehensive monitoring to forecast the deformation dynamics of the Alexander Column.
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Date submitted2022-10-10
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Date accepted2023-01-19
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Date published2023-12-25
Assessment of the possibility of using leucoxene-quartz concentrate as raw material for production of aluminium and magnesium titanates
Leucoxene-quartz concentrate is a large-tonnage by-product of development of the Timan oil-titanium field (oil-saturated sandstones) which is not commercially used at present. High content of titanium compounds (to 50 % by weight) and lack of industrial, cost-effective, and safe technologies for its processing determine a high relevance of the work. Conventional processing technologies allow increasing the concentration of TiO2, but they are only a preparation for complex and hazardous selective chlorination. The process of pyrometallurgical conversion of leucoxene-quartz concentrate into aluminium and magnesium titanates was investigated. It was ascertained that the temperature of solid-phase reaction in Al2O3-TiO2-SiO2 system necessary for the synthesis of aluminium titanate (Al2TiO5) is 1,558 °С, and for MgO-TiO2-SiO2 system – 1,372 °С. Scaling up the process made it possible to synthesize a significant number of samples of titanate-containing products, the phase composition of which was studied by X-ray phase analysis. Two main phases were identified in the products: 30 % aluminium/magnesium titanate and 40 % silicon dioxide. In products of pyrometallurgical processing in the presence of aluminium, phases of pseudobrookite (3.5 %) and titanite (0.5 %) were also found. It was ascertained that in magnesium-containing system the formation of three magnesium titanates is possible: MgTiO3 – 25, Mg2TiO4 – 35, MgTi2O5 – 40 %. Experiments on sulphuric acid leaching of samples demonstrated a higher degree of titanium compounds extraction during sulphuric acid processing. An integrated conceptual scheme for processing leucoxene-quartz concentrate to produce a wide range of potential products (coagulants, catalysts, materials for ceramic industry) was proposed.
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Date submitted2022-01-16
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Date accepted2022-04-06
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Date published2023-04-25
Production of biodiesel fuel from vegetable raw materials
One way to reduce the amount of harmful emissions from diesel fuel could be the replacement of part of the fuel with biofuel. Research is related to the production of biodiesel fuel in three ways: transesterification of vegetable oils; esterification of fat acids extracted from vegetable oil; and hydroprocessing of vegetable oils using catalysts in the diesel hydrotreatment process. Food and non-food oils, monatomic and diatomic alcohols were used to produce biodiesel fuel. Optimal parameters of vegetable oil transesterification have been determined: temperature; raw material ratio (oil/alcohol); mixing speed; time; type of process catalyst. The characteristics of the obtained biodiesel fuel samples were studied and compared with each other as well as with the requirements of EN 14214 “Automotive fuels. Fat acid methyl ethers for diesel engines. General technical requirements” and EN 590:2009 “EURO diesel fuel. Technical specifications”. With regard to the physical and chemical characteristics of biodiesel fuel, the best way to produce it is by transesterification of vegetable oils. However, all fuels can be used as components of a blended environmentally friendly diesel fuel.
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Date submitted2022-06-27
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Date accepted2022-09-09
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Date published2022-11-03
Study of the composition and properties of the beneficiation tailings of currently produced loparite ores
The increase in demand for rare earth metals and the depletion of natural resources inevitably causes the need to search for alternative unconventional sources of rare metal raw materials. The article presents the results of a study of the composition and properties of the beneficiation tailings of currently produced loparite ores. Sieve, mineralogical, chemical, and radionuclide analyses were carried out. The average content of loparite in tailings was determined. Using scanning electron microscopy, minerals-concentrators of rare earth elements in the loparite ore beneficiation tailings were diagnosed. The distribution of valuable components and thorium in the tailings was determined depending on the particle size class. The radium-thorium nature of radioactivity was established, the values of the effective specific activity of the samples were calculated. We concluded that it is necessary to develop an integrated technology for processing the beneficiation tailings of loparite ore, due to the complex and heterogeneous mineral and chemical composition of the tailings material.
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Date submitted2022-04-14
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Date accepted2022-07-21
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Date published2022-11-03
Technological mineralogy: development of a comprehensive assessment of titanium ores (exemplified by the Pizhemskoye deposit)
Technological mineralogy of titanium ores is the basis for assessing their complexity. It enables, from a unified standpoint, to trace the entire course of changes in mineral matter through operating procedures, including beneficiation, processing, and obtaining target industrial products. The study targets are Pizhemskoye ilmenite-leucoxene sandstones, which are distinguished by a complex polymineral composition. Along with the main ore components, there are other metals with different speciation (isomorphic admixture, independent mineral phases). The optimal set of mineralogical analysis methods for the predictive assessment of their further use is substantiated exemplified by titanium ores of the Pizhemskoye deposit, which are complex, noted for a variable content of iron oxides and contain rare earth metals. Examinations by X-ray phase analysis and scanning electron microscopy confirm that the main titanium phases of sandstones are pseudorutile and a polymineral aggregate, “leucoxene”. Considering the granulometric peculiarities of the magnetic and non-magnetic fractions of the gravity concentrate, the prospects of technologies for processing titanium raw materials are discussed. Along with the problems of obtaining high-quality raw materials, the transformations of mineral phases as a result of extreme impacts and their physicochemical properties as a consequence of isomorphic substitution of a part of Ti atoms with natural modifier agents (Fe and V) in the synthesis of titanium oxide nanostructures for industrial applications are considered (photocatalytic nanoreactor).
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Date submitted2021-09-02
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Date accepted2022-01-24
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Date published2022-04-29
Complex processing of high-carbon ash and slag waste
The paper considers a current issue of ash and slag processing for the Polyus Aldan JSC, that has accumulated over 1 million tons of this waste. Following the results of the review of Russian and foreign literature, four promising areas of their use were selected: road construction, building materials, reclamation of disturbed lands, and inert aggregates. To assess the possibility of implementing the selected disposal directions, the samples of ash and slag waste of the enterprise were sampled and analyzed. Fuel characteristics, chemical and mineral composition, as well as physico-chemical and mechanical properties of waste were determined. Taking into account the results of complex laboratory studies and the requirements of regulatory documents, each of the selected areas of using ash and slag waste was evaluated. It was found that their disposal by traditional methods has limitations, mainly related to the high content of unburned fuel residues. The high content of combustible substances and the high specific heat of combustion with a relatively low ash content suggested the possibility of thermal disposal of the studied waste. Based on the literature data, the characteristics of the preparation of organic coal-water suspensions based on the studied ash and slag waste were selected. As a result of a series of experiments on their flaring, the expediency of using the obtained fuel at the enterprise under consideration has been proved. The authors note the possibility of using ash obtained after thermal waste disposal in the road construction industry. The prospects for further research of technologies for the preparation and combustion modes of suspension fuel based on ash and slag waste are determined.
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Date submitted2021-03-30
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Date accepted2021-07-27
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Date published2021-10-21
Integrated development of iron ore deposits based on competitive underground geotechnologies
- Authors:
- Vladimir L. Trushko
- Olga V. Trushko
The article presents an analytical review of the current state of the iron ore base of the ferrous metallurgy of Russia and the world, identifies the largest iron ore provinces and iron ore producers. The promising directions of development and improvement of the quality of the iron ore base of Russia and the features of the development of new deposits of rich iron ores are identified. Effective technologies for the development of rich iron ores deposits that ensure an increase in production volumes are proposed. The geomechanical justification of rational technological parameters that are easily adapted to changes in mining and geological conditions has been performed. Based on the results of field studies, the use of an elastic-plastic model with the Coulomb – Mohr strength criterion for modeling changes in the stress-strain state of an ore rock mass during mining operations is justified and recommendations for ensuring the stability of mine workings are developed. Effective engineering and technical solutions for the complex development and deep processing of rich iron ores with the production of fractionated sinter ore, which increases the efficiency of metallurgical processes, the production of high-grade iron oxide pigments and iron ore briquettes, which increase the competitiveness of iron ore companies and the full use of the resource potential of deposits, are presented.
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Date submitted2020-05-13
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Date accepted2021-05-21
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Date published2021-09-20
Increasing the efficiency of technological preparation for the production of the manufacture components equipment for the mineral resource complex
An increase of components production for the equipment intended for oil and gas production is a key factor for analyzing existing technological processes and searching for new technological solutions to improve the efficiency of the production process and the quality of components. The article presents a simulation model designed to determine the rational technological processing parameters for the production of the “Centralizer shell” part. The basis for optimizing the working cycle of a production line is synchronization based on the principle of proportionality, which involves equalizing the duration of all technological operations with the rhythm of the production line. Synchronization of technological operations on the production line is carried out by choosing rational cutting parameters for each technological transition (cutting speed, feedrate, number of working passes). The “Centralizer shell” part is made of titanium alloy VT16, which has high strength, corrosion resistance and ductility. For the part under consideration, the permissible values of the cutting parameters were determined based on the calculation of the total processing error, as well as the frequency of replacement of the worn cutting tool. The simulation model described in the article made it possible to increase the efficiency of the production process due to the synchronization of technological operations and the search for rational technological parameters, as well as to improve the manufacturing quality of the “Centralizer shell” part by analyzing the processing error at various parameters of the technological process.
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Date submitted2020-10-05
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Date accepted2021-03-30
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Date published2021-06-24
Improving the efficiency of relay protection at a mining and processing plant
The paper presents the results of constructing effective relay protection in the power supply system of a mining and processing plant (MPP). A brief description of the MPP is given, the power supply and substitution circuits used to calculate the short-circuit currents are given. A statistical analysis of failures in the electric network of the MPP has been carried out, which makes it possible to draw conclusions about the nature of failures ranges. Analysis of the registered faults shows that a significant part of them are line-to-earth faults, which in most cases turn into multiphase short circuits, which are interrupted by overcurrent protection. In order to improve the efficiency and reliability of the relay protection, the power supply scheme of the MPP was refined and analyzed. The calculation of the short-circuit currents was made, which made it possible to calculate the settings of the relay protection and give recommendations on the place of its installation and adjustment in order to ensure the normal operation of electricity consumers. To reduce the number of failures to the cable insert on the line leaving the administrative and household complex (AHC), and to increase the reliability of power supply to consumers, it is advisable to divide the capacities of the existing 10 kV line into two parallel ones by laying a second line. It is recommended to install a current cut-off on the line outgoing to the AHC, the feasibility of the installation of which was shown by calculations. This will reduce the chance of failures to the cable gland. Data on the setting currents of overcurrent protection and current cut-off are given on the selectivity card.
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Date submitted2020-06-23
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Date accepted2021-03-02
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Date published2021-04-26
Automated digitization of radial charts
Radial charts were commonly used in the industry to allow retrospective assessment of technological parameters. Today it is relevant to digitize the obtained data in order to simplify the automation of technological processes. Digitization of radial charts by means of standard methods is carried out with the help of human labor at significant time costs. The article proposes an automated method for digitizing radial charts using software, developed in the LabVIEW programming environment. The results of processing radial charts are displayed on the screen in numerical and graphical form, and can also be exported to a file (for example, to Notepad or MS Excel). The presented technique can be applied to images obtained on a color or black-and-white scanner, which minimizes geometric distortions, associated with the conversion of a paper document into electronic form, and ensures recognition quality of the clear plot line with an average relative error of up to 3 %. In case of ink fading or perspective photos of the diagram, the value of relative error can reach 8 %, as a result of which additional manual correction of the data will be required.
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Date submitted2020-05-24
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Date accepted2020-07-23
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Date published2020-11-24
Estimation of ore contour movements after the blast using the BMM system
Measurement of ore movements by blast is one of the key components of the quality control system at any mining enterprise, which allows to obtain the accuracy necessary for determining the location of ore contours. About 15 years ago, a monitoring system was developed in Australia that allows mine personnel to make three-dimensional measurements of ore blocks movement at each blast. Studies have shown that ore blocks movement is extremely variable, and it characterized by a complete absence of a deterministic component. The consequence is that modeling ore contour movements during the blast will be inaccurate, and the best results for the mining enterprise can only be achieved by directly measuring the movement. The technology of measuring ore contours movements considered in the article is based on three-dimensional movement vectors obtained in different parts of the blasted block, characterized by different movements. It is obvious that the accuracy of determining the ore contours position after the blast is proportional to the number of measurements made on the block. Currently, the movement control technology based on the BMM system is actively used by global mining companies, its use reduces losses and dilution of ore. In 2017, the pilot implementation of the BMM system was started at the Olympiadinsky GOK, and the system is being implemented in several Russian mining companies.
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Date submitted2020-04-15
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Date accepted2020-05-13
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Date published2020-10-08
Processing of platinum group metal ores in Russia and South Africa: current state and prospects
- Authors:
- Tatyana N. Aleksandrova
- Cyril О’Connor
The presented study is devoted to a comparative review of the mineral raw material base of platinum group metals (PGMs) and technologies of their processing in South Africa and Russia, the largest PGM producers. Mineralogical and geochemical classification and industrial value of iron-platinum and platinum-bearing deposits are presented in this work. The paper also reviews types of PGM ore body occurrences, ore processing methods (with a special focus on flotation processes), as well as difficulties encountered by enterprises at the processing stage, as they increase recovery of the valuable components. Data on mineralogical features of PGM deposits, including the distribution of elements in the ores, are provided. The main lines of research on mineralogical features and processing of raw materials of various genesis are identified and validated. Sulfide deposits are found to be of the highest industrial value in both countries. Such unconventional PGM sources, as black shale, dunites, chromite, low-sulfide, chromium and titanomagnetite ores, anthropogenic raw materials, etc. are considered. The main lines of research that would bring into processing non-conventional metal sources are substantiated. Analysis of new processing and metallurgical methods of PGM recovery from non-conventional and industrial raw materials is conducted; the review of existing processing technologies for platinum-bearing raw materials is carried out. Technologies that utilize modern equipment for ultrafine grinding are considered, as well as existing reagents for flotation recovery; evaluation of their selectivity in relation to platinum minerals is presented. Basing on the analysis of main technological processes of PGM ore treatment, the most efficient schemes are identified, i.e.,gravity and flotation treatment with subsequent metallurgical processing.
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Date submitted2019-07-06
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Date accepted2019-08-25
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Date published2019-12-24
Improving the efficiency of technological preparation of single and small batch production based on simulation modeling
Technological preparation of production is an integral stage of the production process, which is characterized by high complexity, which is largely felt in the conditions of single and small-scale types of production. The effectiveness of technological preparation of production is increased through automation with the use of simulation modeling. The objective of the study is to develop a simulation model that allows you to determine a rational version of the process for processing a batch of parts. The simulation model described in the article allows to analyze the production schedule of the enterprise, build processing routes, evaluate options for using various types of workpieces and technological equipment, determine the acceptable values of cutting conditions, and choose a rational variant of the technological process of processing a batch of parts. The developed simulation model is based on the principles of modular technologies, the part is considered as a combination of individual elementary surfaces. Each elementary surface contains information about the technological processing route, technological equipment and the type of technological equipment used in its manufacture, cutting conditions and the size of the allowance for each processing stage. The rational choice of the technological process is selected on the basis of multicriteria analysis according to three criteria: the value of variable costs, the production time of a batch of parts and the value of the processing error. The analysis of these criteria is made and the parameters that have the greatest impact on their value are determined. The developed classification of surface elements is described: design elements, technological elements, basic elements, as well as a mathematical model based on which the calculation of the values of the criteria for choosing a rational option.
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Date submitted2019-07-11
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Date accepted2019-09-04
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Date published2019-12-24
Recent scientific research on electrothermal metallurgical processes
- Authors:
- E. Baake
- V. A. Shpenst
A wide range of industrial metallurgical heating and melting processes are carried out using electrothermal technologies. The application of electrothermal processes offers many advantages from technological, ecological and economical point of view. Although the technology level of the electro heating and melting installations and processes used in the industry today is very high, there are still potentials for improvement and optimization due to the increasing complexity of the applications and the strong requirements regarding the performance and quality of the products but also regarding the reduction of time and costs for the development of new processes and technologies. In this paper recent applications and future development trends for efficient heating and melting by electrothermal technologies in metallurgical processes are described along selected examples like induction heating for forging or rolling of billets, heat treatment of strips and plates, press-hardening processes, induction surface hardening of complex geometries, induction welding as well as induction melting processes.
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Date submitted2019-03-19
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Date accepted2019-05-22
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Date published2019-08-23
Engineering of Complex Structure Apatite Deposits and Excavating-Sorting Equipment for Its Implementation
- Authors:
- A. Yu. Cheban
Development of Oshurkovskoye apatite deposit with conventional methods, using drilling, blasting and then processing of extracted ore by means of flotation and construction of hydraulic structures to store wet tailings, turns out to be impossible, as the reservoir is located in a special ecological zone of Transbaikal; moreover, the deposit has a complex geological structure and a low grade of valuable component in the orebody. Refinement of the mineral product occurs primarily during its processing; however, ore grade can already be controlled in the process of its extraction. Advancement of technical facilities opens up new opportunities of selective mining for complex structure deposits. The purpose of this research is to create a technology, which will upgrade the quality of mineral substance, fed to the processing plant, directly at the extraction stage. The paper proposes a technological development scheme for Oshurkovskoye deposit using an excavating-sorting complex containing a transport-sorting facility and a measuring unit for estimation of the grade in a milled rock mass; it allows to separate a rich fine fraction of substandard ore, which under conventional mining practices would have been sent to the stockpile of temporarily substandard ore. Separation of fine fractions of apatite ore in the transport-sorting facility allows to reduce dusting during production and cuts the losses of valuable component, associated with aeration of fine fractions during loading and transportation of the rock mass. Positioning of oversize material in the open trench with its subsequent selective extraction by the loading machine facilitates non-stop operation of the mining-sorting equipment, which provides an increase in the productivity of mining operations.
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Date submitted2018-10-28
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Date accepted2018-12-30
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Date published2019-04-23
Development and research of formation technologies on specialized presses with subsequent sintering of high-density details from iron-based powders
- Authors:
- A. M. Dmitriev
- N. V. Korobov
- A. Zh. Badalyan
Creating shifts of the lyaers in a deforming workpieces improves the quality of the product produced by pressure treatment. qual-channel angular pressing and precipitations of a cylindrical billet with a rotating turnaround were developed by specialists earlier and became basic for scientists engaged in nanotechnology. One of the most modern schemes for creating nanostructures by processing on presses is the «Cyclic Extrusion Compression» scheme (in Russia – «Hourglass»), which has significant drawbacks. To date, research on the creation of layer shifts in compacted metal powders is substantially less than in compaction of compact blanks. The article developed compaction schemes for presses of blanks from iron-based powders that have a certain analogy with the «Hourglass», while lacking the disadvantages inherent in the named scheme and implemented on the created samples of specialized hydraulic presses. The results of the studies of density, strength and microhardness before sintering the samples molded from a number of domestic and imported powders on iron base, including those doped with carbon and other alloying components, are described. It has been established that with the use of the formation schemes for powders providing large shifts between particles, the density of the preforms increases on average by 10-12 %. With an average stress (16.32 MPa) of the transverse section of the molded specimen prior to its sintering, molding with shifts between particles increases this stress by 78 %. The strength after sintering of samples made using the compaction schemes developed by the authors of the article increases approximately by 2 times. Magnetic pulse treatment (MPT) of a molded sample prior to its sintering increases its resistance to shearing before sintering, regardless of the molding pattern. When MPT of both the powder and the molded sample is executed, the most uniform distribution of microhardness in the sample is achieved, and after subsequent sintering, the most uniform distribution of the mechanical characteristics of the product. The results of all studies are described by regression equations.
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Date submitted2018-09-08
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Date accepted2018-10-27
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Date published2019-02-22
Special strategy of treatment of difficulty-profile conical screw surfaces of single-screw compressors working bodies
- Authors:
- A. S. Vasilev
- A. A. Goncharov
The article deals with the problems arising during the shaping of complex profile tapered helical surfaces. These surfaces form the geometry of the working bodies of single-screw miniature compressors, which have great prospects for use in mobile miniature compressor plants, which is especially important for medical and space technology, robotics, oil and gas and mining industries. Due to the fact that the capabilities of existing CAD systems do not allow obtaining three-dimensional models of these surfaces, the problem of preparing a control program for a CNC machine arises, since the calculation of the tool path in CAM systems when processing complex surfaces is impossible without a three-dimensional surface model. To solve the problem, an automated programming system was developed that implements a formalized toolpath calculation in accordance with the proposed special processing strategy for conical helical surfaces. As the initial data for calculating the toolpath, the system needs information about the tool geometry and the helical surface in a parametric form, which makes it possible to abandon the construction of a three-dimensional surface model. The results of processing prototypes for the proposed strategy are given.
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Date submitted2018-05-21
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Date accepted2018-07-14
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Date published2018-10-24
Increasing the wear resistance of adapters and drill pipes by elec-tromechanical processing
The directions of the research on increasing the wear resistance of drill pipe locks, threaded joints and casing drill string have been defined: application of drill pipes from the nose-resistant surfacing to the lock with Russian and foreign materials (hardbanding); hardening of the surface layer of drill pipe locks by electromechanical processing; hardaning of the external and internal locking thread of drill pipes by electromechanical processing. Comparative tests of the wear resistance of various hardening materials (hardbanding) of Russian and foreign production and the drill pipe lock without surfacing have been made. The recommendations for increasing the wear resistance of threaded joints by the method of electromechanical processing are developed, which determine the ways of increasing the resource and reliability of drill pipes and sub-assemblies, the formation of unique properties of parts, reducing the labor-capacity of manufacturing and restoring parts, increasing the efficiency of enterprises and organizations, protecting the environment and creation of competitive products. The materials of the article are of practical value for specialists of various fields engaged in the issues of increasing the reliability of technological equipment. The production success of using wear resistant surfacing technology on the body of a drill pipe joint is due to the possibility of using relatively simple and mobile welding equipment, carrying out work in the places of use of a drilling tool or temporary (permanent) production bases with a small transport arm from the field, re-depositing surfacing materials restoration of drill pipe locks; a wide and growing list of companies that receive accreditation for the production of these works.
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Date submitted2017-12-29
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Date accepted2018-03-06
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Date published2018-06-22
Evaluation of signal properties when searching for cavities in soil under concrete slabs by radio detection stations of subsurface investigation
- Authors:
- G. V. Rudianov
- E. I. Krapivskii
- S. M. Danilev
A method of localization of concealed cavities on the basis of studying of the reflected electromagnetic impulses is considered in the paper. An issue of early detecting of concealed cavities in engineering facilities is a critical one due to a significant influence on further serviceability of a structure. Problems of localization of concealed cavities in the soil body under the concrete slabs of hydropower stations were studied; the results of ground radar detecting investigations of the cavities, physical simulation of a cavity as well as a mathematical modeling of a reflected signal are presented. Modern subsurface radar detection provides methods which allow to reliably detect concealed cavities in the soil. However, it is possible only in case of a clear boundary between the adjacent layers that conditions a jump of dielectric permeability. In the result of an abrupt change of dielectric permeability a reflected wave occurred; the existence of subsurface heterogeneity is conditioned by the properties of this wave. Moreover, the greater is the difference between the values of dielectric permeability in the adjacent layers, the larger amplitude the reflected wave will have. If the cavity is at the stage of forming, i.e. it is filled with the soil of reduced density, then there is no clear boundary at the border of the layers which will condition a gradual change of dielectric permeability with depth. In this case an amplitude of a reflected wave will be minimal and a formation signal will be masked out by jamming signals reflected from various heterogeneities. In such case to determine a cavity at the stage of forming seems to be impossible. To determine poor signals an analysis of a phase of a reflected signal may be used; phase alters in compliance with the reflection coefficient change pattern. The article contains information about signals reflected from the heterogeneities and a conclusion regarding a possibility of detecting cavities in the soil on the basis of a method of coherent processing of signals is made.
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Date submitted2016-10-30
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Date accepted2017-01-14
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Date published2017-04-14
HYDRO-IMP technology for upgrading of heavy petroleum
- Authors:
- Khorkhe Anchita
Hydroprocessing is one of the most important processes in petroleum refining industry, not only for upgrading of heavy oils but also for producing low-impurity content fuels and preparing feeds for various conversion processes. Experimental results obtained in pilot plant and semi-commercial scales for hydroprocessing of heavy oils are reported in this work. Mexican heavy crude oils (10, 13 and 16°API) with high amount of impurities were used for all tests. Hydroprocessing was conducted at moderate reaction severity in two fixed-bed reactors in series. Removals of sulfur, metals and asphaltenes, as well as changes of API gravity and viscosity were monitored at different reaction conditions with time-on-stream. Upgraded oils with reduced amounts of impurities and increased API were obtained, keeping sediment formation below maximum allowable content. Removal of impurities was higher in semi-commercial scale compared with pilot plant test. Have been proved that the heavier the feed the greater the gain in product quality. For instance, 10°API crude can increase its gravity up to ~22°API (Δ°API = 12), while 16°API crude increases its gravity up to ~25°API (Δ°API = 9). Sediment formation was also kept below 0.05 wt % and no other problems (excessive reactor delta-P, plugging, etc.) were observed during the test.
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Date submitted2016-09-16
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Date accepted2016-11-12
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Date published2017-02-22
Possibilities of seismic exploration for crystalline basement study
- Authors:
- A. N. Telegin
Possibilities of seismic methods of reflected and refracted waves have been examined for the purposes of detailed study on crystalline basement structure. Investigation of depth and structure of the basement plays an important role in the exploration of various deposits. Sedimentary cover is usually associated with oil and gas reserves. Ore deposits are formed in the basement rocks, basement splits and structure of its surface have a genetic relation not only to ore minerals, but also to oil resources. Reflection seismology is one of the main seismic methods of investigating structural geometry of the sedimentation mass, forecasting its material composition and possible hydrocarbon reserves. However, its possibilities for investigating crystalline basement are limited. Basing on many years’ experience of reflection seismology and physical modeling it has been identified that actual roughness of basement surface limits the obtainable amount of waves reflected from it. Possibilities of reflection seismology for basement structure study are mostly related to investigation of discontinuous faults as diffraction objects using diffracted waves. Method of refracted waves combined with modern procedures and material processing aimed at getting dynamic seismic sections holds much significance for the basement study, especially in the process of surface mapping and, to a lesser extent, in investigating discontinuous faults.
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Date submitted2015-10-14
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Date accepted2015-12-18
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Date published2016-08-22
Complex utilization of treatment wastes from thermal power plants
- Authors:
- A. N. Shabarov
- N. V. Nikolaeva
The paper investigates present-day challenges related to accumulation, processing and disposal of the coal combustion wastes. The analysis of technogenic materials beneficiation practices using gravitation, magnetic and flotation beneficiation methods has been carried out. Quantitative and qualitative microscopic analysis of materials has been conducted. The study target were ash and slag wastes (ASW) from thermal power plant and coal combustion ash. Most metals are contained in coals and coal ashes in fine-dispersed (1-10 μm) mineral form. Various native metals and intermetallic compounds, sulfides, carbonates, sulfates, tungstates, silicates, rare earths phosphates and niobates have been discovered. Each metal may occur in several mineral phases, for instance tungsten may be in the form of wolframite, stolzite, ferberite, scheelite and represented by impurities. Not only composition of compounds is diversified, but also morphology of grains: well-defined and skeleton crystals, aggregates and polycrystalline structures, crystal twins and fragments; druses, globules and microspherules; porous shapes, flocculous and splintery clusters, lumpy aggregations, etc. Based on chemical silicate analysis of main ASW components the petrochemical properties of material have been assessed. Preliminary analyses have shown that concentration of ferrum-bearing components in ASW is around 5-11 %. The magnetic method of technogenic waste beneficiation with the help of high-gradient magnetic separation has been studied. The obtained evidences show that fine ASW are most efficiently separated in separators with high-gradient magnetic system. The studies provided justification of a process flow for complex treatment of technogenic carbon-containing material, including flotation, gravitation separation, magnetic heteroflocculation enrichment and high-gradient magnetic separation. The determined complex utilization ratio has proven the efficiency of complex processing.
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Date submitted2015-10-01
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Date accepted2015-12-11
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Date published2016-08-22
The technology of extracting gaseous fuel based on comprehensive in situ gasification and coalbed degassing
The study considers a comprehensive technology (designed and patented by the authors) of developing coal and methane deposits which combines in situ gasification of lower coalbeds in the suite of rock bump hazardous gassy beds, extraction of coal methane and mechanized mining of coal. The first stage of the technology consists in mining gaseous fuel that enables one to extract up to 15-20 % of total energy from the suite of coalbeds. Geodynamic zoning is used to select positions for boring wells. Using the suggested technology makes it possible to solve a number of tasks simultaneously. First of all that is extracting gaseous fuel from the suite of coalbeds without running any mining works while retaining principal coalbeds in the suite and preparing them for future processing (unloading and degassing). During the first phase the methane-coal deposit works as a gas deposit only, the gas having two sources – extracted methane (which includes its locked forms, absorbed and adsorbed) and the products of partial incineration of thin coalbeds, riders and seams from thee suite. The second stage consists in deep degassing and unloading of coal beds which sharply reduces the hazards of methane explosion and rock bumps, thus increasing the productivity of mechanized coal mining. During the second stage coal is mined in long poles with the account of degassing and unloading of coal beds, plus the data on gas dynamic structure of coal rock massif.
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Date submitted2015-07-14
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Date accepted2015-09-27
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Date published2016-02-24
Chemical and technological mechanisms of a alkaline aluminum silicates sintering and a hydrochemical sinter processing
- Authors:
- V. M. Sizyakov
Complex mineral raw material, as alkali aluminum silicates, is an interest for aluminum industry, chemical industry and for the production of constructional materials. They are well represented in the earth's crust, characterized by the complexity of material composition and variable content of the main components such as alumina, silica and alkalies. They often occur where due to the geological conditions there is no bauxite, for instance, in the United States, Canada, Venezuela, Mexico, Iran, Egypt, Portugal, Spain, Bulgaria and other countries. At the present time for the Russian economy the nephelines from this list are the most valuable and have the great concern for the raw materials balance of the national aluminum industry. Because of limited reserves the bauxites proportion of alumina produced from nephelines by sintering is 40 % and in time this proportion will increase due to the involvement in the production of new deposits of alkali aluminum silicates. Many of foreign companies have also shown interest to the complex processing of ores. The investigation of technology is based on the method of sintering ore with limestone. As a result, the after-sintering mixture consists of alkali metal aluminates and dicalcium silicate; after-sintering mixture is leached by circulating alkaline aluminate solution, alumina, soda and potash are thrown out from the solution. Dicalcium silicate (nepheline sludge) is processed to Portland. For the investigated after-sintering mixture the tendency shows the increasing of optimum sintering temperature with the lowering Al 2 O 3 content. With the increasing of silicate module (SiO 2 / Al 3 O 3 ) of the initial alkali aluminum silicates charges the temperature of after-sintering mixture formation increases. After-sintering mixtures that are on base of alkali aluminum silicates have different microstructure and the degree of crystallization in which b-С 2 S and sodium aluminate is improved with a decrease of the aluminate phase amount. Results of investigations show a very limited solubility of aluminate phase in dicalcium silicate, which theoretically justifies a sufficiently high level of useful components chemical extraction in the processing of different types of alkali aluminum silicates by sintering.