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Date submitted2023-04-04
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Date accepted2023-09-20
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Online publication date2023-12-19
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Date published2024-08-26
Association of quartz, Cr-pyrope and Cr-diopside in mantle xenolith in V.Grib kimberlite pipe (northern East European Platform): genetic models
The first results of mineralogical and geochemical studies of a unique xenolith of lithospheric mantle are presented illustrating the earlier non-described mineral association of quartz, Cr-pyrope and Cr-diopside. Structural and textural features of the sample suggest a joint formation of these minerals. The calculated P-T-parameters of the formation of Cr-diopside indicate the capture of xenolith from the depth interval ~ 95-105 km (31-35 kbar) corresponding to the stability field of coesite. This suggests that quartz in the studied xenolith can represent paramorphs after coesite. It was shown that quartz in this rock is not a product of postmagmatic processes. The transformation stage of the source lherzolite into garnet- and clinopyroxene-enriched rock/garnet pyroxenite as a result of exposure to a high-temperature silicate melt was reconstructed. Subsequent stages of the influence of metasomatic agents were identified by the presence of a negative Eu-anomaly in some garnet grains, which could result from the impact of subduction-related fluid and the enrichment of rock-forming minerals with light rare earth elements, Sr, Th, U, Nb and Ta as a consequence of fluid saturated with these incompatible elements. Several models for the formation of SiO2 phase (quartz/coesite) in association with high-chromium mantle minerals are considered including carbonatization of mantle peridotites/eclogites and melting of carbonate-containing eclogites at the stage of subduction and the impact of SiO2-enriched melt/fluid of subduction genesis with peridotites of the lithospheric mantle.
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Date submitted2022-11-21
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Date accepted2024-05-02
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Online publication date2024-07-18
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Date published2024-08-26
M1 formation tectono-structural features and gas-oil potential within Archinskaya area Paleozoic basement (Western Siberia)
- Authors:
- Vladimir B. Belozerov
- Mikhail O. Korovin
Western Siberian Plate basement oil and gas potential evaluation largely depends on structural and stratigraphic complex architecture representation. New modern procedures for seismic data processing, detailed Paleozoic deposits stratigraphic studies and expanded geophysical well logging significantly change the representation of the basement rocks fold-block structure and previously developed hydrocarbon reservoirs models. Detailed studies conducted within the Archinskii uplift showed that Paleozoic sediments form a contrasting folded structure complicated by block tectonics. The significant block displacements amplitude determines the lithological and stratigraphic basement rocks erosional-tectonic surface, while the identified stratigraphic blocks control the oil productivity distribution within the Archinskaya area. The filtration-capacity heterogeneity folded structure of the Paleozoic sediments is reflected in the distribution of hydrocarbon saturation in the well section, forming independent gas, oil, and oil-water zones for the development process. The relationship between anticlinal structural forms of basement rocks to lowered, and synclinal to elevated blocks, determines the necessity to conduct exploration prospecting within younger stratigraphic blocks when assessing the deep Paleozoic oil and gas potential.
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Date submitted2023-05-21
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Date accepted2024-05-02
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Online publication date2024-06-20
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Date published2024-08-26
Assessment of the influence of lithofacies conditions on the distribution of organic carbon in the Upper Devonian “Domanik” deposits of the Timan-Pechora Province
The study of high-carbon formations was instigated both by the decreasing raw material base of oil as a result of its extraction, and by the progress in development of low-permeability shale strata, primarily in the USA, Australia, and China. The most valuable formations occur in traditional hydrocarbon production areas – the West Siberian, Volga-Ural and Timan-Pechora, North Pre-Caucasian and Lena-Tunguska oil and gas provinces. Specific features of the Late Devonian-Early Carboniferous high-carbon formation occurring in the eastern marginal part of the East European Platform are: heterogeneous section due to intense progradation of the carbonate platform from west to east; succession of lithofacies environments that determined the unevenness of the primary accumulation and secondary distribution of organic matter (OM); possible migration or preservation in the source strata during the subsidence stages of the moving parts of bitumides, which determined the prospects for oil and gas potential. The distribution pattern of the present OM content was investigated depending on lithofacies conditions and lithological composition of rocks in the “Domanik type” Upper Devonian-Tournaisian deposits in the Timan-Pechora Province (TPP), its transformation degree to bring it to the initial content of organic carbon and further estimation of the share of stored “mobile oil” in oil and gas source formation. The study was based on the analysis of the data set on organic carbon content in core samples and natural exposures in the Ukhta Region in the Domanik-Tournaisian part of the section including more than 5,000 determinations presented in reports and publications of VNIGRI and VNIGNI and supplemented by pyrolytic and bituminological analyses associated with the results of microtomographic, macro- and lithological studies and descriptions of thin sections made at the Saint Petersburg Mining University. For each tectonic zone of the TPP within the investigated high-carbon intervals, the content of total volumes of organic carbon was determined. The data obtained allow estimating the residual mass of mobile bitumoids in a low-permeability matrix of the high-carbon formation.
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Date submitted2023-11-02
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Date accepted2024-03-05
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Online publication date2024-04-17
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Date published2024-08-26
The polyphase Belokurikhinsky granite massif, Gorny Altai: isotope-geochemical study of zircon
Based on the isotopic-geochemical analyses of zircons from granites of the Belokurikhinsky massif in the Gorny Altai using the U-Pb method, the ages of three intrusion phases have been determined for the first time: the age of the first phase refers to the time interval of 255-250 Ma, the second and the third phases have similar ages of about 250 Ma. The formation time of the Belokurikhinsky massif is estimated as not exceeding 5-8 Ma. The δ18O values for zircons from granites of the second and the third intrusion phases average around 11.5-12.0 ‰, indicating a significant contribution of a crustal component in the formation of the parent melts for granites of these phases. The crystallization temperature values of the zircons by the Ti-in-zircon thermometer for three phases range from 820 to 800 °C. The P-T crystallization parameters of titanite from the first phase, determined using a titanite thermobarometer, average around 770 °C and 2.7 kbar. The zircons from the first phase mostly exhibits geochemical characteristics of typical magmatic zircons. The zircons from the second and the third intrusion phases either may be unaltered magmatic zircons or enriched in incompatible elements (LREE, Th, U, Ti, Ca, etc.) due to fluid influence, resembling hydrothermal-metasomatic type zircons in terms of their geochemical characteristics. A number of zircon grains from the second and the third phases of granites demonstrate anomalous geochemical characteristics – the REE distribution spectra atypical for zircons (including “bird's wing” type spectra with oppositely tilted of light and heavy REE distribution profiles), as well as significantly higher contents of certain trace elements compared to other varieties. Such an enriched zircon composition and wide variations in the incompatible element content are due to non-equilibrium conditions of zircon crystallization and evolution of the fluid-saturated melt composition during the final stages of the massif formation.
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Date submitted2023-07-25
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Date accepted2024-05-02
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Online publication date2024-05-29
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Date published2024-08-26
Finite element analysis of slope failure in Ouenza open-pit iron mine, NE Algeria: causes and lessons for stability control
Slope failures in mining engineering pose significant risks to slope stability control, necessitating a thorough investigation into their root causes. This paper focuses on a back analysis of a slope failure in the Zerga section of the Ouenza – Algeria open-pit iron mine. The primary objectives are to identify the causes of slope failure, propose preventive measures, and suggest techniques to enhance stability, thereby providing crucial insights for monitoring slope stability during mining operations. The study commenced with a reconstruction of the slopes in the affected zones, followed by a numerical analysis utilizing the Shear strength reduction method within the Finite element method (SSR-FE). This approach enables the examination of slope stability under both static and dynamic loads. The dynamic load assessment incorporated an evaluation of the vibrations induced by the blasting process during excavation, introducing seismic loading into the finite element analysis. The findings reveal that the primary triggering factor for the landslide was the vibration generated by the blasting process. Furthermore, the slope stability was found to be critically compromised under static loads, highlighting a failure to adhere to exploitation operation norms. The challenging geology, particularly the presence of marl layers where maximum shear strain occurs, contributed to the formation of the landslide surface. The study not only identifies the causes of slope failure but also provides valuable lessons for effective slope stability management in mining operations.
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Date submitted2023-05-19
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Date accepted2024-03-05
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Online publication date2024-04-17
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Date published2024-08-26
Development and research of backfill compounds with improved elastic and strength properties for oil and gas well lining
This article describes operations from the well construction cycle where the cement rock behind the casing is subjected to dynamic action (impacts of the drill stem during drilling and normalization of the cement sleeve, secondary drilling operations, hydraulic fracturing, etc.). The developed cement mortar compositions were tested following API 10B-2, API 10B-6, API STD-65-2, and GOST 28985-91 standards. The composition of the cement system without the use of imported components (CM-5) was developed, which improved elastic and strength properties compared to existing industry solutions. An improvement in the elastic and strength features and technological properties of cement rock when using epoxy resins was identified, the optimal composition of the cement-and-epoxy grout was determined, and the internal structure of the formed backfill rock, its permeability, and porosity were studied.
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Date submitted2022-10-04
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Date accepted2024-03-05
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Online publication date2024-05-21
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Date published2024-08-26
Localization and involvement in development of residual recoverable reserves of a multilayer oil field
During waterflooding of a multilayer oil field there is a constant deterioration of the structure and composition of residual reserves due to geological and technological reasons. The largest share of residual reserves is localized in pillars, which arise from uneven development of the production facility and are undrained or poorly drained zones. The results of a quantitative assessment of the distribution of residual oil reserves in the Middle and Upper Devonian deposits of the Romashkinskoe oil field of the Republic of Tatarstan are presented. A retrospective method is proposed to identify reserves by analyzing and summarizing historical exploration data and the long history of reservoir development, and a calculation algorithm is proposed to quantify them. It has been established that residual oil reserves are localized in rows of dividing and injection wells, as well as in the central rows of producing wells in a three-line drive, in abandoned and piezometric wells, in the areas adjacent to the zones of reservoir confluence, pinch-out, oil-bearing contours, distribution of reservoirs with deteriorated porosity and permeability properties. Depending on geological conditions, algorithms for selecting geological and technical measures to include localized reserves in development and forecasting production profiles were proposed. According to the proposed method, residual recoverable reserves were identified and a number of wells were recommended for experimental works on their additional recovery: in well 16 (hereinafter in the text, conventional well numbers are used) after isolation of overlying high-water-cut formations, the additional perforation was carried out and oil flow was obtained. Additional perforation in well 6 resulted in oil recovery during development as well. Thus, the developed approaches to identifying residual recoverable reserves and patterns of their spatial distribution can be recommended in other multilayer oil fields with a long history of development.
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Date submitted2023-07-07
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Date accepted2023-12-27
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Online publication date2024-04-09
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Date published2024-08-26
Landslide hazard assessment in Tinh Tuc town, Cao Bang province, Vietnam using Frequency ratio method and the combined Fractal-frequency ratio method
Landslides are one of the most frequent natural disasters that cause significant damage to property in Vietnam, which is characterized by mountainous terrain covering three-quarters of the territory. In 17 northern mountainous provinces of the country, over 500 communes are at a high to very high landslide hazard. The main goal of this study was to establish landslide hazard maps and conduct a comparative evaluation of the efficiency of the methods employed in Tinh Tuc town, Cao Bang province. The landslide hazard assessment was carried out in this study using the combined Fractal-frequency ratio (FFR) and the Frequency ratio (FR) methods. The FR method is based on the actualist principle, which assumes that future landslides may be caused by the same factors that contributed to slope failure in the past and present. The FFR method is based on the determination of the fractal dimension, which serves as a measure of the landslide filling density in the study area. Eight landslide-related factors were considered and presented in cartographic format: elevation, distance to roads, slope, geology, distance to faults, land use, slope aspect, and distance to drainage. Determining the area under the receiver operating characteristic curve (ROC-AUC) and verification index (LRclass) was performed to assess the performance of prediction models and the accuracy of the obtained maps. As a result, five zones were identified for the study area, characterized by very low, low, moderate, high, and very high landslide hazards. The analysis of the reliability of the obtained landslide hazard maps using the AUC and LRclass indices revealed that the FFR model has a higher degree of reliability (AUC = 86 %, LRclass = 86 %) compared to the FR model (AUC = 72 %, LRclass = 73 %); therefore, its use is more effective.
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Date submitted2023-10-22
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Date accepted2024-03-05
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Online publication date2024-04-11
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Date published2024-08-26
The mechanism and thermodynamics of ethyl alcohol sorption process on activated petroleum coke
The low-quality petcoke does not find qualified application and is stockpiled at refineries or used as solid fuel. One of the promising ways to use low-quality petroleum coke is its physical or chemical activation in order to obtain a highly porous carbon material that can be used as a catalyst carrier, adsorbent, base for electrodes, etc. The possibility of using petroleum coke to produce sorbent for organic compounds was studied. The activated petroleum cake was obtained by chemical activation with KOH, a specific surface area is 1218 m2/g. Sorption of ethyl alcohol was studied at temperatures 285, 293 and 300 K. It is a physical process proceeding mainly in pores of activated petroleum coke, also sorption can be described as a reversible exothermic process. The effective Gibbs energy at a temperature of 293 K is –12.74 kJ/mol, the heat of sorption is –26.07 kJ/mol. The obtained data confirm that porous carbon material obtained from petroleum coke can be used as sorbent for ethanol at room temperature. For example, for adsorption of bioethanol from the effluent of the fermentation process or for purification of wastewater from organic compounds.
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Date submitted2023-06-21
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Date accepted2023-10-25
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Online publication date2023-12-29
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Date published2024-08-26
Specific action of collector from phosphoric acid alkyl esters class in flotation of apatite-nepheline ores
Increasing amount of apatite-nepheline ores with complex mineral composition involved in processing, growing content of the associated minerals in ore which are similar in their floatability to apatite lead to the necessity of using highly selective collectors. Non-frothing flotation method gave a comparative assessment of floatability of pure minerals and demonstrated a high selectivity of the action of phosphoric acid esters in relation to apatite. The effect of four reagent modes differing in the number of selective synthetic collectors was studied using the example of flotation of an apatite-nepheline ore sample containing 17.27 % apatite and 40.18 % nepheline. Mineralogical analysis of crushed ore showed that it contained two apatite varieties – coarse-grained free and finer poikilitic as inclusions in rock-forming minerals. Free apatite opens and occurs as open grains even in coarse-grained (+0.16 mm) grades. Poikilitic apatite occurs as intergrowths with different minerals, mainly with nepheline and its alteration products (natrolite, spreustein, sodalite, etc.), and pyroxene. Optical microscopy demonstrated that a growing share of reagent from the phosphoric acid oxyethylated esters class in the composition of the collector mixture allows improving the quality of the produced apatite concentrates by reducing the number of apatite intergrowths with nepheline and pyroxenes in the concentrates. In the concentrate obtained in the most selective reagent mode, the intergrowths are characterized by a 50/50 and higher ratio in favour of apatite. Concentrates of lower quality comprised intergrowths with lower apatite content, to 20/80 or less.
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Date submitted2023-09-29
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Date accepted2023-10-25
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Online publication date2023-12-12
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Date published2024-08-26
Laboratory studies of transformation of porosity and permeability and chemical composition of terrigenous reservoir rocks at exposure to hydrogen (using the example of the Bobrikovskii formations in the oil field in the northeast Volga-Ural oil and gas province)
The article describes the methodology for laboratory studies of reservoir rock exposure to hydrogen. The stages of sample research and the instruments used in the experiments are considered. A comparative analysis of the results of studies on porosity and permeability of core samples was performed. It was shown that after exposure to hydrogen, the porosity decreased by 4.6 %, and the permeability by 7.9 %. The analysis of correlation dependencies demonstrated a typical change in the relationship of these characteristics: after the samples exposure to hydrogen the scatter of the values increased and the correlation coefficient decreased, which indicates a change in the structure of the void space. Based on the research results, it was concluded that the decrease in porosity and permeability of the core samples occurred due to their minor compaction under the action of effective stresses. The chemical analysis of the rock showed no major difference in the composition of the basic oxides before and after exposure to hydrogen, which points to the chemical resistance of the studied formation to hydrogen. The experimental results showed that the horizon under consideration can be a storage of the hydrogen-methane mixture.
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Date submitted2021-12-20
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Date accepted2024-05-02
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Online publication date2024-06-04
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Date published2024-08-26
A new formula for calculating the required thickness of the frozen wall based on the strength criterion
- Authors:
- Mikhail А. Semin
- Lev Yu. Levin
The study delves into the elastoplastic deformation of a frozen wall (FW) with an unrestricted advance height, initially articulated by S.S.Vyalov. It scrutinizes the stress and displacement fields within the FW induced by external loads across various boundary scenarios, notably focusing on the inception and propagation of a plastic deformation zone throughout the FW's thickness. This delineation of the plastic deformation zone aligns with the FW's state of equilibrium, for which S.S.Vyalov derived a formula for FW thickness based on the strength criterion. These findings serve as a pivotal launchpad for the shift from a one-dimensional (1D) to a two-dimensional (2D) exploration of FW system deformation with finite advance height. The numerical simulation of FW deformation employs FreeFEM++ software, adopting a 2D axisymmetric approach and exploring two design schemes with distinct boundary conditions at the FW cylinder's upper base. The initial scheme fixes both vertical and radial displacements at the upper base, while the latter applies a vertical load equivalent to the weight of overlying soil layers. Building upon the research outcomes, a refined version of S.S.Vyalov's formula emerges, integrating the Mohr – Coulomb strength criterion and introducing a novel parameter – the advance height. The study elucidates conditions across various soil layers wherein the ultimate advance height minimally impacts the calculated FW thickness. This enables the pragmatic utilization of S.S.Vyalov's classical formula for FW thickness computation, predicated on the strength criterion and assuming an unrestricted advance height.
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Date submitted2023-06-01
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Date accepted2024-03-05
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Online publication date2024-04-23
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Date published2024-08-26
Analyzing friction bolts load bearing capacity in varying rock masses: an experimental study in Anti Atlas Imiter silver mining region, Morocco
This study analyzes how key factors impact friction rock bolt capacity using standard pull-out tests, focusing on 39 mm diameter, 180 cm long split-tube bolts. We investigate bolt performance dependence on rock mass rating (RMR), time after installation, schistosity orientation, surface roughness, and installation quality. The aim is optimizing bolt design and implementation for enhanced underground stability and safety. Results show RMR strongly exponentially correlates with pull-out resistance; higher quality rock masses increase capacity. Anchorage capacity significantly rises over time, especially for RMR above 70. Increasing angle between bolt axis and rock foliation from 0 to 90° boosts pull-out response. Reducing borehole diameter below bolt diameter grows bolt-ground friction. Empirical models estimate load capacity based on RMR, time, orientation, diameter, roughness and installation quality. These reliably predict bolt performance from site conditions, significantly improving on basic RMR methods. Experiments provide practical friction bolt behavior insights for typical rock masses. The data-driven analysis ensures models are applicable to actual underground scenarios. This enables tailored optimization of bolting configurations and supports. Methodologies presented should improve safety, efficiency and cost-effectiveness of reinforced mining and tunneling. Overall, this study fundamentally furthers friction bolt performance understanding, enabling superior underground support design.