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Date submitted2023-07-31
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Date accepted2024-11-07
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Date published2025-02-25
Environmental assessment of biochar application for remediation of oil-contaminated soils under various economic uses
- Authors:
- Tatiana V. Minnikova
- Sergey I. Kolesnikov
Remediation is an important area of oil-contaminated soil restoration in Russia, since oil refining industry is the major one for Russia and neighbouring countries, and the issues of environmentally effective and economically profitable remediation of oil contamination have not yet been solved. Soils under various economic uses have different surface areas and degrees of soil particles envelopment with oil due to the presence or absence of cultivation, the amount of precipitation and plant litter. The introduction of various substances for remediation into oil-contaminated soils of steppes (arable land), forests, and semi-deserts, considering their differences, gives different results. Biochar is coal obtained by pyrolysis at high temperatures and in the absence of oxygen. The uniqueness of this coal lies in the combination of biostimulating and adsorbing properties. The purpose of the study is to conduct an environmental assessment of biochar application for remediation of oil-contaminated soils under various economic uses. The article compares the environmental assessments of biochar application in oil-contaminated soils with different particle size fraction. The following indicators of soil bioactivity were determined: enzymes, indicators of initial growth and development intensity of radish, microbiological indicators. We found that the most informative bioindicator correlating with residual oil content is the total bacteria count, and the most sensitive ones are the roots length (ordinary chernozem and brown forest soil) and the shoots length (brown semi-desert soil). The use of biochar on arable land and in forest soil (ordinary chernozem and brown forest soil) is less environmentally efficient than in semi-desert soil (brown semi-desert soil). The study results can serve to develop measures and managerial and technical solutions for remediation of oil-contaminated soils under various economic uses.
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Date submitted2024-07-28
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Date accepted2024-11-26
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Date published2024-12-12
From import substitution to technological leadership: how local content policy accelerates the development of the oil and gas industry
- Authors:
- Oleg V. Zhdaneev
- Ivan R. Ovsyannikov
Achieving technological sovereignty implies accelerating innovation and reducing import dependence. An effective tool for addressing these challenges is local content policy (LCP). The purpose of this study is to assess the impact of LCP on innovation activity in oil and gas companies and to provide recommendations for enhancing the effectiveness of this policy in Russia. The paper analyzes the influence of LCP on innovation levels in the oil and gas sector, drawing on examples from 10 countries. A positive short-term impact of LCP on innovation was identified in Brazil, Malaysia, and Saudi Arabia, with long-term effects observed in China and South Africa. Recommendations for improving the effectiveness of LCP in Russia are supplemented with a methodology for calculating the level of technological sovereignty. A refinement of the method for solving the «responsiveness» problem, incorporating the level of localization, has been proposed.
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Date submitted2023-03-14
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Date accepted2023-10-25
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Date published2024-04-25
Predictive assessment of ore dilution in mining thin steeply dipping deposits by a system of sublevel drifts
The purpose of research is the study of stress-strain state of marginal rock mass around the stope and predictive assessment of ore dilution with regard for changes in ore body thickness in mining thin ore deposits on the example of the Zholymbet mine. Study of the specific features of the stress-strain state development was accomplished applying the methodology based on numerical research methods taking into account the geological strength index (GSI) which allows considering the structural features of rocks, fracturing, lithology, water content and other strength indicators, due to which there is a correct transition from the rock sample strength to the rock mass strength. The results of numerical analysis of the stress-strain state of the marginal part of the rock mass using the finite element method after the Hoek – Brown strength criterion made it possible to assess the geomechanical state in the marginal mass provided there are changes in ore body thickness and to predict the volume of ore dilution. It was ascertained that when mining thin ore deposits, the predicted value of ore dilution is influenced by the ore body thickness and the GSI. The dependence of changes in ore dilution values on the GSI was recorded taking into account changes in ore body thickness from 1 to 3 m. Analysis of the research results showed that the predicted dimensions of rock failure zone around the stopes are quite large, due to which the indicators of the estimated ore dilution are not attained. There is a need to reduce the seismic impact of the blasting force on the marginal rock mass and update the blasting chart.
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Date submitted2022-06-20
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Date accepted2023-01-10
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Date published2023-08-28
Laboratory, numerical and field assessment of the effectiveness of cyclic geomechanical treatment on a tournaisian carbonate reservoir
Results are discussed for evaluation of effectiveness of the cyclic geomechanical treatment (CGT) on a Tournaisian carbonate reservoir. Analysis of laboratory experiments performed according to a special program to assess permeability changes for Tournaisian samples under cyclic changes in pore pressure is presented. The main conclusion is the positive selectivity of the CGT: an increase in permeability is observed for samples saturated with hydrocarbons (kerosene) with connate water, and maximal effect is related to the tightest samples. For water-saturated samples, the permeability decreases after the CGT. Thus, the CGT improves the drainage conditions for tight oil-saturated intervals. It is also confirmed that the CGT reduces the fracturing pressure in carbonate reservoirs. Using flow simulations on detailed sector models taking into account the results of laboratory experiments, a possible increase in well productivity index after CGT with different amplitudes of pressure variation was estimated. Results of a pilot CGT study on a well operating a Tournaisian carbonate reservoir are presented, including the interpretation of production logging and well testing. The increase in the well productivity index is estimated at 44-49 % for liquid and at 21-26 % for oil, with a more uniform inflow profile after the treatment. The results of the field experiment confirm the conclusions about the mechanisms and features of the CGT obtained from laboratory studies and flow simulations.
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Date submitted2022-04-08
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Date accepted2023-03-02
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Date published2023-04-25
Geochemical properties and transformation of the microelement composition of soils during the development of primary diamond deposits in Yakutia
Extraction of diamonds from primary deposits in Siberia is associated with the development of kimberlite pipes in challenging environmental conditions, accompanied by a complex impact on the environment. The article presents the results of monitoring the soil cover of the Nakyn kimberlite field in the Yakutia diamond province, which is affected by the facilities of the Nyurba Mining and Processing Division. Development of primary diamond deposits has a large-scale impact on the subsoil, topography, and soil cover: creation of the world's largest quarries, formation of dumps more than 100 m high, arrangement of extensive tailings, formation of solid and liquid industrial wastes of various chemical composition. The research is aimed at studying the spatial and temporal patterns of the technogenic impact on the soil cover, identifying the nature and level of transformation of the microelement composition of soils based on the analysis of the intra-profile and lateral distribution of mobile forms of trace elements. The study targets in 2007-2018 were zonal types of permafrost soils of northern taiga landscapes, cryozems, occupying 84 % of the total study area, which are characterized by biogenic accumulation of mobile forms of Ni, Mn, and Cd in the upper AO, A cr horizons, and Cr, Ni, Co, Mn, Cu in the suprapermafrost CR horizon. We found out that the contamination of the soil cover of the industrial site at the Nyurba Mining and Processing Division is of a multielement nature with local highly to very highly contaminated areas. Over a ten-year observation period, areas of stable soil contamination are formed, where the main pollutants are mobile forms of Mn, Zn, Ni. We suggest that against the background of a natural geochemical anomaly associated with trap and kimberlite magmatism, technogenic anomalies are formed in the surface horizons of soils. They are spatially linked to technogenically transformed landscapes. One of the sources of pollutants is the dispersion of the solid phase of dust emissions in the direction of the prevailing winds, which leads to the formation of soils with abnormally high contents of mobile forms of Mn, Zn, Ni.
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Date submitted2022-11-04
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Date accepted2023-03-03
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Date published2023-04-25
Efficiency of acid sulphate soils reclamation in coal mining areas
During the development of coal deposits, acid mine waters flowing to the surface cause the formation of acid sulphate soils. We study the effectiveness of soil reclamation by agrochemical and geochemical methods at the site of acid mine water discharge in the Kizel Coal Basin, carried out in 2005 using alkaline waste from soda production and activated sludge. A technosol with a stable phytocenosis was detected on the reclaimed site, and soddy-podzolic soil buried under the technogenic soil layer with no vegetation on the non-reclaimed site. The buried soddy-podzolic soil retains a strong acid рН concentration Н 2 О = 3. A high content of organic matter (8-1.5 %) is caused by carbonaceous particles; the presence of sulphide minerals reaches a depth of 40 cm. Technosol has a slightly acid pH reaction H 2 O = 5.5, the content of organic matter due to the use of activated sludge is 19-65 %, the presence of sulphide minerals reaches a depth of 20-40 cm. The total iron content in the upper layers of the technosol did not change (190-200 g/kg), the excess over the background reaches 15 times. There is no contamination with heavy metals and trace elements, single elevated concentrations of Li, Se, B and V are found.
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Date submitted2022-05-12
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Date accepted2022-11-17
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Date published2023-04-25
Microbiological remediation of oil-contaminated soils
- Authors:
- Irina D. Sozina
- Aleksandr S. Danilov
Microbiological remediation is a promising technology for the elimination of environmental contamination by oil and petroleum products, based on the use of the metabolic potential of microorganisms. The issue of environmental contamination by crude oil and its refined products is relevant in the Russian Federation since the oil industry is one of the leading sectors of the country. Mechanical and physico-chemical methods of treatment are widely used to clean oil-contaminated soils. However, the methods belonging to these groups have a number of significant drawbacks, which actualizes the development of new methods (mainly biological), since they are more environmentally friendly, cost-effective, less labor-intensive, and do not require the use of technical capacities. Various bio-based products based on strains and consortia of microorganisms have been developed that have proven effectiveness. They include certain genera of bacteria, microscopic fungi, and microalgae, substances or materials acting as sorbents of biological agents and designed to retain them in the soil and increase the efficiency of bioremediation, as well as some nutrients. Statistical data, the most effective methods, and technologies, as well as cases of using microorganisms to restore oil-contaminated soils in various climatic conditions are presented.
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Date submitted2021-02-12
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Date accepted2022-07-26
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Date published2022-11-10
Manifestation of incompatibility of marine residual fuels: a method for determining compatibility, studying composition of fuels and sediment
- Authors:
- Radel R. Sultanbekov
- Andrey M. Schipachev
The results of studying the problem of active sediment formation when mixing residual fuels, caused by manifestation of incompatibility, are presented. A laboratory method has been developed for determining the compatibility and stability of fuels allowing identification of a quantitative characteristic of sediment formation activity. Laboratory studies were performed, and incompatible fuel components were identified. Tests were made to determine the quality indicators of samples and group individual composition of fuels. Results on the content of total and inorganic carbon in the obtained sediments were determined using Shimadzu TOC-V SSM 5000A. Chemical composition was determined and calculated on LECO CHN-628 analyser. Group composition of hydrocarbon fuels contained in the sediment was studied by gas chromato-mass spectrometry on GCMS-QP2010 Ultra Shimadzu. To obtain additional information on the structural group composition of fuel sediment, IR spectrometry was performed on IR-Fourier spectrometer IRAffinity-1. X-ray diffraction analysis of sediment samples was made using X-ray diffractometer XRD-7000 Shimadzu; interplanar distances d002 and d100 as well as Lс and Lа crystallite sizes served as the evaluation criteria. Microstructural analysis of total sediment was performed by scanning electron microscopy. The results of the research confirmed that the content of normal alkanes in the fuel mixture mainly affects sediment formation. Recommendations were drawn on preserving the quality of fuels and reducing sediment formation during storage and transportation.
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Date submitted2022-01-24
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Date accepted2022-04-26
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Date published2023-04-25
Forecast of radionuclide migration in groundwater of the zone affected by construction drainage at the Leningrad NPP-2
The distribution of natural (at the level of global background) and technogenic radionuclides in groundwater of the industrial zone in Sosnovy Bor town, where several nuclear power facilities are operating, was analyzed. The main technogenic radionuclides recorded in groundwater samples are cesium ( 137 Cs), strontium ( 90 Sr), and tritium isotopes. The first two aquifers from the surface are subject to contamination: the Quaternary and the upper zone of the Lomonosov aquifer. Based on extensive material on the engineering and geological studies of the work area, a 3D geological model and hydrodynamic and geomigration models of the industrial zone were constructed. By means of modeling, the extent and nature of changes in hydrogeological conditions of area resulting from the construction and operational drainage of the new stage of the Leningrad Nuclear Power Plant (LNPP-2) were determined. The “historical” halo of radioactive contamination of groundwater forming (1970-1990) at the site adjacent to the NPP, where the storage facility of low- and medium-level radioactive waste is located, falls into the zone of influence. Interpretation of monitoring data allowed obtaining the migration parameters for predictive estimates. Modeling has shown that during the time of the LNPP-2 operation there was no intake of contaminated water by the drainage system of the new power plant.
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Date submitted2021-10-08
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Date accepted2022-01-24
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Date published2022-04-29
Methodology for thermal desorption treatment of local soil pollution by oil products at the facilities of the mineral resource industry
- Authors:
- Mariya A. Pashkevich
- Marina V. Bykova
The analysis of the main environmental consequences of leaks and local spills of petroleum products at the enterprises of the mineral resource complex is presented. It is established that the problem of soil contamination with petroleum products at the facilities of the mineral resource complex and enterprises of other industries is caused by significant volumes of consumption of the main types of oil products. Based on the results of the author's previous field research, a series of experiments was carried out, consisting in modeling artificial soil pollution with petroleum products such as gasoline, diesel fuel, highly refined oil, motor oil, and transmission oil, followed by their purification by heat treatment at temperatures of 150, 200, and 250 °C. The 250 °C limit of the heating temperature was set due to the need to partially preserve the structure and quality of the soil after heat treatment to preserve its fertility. When the processing temperature rises to 450 °C, all humates are completely burned out and, as a result, productivity is lost. Confirmation is provided by the results of experiments to determine the humus content in uncontaminated soil and soil treated at different temperatures. It was found that at a maximum processing temperature of 250 °C, about 50 % of the initial organic carbon content is preserved. According to the results of the conducted experimental studies, the dependences of the required processing temperature on the concentration of petroleum products to reduce the concentration of petroleum products to an acceptable level have been established. The methodology of thermal desorption cleaning of soils with varying degrees of contamination at enterprises of the mineral resource complex is presented.
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Date submitted2020-06-02
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Date accepted2021-05-21
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Date published2021-09-20
Analysis of technological schemes for creating a geodetic control at the industrial site
The article highlights the issues of creating with the necessary accuracy a planned control on the industrial site of the engineering structures under construction using satellite technologies and total stations. Depending on the design features of the engineering structures under construction, as well as the technological scheme for the installation of building constructions and industrial equipment, various schemes for creating such control are considered, based on the application of the inverse linear-angular notch. Errors in the source data are one of the main errors that affect the accuracy of geodetic constructions, including the solution of the inverse linear-angular notch. When creating a geodetic network in several stages, the errors of the initial data of the first stage affect the values of the root-mean-square errors (RMS) of determining the position of the second stage points, the errors of which affect the value of the RMS of the position of the third stage points, etc. The reason for their occurrence is the errors of geodetic measurements that occur at each stage of control creating, as well as the stability violation of the points during the production of excavation, construction and installation works. When determining the coordinates of a separate project point at the stage of its removal in-situ by a total station, the entire network is not equalized in the vast majority of cases, and the coordinates of the starting points to which the total station is oriented are considered error-free. As a result, the RMS determination of the points coordinates of the control network or the removal of the design points of the elements of building structures and equipment will also be considered satisfying the requirements, i.e. the measurement accuracy will be artificially overestimated and will not correspond to the actual one obtained. This is due to the fact that the accumulation of errors in the initial data is not taken into account when the number of steps (stages) of control creating increases. The purpose of this work is to analyze the influence of measurement errors and initial data when creating a geodetic control on an industrial site by several stages of its construction based on inverse linear-angular notches and a priori estimation of the accuracy of the determined points position.
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Date submitted2020-11-20
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Date accepted2021-03-30
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Date published2021-06-24
Petrochemical features of tholeiites from the Shaka ridge (South Atlantic)
The article presents original data of chemical composition of tholeiitic basaltoids and andesites, dredged from the Shaka Ridge (South Atlantic) in the course of field research in spring 2016 on the scientific expedition vessel “Akademik Fedorov”. The analytical part of the work on estimating the contents of petrogenic, trace and rare-earth elements was carried out using the classical method (“wet chemistry”), X-ray fluorescence analysis (XRF) and inductively coupled plasma mass spectrometry (ICP-MS). The studied samples demonstrate elevated concentrations of large-ion lithophile elements, or LILE, (Ba, Rb, Pb) and light rare earth elements, or LREE, (La, Ce, Nd, Sm) relative to high field strength elements, or HFSE, (Nb, Ta) and heavy rare earth elements, or HREE, (Dy, Yb, Lu). The specifics of trace element geochemistry suggest a significant contribution of crustal or subduction components to the magmas of the Shaka Ridge. Discrimination diagrams of basaltoids and allied rocks with fields of different geodynamic settings indicate that they were formed in the setting of the mid-ocean ridge basalt (MORB). The reason behind the appearance of subduction and crustal marks in the rocks is possibly associated with assimilation of crustal matter by magmas or lies in their inheritance from the mantle source.
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Date submitted2018-12-25
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Date accepted2019-03-02
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Date published2019-06-25
Non-linear electrical load location identification
- Authors:
- S. Pirog
- Ya. E. Shklyarskiy
- A. N. Skamyin
The article discusses the issues of identifying the location of non-linear loads in electrical networks which makes the main contribution to the distortion of the non-sinusoidal voltage and current in the distribution network of an industrial enterprise, including mining enterprises. The existing methods for determining the location of the source of higher harmonic components in voltage and current are considered, their advantages and disadvantages are revealed. The main disadvantages of the methods used include the low accuracy and incorrectness of their use in existing enterprises. When developing a new method, the authors were faced with the task of simplicity of its use in the conditions of industrial operation of electrical equipment and the absolute correctness of the results obtained. The proposed method of identifying the source of higher harmonics is based on the variation of the parameters of the power system, in particular, the change in resistance of power transformers taking into account their transformation ratio. It is shown that by varying the transformation ratio during regulation under load, the total coefficient of the harmonic components of the voltage changes. Based on the constructed dependencies, the variation of the derivative of this function with different variations of the parameters of sources of higher harmonics is analyzed and a method is developed that allows determining the share contribution of consumers to the total harmonic component of the voltage.
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Date submitted2009-10-26
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Date accepted2009-12-27
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Date published2010-09-22
Support of geodynamic safety in mining of the Khibini deposits
The paper deals with the problems of geodynamics in mining of the Khibini deposits. Description is given to the complex of organizational-technical arrangements for provision of geodynamic safety at the Apatit Co and to principal trends of its development.