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Date submitted2022-09-21
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Date accepted2024-06-03
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Date published2024-12-25
Analysis of the assessment of the prospects for the burial of CO2 in unexplored aquifer complexes on the example of a facility in the Perm Region
One of the most important problems of our time is the annual increase in greenhouse gas emissions into the atmosphere. It is possible to combat this phenomenon by reducing emissions or developing and applying technologies for capturing, storing, using and disposing of CO2. In this work, an assessment of the expediency and possibility of carbon dioxide burial in deep aquifers is considered, the study of which is carried out to a small extent and due to the lack of useful material in them. The parameters and results of CO2 injection into the aquifer of one of the oil fields of the Perm Region, the geological properties and characteristics of which are determined in this work, are studied. The criteria of applicability, methods of estimating the volume of the reservoir and laboratory studies to determine the properties of CO2 and the features of its interaction with the model of the reservoir fluid are considered. The injection object and reservoir volume were determined, PVT studies of the target gas were performed, and its solubility in reservoir water was determined. The duration of filling the full volume of the trap when capturing 400 thousand tons of CO2 per year from the target industrial facility is calculated to be 202 years. This conclusion signals the prospects for the burial of carbon dioxide in the underground deposits of an undeveloped aquifer complex in the Perm Region, which reflects the importance of studying such geological CO2 burial sites in order to achieve global carbon neutrality goals.
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Date submitted2024-05-02
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Date accepted2024-06-03
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Date published2024-07-04
Iron ore tailings as a raw material for Fe-Al coagulant production
The paper presents the results of experimental research into the recovery of Fe-Al coagulant from iron ore tailings (IOTs). The variables investigated in the laboratory tests included sulphuric acid concentration, temperature, leaching time, solid/liquid phase ratio (S:L) and the presence of stirring. The experiment determined the composition of the coagulant and the solid residue after leaching. The maximum iron content in the solution after leaching was obtained using 40 % H2SO4 at a temperature of 100 °C (or with stirring at 75 °C) and a contact time of 60 minutes. In this case, the iron yield was at the level of 25 % of the total content in the iron ore tailings. Chemical analysis of the solution obtained after leaching showed Fe and Al sulphate contents of 11 and 2 % respectively. In the next step, the efficiency of the coagulant was evaluated on model solutions of colour. The experimental results showed that the coagulant obtained from the iron ore tailings can be used for wastewater treatment in a wide pH range from 4 to 12 pH units. The solid residue after leaching is a fine-grained powder rich in silica, which can potentially be used as an artificial raw material in the construction industry. The research carried out in this thesis has shown that the extraction of coagulants from iron ore tailings can be considered as a way to extend the production chain of iron ore mining and to minimise the amount of tailings to be stored in tailing ponds. The technical solution presented in this work allows to comprehensively solve the problem of environmental protection by creating new target products for wastewater treatment from IOTs.
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Date submitted2024-04-22
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Date accepted2024-06-13
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Date published2024-07-04
Comprehensive utilization of urban wastewater sludge with production of technogenic soil
The article presents the analysis of the existing approach to wastewater sludge treatment and justifies the selection of the most promising management technology that allows maximum use of wastewater sludge resource po-tential. To obtain a useful product (biocompost) suitable for use as part of technogenic soil, experimental studies of aerobic stabilization of organic matter of dehydrated urban wastewater sludge with the addition of other waste by using passive composting technology were carried out. The technology is included in the list of best available technologies (BAT). The selection of the most optimal components for the mixture was based on the results of determining the C and N content, humidity and pH of the components used that ensured the composting of organic waste. The results of laboratory studies of the obtained biocompost according to the main agrochemical and sanitary-epidemiological indicators are presented. Testing was carried out according to the criterion of toxicity of the biocompost’s aqueous extract. The assessment of the technogenic soil was performed when using biocompost in its composition for compliance with existing hygienic requirements for soil quality in the Russian Federation. Based on the results of the vegetation experiment, optimal formulations of the technogenic soil were determined, i.e., the ratio of biocompost and sand, under which the most favorable conditions for plant growth are observed according to a combination of factors such as the number of germinated seeds, the maximum height of plants and the amount of biomass. The conducted research makes it possible to increase the proportion of recycled urban wastewater sludge in the future to obtain soils characterized by a high degree of nutrient availability for plants and potentially suitable for use in landscaping, the biological stage of reclamation of technogenically disturbed lands, as well as for growing herbaceous plants in open and protected soil.
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Date submitted2024-04-22
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Date accepted2024-06-13
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Date published2024-07-04
Lithification of leachate from municipal solid waste landfills with blast furnace slag
- Authors:
- Mariya A. Pashkevich
- Yuliya A. Kulikova
The article presents an alternative method of utilization of blast furnace slag and leachate from solid municipal waste landfills, the formation of which occurs during the infiltration of atmospheric precipitation through the thickness of deposited waste. The method is based on the conversion of leachate from the liquid phase to the solid aggregate state by lithification using blast furnace slag as an astringent material. The hydraulic activity of slag, which depends on the amount of oxides contained in it, has been estimated. The investigated slag belongs to the 3rd grade, which confirms the possibility of its use as an astringent material. The filtrate was analyzed for the content of various elements, and the maximum permissible concentrations for each element were found to be exceeded. Chemical and biological oxygen demand were determined, and critically high values were installed (17200 mgO2/l and 4750 mgO2/l, respectively). The lithification process was divided into two stages. The first stage was to reduce the organic component in the filtrate using a coagulant, aluminum sulfate; the second stage was slag hydration. The optimum ratio of lithificate components in terms of mixture solidification rate was established at 1:0.03:1.25 (leachate, coagulant, blast furnace slag). The obtained material was analyzed for the solubility and content of various forms of metal. It is established that at infiltration of atmospheric precipitations through lithificate only 3 % of material will be washed out; concentrations of gross and mobile forms of heavy metals do not exceed the maximum permissible, except for the gross content of arsenic, mobile, and water-soluble forms of which were not found. The values of chemical (687 mgO2/l) and biological (173 mgO2/l) oxygen demand in the aqueous extract from lithificate decreased more than 25 times in comparison with the initial filtrate. According to the results of toxicological studies, lithificate was assigned an IV class of waste hazard, which confirms the possibility of its use as bulk material at landfills.
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Date submitted2022-10-31
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Date accepted2023-03-02
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Date published2023-12-25
Lightweight ash-based concrete production as a promising way of technogenic product utilization (on the example of sewage treatment waste)
- Authors:
- Tatyana E. Litvinova
- Denis V. Suchkov
The study is devoted to the development of a method for the technogenic raw materials utilization. Special attention is paid to the prospect of involving products based on them in the production of new building materials. The results of Russian and foreign studies on the reuse of wastes, such as phosphogypsum, metallurgical slag, waste from municipal and industrial wastewater treatment, etc., in the building materials industry are considered. It has been established that the use of incinerated sewage sludge ash in construction is a promising direction in terms of environmental and economic efficiency. The research confirmed the compliance of the lightweight ash-based concrete components to the regulatory documentation requirements for a number of indicators. As a result of the research, the composition of the raw mixture for the lightweight concrete production with incinerated sewage sludge ash as a replacement for a part of the cement has been developed. In terms of parameters, the developed concrete corresponds to standard lightweight concrete, marked in accordance with the regulatory documents of the Russian Federation as D1300 (density not less than 1.3 g/cm3), Btb2 (flexural strength not less than 2 MPa), M200/B15 (compressive strength not less than 15 MPa). Lightweight ash-based concrete is suitable for use in construction, repair of roads and improvement of urban areas.
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Date submitted2022-09-30
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Date accepted2023-02-13
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Date published2023-04-25
Hydrogeoecological conditions of technogenic groundwater in waste disposal sites
The specific hydrogeoecological conditions of aquifers of some technogenic formations, mainly iron ore skarn-magnetite and titanium-magnetite formations, are considered. The resulting wastes, which are stored in waste disposal sites during development of deposits, due to the impact of a number of factors (natural and technogenic) form technogenic waters. Waste disposal facilities are complex engineering structures (dumps and sludge storages), which in turn create their own hydrogeoecological conditions, which must be investigated in order to prevent and minimize environmental and economic damage caused by these objects to the aquatic environment. The paper presents long-term field and laboratory studies of the aquatic environment under the influence of a waste disposal facility in the Middle Urals – one of the largest tailings, representing a potential environmental and man-made hazard. This tailing dump contains tens of tons of waste – enrichment tailings and creates specific hydrogeoecological conditions on the territory. Based on many years of monitoring studies, an analysis of these conditions was carried out – the quality of groundwater affected by the tailings was assessed. It is shown that groundwater is of technogenic nature, i.e. are man-made waters that have a significant impact on the surface and underground hydrospheres of the territory.
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Date submitted2021-03-05
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Date accepted2021-09-07
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Date published2021-12-16
Utilization of sewage sludge as an ameliorant for reclamation of technogenically disturbed lands
- Authors:
- Tatyana A. Petrova
- Edelina Rudzisha
When rehabilitating technogenically disturbed lands of mining facilities, fertilizers and ameliorants are to be applied due to the lack of organic matter and nutrients required for the restoration of the soil and vegetation layer. The use of unconventional fertilizers (ameliorants) based on sewage sludge is one of the actual directions of land reclamation at mining sites. The purpose of the work is to summarize and analyze up-to-date information on the effectiveness of the use of sewage sludge for the reclamation of technogenically disturbed lands of mining and processing industries. The analysis is based on a review of recent studies aimed at assessing the impact of introduced sediment on soils, plant communities, and rehabilitated areas. The introduction of sewage sludge has a positive effect on the physical and chemical parameters of the soil (optimizes density and aggregation), saturates it with nutrients, i.e. N, P, K, Ca, Mg, and Na, thus improving plant growth indicators. However, it may contain a number of heavy metals and pathogens; therefore, studies of each sediment and conditions of reclaimed areas are necessary.
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Date submitted2019-02-01
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Date accepted2019-09-16
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Date published2020-02-25
Priority parameters of physical processes in a rock mass when determining the safety of radioactive waste disposal
- Authors:
- V. S. Gupalo
Consideration of geodynamic, hydrogeochemical, erosion and other quantitative characteristics describing evolutionary processes in a rock mass is carried out when choosing a geological formation for the disposal of radioactive waste. However, the role of various process parameters is not equal for safety ensuring and additional percentages of measurement accuracy are far from always being of fundamental importance. This makes it necessary to identify various types of indicators of the geological environment that determine the safety of radioactive waste disposal for their detailed study in the conditions of the burial site. An approach is proposed to determine the priority indicators of physical processes in the rock mass that determine the safety of disposal of various types of radio active waste and require increased attention (accuracy, frequency of measurements) when determining in - situ conditions. To identify such factors, we used the sensitivity analysis method that is a system change in the limits of variable values during securty modeling in order to assess their impact on the final result and determine the role of various physical processes in ensuring safety.
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Date submitted2019-07-11
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Date accepted2019-09-02
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Date published2019-12-24
Stakeholders management of carbon sequestration project in the state – business – society system
Prevention of catastrophic effects of climate change is one of the most pressing challenges of this century. A prominent place in the low-carbon development system today is carbon capture and storage technology (CCS). This technology can significantly reduce greenhouse gas emissions, leading to global warming. Effectiveness of technology has been proven through successful implementation of a number of CCS projects. CCS projects are implemented in the context of national and often international interests, consolidating efforts of many parties. Sequestration projects involve government bodies, public, industrial and scientific sectors, as well as a number of other business structures. Each participant presents his own expectations for results of the project, which can compete among themselves, creating threats to its successful implementation. World experience in implementing CCS projects indicates that opposition from a certain group of stakeholders can lead to closure of a project, therefore, interaction with environment is one of the key elements in managing such projects. This study focuses on specifics of stakeholder management in implementation of CO 2 sequestration projects. Based on the analysis of world experience, role of the state, business and society in such projects is determined, their main expectations and interests are summarized. The main groups of stakeholders of CCS and CCUS (carbon capture, utilization and storage) projects were identified, differences in their interests and incentives to participate were analyzed. It is proved that system of interaction with stakeholders should be created at the early stages of the project, while management of stakeholders is a continuous process throughout the life cycle. An author’s tool is proposed for assessing degree of stakeholder interest, the use of which allowed us to determine interaction vectors with various groups of stakeholders.
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Date submitted2019-01-22
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Date accepted2019-03-16
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Date published2019-06-25
Key factors of public perception of carbon dioxide capture and storage projects
- Authors:
- S. V. Fedoseev
- Pavel S. Tcvetkov
One of the major challenges of the modern world is the problem of global warming, the solution of which requires the implementation of a set of strategic projects in the field of transition of the energy sector to the path of environmentally balanced development. One of the ways to implement this transition is the development of technologies for capturing and storage of technogenic carbon dioxide, which is recognized as the main one of greenhouse gases. At the same time, in the Russian context, the most expedient is the implementation of technological chains for capturing and storing CO 2 which are aimed at enhanced oil recovery, the effectiveness of which has been proven by world practice. Implementation of these projects requires consolidation of efforts of many parties, including government agencies, enterprises-issuers (power generating facilities and energy-intensive industry), oil-producing enterprises, non-state environmental organizations, media and public. World practice has many examples when uncoordinated actions of one of the stakeholders led to the closure of such a project, and therefore it is necessary to develop a mechanism of interaction between them, taking into account the specifics of Russian conditions. One of the least studied and controversial aspects of this interaction is to involve the public in the implementation of national carbon intensity programs and the local population in the implementation of a specific project. Research in this field has been conducted in the world over the past 14 years, which allowed the current research base to be used to develop fundamental principles for the development and promotion of CO 2 capture and storage technologies in Russia. Key factors affecting the perception of such projects by public were also analyzed and systematized. The research identified the main arguments for and against the development of CO 2 capture and storage technologies.
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Date submitted2018-09-13
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Date accepted2018-11-09
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Date published2019-02-22
Lignin sludge application for for-est land reclamation: feasibility assessment
- Authors:
- M. A. Pashkevich
- T. A. Petrova
- E. Rudzisha
The article analyses waste generation of pulp and paper industry in North-Western Russia. The environmental impact of waste storage facilities of the pulp and paper mill was assessed, the need for utilization of lignin sludge was justified. In North-Western Russia, 1.21 million hectares of disturbed areas are in need for reclamation; they are abandoned quarries and lands alienated for pipeline and road construction. The suitability of lignin sludge for preparation of artificial fertile soils for reclamation purposes is estimated. For this purpose, experiments were carried out to create an artificial mixture with different ratios of lignin sludge and soil, to detect the maldevelopment of several plant species grown on various compositions of lignin sludge and soils. It was revealed that lignin sludge as an organic additive to soils is not toxic to vegetation and living organisms, allowing improving fertility of artificial soils.
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Date submitted2015-07-14
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Date accepted2015-09-09
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Date published2016-02-24
Engineering and geomechanical forecast for waste disposal in underground caverns including earthquake-prone zones
- Authors:
- O. V. Kovalev
The article aims at obtaining representative scientifically based data to determine parameters of a necessary-safe condition of the rock massif (RM) in underground waste diposal caverns zones, including earthquake-prone zones. The main requirements for underground caverns for hazardous waste disposal and for their construction technology are described. The subject of the research is underground solution caverns in halogen rocks. Data for justification of safe waste disposal conditions in underground salt caverns and its stages are presented. A complex approach to the solution of the research problem is described. The main aspects of dynamic influence of seismic waves on underground caverns stability are considered. Taking into account seismic-risk zoning data on the research region some significant parameters of a possible seismic impact on the experimental cavern are calculated. The article points out the necessity of superincumbent rock and surface displacement assessment for the experimental site zone using the suggested complex approach and including the analysis of surveying data and results of rock mass geomechanical modeling.
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Date submitted2014-10-04
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Date accepted2014-12-26
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Date published2015-08-25
Conservation of municipal solid waste landfills for landfill gas utilization
- Authors:
- M. A. Pashkevich
- T. A. Petrova
The assessment of existing technologies for storage and utilization of domestic solid waste in Russia and other countries is conducted. The regions of landfill sites for household waste disposal are investigated. The results of field observations of the quality of air, surface water and ground-water are given. The method of effective isolation of a landfill surface using polymer materials is proposed. The technological process of landfill surface covering with the help of a selfpropelled screening machine is described. This method allows organizing centralized biogas utilization from landfills, improves the environmental situation in the regions of their location, reduces air pollution and practically eliminates spontaneous combustion of waste.
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Date submitted2014-07-09
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Date accepted2014-08-31
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Date published2014-12-22
Properties of electric arc furnace dust and methods of utilizing it
- Authors:
- M. A. Pashkevich
- T. A. Lytaeva
The least utilized recyclable wastes from mining and processing enterprises are dispersed wastes, which are in the form of dust captured by systems of gas purification. This dust is a technogenic raw material for the production of zinc and other metals. Various ways of utilizing the steelmaking dust are presented. For utilization of the steel-making dust, a hydrometallurgical method with the use of autoclave technologies is proposed. The results of experiments in sulfate autoclave leaching are described.
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Date submitted2008-11-23
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Date accepted2009-01-30
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Date published2009-12-11
The estimate of the utilization’s efficiency of the production waste products, which appeared as a result of the preservation of the environment measures
- Authors:
- E. M. Pronin
Nowadays the problems of the stable growth of mineral and source of raw materials and fuel and energy complex industries are attached great importance to, since it influences the country social-economic condition. In its turn the development of the mining industry requires opening up new lands, which are especially vulnerable to different kinds of anthropogenous and technogenous factors. The changes in the state of economic system have excluded the lowering expenditure by the economy of the production scale. The typical features of a new economy became the progress of free competition and intensive demonopolization. At the same time for the mining industry it is significant that large-scale enterprises should be the foundation of many cities economies of the Russian Federation. For the way out of a system crisis it is necessary to change the strategy – to alter not only the condition of the system, but its management. The formation of the mining complexes permits to use sources of raw materials of the exploited deposits in the proper way, to process waste products of the basic production into the commodity output, to raise the efficiency and cut costs of the preservation of the environment measures from concentration waste products, exhaust solutions, gases, warm water harmful influence on the environment. The practical use of the production waste products of the mining complexes is unprofitable and makes sense only because of its opportunity partially compensating the aggregate investments for the preservation of the environment. The estimate of the utilization s efficiency of the production waste products has made.
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Date submitted2008-10-12
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Date accepted2008-12-17
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Date published2009-12-11
Principles of development of geological engineering and geological criteria for safe burial of low radioactive wastes in lower cambrian blue clays in the Leningrad region
- Authors:
- R. E. Dashko
It is noticed that the chosen territory for nuclear-waste disposal in Lower Cambrian clay massif nearby Koporje of Leningrad region takes place in a tectonic zone. Lower Cambrian clays are considered as the block-fractured rock mass having a depth zone structure. The long radioactive irradiation of dark blue clays has led to transformation of their structure, physical-chemical and physical-mechanical properties, and also to activization of microbial activity. Nine criteria to the geoenvironmental and engineering geological characteristics allowing in a complex to estimate safety and reliability of a nuclear-waste disposal in clay formations on an example of dark blue clays are suggested.