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Date submitted2023-11-27
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Date accepted2023-12-27
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Date published2024-02-29
Physico-chemical aspects and carbon footprint of hydrogen production from water and hydrocarbons
Physico-chemical aspects determine the efficiency and competitiveness of hydrogen production technologies. The indicator of water consumption is especially relevant, since water is one of the main sources of hydrogen in almost all methods of its production. The article analyzes comparative water consumption indicators for various technologies based on published research and actual data from production plants. The volume of water consumption depends on the quality of the source water, which should be taken into account when implementing hydrogen projects in order to minimize the negative impact on the environment. Based on the operating industrial plant, the material balance of hydrogen production by steam reforming was demonstrated, which made it possible to determine the proportion of hydrogen (48.88 %) obtained from water. Currently, the carbon footprint indicator is becoming more important, reflecting greenhouse gas emissions throughout the production chain. According to the results of the total greenhouse gas emissions assessment for hydrogen production by steam reforming (about 10.03 kg CO2-eq/kg H2), the carbon footprint of hydrogen from water (4.2-4.5 kg CO2-eq/kg H2) and hydrogen from methane (15.4-15.7 kg CO2-eq/kg H2) has been determined. Consequently, almost half of the hydrogen produced by steam reforming is produced from water, corresponds to the indicators of “low-carbon” hydrogen and can be considered as “renewable” hydrogen. To make management decisions, an objective assessment in terms of energy and water costs is necessary based on a system analysis by the development of hydrogen energy and the growth of global hydrogen production. The impact of these indicators on the water cycle and global water resources will increase.
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Date submitted2023-03-16
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Date accepted2023-06-20
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Date published2023-07-19
Energy efficiency of the linear rack drive for sucker rod pumping units
- Authors:
- Oksana Yu. Ganzulenko
- Ani P. Petkova
At present, in order to increase oil production and reduce economic costs in the development of marginal fields, the development of a cluster method using compact mobile drives of sucker rod pumping units (SRPU) is relevant. The aim of the work is to analyze the ways to improve the energy efficiency of the SRPU by reducing the loss of mechanical and electrical energy, to select the most energy-efficient compact drive for the development of marginal fields in the cluster method, to carry out the kinematic and strength calculations of the drive of the selected size, to develop an adaptive control system for a group of drives in the cluster development of drillings. According to the results of the performed calculations, the linear rack-and-gear drive has the highest efficiency of the drive mechanism. The kinematic and strength calculations of a linear rack-and-gear drive with a stroke length of 1120 mm and a load of up to 8 tons are presented. It was shown that the usage of a direct torque control system and a kinetic energy storage system for the SRPU drive elements and a rod string is an effective means of reducing energy costs in oil production from marginal fields. The use of the developed system for storing and redistributing the potential energy of the rods between the SRPUs that lift oil made it possible to eliminate fluctuations in the power consumption, reduce the power peak value by three times, the peak value of the current consumed from the electric network by two times, and reduce losses in the input converter and cables by three times.
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Date submitted2022-10-19
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Date accepted2023-02-14
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Date published2023-04-25
Electric steelmaking dust as a raw material for coagulant production
The paper describes the issues associated with waste generated during steel production and processing, in particular the dust from electric arc furnaces (EAF). An effective solution for the disposal of such waste is its involvement in processing to obtain valuable products. This paper studies the physical and chemical properties of EAF dust produced during the smelting of metallized pellets and captured by the dust and gas cleaning system of the steel-smelting shop at the Oskol Electrometallurgical Combine, Belgorod Region. The results obtained in the study of the chemical and disperse compositions of dust, the microstructure of the surface made it possible to propose the use of dust as a raw material for coagulant production. The conditions of acid-thermal treatment of dust are determined, contributing to the partial dissolution of iron (II), (III), and aluminium compounds, which ensure the coagulation processes during wastewater treatment. Model solutions show high efficiency (> 95 %) of water treatment from heavy metal ions by modified EAF dust.
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Date submitted2021-03-31
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Date accepted2022-04-26
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Date published2022-11-03
Features of obtaining metallurgical products in the solid-state hydride synthesis conditions
- Authors:
- Andrey G. Syrkov
- Lyudmila A. Yachmenova
A scientific substantiation of solid-phase feedstock choice and preparation has been carried out, and the thermodynamic and kinetic aspects of solid-state hydride synthesis (SHS) of metal products have been analyzed using the nickel dichloride reduction as an example. The preliminary dehydration modes and methods for controlling the complete removal of crystalline water from chloride raw materials and Olenegorsk superconcentrate, which is natural oxide raw material, are described. Conditions, including initial solid chloride particle sizes, are established under which diffusion complications of reduction to metal in methyldichlorosilane vapor are minimized. Thermodynamic estimates of nickel chlorides and oxides reduction possibility, iron and copper with ammonia and methane at temperatures of 400-1000 K in equilibrium conditions have been carried out. It has been shown that the stoichiometric coefficients of the nickel dichloride in ammonia overall reduction reaction calculated by thermodynamic modeling are in agreement with experimental data. In contrast to the copper dichloride reduction, for nickel dichloride the formation of metal monochloride at the intermediate stage is uncharacteristic, which is associated with a higher thermal stability of nickel dichloride. The main kinetic regularities of the reduction of nickel, copper, and iron to metal under SHS conditions in ammonia, monosilane, and methane, as well as the nickel dichloride with methyldichlorosilane vapor and methane successive reduction, are considered. Approximation of experimental data by topochemical equations in a linear form showed that for reduction degrees a up to 0.7-0.8, these data are satisfactorily described by the Roginsky – Schultz equation. For a > 0,8 the “shrinking sphere” model works better, which confirms the localization of the solid-state reduction reaction at the interface, moves deep into the crystal with the formation of a of interlocked metal germs. The importance and prospects of the results obtained for the theory development of metallurgical processes, deep complex processing of natural iron oxide raw materials, metal products and new generation materials production, including superhydrophobic ones, are discussed. The relevance of the study from the point of view of applying the method of physical and chemical analysis to the study of complex heterogeneous metallurgical processes is noted.
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Date submitted2021-03-11
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Date accepted2021-04-12
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Date published2022-04-29
Operation mode selection algorithm development of a wind-diesel power plant supply complex
- Authors:
- Yaroslav E. Shklyarskiy
- Daria E. Batueva
The power supply system is affected by external disturbances, so it should be stable and operate normally in compliance with power quality standards. The power supply system goes into abnormal modes operation when, after a short-term failure or disturbance, it does not restore normal mode. The electrical complex, which includes a wind power plant, as well as a battery and a diesel generator connected in parallel, is able to provide reliable power supply to consumers which meets the power quality indicators. The article develops an algorithm that is implemented by an automatic control system to select the operating mode depending on climatic factors (wind) and the forecast of energy consumption for the day ahead. Forecast data is selected based on the choice of the methods, which will have the smallest forecast error. It is concluded that if the energy consumption forecast data is added to the automatic control system, then it will be possible to increase the efficiency of the power supply complex. In the developed algorithm the verification of normal and abnormal modes of operation is considered based on the stability theory. The criteria for assessing the normal mode of operation are identified, as well as the indicators of the object’s load schedules for assessing the load of power supply sources and the quality standards for power supply to consumers for ranking the load by priority under critical operating conditions and restoring normal operation are considered.
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Date submitted2021-03-31
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Date accepted2021-09-29
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Date published2021-10-21
Methodology of modeling nonlinear geomechanical processes in blocky and layered rock masses on models made of equivalent materials
- Authors:
- Boris Yu. Zuev
The research purpose is to develop a methodology that increases the reliability of reproduction and research on models made of equivalent materials of complex nonlinear processes of deformation and destruction of structured rock masses under the influence of underground mining operations to provide a more accurate prediction of the occurrence of dangerous phenomena and assessment of their consequences. New approaches to similarity criterion based on the fundamental laws of thermodynamics; new types of equivalent materials that meet these criteria; systems for the formation of various initial and boundary conditions regulated by specially developed computer programs; new technical means for more reliable determination of stresses in models; new methods for solving inverse geomechanical problems in the absence of the necessary initial field data have been developed. Using the developed methodology, a number of complex nonlinear problems have been solved related to estimates of the oscillatory nature of changes in the bearing pressure during dynamic roof collapse processes; ranges of changes in the frequency of processes during deformation and destruction of rock mass elements, ranges of changes in their accelerations; parameters of shifts with a violation of the continuity of the rock mass under the influence of mining: secant cracks, delaminations, gaping voids, accounting for which is necessary to assess the danger of the formation of continuous water supply canals in the water-protection layer.
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Date submitted2020-07-29
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Date accepted2021-03-29
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Date published2021-09-20
Critical analysis of methodological approaches to assessing sustainability of arctic oil and gas projects
Development of hydrocarbon resources in the Arctic is one of the priority tasks for the economy of the Russian Federation; however, such projects are associated with significant risks for the environment of nearby regions. Large-scale development of hydrocarbon resources in the Arctic should be based on the principles of sustainable development, which imply a balance between socio-economic benefits and environmental risks. The purpose of this study is to analyze the gaps in scientific knowledge on the issues of assessing sustainability of Arctic oil and gas projects (OGPs) and systematize the key problematic elements of such assessments. The analysis was carried out in terms of four key elements that determine the feasibility of implementing Arctic OGPs in the context of sustainable development: economic efficiency, social effects, environmental safety and technological availability. The methodology for conducting bibliometric analysis, which included more than 15.227 sources from the Scopus database over the period of 2005-2020, was based on PRISMA recommendations for compiling systematic reviews and meta-analyses. Methodological problems of assessing sustainability of Arctic OGPs were mapped and divided into four key sectors: consideration of factors that determine sustainability; sustainability assessment; interpretation of assessment results; sustainability management. This map can serve as a basis for conducting a series of point studies, aimed at eliminating existing methodological shortcomings of the sustainable development concept with respect to Arctic OGPs.
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Date submitted2020-06-10
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Date accepted2020-11-19
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Date published2021-04-26
Influence of jarosite precipitation on iron balance in heap bioleaching at Monywa copper mine
Ferric iron is an important oxidant in sulfide ore bioleaching. However, recirculating leach liquors leads to excess iron accumulation, which interferes with leaching kinetics and downstream metal recovery. We developed a method for controlling iron precipitation as jarosite to reduce excess iron in heap bioleaching at Monywa copper mine. Jarosite precipitation was first simulated and then confirmed using batch column tests. From the simulations, the minimum pH values for precipitation of potassium jarosite, hydronium jarosite, and natrojarosite at 25 °C are 1.4, 1.6, and 2.7, respectively; the minimum concentrations of potassium, sulfate, ferric, and sodium ions are 1 mM, 0.54, 1.1, and 3.2 M, respectively, at 25 °C and pH 1.23. Column tests indicate that potassium jarosite precipitation is preferential over natrojarosite. Moreover, decreased acidity (from 12 to 8 g/L), increased temperature (from 30 to 60 °C), and increased potassium ion concentration (from 0 to 5 g/L) increase jarosite precipitation efficiency by 10, 5, and 6 times, respectively. Jarosite precipitation is optimized by increasing the irrigating solution pH to 1.6. This approach is expected to reduce the operating cost of heap bioleaching by minimizing the chemicals needed for neutralization, avoiding the need for tailing pond construction, and increasing copper recovery.
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Date submitted2019-01-01
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Date accepted2019-03-03
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Date published2019-06-25
Strategic approach to assessing economic sustainability objects of mineral resources sector of Russia
The article gives a new definition of economic systems (ES) stability with its distinct strategic content. The main approaches to assessment of sustainability, based on the use of strategic cards, including Balanced Scorecard (BSC), are considered. Synchronous management of effectiveness, risks and chances of the ES exhausts the agenda of managing economic sustainability of ES when it operates in the face of a wide range of challenges. BSC in mineral resources sector (MRS) can be built during the aggregation of BSC by industry and individual enterprises. The use of 4 ´ 6 matrix formalism is proposed as the main tool for modeling economic sustainability of the ES.
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Date submitted2014-07-21
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Date accepted2014-09-19
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Date published2014-12-22
Preliminary preparation of oil for primary processing
Oil supplied for primary processing always undergoes preliminary preparation, the purpose of which is to eliminate the harmful effect of water and salt contained in the oil. It is thought that corrosion of the equipment is connected mainly with chlorides of magnesium and calcium, which are subjected to hydrolysis with the formation of hydrochloric acid. Under the influence of hydrochloric acid the destruction (corrosion) of metal equipment at technological plants occurs (especially refrigerating-condensing and heatexchange equipment, furnaces of rectification units etc.). The authors of the article, on the basis of thermodynamic calculations, provide their point of view on this process and give a methodology by which the process of preliminary oil dehydration and desalting can be controlled. The thermodynamic calculations executed for standard conditions on the basis of refer-enced data confirm a high probability of chemical interaction of iron with hydrogen ions, hy-drogen sulphide and especially with carbonic acid. This testifies to high activity of the carbon dioxide dissolved in water and the impossibility of hydrolysis of ions of magnesium, calcium and iron. The calculations show that only the hydrolysis of magnesium chloride is possible tak-ing into account the ionic composition of the water phase in the oil. It should be noted that the presence of ions of chlorine shifts the iron potential in a nega-tive direction and increases the speed of corrosion of petrochemical equipment. The solution of this problem is in the development of modern methods of crude oil dehydration and desalting. It is also, however, in an intensification of the processes of mixing water-oil emulsions with wash-ing water by using various physical fields (for example, ultrasound) and creating new effective mixing devices on the basis of them.
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Date submitted2013-07-27
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Date accepted2013-09-03
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Date published2014-03-17
Gas balance definition of working area with face zone isolation
- Authors:
- V. V. Smirnyakov
The article describes the methods for gas balance definition of working area with face zone isolation from mined-out space, that have allowed to change the air distribution in face zone and to determine the part of evolved gas from bed and marked bed.
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Date submitted2009-07-23
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Date accepted2009-09-22
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Date published2010-04-22
Conceptual principles of mining company’s balanced development in condition of necessity of innovation transformation
- Authors:
- A. A. Gurev
Necessity of forming strategy of balanced development of mining company on based innovation transformation is proved. Algorithm of analysis of strategic opportunity realization is proposed. Conceptual scheme of formation of strategy of balanced development of mining company is developed.
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Date submitted2008-11-15
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Date accepted2009-01-11
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Date published2009-12-11
Economic mechanism of forming of hydrocarbon fields special fund
- Authors:
- A. E. Cherepovitsyn
- A. V. Radko
Factors and presuppositions of forming of special fund of fields are determined. Scheme of functioning of special fund of fields, inclusive elements of production share and privileged taxation are proposed. Economic efficiency of special funds of oil and gas fields’ development are defined.
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Date submitted2008-11-19
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Date accepted2009-01-03
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Date published2009-12-11
Prerequisites for sustainable development of mining region
- Authors:
- M. A. Nevskaya
The article deals with issues related to the identification of conditions for sustainable development of mining area. In such conditions, the author highlights the investment potential, the specificity of specialization and structure of economy of the region, the balance of state, regional and sectoral interests. As the characteristics used in evaluating the productive capacity of the territory proposed rates structure, dynamics and effectiveness, based on the integral rate of gross regional product.
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Date submitted2008-10-24
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Date accepted2008-12-01
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Date published2009-12-11
History and prospects for the development of the karelian isthmus facing stone mineral base
- Authors:
- A. Y. Tutakova
The prerequisites for the development of the deposits, the previous studies and the current state of Karelian Isthmus facing stone sources as well as their comparison with those of other regions of Northwestern Federal Districts of Russia are considered. The objects for top-priority geological prospecting are determined.