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Date submitted2024-04-24
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Date accepted2024-09-24
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Date published2024-11-12
Study and justification of the combination of beneficiation processes for obtaining flake graphite from technogenic carbon-containing dusts
The most important task of modern production development is to provide the mineral and raw materials sector of the economy with resources included in the list of strategic raw materials, including flake graphite. In addition to natural raw materials, the source of its obtaining can be metallurgical production wastes not involved in processing. Development of metallurgical dust beneficiation technology will solve the problem of obtaining high-purity flake graphite with a crystal structure close to ideal and in demand in the production of high-tech materials. It will allow creating a renewable raw material base of graphite and utilising metallurgical production wastes. The research included the study of dust beneficiation by coarseness, magnetic and flotation methods, the influence of dust disintegration processes on beneficiation indicators. Based on the established technological properties of the components of dusts, magnetic, flotation and gravity beneficiation methods can be applied for their separation in different sequence. It is shown that dusts from different sites have different enrichability by these methods, and it should be taken into account when developing a complex technology of their processing. The degree of beneficiation increases in a row of dusts from the blast furnace shop (BF) – electric steel smelting shop (ESS) – oxygen-converter shop (OCS). The method of grinding has a significant influence on the separation indicators – at dry grinding in a centrifugal-impact mill with subsequent pneumatic classification the quality of graphite concentrates increases by 22.7 % of carbon for BF dust and by 13.48 % of carbon for ESS dust. OCS dust beneficiation indicators are high at coarse grinding with steel medium – mass fraction of carbon 96.1 %.
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Date submitted2024-05-17
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Date accepted2024-10-14
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Date published2024-11-12
Black shales – an unconventional source of noble metals and rhenium
The content of noble metals and rhenium in the Lower Paleozoic black shales of the eastern Baltic paleobasin in Russia was estimated. Shales are enriched in platinoids (PGM to 0.12 g/t) and rhenium (to 1.54 g/t). The main accessory elements of noble metals and Re are U, V, Mo, Cu, and Ni. Black shales consist of organic (9-26 rel.%), clay (40-60 rel.%), and silt-sandy (25-50 rel.%) components and a nodule complex (2-5 rel.%) (carbonate, sulfide, phosphate and silicate nodules). Noble metals occur sporadically in the silt-sandy admixture as native forms and intermetallics: Aunat, Au-Ag, Au-Cu, Au-(Cu)-Hg, Au-Hg, Ag-Cu, Pt-Fe. Micromineral phases of noble metals were found in diagenetic sulfides: Aunat, chalcopyrite with Au admixture, pyrite with platinoid admixture. Clay fraction is 10-fold enriched in noble metals as compared to shale – to 0.28 g/t Au, 0.55 g/t Pt, 1.05 g/t Pd, and 1.56 g/t Re. Organic matter sorbs noble metals to a limited extent but accumulates rhenium. Pore space of black shales contains a colloidal salt component (submicron fraction) which is represented by particles smaller than 1,000 nm. The share of submicron fraction in black shales is 0.1-6 wt.%. The submicron fraction contains on average: PGM – 14 g/t, Au – 0.85 g/t, and Re – 4.62 g/t. The geochemical resource of noble metals (Au, Pt, Pd), Re and the accessory elements (U, V, Mo, Cu, and Ni) for black shales as a whole and their submicron fraction was estimated. Black shales are recommended as an integrated source of raw materials.
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Date submitted2024-03-30
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Date accepted2024-06-13
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Date published2024-07-04
Organotin pollutants in emerging coastal-marine sediments of the Kaliningrad shelf, Baltic Sea
Based on two years of monitoring of modern bottom sediments of two sections of the Kaliningrad shelf of the Baltic Sea – “Curonian Spit” and “Northern Sambian” – an assessment of the sources of pollution with organotin compounds (OTs) and heavy metals was carried out. The content of individual organotin compounds and OTCs spectra obtained by gas chromatography with mass spectrometry of relatively coarse-grained bottom sediments indicate the presence of organotins in significant quantities – the total OTs content (ΣOTs) is from 0.6 to 8.3 ng/g. However, the content of tributyltin (TBT), the main component of anti-fouling systems for marine vessels and the most dangerous endocrine-disrupting compound among the hazardous substances for marine ecosystems, is at a low level (0-2.3 ng/g) in all studied samples and has not increased over the two-year observation period (biodegradation index 1.7-12.4). At the same time, the presence of abnormally high concentrations of mono-, triphenyl- and tricyclohexyltin in the sediments of the ”Northern Sambian” site (up to 30, 7 and 6.4 ng/g, respectively) indicates an additional source of pollution of coastal waters and shelf sediments (for example, plastic litter and agricultural runoff). The absence of significant shipping in the study areas ensures a consistently low level of pollution with tributyltin and its derivatives (less than 0.3 and 2.3 ng/g of TBT in 2017 and less than 0.1 and 1.3 ng/g in 2018 for the sites “Curonian Spit” and “Northern Sambian”, respectively), which indicates the activity of the processes of TBT transformation and self-cleaning of sandy sediments. However, the identified trends and their predictive accuracy require long-term observation and monitoring of the sediment environment using data on the deep-water part of the shelf, enriched in clay and humus components.
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Date submitted2023-04-13
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Date accepted2023-10-25
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Date published2025-02-25
Assessment of the ecological state of aquatic ecosystems by studying lake bottom sediments
- Authors:
- Mariya A. Chukaeva
- Tatyana V. Sapelko
The article presents the results of coupled palynological and geochemical studies of five various genesis lakes, located along the route of the expedition “In the footsteps of Alexander von Humboldt in Siberia, Altai and Eastern Kazakhstan”, dedicated to the double anniversary: the 190th anniversary of the expedition across Russia of the famous scientist and his 250th birthday. A geochemical analysis of water and bottom sediments of Ik Lake (Siberia), Lakes Kolyvanskoe and Beloe (Altai), Lake Bezymyannoe (Kazakhstan) and Nagornyi Pond (Altai) was carried out. Based on their results an assessment of studied lakes ecological state was given through single and integral criteria. A high level of pollution was noted for Nagornyi Pond and Lake Bezymyannoe, which is caused by a significant technogenic load from nearby mines. This is consistent with the data of palynological research. The aquatic ecosystems of Lakes Kolyvanskoe and Beloe are characterized by a satisfactory ecological situation, but they experience an increased recreational load. The results of spore-pollen analysis and analysis of non-pollen palynomorphs showed the low ability of these lakes to self-healing. The most favorable ecological state and high self-cleaning capacity were noted for Lake Ik, which is consistent with the data of palynological studies. It is being confirmed with the results of palynological studies. It was therefore concluded about the ability to make a quick assessment of the aquatic ecosystems’ ecological state by studying lakes using coupled palynological and geochemical analysis.
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Date submitted2022-06-27
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Date accepted2023-06-20
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Date published2023-12-25
Analysis of the problems of high-quality drinking water extraction from underground water intakes on Vysotsky Island in the Vyborg district of the Leningrad region
This article presents the results of drilling, experimental filtration work and laboratory studies aimed at assessing the resources and quality of groundwater in the licensed area of Vysotsky Island located in the Leningrad region, in the Gulf of Finland in accordance with the requirements of regulatory documents. Analysis of the results of hydrochemical studies and their comparison with data on water intakes in adjacent areas gives the right to conclude that it is possible to classify a hydrogeological unit as a different type of resource formation than those located in the surrounding areas. Groundwater in this area is confined to an unexplored deep fractured regional high-pressure zone. According to the received data, the explored water intake can be attributed to a unique groundwater deposit, which has an uncharacteristic composition of groundwater in the north of the Leningrad region, which may be due to the mixing of modern sediments and relict waters of the Baltic glacial lake. The stability of groundwater characteristics is confirmed by long-term monitoring.
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Date submitted2022-03-14
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Date accepted2022-06-20
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Date published2022-11-10
Model of a walking sampler for research of the bottom surface in the subglacial lake Vostok
Technologies and technical means for investigation of subglacial lakes in Antarctic is a new developing scientific and technical direction, which today has no clearly established methodology. Based on the developed technology of drilling a new access well to lake Vostok and its penetration as well as analysis of existing methods and devices for bottom sediment sampling, a basic model of a sampler with a walking-type mover, capable of moving along different trajectories and operating in a wide technological range, is proposed. The proposed device model is equipped with different actuators for sampling the bottom surface with different physical and mechanical properties. Based on the presented basic model of the walking sampler, a mathematical model of the device was developed, which was based on the theoretical mechanics methods. As a result of conducted research the dependencies were obtained, which allow making a scientifically justified choice of optimal values for geometric and force parameters of the walking sampler. A conceptual design of the walking sampler has been developed, taking into account the mutual location and coupling of its main components, the overall dimensions of the delivery tool, as well as the esthetic component of the device.
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Date submitted2022-03-22
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Date accepted2022-06-15
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Date published2022-07-26
Gold in biogenic apatites of the Baltic-Ladoga phosphorite basin
- Authors:
- Sergey B. Felitsyn
- Nadezhda A. Alfimova
The distribution of gold in biogenic apatites from the Ordovician deposits in the northwest of the East European Platform shows that the maximum concentration of gold in apatites is found within the Ladoga-Baltic suture zone. Gold mineralization has a superimposed character, which is confirmed by the dependence of the gold content on the size of apatite particles and a number of isotope geochemical systematics in biogenic apatites. Gold is present in the form of high fineness particles to 20 µm in size on the surface of biogenic apatite fragments (phosphate brachiopod shells and conodont elements) and is easily extracted. In 10 % of samples of biogenic apatites, the total content of rare earth elements is more than 1 wt.%.
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Date submitted2021-10-19
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Date accepted2021-11-30
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Date published2021-12-27
Potential technological solution for sampling the bottom sediments of the subglacial lake Vostok: relevance and formulation of investigation goals
The subglacial Lake Vostok in Antarctic is a unique natural phenomenon, its comprehensive study involves sampling of water and bottom surface rocks. For further study of the lake, it is necessary to drill a new access well and develop environmentally safe technologies for its exploration. This article discusses existing and potential technologies for sampling bottom surface rocks of subglacial lakes. All these technologies meet environmental safety requirements and are conducive for sampling. The authors have proposed an alternative technology, using a walking device, which, due to its mobility, enables selective sampling of rocks across a large area from a single access well. The principal issues, related to the implementation of the proposed technology, are investigated within this article. This report is prepared by a team of specialists with many years of experience in drilling at the Vostok Station in Antarctic and in experimental work on the design of equipment and non-standard means of mechanization for complicated mining, geological and climatic conditions.
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Date submitted2018-07-05
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Date accepted2018-08-31
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Date published2018-12-21
The lake Il’men clint, Russia: a potential devonian geopark
- Authors:
- John E.A. Marshall
- David J. Siveter
The Devonian rocks exposed on the shores of Lake Il’men, some 150 km SSE of Saint Petersburg, are important historically in the context of the recognition of the Devonian System. Moreover, they provide unique potential for a range of geological studies today. The non-geological heritage of the area – its flora, fauna, past and current industrial use and cultural links – is also a very worthy one. Since 2001 the area has been recognised asa Specially Protected Natural Territory. A ‘Geopark’ is a unified area of local or wider extent that has been so designated based on its significant geological and associated natural and cultural heritage. There are many positive criteria for considering that the Lake Il’men area could acquire the appellation of a Geopark. Scientific investigations dedicated to understanding the geodynamical conditions operating at Lake Il’men would resolve how to best to help promote the future preservation of this unique natural area.
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Date submitted2016-11-21
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Date accepted2017-01-23
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Date published2017-04-14
Prospects of obtaining samples of bottom sediments from subglacial lake Vostok
- Authors:
- N. I. Vasilev
- G. L. Leichenkov
- E. A. Zagrivnyi
The paper proves the timeliness of obtaining and examining bottom sediments from subglacial Lake Vostok. Predictive geological section of Lake Vostok and information value of bottom sediments have been examined. Severe requirements towards environmental security of lake examinations and sampling of bottom sediments rule out the use of conventional drilling technologies, as they would pollute the lake with injection liquid from the borehole. In order to carry out sampling of bottom sediments from the subglacial lake, it is proposed to use a dynamically balanced tool string, which enables rotary drilling without any external support on borehole walls to transmit counter torque. A theoretical analysis has been carried out to assess the operation of the tool string, which is a two-mass oscillatory electromechanical system of reciprocating and rotating motion (RRM) with two degrees of freedom.
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Date submitted2015-12-08
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Date accepted2016-02-20
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Date published2016-12-23
The ways of transformation of salt production from the saline lakes of Apsheron peninsula
- Authors:
- V. A. Mamedov
- Kh. Kh. Khalilova
The issues of salt production at salt lakes of Apsheron Peninsula in Azerbaijan are reviewed here. The paper objective is to examine the brine formation process and analyze the ways of transformation of salt extraction from the lakes of Apsheron Peninsula under ever increasing industrial development and urbanization. The research on ecological state of salt lakes at the peninsula have shown that the decades-long development of oil and gas and other industries had a dramatical impact on the natural properties of water resources in this area. Laboratory test revealed high concentrations of total hydrocarbons, phenols, toxic metals (Cd, Pb, Zn, Ni, Cu, V, Mo, etc.), surface-active suspended solids and other pollutants in water samples of salt lakes. The paper presents physical and chemical properties of Boyukshore Lake, which for many years was the republic’s primary source of cooking salt. Based on comparative analysis of obtained properties with the maximum allowable concentrations and international standards the level of pollution of natural salt lakes of Apsheron has been assessed and the contribution of each anthropogenic source to the pollution of these water bodies has been determined. The paper presents quantitative and qualitative properties and pictures of the lakes depicting formation of saline deposits and volumes of salt produced at brine lakes of Apsheron. It has been established that decades-long negative impact on the environment led to disruption of ecological balance of the open waters in the region. Most saline lakes in the peninsula lost their natural qualities and became unsuitable for salt production.
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Date submitted2015-08-21
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Date accepted2015-10-24
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Date published2016-04-22
Results of the 5G borehole drilling at russian antarctic station «Vostok» and researches of ice cores
- Authors:
- N. I. Vasilev
- A. N. Dmitriev
- V. Ya. Lipenkov
We produce an information about results and features of the 5G borehole drilling in Antarctic layer at Russian station Vostok. Main regularities of the change structured and physical properties by Antarctic ice layer depth, which determine mechanical and reological properties if ice, which influence to sinking of a borehole and to the maintaining of it in a working condition, the safe and competitive technologies creation for drilling of strong ice layers and the environmentally safe technology of the subglacial reservoirs unsealing. We also produce results of the ice cores researching and the paleoclimatic raws construction, which are reconstructed by the ice cores researching from Vostok station, which is compared with isotopic graph. This graph describes changes of World ocean level.
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Date submitted2014-06-24
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Date accepted2014-08-31
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Date published2014-12-22
Unique engineering and technology for drilling boreholes in Antarctic ice
- Authors:
- Vladimir S. Litvinenko
As the result of many years of research into the processes of the transfer of ice as a rock mass on a global scale, concerning the Antarctic ice sheet at the ultra-deep 5G borehole, a discovery has been made that is of international significance in the areas of glaciology and geodynamics. Those who created the theory of thermal and mechanical penetration into ice and loose sediments have developed unique technology and engineering processes in order to drill boreholes using thermal and mechanical methods.
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Date submitted2010-07-28
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Date accepted2010-09-30
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Date published2011-03-21
Ingineering geological problems of high-rise construction with underground space development in Saint-Petersburg
- Authors:
- R. E. Dashko
- A. M. Zhukova
The history of high-rise construction is considered summarily. The main features of high-rise buildings and difficulties connected with theirs engineering and construction especially with underground space development and deep excavations in soft water saturated soils are characterized. Territorial construction guides «Residential and social high-rise buildings» prevail in Saint-Petersburg are analyzed in the context of recommendations for reliable basement choice. Brief description of Pre-Quanernary clays (Upper Vendian clays and Lower Cambrian clays) as basement for high-rise constructions are given. It is placed emphasis that the main feature of Pre-Quaternary clays is zone sequence of physical and mechanical properties and fissuring in depth. Physical and mechanical properties of Upper Vendian clays, Lower Cambrian clays and glacial clays are given. In addition, it is confirmed that glacial soils is not recommended to use as a basement for high-rise buildings.
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Date submitted2009-07-22
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Date accepted2009-09-14
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Date published2010-04-22
Cycles of the Earth and Sun – the important factor оf activity of geodynamic processes at coal- and ore mines
- Authors:
- A. N. Shabarov
- B. G. Tarasov
The paper contains the substantiation of the determinable role of the cosmos in rhythms of natural and technogenic phenomena at coal- and ore mines. The latent and explicit periods of up-to-date phase of attenuation of the solar constant in the cycle since 1982 to 2070 are shown, as well as the geodynamic consequences of this depression. This paper seeks to give rise to discussion of this problem for working out of coordinated actions in the decrease of geodynamic risks.