Submit an Article
Become a reviewer
Vol 278
Pages:
67-76
In press

The influence of seasonal changes in the physicochemical properties of fresh water on the rheological properties of hydraulic fracturing fluids (a case study of the Almetyevsk District, Republic of Tatarstan)

Authors:
Ilya A. Alenkin1
Arslan V. Nasybullin2
Aleksandr V. Kochetkov3
Rinat R. Zakirov4
Timur L. Gaifullin5
Ramis R. Sakhibgaraev6
About authors
  • 1 — Junior Researcher lmetyevsk State Technological University “Petroleum Higher School” ▪ Orcid
  • 2 — Ph.D., Dr.Sci. Head of Department Almetyevsk State Technological University “Petroleum Higher School” ▪ Orcid
  • 3 — Ph.D. Leading Expert on New Reagents PJSC Tatneft named after V.D.Shashin ▪ Orcid
  • 4 — Engineer Almetyevsk State Technological University “Petroleum Higher School” ▪ Orcid
  • 5 — Postgraduate Student Almetyevsk State Technological University “Petroleum Higher School” ▪ Orcid
  • 6 — Chief Design Expert PJSC Tatneft named after V.D.Shashin ▪ Orcid
Date submitted:
2025-06-10
Date accepted:
2025-12-09
Online publication date:
2026-03-19

Abstract

The work investigates the influence of seasonal changes in the composition of fresh water on the rheological properties of guar‑borate hydraulic fracturing fluids. Between October 2024 and August 2025, monthly samples were taken from three sources in the Republic of Tatarstan, with analysis of pH (7.3-7.9), alkalinity (73-275 mg/l HCO-3), total hardness (180-520 mg/l Ca2⁺+ Mg2⁺), chlorides (42-284 mg/l), sulphates (61-146 mg/l), and iron ions (0.1-0.3 mg/l). Fracturing fluids were prepared using these waters and tested on a Brookfield PVS high‑pressure rheometer at 32 °C in accordance with ISO 3219:1993. The target viscosity range was approximately 400-700 mPa·s. We found that in water with high salinity (source N 2, average hardness ~419 mg/l, Cl>180 mg/l), gel viscosity decreased by 10-15 %, the time to recover to operating viscosity increased, and breakdown accelerated, which raised the risk of premature proppant settling. Correlation analysis showed strong positive correlations between hardness, chlorides, sulphates, and alkalinity (r  =  0.53-0.90) for “soft” sources N 1 and 3, whereas in the mineralized water of source N 2 these correlations are weakened (r  =  0.17-0.51). The results demonstrate that the seasonal increase in salinity (winter‑spring period) significantly impairs the rheological stability of hydraulic fracturing fluids and emphasize the need for mandatory monitoring of water composition and adaptation of formulations during periods of peak salinity.

Область исследования:
Geotechnical Engineering and Engineering Geology
Keywords:
hydraulic fracturing hydraulic fracturing fluids guar based fluids borate crosslinkers rheological properties water quality gel breakdown viscosity recovery proppant placement efficiency
Funding:

None

Go to volume 278

References

  1. Zhiqiang Xie, Dongya Han, Jiangteng Li, Kaihui Li. A State-of-the-Art Review of Hydraulic Fracturing in Geothermal Systems. Sustainability. 2024. Vol. 16. Iss. 24. N 11087. DOI: 10.3390/su162411087
  2. Hui Gao, Xiaohang Li, Teng Li et al. Characteristics of Oil Production by Fracturing Fluid Additive-Assisted Displacement in Tight Oil Reservoirs. Energy & Fuels. 2024. Vol. 38. Iss. 18, p. 17541-17553. DOI: 10.1021/acs.energyfuels.4c02634
  3. Hao Yu, WenLong Xu, Bo Li et al. Hydraulic Fracturing and Enhanced Recovery in Shale Reservoirs: Theoretical Analysis to Engineering Applications. Energy & Fuels. 2023. Vol. 37. Iss. 14, p. 9956-9997. DOI: 10.1021/acs.energyfuels.3c01029
  4. Sultanov S.K., Mukhametshin V.Sh., Stabinskas A.P. et al. Study of the possibility of using high mineralization water for hydraulic fracturing. Journal of Mining Institute. 2024. Vol. 270, p. 950-962.
  5. Fokker P.A., Borello E.S., Verga F., Viberti D. Harmonic pulse testing for well performance monitoring. Journal of Petroleum Science and Engineering. 2018. Vol. 162, p. 446-459. DOI: 10.1016/j.petrol.2017.12.053
  6. Khan H.J., Spielman-Sun E., Jew A.D. et al. A Critical Review of the Physicochemical Impacts of Water Chemistry on Shale in Hydraulic Fracturing Systems. Environmental Science & Technology. 2021. Vol. 55. Iss. 3, p. 1377-1394. DOI: 10.1021/acs.est.0c04901
  7. Khuzin R.R., Andreev V.E., Mukhametshin V.V. et al. Influence of hydraulic compression on porosity and permeability properties of reservoirs. Journal of Mining Institute. 2021. Vol. 251, p. 688-697. DOI: 10.31897/PMI.2021.5.8
  8. Almuhametova E.M., Gutorov A.Yu., Yumadilov D.B. et al. Reducing the cost of hydraulic fracturing. Petroleum Engineering. 2024. Vol. 22. N 5, p. 103-112 (in Russian). DOI: 10.17122/ngdelo-2024-5-103-112
  9. Jiarun Zhou, Shibin Wang, Ruoyu Yang et al. A Study on a Novel Hydrophobic Associative Polymer Thickener for High-Salinity Water in Hydraulic Fracturing. ChemistrySelect. 2025. Vol. 10. Iss. 20. N e01613. DOI: 10.1002/slct.202501613
  10. Rodriguez A.Z., Huiyao Wang, Lei Hu et al. Treatment of Produced Water in the Permian Basin for Hydraulic Fracturing: Comparison of Different Coagulation Processes and Innovative Filter Media. Water. 2020. Vol. 12. Iss. 3. N 770. DOI: 10.3390/w12030770
  11. Zang A., Hofmann H., Yinlin Ji et al. How rock hydraulic fatigue methods from mining and petroleum industry assist in unlocking deep heat for a clean energy future. Renewable and Sustainable Energy Reviews. 2025. Vol. 217. N 115683. DOI: 10.1016/j.rser.2025.115683
  12. Vylomov D.D., Shulgin P.A., Shakirov R.R., Snohin A.A. Selection of an alternative hydraulic fracturing fluid in the conditions of a low permeability gas reservoir turonian. Exposition Oil Gas. 2023. N 2 (95), p. 56-61 (in Russian). DOI: 10.24412/2076-6785-2023-2-56-61
  13. Nasybullin A.V., Sadreeva R.Kh., Burlutsky E.A. Determination of the efficiency of clay stabilizer component of fracturing fluid through coreflood experiments with terrigenous clay reservoir rock samples. Neftyanaya provintsiya. 2023. N 2 (34), p. 208-226 (in Russian). DOI: 10.25689/NP.2023.2.208-226
  14. Musin R.Kh., Galieva A.R., Khamitov A.D. Transformation of fresh groundwater composition over time in the Republic of Tatarstan. Uchenye zapiski Kazanskogo universiteta. Seriya Estestvennye nauki. 2023. Vol. 165. N 3, p. 427-446 (in Russian). DOI: 10.26907/2542-064X.2023.3.427-446
  15. Rakhimov I.I., Zainullin M.A., Ignashev N.E. Natural and technogenic water bodies as reserves for the conservation of biological diversity in the Republic of Tatarstan: problem statement and analysis. The Academic Journal of Moscow City University. Series “Natural Sciences”. 2023. N 2 (50), p. 21-36 (in Russian). DOI: 10.25688/2076-9091.2023.50.2.02
  16. Musin R.Kh., Kalkamanova Z.G. Geochemistry of fresh groundwater in regions with oil technogenesis (on the example of Tatarstan). Georesources, Geoenergetics, Geopolitics. 2015. N 2 (12), p. 14 (in Russian). DOI: 10.29222/ipng.2078-5712.2015-12.art12
  17. Musin R.Kh., Galieva A.R., Kudbanov T.G. et al. Soil influence on the chemical composition of ground waters in the republic of Tatarstan. Proceedings of higher educational establishments. Geology and Exploration. 2020. Vol. 63. N 1, p. 90-99 (in Russian). DOI: 10.32454/0016-7762-2020-63-1-90-99
  18. Korcheva E.S., Stepanova S.V., Shaikhiev I.G. Assessment of the Kazanka River water quality. Bulletin of the Technological University. 2016. Vol. 19. N 20, p. 186-189 (in Russian).
  19. Milke J., Gałczyńska M., Wróbel J. The Importance of Biological and Ecological Properties of Phragmites Australis (Cav.) Trin. Ex Steud., in Phytoremendiation of Aquatic Ecosystems – The Review. Water. 2020. Vol. 12. Iss. 6. N 1770. DOI: 10.3390/w12061770
  20. Mingazova N.M., Nabeeva E.G., Cheban E.Yu. et al. Water quality assessment of Kuibyshev reservoir in the Tatarstan Republic according to the expedition “Floating University”. Problemy ehkologii Volzhskogo basseina: Trudy 8-i vserossiiskoi nauchnoi konferentsii, 21-22 noyabrya 2023, Nizhnii Novgorod, Rossiya. Nizhnii Novgorod: Volzhskii gosudarstvennyi universitet vodnogo transporta, 2023. Iss. 6, p. 5 (in Russian).
  21. Leiming Li, Al-Muntasheri G.A., Feng Liang. A review of crosslinked fracturing fluids prepared with produced water. Petroleum. 2016. Vol. 2. Iss. 4, p. 313-323. DOI: 10.1016/j.petlm.2016.10.001
  22. Das P., Konale S., Kothamasu R. Effect of Salt Concentration on Base-gel Viscosity of Different Polymers used in Stimulation Fluid Systems. SPE/EAGE European Unconventional Resources Conference and Exhibition, 25-27 February 2014, Vienna, Austria. OnePetro, 2014. N SPE-167786-MS. DOI: 10.2118/167786-MS
  23. Earnden L., Laredo T., Marangoni A.G. et al. Modulation of the Viscosity of Guar-Based Fracking Fluids Using Salts. Energy & Fuels. 2021. Vol. 35. Iss. 19, p. 16007-16019. DOI: 10.1021/acs.energyfuels.1c02835
  24. Salnikova Yu.I. Results of studies on the compatibility of formation and injected water in hydrocarbon fields in Western Siberia. Advances in current natural sciences. 2024. N 2, p. 44-53 (in Russian). DOI: 10.17513/use.38217
  25. Shvydkyi V.O., Dubovik A.S., Kozlov M.V. et al. The Effect of the Physicochemical Properties and the Composition of Dubna River Water on the State of the Processes of Lipid Peroxidation in Biological Systems. Water Resources. 2024. Vol. 51. N 4, p. 525-533. DOI: 10.1134/S0097807824700933
  26. Kilyanov M.Yu., Igrevsky L.V., Khafizov S.F. et al. Efficiency improvement of Bactericides and Biostats Application when Using Seawater in a Reservoir Pressure Maintenance System. Kazakhstan journal for oil & gas industry. 2023. Vol. 5. N 3, p. 59-70 (in Russian). DOI: 10.54859/kjogi108636
  27. Pereira G.F., Rosin T.R., Braga B. et al. Evaluation of biofilm inhibition and detachment by commercial biocides in sulfate-reducing bacteria consortia from oil fields. Journal of Water Process Engineering. 2024. Vol. 63. N 105547. DOI: 10.1016/j.jwpe.2024.105547
  28. Buldakova N.S., Novikova N.V., Fakhrieva G.V. et al. Formation of approaches to the selection of bactericides to suppress the vital activity of sulphate-reducing bacteria. Oilfield engineering. 2020. N 6 (618), p. 68-72 (in Russian). DOI: 10.30713/0207-2351-2020-6(618)-68-72
  29. Mammedov K.A., Hamidova N.S. Application of Integrated Activity Bactericide for Corrosion Protection of Oilfield Equipment and Pipelines. Oil and Gas Territory. 2018. N 3, p. 20-25 (in Russian).
  30. Arroyo J.I., Díez B., Kempes C.P. et al. A general theory for temperature dependence in biology. PNAS. 2022. Vol. 119. N 30. N e2119872119. DOI: 10.1073/pnas.2119872119
  31. Mushaeva T.I., Demidov V.V. Regularities of formation and erosion processes during spring snowmelt on the territory of agrolandscape and their impact on the quality of river water. Live and bio-abiotic systems. 2015. N 11, p. 9 (in Russian).
  32. Okwonu F.Z., Chiyeaka O.M., Ahad N.A., Sharipov O. Robust Pearson correlation coefficient for imbalanced sample size and high dimensional data set. Science World Journal. 2025. Vol. 20. N 1, p. 131-136. DOI: 10.4314/swj.v20i1.17

Similar articles

Reagent treatment of fluorin-containing wastewater from the processing industry
2026 Yuliya D. Peresunko, Anastasiya A. Pisareva, Sergei V. Azopkov, Evgenii N. Kuzin, Nataliya E. Kruchinina
Geological and geochemical characteristics of solid bitumen inclusions in volcanites of the pre-Jurassic complex of the Litvakovsky oil field
2026 Gulmira T. Salakhidinova, Mikhail G. Kulkov, Konstantin Yu. Kudrin, Roman I. Butyrin, Azim E. Aliev, Evgenii M. Motoshin
Three-dimensional modeling of stress-strain state and rock massif stability analysis during the construction of an underground research laboratory
2026 Viktor N. Tatarinov, Vladimir S. Gupalo, Dastan Zh. Akmatov, Aleksandr I. Manevich, Roman V. Shevchuk, Ilya V. Losev, Artem A. Kamaev
Investigation of rock burst hazard formation features in tectonic discontinuity zones of the Khibiny deposits
2026 Ilya I. Bagautdinov, Arkadii N. Shabarov
Geometric models of typical complex-structured bench blocks
2026 Bayan R. Rakishev, Abdraman I. Edilbaev, Auzhan S. Sakabekov, Asfandiyar A. Orynbay, Nazira A. Mekebai, Temirlan S. Ibyrkhanov
Biogeochemical characterization and assessment of geoecological risks in the Daldyn kimberlite field
2026 Anna G. Gololobova, Yana B. Legostaeva