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Date submitted2022-10-23
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Date accepted2023-02-13
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Date published2023-12-25
Sorption purification of acid storage facility water from iron and titanium on organic polymeric materials
Obtaining and production of metals from natural raw materials causes a large amount of liquid, solid, and gaseous wastes of various hazard classes that have a negative impact on the environment. In the production of titanium dioxide from ilmenite concentrate, hydrolytic sulphuric acid is formed, which includes various metal cations, their main part is iron (III) and titanium (IV) cations. Hydrolytic acid waste is sent to acid storage facilities, which have a high environmental load. The article describes the technology of ion exchange wastewater treatment of acid storage facility from iron (III) and titanium (IV) cations, which form compounds with sulphate ions and components of organic waste in acidic environments. These compounds are subjected to dispersion and dust loss during the evaporation of a water technogenic facility, especially in summer season. Sorption of complex iron (III) cations [FeSO4]+ and titanyl cations TiO2+ from sulphuric acid solutions on cation exchange resins KU-2-8, Puromet MTS9580, and Puromet MTS9560 was studied. Sorption isotherms were obtained both for individual [FeSO4]+ and TiO2+ cations and in the joint presence. The values of the equilibrium constants at a temperature of 298 K and the changes in the Gibbs energy are estimated. The capacitive characteristics of the sorbent were determined for individual cations and in the joint presence.
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Date submitted2023-01-27
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Date accepted2023-03-04
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Date published2023-04-25
Use of the UNIFAC model in the calculation of physicochemical properties of ecotoxicants for technological and ecoanalytical purposes
- Authors:
- Vladimir G. Povarov
- Ignatyi I. Efimov
Modern development vector of environmental monitoring leads to elaboration of analytical methods for qualitative and quantitative analysis of different ecotoxicants. Many studies face the lack of information on isomers and homologues of already studied compounds. This problem cannot always be solved experimentally due to the difficulty of separating or synthesizing certain compounds; the use of group theories of solutions will help partly; using them, solubility in water or partition coefficient between two immiscible solvents is calculated for ecotoxicants. These parameters are important for solving the analytical and ecological problems. The partition coefficient in the octanol – water system is associated with a possibility of accumulation of different compounds in living organisms; the partition coefficient in the hexane – acetonitrile system can be used in gas chromatographic analysis. Solubility in water is closely associated with accumulation of ecotoxicants in water bodies, as well as with their ability to be transferred. This paper presents the capabilities of the UNIFAC model for solving physicochemical problems using the example of calculating the properties of real ecotoxicants on the basis of the available thermodynamic data. All the obtained calculated values were compared with those determined experimentally. In the case of pyrene derivatives, solubility data were obtained for the first time using a correlation group model to calculate the heat of fusion and melting temperature.
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Date submitted2021-04-23
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Date accepted2021-09-07
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Date published2021-12-16
Development of the concept of an innovative laboratory installation for the study of dust-forming surfaces
Currently, the determination of the emission rate of suspended solids from a unit of the surface area of a man-made mass at various parameters of the wind flow is not sufficiently described. The analysis of the world experience of researchers shows that existing laboratory installations have various design features that do not allow to correctly determine the mass of the dust being flapped and wind-blown. Based on the analysis results, the concept of an innovative laboratory installation for the study of dust-forming surfaces has been developed. It takes into account the influence of wind shadows, the deturbulization of an artificially created air flow, the possibility of regulating not only the flow velocity mode, but also the creation of a vacuum or disturbance in the area of sample placement, as well as the formation of a certain angle of wind flow attack relative to the surface. The concept provides for the possibility of determining the volume of dust emissions by the values of the lost dust masses in the sample and by the values of dust concentrations in the outgoing stream. The calculation of the main basic elements of the installation using the ANSYS FLUENT software package was carried out. The model and configuration of the wind tunnel have been developed and calculated, the main geometric parameters and functional elements for the possibility of use in scientific work have been determined. For practical use of the empirical roughness value of the underlying surface, its values are recommended in a wide range – from zero for the water surface to 0.44 for large cities with tall buildings and skyscrapers.
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Date submitted2020-05-07
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Date accepted2020-05-24
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Date published2020-06-30
Study of the technogenesis of the Degtyarsky mine by audio-magnetotelluric express sounding
- Authors:
- Vadim A. Davydov
The audio-magnetotelluric express sounding was performed at four sections crossing the mine field of the currently not functioning Degtyarsky mine. Field measurements were carried out by a universal broadband receiver “OMAR-2m” with active electromagnetic field sensors developed at the Institute of Geophysics UB RAS. Based on the obtained data, deep sections of the electrophysical parameters of the medium – apparent resistivity and effective longitudinal conductivity – are drawn. The nature of the geoelectric structure of the section allows mapping of the major lithochemical contamination plume and identifying the tectonic disturbance zones that drain aggressive mine waters. The mine waters of the Degtyarsky mine are a source of dangerous technogenic pollution. Despite the neutralization of surface runoff, underground routes of acidic water migration occur along tectonic cracks, primarily in the zone of the regional Serovsko-Mauksky fault. Tectonic zones in the mine area contain contaminated fissure-vein water, which is transited at a depth of 70 to over 200 m. Discharging ascending springs of such waters can be located at a great distance from controlled hydrological objects and pollute sources of drinking and household water supply. Urban development in the western and eastern parts of Degtyarsk does not fall within the distribution zone of polluted water. The southern part of the city is located beyond the watershed of the mine water flow area, but a danger of local contamination by tectonic disturbance zones remains possible. The worst environmental situation is observed in the northern outskirts of Degtyarsk, which falls into the area of heavy pollution of underground and surface waters. Besides, acidic fumes from the flooded Kolchedanny quarry can affect the health of city residents when emitted to the atmosphere.
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Date submitted2020-01-10
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Date accepted2020-01-14
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Date published2020-02-25
Biogeochemical assessment of soils and plants in industrial, residential and recreational areas of Saint Petersburg
Soils and plants of Saint Petersburg are under the constant technogenic stress caused by human activity in industrial, residential, and recreational landscapes of the city. To assess the transformed landscapes of various functional zones, we studied utility, housing, and park districts with a total area of over 7,000 hectares in the southern part of the city during the summer seasons of 2016-2018. Throughout the fieldwork period, 796 individual pairs of soil and plant samples were collected.A complex of consequent laboratory studies performed in an accredited laboratory allowed the characterization of key biogeochemical patterns of urban regolith specimens and herbage samples of various grasses. Chemical analyses provided information on the concentrations of polluting metals in soils and plants of different land use zones.Data interpretation and calculation of element accumulation factors revealed areas with the most unfavorable environmental conditions. We believe that a high pollution level in southern city districts has led to a significant degree of physical, chemical, and biological degradation of the soil and vegetation cover. As of today, approximately 10 % of the Technosols in the study area have completely lost the ability to biological self-revitalization, which results in ecosystem malfunction and the urgent need for land remediation.
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Date submitted2009-10-21
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Date accepted2009-12-05
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Date published2010-09-22
Ecologycal and geodynamic safety and problems in industrial ecological monitoring at objects of an oil-gas complex
- Authors:
- A. I. Nikonov
- O. V. Luk"yanov
This article is focused on the influence of modern geodynamics on landscape and its structure. Modern geodynamical processes manifest in anomalous rock deforming in the fault zones. Their natural or technogenic activation causes the appearance of dangerous geological processes. It can be taken into account only by geodynamical monitoring on the objects of oil and gas industry.
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Date submitted2009-09-14
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Date accepted2009-11-30
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Date published2010-06-25
Humanitarization of the ecological education аs a function of the ecological expert training system
- Authors:
- I. G. Rebeshchenkova
Ecological crisis is the essential part of the total crisis of the modern civilization. It is the consequence of the number of the causes, including dehumanization of society, moral decadence, loss of need in the beauty and so on. These processes are the special danger for the young generation. For the neutralization of the negative processes it is necessary to combine the ecological education with the ecological training, is engaged in its humanitarisation. In this connection we have the task of the creation of the ecological preparation system of the specialists. Saint Petersburg State Mining Institute is the first institute in Russia, in which are introduced the disciplines of the ecological profile and in which is accumulated the considerable experiment in the education of the engineers-ecologists, is created the scientific base and the skilled workers, is extended the spectrum of the directions and the disciplines – is laid of the stable foundation for the proposed system of the ecological education. The natural-science and engineering blocks of this foundation with the necessity must are cemented with the block of the social and humanistic disciplines, including ecoethics, ecoesthetics, ecopsychology, ecophilosophy, ecohistory, ecopolitology, ecoethnology, etc.
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Date submitted2008-11-01
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Date accepted2009-01-27
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Date published2009-12-11
The influence of the technological and organizational factors on the steady growth of the mining industry
- Authors:
- E. M. Pronin
- V. E. Vasiliev
The steady growth of the mining industry calls forth the character of its activities connected with the dependence of the work on the natural conditions which are practically unpredictable and constantly changeable. The two basic factors are chosen – the technology of the mining work and the organization of the industry, which have the decisive importance in the increasing of the basic indices of the activity of the enterprise. The possible technological and organizational solutions are offered as they permit to find possible directions in the lowering of the negative influence of the appearing problems.
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Date submitted2008-11-16
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Date accepted2009-01-30
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Date published2009-12-11
Social and ecological responsibility of mineral and raw materials companies
- Authors:
- A. O. Kharchenko
In this article the author describes the basic concept of the corporate social responsibility, analyzes main features and standards of making of social reports of major companies. Specificity of reports in the Russian companies is allocated, and some offers with a view of activization of promotion both further ordering CSR and the eco-reporting in the Russian Federation on the basis of introducing new administrative and economic methods.