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Date submitted2024-05-06
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Date accepted2024-06-14
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Date published2024-07-04
Natural carbon matrices based on brown coal, humic acids and humine extracted from it for purification of aqueous solutions from low molecular weight organic impurities
Heterogeneous systems including natural carbon matrices in the solid phase and aqueous solutions of low molecular weight organic compounds with positive and negative variations from ideality in the liquid phase are considered. The technical characterization of the considered supramolecular ensembles on the basis of brown coal of the Kara-Keche deposit (Kyrgyzstan), humic acids and humine extracted from it is given. Functional analysis of the samples was carried out using FTIR spectroscopy. The morphology of the surface of the considered carbon matrices has been investigated, in different points of which the local microelement composition has been established. An X-ray phase analysis of Kara-Keche brown coal and humic acids and humine extracted from it was carried out. The isothermal adsorption of bipolar molecules of glycine and urea, neutral D-glucose from aqueous solutions on solid carbon sorbents has been studied. An assumption has been made about the adsorption of low molecular weight organic compounds from aqueous solutions on humine and Kara-Keche coal in irregularities and pores of the carbon matrix of sorbents, for humic acids – on surface reaction centers. Due to its developed pore structure and resistance to acids and alkalis, humine from Kara-Keche coal is recommended for the purification of industrial wastewater from low molecular weight organic ecotoxicants.
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Date submitted2022-10-31
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Date accepted2023-04-21
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Date published2024-02-29
Study of the properties and action of polyelectrolytes in the treatment of the dressing plant’s discharges
The organization of intrafactory water circulation at mining and processing enterprises, when production wastes and discharges are not sent to an external tailings dump, is an urgent environmental and economic task. Returning even a part of water into the technological process after preliminary treatment will significantly reduce the volume of polluted water discharged into tailings, which will reduce energy costs for waste transportation and the negative environmental impact. One of the wastes sent to the tailings during the ore dressing wastes from the Kovdor deposit to the tailings dump is the discharge of thickeners for the preparation of apatite flotation feed. In order to choose the effective discharge cleaning regime, the authors have evaluated the action of polyacrylamide flocculants. It has been discovered that the apatite and calcite particles interact more effectively with the anionic flocculant. This fact determines its advantage for the treatment of suspended particles. The influence of the residual concentration of a flocculant on the apatite flotation, where a part of the returned treated water goes, has been assessed. Compared to flotation with recycled water, there is a decrease of P2O5 extraction into apatite concentrate of equal quality. In order to obtain the required enrichment indicators on the treated water, it is necessary to adjust the collector (tall oil fatty acids) and depressor (liquid glass) costs.
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Date submitted2021-03-31
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Date accepted2022-04-26
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Date published2022-11-03
Features of obtaining metallurgical products in the solid-state hydride synthesis conditions
- Authors:
- Andrey G. Syrkov
- Lyudmila A. Yachmenova
A scientific substantiation of solid-phase feedstock choice and preparation has been carried out, and the thermodynamic and kinetic aspects of solid-state hydride synthesis (SHS) of metal products have been analyzed using the nickel dichloride reduction as an example. The preliminary dehydration modes and methods for controlling the complete removal of crystalline water from chloride raw materials and Olenegorsk superconcentrate, which is natural oxide raw material, are described. Conditions, including initial solid chloride particle sizes, are established under which diffusion complications of reduction to metal in methyldichlorosilane vapor are minimized. Thermodynamic estimates of nickel chlorides and oxides reduction possibility, iron and copper with ammonia and methane at temperatures of 400-1000 K in equilibrium conditions have been carried out. It has been shown that the stoichiometric coefficients of the nickel dichloride in ammonia overall reduction reaction calculated by thermodynamic modeling are in agreement with experimental data. In contrast to the copper dichloride reduction, for nickel dichloride the formation of metal monochloride at the intermediate stage is uncharacteristic, which is associated with a higher thermal stability of nickel dichloride. The main kinetic regularities of the reduction of nickel, copper, and iron to metal under SHS conditions in ammonia, monosilane, and methane, as well as the nickel dichloride with methyldichlorosilane vapor and methane successive reduction, are considered. Approximation of experimental data by topochemical equations in a linear form showed that for reduction degrees a up to 0.7-0.8, these data are satisfactorily described by the Roginsky – Schultz equation. For a > 0,8 the “shrinking sphere” model works better, which confirms the localization of the solid-state reduction reaction at the interface, moves deep into the crystal with the formation of a of interlocked metal germs. The importance and prospects of the results obtained for the theory development of metallurgical processes, deep complex processing of natural iron oxide raw materials, metal products and new generation materials production, including superhydrophobic ones, are discussed. The relevance of the study from the point of view of applying the method of physical and chemical analysis to the study of complex heterogeneous metallurgical processes is noted.
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Date submitted2022-04-13
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Date accepted2022-05-25
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Date published2022-11-03
Mineralogical and technological features and patterns of selective disintegration of ferruginous quartzites of the Mikhailovskoye deposit
The growing demand for ferrous metallurgy products necessitates the introduction of technologies that increase the efficiency of the processing of iron-bearing raw materials. A promising trend in this area is the implementation of solutions based on the possibility of selective disintegration of ores. The purpose of this work was to establish the laws of selective disintegration of ferruginous quartzites based on the results of the study of mineralogical and technological properties of raw materials. We present data on the study of mineralogical and technological features of ferruginous quartzites of the Mikhailovskoye deposit. The data were obtained using X-ray fluorescence analysis and automated mineralogical analysis. Based on studies of the nature of dissemination and the size of grains of rock-forming and ore minerals, the tasks of ore preparation are formulated. The parameters for the iron and silicon oxide distribution by grain-size classes in the grinding products were established during the study. Based on empirical dependences, the grain size of grinding was predicted, at which the most effective release of intergrowths of ore minerals and their minimum transition to the size class of –44 µm should be achieved.
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Date submitted2022-04-14
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Date accepted2022-07-21
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Date published2022-11-03
In-situ leaching of molybdenum and uranium by percarbonate and chloride-hypochlorite solutions
In-situ leaching of molybdenum and uranium is becoming an increasingly common process. The features of the material composition of ores, leading to a decrease in their filtration properties, were considered. Activation leaching with leaching solutions that have undergone electrophotochemical activation before contact with the ore mass were studied. Activation preparation of leaching solutions promotes the synthesis of clustered water molecules with collectivized protons and hydroxyl ions, as well as active forms of oxygen and hydrogen. Cell leaching of molybdenum from mature tailings of the Shakhtaminsk deposit was studied experimentally. After pre-oxidation with an active carbonate solution, a model borehole leaching was carried out with a chloride-hypochlorite solution. Molybdenum extraction on resin a was 85 % in 30 days. Experiments on the percolation leaching of uranium from the ores of the Uchkuduk and Sugraly deposits confirmed the potential possibility of a significant increase in the extraction of uranium by electrophotoactivated percarbonate solutions relative to aqueous solutions of sodium and ammonium carbonate. When leaching with carbonate solutions without an additional oxidizing agent, the extraction of uranium from the Sugraly deposit ore sample was 52 and 59 % (sodium carbonate and ammonium carbonate). The use of hydrogen peroxide as an oxidizing agent made it possible to achieve 87-88 % extraction into pregnant solutions in 21 days without pre-oxidation. The performed studies confirm the processing capability of extracting uranium and molybdenum by percolation leaching in columns and borehole leaching.
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Date submitted2019-07-09
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Date accepted2019-09-26
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Date published2020-04-24
Development of mathematical models to control the technological properties of cement slurries
Oil and gas producing enterprises are making increasingly high demands on well casing quality, including the actual process of injection and displacement of cement slurry, taking into account requirements for the annular cement level, eliminating possible hydraulic fracturing, with developing a hydraulic cementing program. It is necessary to prevent deep invasion of cement slurry filtrate into the formation to exclude bridging of productive layers. It is impossible to fulfill all these requirements at the same time without application of modifying additives; complex cement compositions are being developed and applied more often. Furthermore, need to adjust cement slurries recipes appears for almost every particular well. In order to select and justify cement slurries recipes and their prompt adjustment, taking into account requirements of well construction project, as well as geological and technical conditions for cementing casing strings, mathematical models of the main technological properties of cement slurries for cementing production casing strings in the Perm Region were developed. Analysis of the effect of polycarboxylic plasticizer (Pl) and a filtration reducer (fluid loss additive) based on hydroxyethyl cellulose (FR) on plastic viscosity (V), spreadability (S) and filtration (F) of cement slurries is conducted. Development of mathematical models is performed according to more than 90 measurements.
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Date submitted2015-07-07
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Date accepted2015-09-16
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Date published2016-02-24
Activation of heap leaching of low-sulfide ores the invisible gold
- Authors:
- A. G. Sekisov
- Yu. I. Rubtsov
- A. Yu. Lavrov
This article deals with a physical-chemical model of heap leaching processes justifying new technological approaches to recovering dispersed forms of gold from ores, placer sands and deute-rogene mineral raw materials. The key process of this model includes lattice diffusion of high-energy hydrion minerals and hydroxyl-radicals formed as a result of photochemical and electro-chemical processing of initial reagent aqueous solutions. Active components of gas-water emulsions obtained while processing initial reagent solutions provide a structural and material trans-formation of a mineral lattice which concentrates clusters of dispersed gold creating conditions for its interacting with complexing compounds of process solutions. The article also considers the technological processes of activation heap leaching of dispersed gold from the Pogromnoe ore field and the results of the experiments conducted in percolators with their charge ranged from 3 to 100 kg. The results have proved the efficiency of using gas-water suspensions prepared in the pho-toelectrochemical reactor with active ion-radical oxidizing agents.
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Date submitted2014-12-30
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Date accepted2015-02-03
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Date published2015-12-25
Open mining technique for unconventional mineral deposits
- Authors:
- G. A. Kholodnyakov
- K. R. Argimbaev
Nowadays the majority of deposits are successfully exploiting by mining enterprises with the help of traditional excavation and loading equipment. Typically, metals, construction materials, etc. are mined and extracted on these deposits, but modern society is progressing and producing new requirements to metals properties for creating a new type of equipment. The metals with new properties are located in unconventional areas: either in technogenic deposits (overburden dumps, tailings, etc.) or in hard-to-get natural formations. Technogenic mines, being a tailing of Kachkanarsky mining and processing plant, are referred to such unique deposits, which have expensive metals (scandium, gallium, strontium, titanium), as well as the natural deposit – rhenium deposit, located in the crater of an active volcano. Potentialities of open mining in the largest rhenium deposit with complex environmental occurrence have been analyzed in the paper. Temperature measurement results of adjacent strata and a temperature scheme of the host rocks on a separate site and the entire field have been presented. An open mining technique for a primary mining area as well as perspective methods of rock preparation for excavation, applicable to this particular deposit, has been considered.
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Date submitted2013-07-13
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Date accepted2013-09-03
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Date published2014-03-17
Technology options for the preparation of new horizons
- Authors:
- G. A. Kholodnyakov
- D. N. Ligotskii
The paper considers the advantages and disadvantages of technological options for the training of new horizons in the fields of mineral resources with large water production using excavators such as direct and backhoes.
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Date submitted2013-07-21
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Date accepted2013-09-04
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Date published2014-03-17
About the long-range programme for industrial and ecological safety in coal branch of industry
- Authors:
- V. V. Smirnyakova
The conditions and the main problems of Russian coal industry development have been envisaged, the purposes, problems and realization terms of the longrange programme for industrial and ecological safety in coal branch of industry and also amount of finance and waiting results have been shown in the article.
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Date submitted2013-07-27
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Date accepted2013-09-21
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Date published2014-03-17
Development free-chemical metod of cltaning water out from oil on the cmf companies
- Authors:
- M. A. Pashkevich
- I. A. Golubev
In this paper deals with the problem of pollution of oil-contaminated wastewater. A method of treatment which increases the quality of recyclable waste water, by improving existing production systems using Reagent-free method.
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Date submitted2009-09-20
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Date accepted2009-11-29
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Date published2010-06-25
Some facts of history of training and employment of mining engineers during 20-30th years of 20th century
- Authors:
- V. G. Afanasev
The article is dedicated to the problem of training mining engineers during the most difficult Soviet period. The problem was solved with foundation of new educational institution as well as reorganization of functional ones primarily Mining Institute. Reformation of universities was justified sometimes not. Disadvantage of reformation was repression to highly qualified specialists of mining. Personnel problem was solved that allowed to increase coal and oil extraction.
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Date submitted2009-09-12
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Date accepted2009-11-05
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Date published2010-06-25
Information culture as one of aspects forming linguistic skills of students in the technical universities
- Authors:
- A. V. Grinko
This paper deals with information culture as one of aspects forming linguistic skills. It is of greater extent defined by information proficiency of students in the technical universities.
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Date submitted2009-07-06
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Date accepted2009-09-24
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Date published2010-04-22
Investigation of geomechanical processes in underground mining of mineral resources at the automated test bench for physical modeling
- Authors:
- B. Yu. Zuev
The paper presents the particular results of development of the method for modeling on equivalent materials in the recent years, concerning the evolution of the primary technical base of the laboratory – test benches, which allowed to supplement substantially the potentialities of physical modeling for its complex application jointly with the full-scale and mathematical methods in solving a number of actual tasks in mining geomechanics.
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Date submitted2009-07-05
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Date accepted2009-09-25
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Date published2010-04-22
Active methods for control of geomechanical state of rock mass in coal deposit mining under complicated geological-and-mining conditions
- Authors:
- F. N. Voskoboev
- Yu. A. Semenov
- V. A. Zvezdkin
The paper presents the main technologies, characteristics, schematic diagrams and parameters of active methods for control of geomechanical state of technogenic rock mass, domain and technical-and-economical efficiency of their industrial application.