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Date submitted2024-04-16
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Date accepted2024-09-24
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Date published2024-11-12
Deep-buried Lower Paleozoic oil and gas systems in eastern Siberian Platform: geological and geophysical characteristics, estimation of hydrocarbon resources
The study of deep-buried oil and gas systems is a promising trend in the preparation of hydrocarbon resources. The study of the factors determining oil and gas potential is extremely important. The Lena-Vilyui sedimentary basin in the eastern Siberian Platform has a potential for the discovery of large oil and gas fields in deep-buried Cambrian deposits. The use of original methodological approaches to the analysis of black shale and overlying deposits, generalization of the results of lithological, biostratigraphic and geochemical studies of Cambrian deposits in territories adjoining the study area, modern interpretation of geophysical data showed that siliceous, carbonate, mixed rocks (kerogen-mixtite) of the Kuonamka complex and clastic clinoform-built Mayan deposits are most interesting in terms of oil and gas potential. Oil and gas producing rocks of the Lower and Middle Cambrian Kuonamka complex subsided to the depths of 14 km. The interpretation of modern seismic surveying data confirms the hypothesis of a limited occurrence of the Upper Devonian Vilyui rift system. Based on generalization of geological, geophysical and geochemical archival and new materials on the Lower Paleozoic deposits of the eastern Siberian Platform, a probabilistic estimation of geological hydrocarbon resources of the Cambrian and younger Paleozoic complexes in the Lena-Vilyui sedimentary basin was performed. Based on basin modelling results it was concluded that the resources were mainly represented by gas. It is presumed that oil resources can be discovered in traps of the barrier reef system as well as on the Anabar and Aldan slopes of the Vilyui Hemisyneclise. With a confidence probability of 0.9, it can be stated that total initial resources of oil and gas (within the boundaries of the Vilyui Hemisyneclise) exceed 5 billion t of conventional hydrocarbons. The recommended extremely cautious estimate of resources of the pre-Permian complexes is 2.2 billion t of conventional hydrocarbons. In the study area, it is necessary to implement a program of deep and super-deep parametric drilling without which it is impossible to determine the oil and gas potential of the Lower Paleozoic.
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Date submitted2024-04-25
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Date accepted2024-09-24
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Date published2024-11-12
Specific features of kinetics of thermal transformation of organic matter in Bazhenov and Domanik source rocks based on results of pyrolysis gas chromatography
Pyrolysis of organic matter with subsequent analysis of hydrocarbon composition of the resulting products allows obtaining multicomponent distribution spectra of the generation potential by the activation energies of reactions of kerogen transformation into hydrocarbons. Configuration of the spectra depends on the structure of kerogen and is individual for each type of organic matter. Studies of kerogen kinetics showed that the distribution of activation energies is unique for each oil source rocks. The kinetic model of thermal decomposition of kerogen of the same type, for example, marine planktonic (type II), can differ significantly in different sedimentary basins due to the multivariate relationship of chemical bonds and their reaction energy threshold. The developed method for calculating multicomponent kinetic spectra (four-component models are used) based on results of pyrolysis gas chromatography allows obtaining one of the most important elements of modelling the history of oil and gas generation in geological basins. Kinetic parameters of organic matter of oil and gas source rocks influence the onset time of generation and directly reflect differences in the composition and structure of different types of kerogens. The results of determining the kinetic parameters of two high-carbon source rocks occurring across the territory of three oil and gas basins are shown. Generation and updating of the data of kinetic models of certain oil and gas source rocks will increase the reliability of forecasting oil and gas potential using the basin modelling method.
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Date submitted2024-05-30
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Date accepted2024-10-14
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Date published2024-11-12
Thermodynamic modelling as a basis for forecasting phase states of hydrocarbon fluids at great and super-great depths
The possibility of discovering oil and gas occurrences at great (more than 5 km) and super-great (more than 6 km) depths is considered in two aspects. The first one is the preservation conditions of large hydrocarbon accumulations forming at depths to 4 km and caused by different geological and tectonic processes occurring at great and super-great depths with partial oil-to-gas transformation. It was ascertained that among the factors controlling preservation of liquid and gaseous hydrocarbons are the temperature, pressure, subsidence rate (rate of temperature and pressure increase), time spent under ultrahigh thermobaric conditions, and initial composition of organic matter. The possibility of existence of liquid components of oil at great and super-great depths is characteristic of sedimentary basins of China, the Gulf of Mexico, the Santos and Campos basins on the Brazilian shelf, and in the Russian Federation it is most probable for the Caspian Depression, some submontane troughs and zones of intense accumulation of young sediments. Determination of critical temperatures and pressures of phase transitions and the onset of cracking is possible using the approach considered in the article, based on estimation of organic matter transformation degree, kinetic and thermobaric models taking into account the composition of hydrocarbon fluid. The second aspect is the estimation of composition of hydrocarbons associated with rocks forming at great depths or rocks transformed under conditions of critical temperatures and pressures. This aspect of considerable science intensity can hardly be considered as practically significant. The study focuses on the investigation of the possibilities of thermodynamic modelling and the use of alternative methods for studying the transformation degree of liquid formation fluid into components of the associated gas through the example of two areas with identified oil, condensate and gas accumulations.
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Date submitted2022-10-10
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Date accepted2023-01-19
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Date published2023-12-25
Assessment of the possibility of using leucoxene-quartz concentrate as raw material for production of aluminium and magnesium titanates
Leucoxene-quartz concentrate is a large-tonnage by-product of development of the Timan oil-titanium field (oil-saturated sandstones) which is not commercially used at present. High content of titanium compounds (to 50 % by weight) and lack of industrial, cost-effective, and safe technologies for its processing determine a high relevance of the work. Conventional processing technologies allow increasing the concentration of TiO2, but they are only a preparation for complex and hazardous selective chlorination. The process of pyrometallurgical conversion of leucoxene-quartz concentrate into aluminium and magnesium titanates was investigated. It was ascertained that the temperature of solid-phase reaction in Al2O3-TiO2-SiO2 system necessary for the synthesis of aluminium titanate (Al2TiO5) is 1,558 °С, and for MgO-TiO2-SiO2 system – 1,372 °С. Scaling up the process made it possible to synthesize a significant number of samples of titanate-containing products, the phase composition of which was studied by X-ray phase analysis. Two main phases were identified in the products: 30 % aluminium/magnesium titanate and 40 % silicon dioxide. In products of pyrometallurgical processing in the presence of aluminium, phases of pseudobrookite (3.5 %) and titanite (0.5 %) were also found. It was ascertained that in magnesium-containing system the formation of three magnesium titanates is possible: MgTiO3 – 25, Mg2TiO4 – 35, MgTi2O5 – 40 %. Experiments on sulphuric acid leaching of samples demonstrated a higher degree of titanium compounds extraction during sulphuric acid processing. An integrated conceptual scheme for processing leucoxene-quartz concentrate to produce a wide range of potential products (coagulants, catalysts, materials for ceramic industry) was proposed.
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Date submitted2022-08-20
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Date accepted2022-11-17
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Date published2022-12-29
Comparison of the approaches to assessing the compressibility of the pore space
- Authors:
- Vitaly S. Zhukov
- Yuri O. Kuzmin
Integral and differential approaches to determining the volumetric compression of rocks caused by changes in the stress state are considered. Changes in the volume of the pore space of rocks are analyzed with an increase in its all-round compression. Estimation of changes in the compressibility coefficients of reservoirs due to the development of fields is an urgent problem, since the spread in the values of compressibility factors reduces the adequacy of estimates of changes in the physical properties and subsidence of the earth's surface of developed fields and underground gas storages. This parameter is key in assessing the geodynamic consequences of the long-term development of hydrocarbon deposits and the operation of underground gas storage facilities. Approaches to the assessment differ in the use of cumulative (integral) or local (differential) changes in porosity with a change in effective pressure. It is shown that the coefficient of volumetric compressibility of pores calculated by the integral approach significantly exceeds its value calculated by the differential approach, which is due to the accumulative nature of pore compression with an increase in effective pressure. It is shown that the differential approach more accurately determines the value of the pore compressibility coefficient, since it takes into account in more detail the features of the change in effective pressure.
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Date submitted2022-04-14
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Date accepted2022-07-21
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Date published2022-07-13
Mullite production: phase transformations of kaolinite, thermodynamics of the process
The growing demand for mullite raw materials, which meet industrial requirements originates the search for new and alternative sources, as well as efficient technologies for obtaining the target products (nanocomposites). The article suggests a method for obtaining mullite from kaolinite experimentally (Vezhayu-Vorykvinsky deposit, Russia). Structural kaolinite transformations (Al-Si-O-Me system), mineral phases transformations, and thermodynamics of the process have been studied. Based on the estimation of the thermodynamics of the reactions, the preferable reaction of mullite formation was determined. The article shows, that formation of the target product, mullite nanocomposite, has several intermediate phases (metakaolinite, pseudomullite). The transformations of the initial kaolinite structure include the removal of structural water and separation of the silica-oxygen tetrahedral and alumina-oxygen octahedral layers, the decomposition into free oxides, breaking of bonds between the silica-oxygen tetrahedrons and the partial increase in the coordination number of aluminium ions, the formation of mullite and cristobalite from free oxides. The proposed approach controls the ratio of Al 2 O 3 and SiO 2 phases at certain stages, which will further improve the mechanical and other properties of the matrix of the obtained raw materials for the target prototypes of industrial products.
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Date submitted2021-05-31
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Date accepted2021-10-18
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Date published2021-12-16
Experimental evaluation of compressibility coefficients for fractures and intergranular pores of an oil and gas reservoir
- Authors:
- Vitaly S. Zhukov
- Yuri O. Kuzmin
The paper is devoted to studies of the volumetric response of rocks caused by changes in their stress state. Changes in the volume of fracture and intergranular components of the pore space based on measurements of the volume of pore fluid extruded from a rock sample with an increase in its all-round compression have been experimentally obtained and analyzed. Determination of the fracture and intergranular porosity components is based on the authors' earlier proposed method of their calculation using the values of longitudinal wave velocity and total porosity. The results of experimental and analytical studies of changes in porosity and its two components (intergranular and fractured) under the action of effective stresses are considered. This approach allowed the authors to estimate the magnitude of the range of changes in the volumetric compressibility of both intergranular pores and fractures in a representative collection of 37 samples of the Vendian-age sand reservoir of the Chayanda field. The method of separate estimation of the compressibility coefficients of fractures and intergranular pores is proposed, their values and dependence on the effective pressure are experimentally obtained. It is determined that the knowledge of the values of fracture and intergranular porosity volumetric compressibility will increase the reliability of estimates of changes in petrophysical parameters of oil and gas reservoirs caused by changes in the stress state during the development of hydrocarbon fields.
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Date submitted2021-03-11
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Date accepted2021-07-27
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Date published2021-10-21
Justification of a comprehensive technology for preventing the formation of asphalt-resin-paraffin deposits during the production of highlyparaffinic oil by electric submersible pumps from multiformation deposits
Production of highly solidifying abnormal oils (with a paraffin content of over 30 % by mass) in the Far North is complicated by the intensive formation of asphalt-resin-paraffin deposits (ARPD) in the bottomhole zone of the productive formation, well and surface equipment. Existing methods and technologies for countering the formation of organic deposits in well equipment have many advantages. However, their application in the production of highly paraffinic oil does not fully prevent the formation of ARPD in the tubing string. This leads to a significant reduction in oil production, reduction of turnaround and intertreatment periods of production wells operation, an increase in specific operating expenses for paraffin removal. Results of theoretical and laboratory investigations presented in the article show that one of the promising ways to improve the operational efficiency of wells equipped with electric submersible pumps during extraction of highly paraffinic oil from multiformation deposits is the application of a new integrated technology based on the joint production of highly solidifying abnormal oil with oil, characterized by a lower paraffin content and manifestation of structural and mechanical properties, in conjunction with the regulation of the parameters for the electric submersible pump. Results of numerical modeling using the PIPESIM steady-state multiphase flow simulator, physical, chemical and rheological investigations show that with a decrease of highly paraffinic oil from the productive formation D2ef in a blend with Stary Oskol oil from the Kyrtaelskoye field, a decrease in the mass content of paraffin in the blend and the temperature of its saturation with paraffin, depth and intensity of the organic deposits formation in the tubing string, pour point, as well as the improvement of the rheological properties of the investigated structured dispersed systems is observed. Article describes a promising assembly of well equipment for the single tubing separate production of highly paraffinic oil from multiformation deposits of the Timan-Pechora province, providing separation of the perforation zones in two productive formations using a packer-anchor system at simultaneous-separate operation of the formations by a double electric submersible pump unit.
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Date submitted2019-07-11
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Date accepted2019-08-25
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Date published2019-12-24
Improving the efficiency of using resource base of liquid hydrocarbons in Jurassic deposits of Western Siberia
Under conditions of the same type of oil deposits with hard-to-recover reserves in Jurassic terrigenous reservoirs of the West Siberian oil and gas province, a study was made about the influence of the geological structure features of objects and water flooding technologies on the response degree of production wells to water injection. Response degree of the wells was determined by analyzing the time series of production rates and injection volumes of injection wells with the calculation of inter-correlation function (ICF) values. It was believed that with ICF values in a given injection period of more than 0.5, production well responds to the injection. Factors that have a prevailing effect on water flooding success have been identified. Among them: effective oil-saturated thickness of the formation in production wells; relative amplitude of the self polarization of the formation in both production and injection wells; grittiness coefficient of the formation in injection wells; monthly volume of water injection and distance between wells. Methodological approach is proposed based on the application of the proposed empirical parameter of water flooding success, which involves the use of indirect data in conditions of limited information about the processes occurring in the formation at justification and selection of production wells for transferring them to injection during focal flooding; drilling of additional production and injection wells – compaction of the well grid; shutdown of injection and production wells; use of a transit wells stock; use of cyclic, non-stationary flooding in order to change the direction of filtration flows; determining the design of dual-purpose L-shaped wells (determining length of the horizontal part); limitation of flow rate in highly flooded wells with a high degree of interaction; determination of decompression zones (without injection of indicators), stagnant zones for drilling sidetracks, improving the location of production and injection wells, transferring wells from other horizons; choosing the purpose of the wells during implementation of the selective water flooding system in order to increase the efficiency of using the resource base of liquid hydrocarbons.
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Date submitted2008-10-22
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Date accepted2008-12-14
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Date published2009-12-11
Peculiarities of structure and comparative analysis of oil-and-gas basins in the Pacific segment of lithosphere
- Authors:
- V. B. Archegov
Comparative analysis was carried out for oil-and-gas-bearing basins of young and oldland platforms of the Pacific segment. Previously the same kind of analysis had been realized for the Atlantic segment of lithosphere. Obtained results confirm the unique geological structure and oil-and-gas capacity of Siberian platform, by these features it differs from all other cratons in the whole world.
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Date submitted2008-10-23
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Date accepted2008-12-05
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Date published2009-12-11
Application of electrical prospecting in combination with seismic prospecting for the geological section prediction and search of hydrocarbon deposits
- Authors:
- V. A. Kuzin
- A. A. Korukhova
The possibility of application of electrical prospecting method SGN (sounding by field growing in the near-field zone) in combination with CDP seismic prospecting for sedimentary section investigations and hydrocarbon deposits prospecting is considered. The physical basis of the method application for hydrocarbon prospecting is the effect of higher resistance of seams, saturated by hydrocarbons. The effect is reflected in the curve of electromagnetic field growth ε(t). The procedures of field works, processing and interpretation of electrical prospecting data are presented.
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Date submitted2008-10-01
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Date accepted2008-12-15
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Date published2009-12-11
Possibilities for localization of zones of hydrocarbon accumulation by application of АМТ-data component analysis
Principal component method was used for qualitative interpretation of a matrix of magnetotelluric parameters. Localization of hydrocarbon congregation was the purpose of the investigations. Model of subvertical diffusion of hydrocarbon from reservoir was used as physical basis of oil and gas prospecting. The hydrocarbon роо l generates continuous spatial halation of hydrocarbon above the reservoir. Due to reducing reactions in the area the volumetric pyritization of rocks took place.