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Date submitted2024-01-31
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Date accepted2024-06-03
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Date published2024-07-04
Rationale for a possibility of using humic preparations production waste for wastewater purification from metals (Cd2+, Zn2+, Mg2+, Cu2+) aimed at developing efficient measures on environmental rehabilitation
Results of studying optimal conditions and parameters for afterpurification of underspoil waters from metal ions using humic acids production waste are presented with a view to develop the efficient measures on environmental rehabilitation of ecosystems disturbed by the development of copper pyrite deposits. The influence of contact time and waste dosage on the purification process was analysed, changes in the pH of wastewater and its impact on the growth and development of plants were studied. The key factors were identified allowing to achieve the efficiency of the purification process – the optimal contact time in the range from 120 to 180 min and waste dosage of 10 g/l. The study showed that the use of waste resulted in a neutral pH value of 7.03 compared to the initial pH value of 5.95. It was ascertained that the use of iron-magnesium production waste in combination with waste from humic preparations production made it possible to achieve the MPC of commercial fishing importance (with the exception of magnesium). Wastewater after the afterpurification process with high magnesium concentrations did not have a stimulating effect on the growth and development of Lepidium sativum L. plants. From biotesting results it can also be stated that there is no negative impact on the growth and development of Lepidium sativum L. The results obtained indicate a potentiality of using afterpurified wastewater for watering plants in the process of initiating the environmental rehabilitation of the disturbed ecosystems.
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Date submitted2022-10-28
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Date accepted2023-03-02
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Date published2023-04-25
Assessment of the possibility of using iron-magnesium production waste for wastewater treatment from heavy metals (Cd2+, Zn2+, Co2+, Cu2+)
Relevant problems associated with treatment of industrial wastewater from heavy metal ions are considered. Due to industrial development, the amount of wastewater increases as well as the risks of heavy metals getting into surface and groundwater, accumulating in water bodies and becoming aggressive environmental pollutants, which affect the animal and human organisms. To assess the possibility of extracting metal ions (Cd 2+ , Zn 2+ , Co 2+ , Cu 2+ ) from industrial wastewater and their further treatment, studies were carried out on redistribution of heavy metals in the “wastewater – waste” system using iron-magnesium production waste. Samples of the investigated waste weighing 0.1; 0.2; 0.5; 1; 1.5; 2 g were taken for wastewater volume of 50 ml per each subsample. Contact time varied from 5 to 180 min, waste fraction was 1 mm. The interaction process showed that the waste efficiently removes metal ions (Cd 2+ , Zn 2+ , Co 2+ , Cu 2+ ) from industrial wastewater. The efficiency of removing a pollutant from the solution depends on the weight of the waste subsample, initial concentration of metal ions, and contact time.
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Date submitted2020-06-12
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Date accepted2020-06-15
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Date published2020-12-29
Analysis of project organization specifics in small-scale LNG production
- Authors:
- Pavel S. Tcvetkov
- S. V. Fedoseev
Gas industry plays an important role in the global energy sector, and in the coming decades amountsof natural gas production will only increase. One of the fastest growing trends in gas industry is the production of liquefiednatural gas (LNG), which is associated with the necessity to organize flexible systems of gas supply to the regions,remote from gas extraction sites. Industrial structure of LNG production includes projects, belonging to several different groups depending to their scale, in particular, small-scale production (SSLNG), cumulative production capacityof which is approximately 10 % from the industry-wide one. Economic aspects of implementing such projects remainunderexplored, which does not allow to draw objective conclusions regarding the prospects of their implementationin particular regions.This paper contains a review of publications, devoted to SSLNG project studies, aimed at identifying specifics oftheir organization compared to projects of greater scale. The results demonstrate that the majority of internationalcompanies classify projects as SSLNG, if their annual production capacity is below 0.5 million tonnes per annum.Specific capital costs, as well as implementation timelines of such projects, are several times lower than those of projects with greater production capacity, which reduces their risks and minimizes barriers to market entry. Furthermore,SSLNG is the most decentralized subsector in gas industry, aiming to cover the market due to a growing numberof projects, not their specific production capacity. These specific features define significant prospects of SSLNGdevelopment in Russia, both in the context of energy supply to remote regions and diversification of export deliveries.
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Date submitted2019-07-09
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Date accepted2019-09-26
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Date published2020-04-24
Development of mathematical models to control the technological properties of cement slurries
Oil and gas producing enterprises are making increasingly high demands on well casing quality, including the actual process of injection and displacement of cement slurry, taking into account requirements for the annular cement level, eliminating possible hydraulic fracturing, with developing a hydraulic cementing program. It is necessary to prevent deep invasion of cement slurry filtrate into the formation to exclude bridging of productive layers. It is impossible to fulfill all these requirements at the same time without application of modifying additives; complex cement compositions are being developed and applied more often. Furthermore, need to adjust cement slurries recipes appears for almost every particular well. In order to select and justify cement slurries recipes and their prompt adjustment, taking into account requirements of well construction project, as well as geological and technical conditions for cementing casing strings, mathematical models of the main technological properties of cement slurries for cementing production casing strings in the Perm Region were developed. Analysis of the effect of polycarboxylic plasticizer (Pl) and a filtration reducer (fluid loss additive) based on hydroxyethyl cellulose (FR) on plastic viscosity (V), spreadability (S) and filtration (F) of cement slurries is conducted. Development of mathematical models is performed according to more than 90 measurements.
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Date submitted2018-11-09
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Date accepted2019-01-22
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Date published2019-04-23
Determining the stability of the borehole walls at drilling intervals of loosely coupled rocks considering zenith angle
- Authors:
- P. A. Blinov
During development of drilling projects, a whole array of data is needed considering the properties of rocks and the conditions of their bedding. Accounting for geomechanical processes occurring in the near-wellbore zone allows avoiding many complications associated with the violation of the wellbore walls stability at all stages of its construction and operation. Technological and technical factors such as vibration and rotation of the drilling string, formation of launders during the descent and ascent of the assembly, pressure pulsation during the start and stop of pumps, hydrostatic and hydrodynamic pressure of the drilling fluid, its composition and properties, have a great influence on the stress-strain state of the medium opened by the well. The washing fluid circulating in the well should provide backpressure to the reservoir, not interact with the rocks chemically, colmatage channels in porous and fractured rocks, preventing penetration of the mud into the medium, by creating an impermeable barrier at drilling clay seams that are prone to swelling, cracking, etc. The article discusses the method for determining the stability of the directed well walls, taking into account the penetration of drilling mud into the pores and fractures of rocks. The technique will allow adjusting the zenith angle of the well during the workout of an unstable interval at the design stage, or selecting a drilling fluid composition to ensure fail-safe drilling.
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Date submitted2018-07-18
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Date accepted2018-08-25
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Date published2018-12-21
Development of vibroacoustic module for fine filtration of drilling muds
- Authors:
- G. B. Fedorov
- O. L. Dudchenko
- D. S. Kurenkov
The issue of drilling mud multiple use is problematic. To reuse, the solution must be efficiently cleaned from solid particles according to the class of 0.04-0.07 mm. An analysis of existing technologies and equipment has shown that drilling mud regeneration schemes are rather difficult to operate and expensive. In world practice there has been a tendency to create universal equipment, which allows most complete cleaning cycle for a drilling mud in fine grades. The paper proposes an innovative vibroacoustic module for cleaning drilling muds from sludge. The creative element of the proposal is the impact of vibroacoustic oscillations on the drilling mud passing through the mesh element. At the same time, specific effects arise around the mesh, which increase the productivity and efficiency of the process. The design of the vibroacoustic apparatus and the principle of its operation are presented. An important element of the proposal is that the oscillation is created by pistons interconnected by rods and located on opposite sides of the mesh. This dipole system provides the excitation of variable pressures of different polarity before the mesh and after it. The results of industrial tests of the vibroacoustic module when servicing the BU-75-BrE drilling rig are presented. The dependence of the installation performance and efficiency on the amplitude of oscillations was found. The optimal dynamic range of exposure (from 5.5 to 6.5 mm) was determined. Analysis showed that in the composition of the cleaned drilling mud, the maximum particle size of the solid phase did not exceed 0.04 mm. The conducted industrial tests confirmed the possibility of using the vibroacoustic module for cleaning the washing fluid and developing a pit-free drilling technology on its basis.
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Date submitted2015-12-28
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Date accepted2016-02-28
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Date published2016-12-23
Ion distribution function in their own gas plasma
- Authors:
- A. S. Mustafaev
- V. S. Sukhomlinov
Flat one-sided probe was used for the first time to measure the first seven coefficients in the Legendre polynomial expansion of ion energy and angle distribution functions for He + in He and Ar + in Ar under the conditions when the ion velocity gained along its free run distance is comparable to the average thermal energy of atoms. Analytic solution of the Boltzmann kinetic equation is found for ions in their own gas for arbitrary tension of electric field in plasma when the dominating process is resonant charge exchange. The dependence of cross-section of resonant charge exchange on the relative velocity is accounted for. It is demonstrated that the ion velocity distribution function differs significantly from the Maxwell distribution and is defined by two parameters instead of just one. The results of computational and experimental data agree quite well, provided the spread function of measurement technique is taken into account.
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Date submitted2015-07-14
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Date accepted2015-09-28
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Date published2016-02-24
Ion velocity distribution function in arbitrary electric field plasma
- Authors:
- A. S. Mustafaev
- V. S. Sukhomlinov
Experimental investigations of the ion velocity distribution function (IVDF) are of great importance to various kinds of application: plasma nanotechnology, surface treatment, nanoelectronics, etching processes et al. In this paper, we propose a new probe method for diagnostics of anisotropic IVDF. The possibilities of the method have been demonstrated in arbitrary electric field plasma under conditions when an ion acquires a velocity on its mean free path comparable with the average thermal velocity of atoms. The energy and angular dependency of seven IVDF Legendre components for He + in He and Ar + in Ar have been measured and polar diagrams of the ion motion have been plotted. In order to verify the reliability and accuracy of the method the analytic solution of the kinetic Boltzmann equation for ions in plasma of their own gas has been found. Conditions under which resonant charge exchange is the dominant process and the ambipolar field is arbitrary have been considered. For the ambipolar field the dependence of resonant charge cross-section on the relative velocity has been taken into account. It is shown that the form of the IVDF is significantly different from the Maxwellian distribution and defined by two parameters. The results of theoretical and experimental data taking into account the instrumental function of the probe method are in good agreement. Calculations of the drift velocity of Hg + ions in Hg, He + in He, Ar + in Ar, and mobility of N 2 + in N 2 are well matched with known experimental data in wide range of electric field values.
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Date submitted2015-07-20
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Date accepted2015-09-26
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Date published2016-02-24
Prospects of biotechnologies application in metallurgy and enrichment
- Authors:
- N. M. Telyakov
- A. A. Darin
- V. A. Luganov
In recent years, application of biotechnologies in enrichment processes and processing of metal-containing ores has gained broad development, considering essential advantages of these technologies from the point of view of economic efficiency and ecological safety. Processes with the application the hemolitotrofnykh of acidophile microorganisms of Acidithiobacillus ferrooxidans, At. thiooxidans, Leptospirillum ferrooxidans and others, are of great interest. This article is devoted to the problem of biocultures application for efficiency improvement of the ore pretreatment technology and extraction of valuable components from metal-containing crude ore. The analysis of the biotechnologies and microorganisms applied at domestic and foreign enterprises is given, alongside with the theoretical bases of ore bioprocessing, research results of oxide and sulphidic metal-containing ores processing technology development, with the application of microorganisms and research results of the mechanism of destructive impact of a certain type bacteria on siliceous ores.
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Date submitted2010-07-18
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Date accepted2010-09-16
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Date published2011-03-21
Two genetic types of peristerites in iridescent plagioclases
- Authors:
- M. A. Ivanov
- A. P. Simakov
Physico-mathematical modeling has shown that color of iridescent depends on spacing of peristerite lattice. The more spacing lattice, the color of iridescent is higher. The phenomenon of iridescent in plagioclases has an interferential nature. We can select two genetic types of peristerites: peristerites of decomposition and segregation peristerites. Segregation peristerites are formed from postcrystallizational consolidation of peristerites of decomposition. The form of segregation pertisrerites is one of the reasons of polychromatic iridescent genesis in plagioclases.
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Date submitted2010-07-21
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Date accepted2010-09-23
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Date published2011-03-21
Engineering-geological substantiation of reshaping wave-built solid masses with partial removal of hydraulic mine dump
- Authors:
- I. V. Kuznetsova
- V. P. Zharikov
Consider the case of partial removal of hydraulic mine dump in the Kuzbass region in connection with the need to retrieve from under him mothballed coal reserves. The results of geotechnical studies alluvial array: the physical and mechanical properties of alluvial rock and measurement of pore pressure in them. The problems of research and some methodological techniques. We settle the question of creating a new sustainable construction is part of the hydraulic mine dump.
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Date submitted2009-08-10
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Date accepted2009-10-15
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Date published2010-02-01
Spacing of lattice in labradorite and interference model of iridescent
- Authors:
- A. P. Simakov
Spacing of lattice for non-iridescent labradorite, blue-iridescent labradorite, green-iridescent labradorite and red-iridescent labradorite were determined with scanning probe electron microscope. Lattice spacing increases the dynamical trend for different kinds of labradorite, line non-iridescent labradorite (107,5 ± 10 nm), blue-iridescent labradorite (150 ± 10 nm), green-iridescent labradorite (196 ± 10 nm), red-iridescent (231 ± 10 nm). This trend let is state iridescent of these samples to be caused by interference of secondary order.