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Date submitted2024-04-12
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Date accepted2024-09-05
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Date published2024-11-12
Promising reagents for the extraction of strategic metals from difficult-to-enrich mineral raw materials
The need of the mining and processing industry for new types of directional reagents is due to the deterioration of the material composition of the processed ores. Low Au content (less than 0.5-1.0 g/t), finely dispersed Au inclusions (0.1-10.0 microns) in the ore, similar properties of the separated minerals have an extremely negative effect on flotation performance when using traditional reagents, which leads to significant losses of valuable metal with enrichment tailings. Expanding the range of domestic flotation reagents based on the latest achievements of fundamental research and their targeted application at mining and processing companies will compensate for the negative impact of the mineral composition of raw materials and ensure maximum extraction of strategic metals from difficult-to-enrich ores. The use of modern research methods (scanning electron and laser microscopy, UV spectrophotometry, XRF and chemical analysis) made it possible to visualize the adsorption layer of new reagents-collectors of a number of dithiocarbamates with different structures of a hydrocarbon radical and an organic modifier on the surface of gold-containing sulfides. The amount of adsorbed reagents on the surface of minerals has been experimentally determined. The specific features of the fixation of reagents on minerals of various compositions led to optimal correlations of their consumption in the flotation process. Scientifically based reagent regimes ensured an increase in the gold content in the concentrate and a decrease in the loss of gold with tailings by 5-6 % during flotation enrichment of the refractory ore of the Malinovskoe deposit.
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Date submitted2023-07-07
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Date accepted2023-12-27
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Date published2024-12-25
A new insight into recording the mineral composition of carbonate reservoirs at well killing: experimental studies
Well killing operation remains an important technological stage before well workover or servicing, during which filtrate penetrates the bottomhole area of the formation. The impact of process fluids and their filtrate on rock has a significant influence on permeability and porosity of carbonate reservoirs, which decrease due to fines migration. There are few known scientific studies of the interaction of killing fluid filtrate with carbonate rock and fines migration. In our experiments, an aqueous phase was used which is the basis for well killing in pure form, for the preparation of blocking agents and is used in reservoir pressure maintenance system. Core samples taken from the pay of the reservoir were used to simulate the well killing process with generation of reservoir thermobaric conditions. Killing fluid filtrate was kept for seven days, which characterizes the average workover time at flowing wells in the fields of the Perm Territory. Using micro-X-ray tomography and scanning electron microscope, images were obtained before and after the experiment, which allowed confirming a decrease in total number of voids due to fines migration and, as a consequence, a decreasing permeability of samples. Measurement of pH and fines concentration in the aqueous phase was performed before and after the experiment and pointed to mineral reactions occurring as a result of rock dissolution. The results of experiments made it possible to record a decrease in permeability of carbonate samples by an average of 50 % due to clogging of void space and migration of fines (clayey and non-clayey).
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Date submitted2022-04-08
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Date accepted2023-03-02
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Date published2023-04-25
Geochemical properties and transformation of the microelement composition of soils during the development of primary diamond deposits in Yakutia
Extraction of diamonds from primary deposits in Siberia is associated with the development of kimberlite pipes in challenging environmental conditions, accompanied by a complex impact on the environment. The article presents the results of monitoring the soil cover of the Nakyn kimberlite field in the Yakutia diamond province, which is affected by the facilities of the Nyurba Mining and Processing Division. Development of primary diamond deposits has a large-scale impact on the subsoil, topography, and soil cover: creation of the world's largest quarries, formation of dumps more than 100 m high, arrangement of extensive tailings, formation of solid and liquid industrial wastes of various chemical composition. The research is aimed at studying the spatial and temporal patterns of the technogenic impact on the soil cover, identifying the nature and level of transformation of the microelement composition of soils based on the analysis of the intra-profile and lateral distribution of mobile forms of trace elements. The study targets in 2007-2018 were zonal types of permafrost soils of northern taiga landscapes, cryozems, occupying 84 % of the total study area, which are characterized by biogenic accumulation of mobile forms of Ni, Mn, and Cd in the upper AO, A cr horizons, and Cr, Ni, Co, Mn, Cu in the suprapermafrost CR horizon. We found out that the contamination of the soil cover of the industrial site at the Nyurba Mining and Processing Division is of a multielement nature with local highly to very highly contaminated areas. Over a ten-year observation period, areas of stable soil contamination are formed, where the main pollutants are mobile forms of Mn, Zn, Ni. We suggest that against the background of a natural geochemical anomaly associated with trap and kimberlite magmatism, technogenic anomalies are formed in the surface horizons of soils. They are spatially linked to technogenically transformed landscapes. One of the sources of pollutants is the dispersion of the solid phase of dust emissions in the direction of the prevailing winds, which leads to the formation of soils with abnormally high contents of mobile forms of Mn, Zn, Ni.
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Date submitted2022-04-12
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Date accepted2022-05-25
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Date published2022-07-26
Rare minerals of noble metals in the collection of the Mining Museum: new data
Modern analytical methods (optical and electron microscopy, X-ray microanalysis) were used to study the unique samples of sulfide ores from the Norilsk ore field from the Mining Museum collections of Saint Petersburg Mining University. Samples containing rare minerals of silver and platinum-group metals (sobolevskite, urvantsevite, sperrylite, argentopentlandite, froodite, kotulskite, and others) were studied. The chemical composition, grain sizes, aggregates, and mineral associations of more than ten noble metal minerals have been refined. The efficiency of combining various methods of electron microscopy and X-ray microanalysis for studying samples of this type is shown. The results of the work made it possible to obtain high-quality images of rare minerals, to detail information on museum objects, and to compile their scientific description. The conducted research showed the relevance of studying museum objects from known deposits of complex genesis and mineral composition in order to find and describe the samples with rare minerals.
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Date submitted2022-03-31
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Date accepted2022-05-11
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Date published2022-07-26
Carbonatite complexes of the South Urals: geochemical features, ore mineralization, and geodynamic settings
- Authors:
- Irina L. Nedosekova
The article presents the results of study of the Ilmeno-Vishnevogorsky and Buldym carbonatite complexes in the Urals. It has been established that the carbonatites of the Ilmeno-Vishnevogorsky complex are represented by high-temperature calciocarbonatites (sövites I and II) with pyrochlore ore mineralization. U-Ta-rich populations of uranium pyrochlores (I) and fluorocalciopyrochlores (II) crystallize in miaskite-pegmatites and sövites I; fluorocalciopyrochlores (III) and Sr-REE-pyrochlores (IV) of late populations form in sövites II. In the Buldym complex, along with high-temperature calciocarbonatites containing fluorocalciopyrochlore (III), medium-temperature varieties of magnesiocarbonatites with REE-Nb mineralization (monazite, niobo-aeschynite, columbite, etc.) are widespread. Miaskites and carbonatites of the Urals are characterized by high contents of LILE (Sr, Ba, K, Rb) and HFSE (Nb, Ta, Zr, Hf, Ti), which are close to the contents in rift-related carbonatite complexes of intraplate settings and significantly differ from synorogenic collisional carbonatite complexes. The Ural carbonatite complexes formed on continental rift margins during the opening of the Ural Ocean at the time of transition from extensional to compressional tectonics. Later on, they were captured and deformed in the suture zone as a result of collision. Plastic and brittle deformations, anatexis, recrystallization of rocks and ores of carbonatite complexes in the Urals are associated with orogenic and post-collision settings.
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Date submitted2022-02-24
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Date accepted2022-05-25
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Date published2022-07-26
Litsa uranium ore occurrence (Arctic zone of the Fennoscandian Shield): new results of petrophysical and geochemical studies
Mineralogical, petrophysical and geochemical studies have been carried out to determine the sequence and formation conditions of uranium mineralization within the Litsa ore occurrence (Kola Region). Mineralogical studies show the following formation sequence of ore minerals: uraninite – sulfides – uranophane, coffinite, pitchblende. Two stages of uranium mineralization are distinguished: Th-U (1.85-1.75 Ga) and U (400-300 Ma). The distribution of physical properties of rocks in the area is consistent with the presence of two temporal stages in the formation of mineralization with different distribution and form of uranium occurrence in rocks. The factors that reduce rock anisotropy are the processes of migmatization and hydrothermal ore mineralization, which heal pores and cracks. Fluid inclusions in quartz studied by microthermometry and Raman spectroscopy contain gas, gas-liquid and aqueous inclusions of different salinity (1.7-18.4 wt.% NaCl-eq.). According to homogenization temperatures of inclusions in liquid phase, the temperature of the Paleoproterozoic and Paleozoic stages of uranium mineralization at the Litsa ore occurrence is ~ 300 and 200 °С, respectively. Correlations of the spatial distribution of elastic anisotropy index with an elevated radioactive background allow using this petrophysical feature as one of the prognostic criteria for uranium and complex uranium mineralization when carrying out uranium predictive work.
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Date submitted2021-01-19
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Date accepted2021-07-27
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Date published2021-10-21
Geological and structural characteristics of deep-level rock mass of the Udachnaya pipe deposit
- Authors:
- Evgenii V. Serebryakov
- Andrei S. Gladkov
For hard rock massifs, structural disturbance is a key indicator of mining structure stability. The presence of intersecting structural elements in the massif reduces rock strength and leads to formation of potential collapse structures. In addition to that, disjunctive deformations that penetrate rock strata serve as channels for fluid migration and connect aquifers into a single system. It was established that the largest of them –faults of east-northeastern, northeastern and northwestern directions – form the kimberlite-bearing junction of the Udachnaya pipe. These faults represent zones of increased fracturing, brecciation and tectonic foliation, distinguished from adjacent areas by increased destruction of the rock mass. Specifics of tectonic fracture distribution within structural and lithological domains are determined by the presence of multidirectional prevailing systems of tectonic fracturing, as well as by differences in their quantitative characteristics. With some exceptions, the main systems form a diagonal network of fractures (northeastern – northwestern orientation), which is typical for larger structural forms – faults. Despite the differences in dip orientation of the systems, most of them correspond to identified directions, which is typical for both kimberlites and sedimentary strata. Overall disturbance of the massif, expressed in terms of elementary block volume, reaches its peak in the western ore body. For such type of deposits, friction properties of fracture structures have average values. Consideration of geological and structural data in the design and development of new levels of the deposit will allow to maintain the necessary balance between efficiency and safety of performed operations.
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Date submitted2019-10-17
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Date accepted2020-01-24
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Date published2020-04-24
Composition and probable ore igneous rocks source of columbite from alluvial deposits of Mayoko district (Republic of the Congo)
The article presents the results of optical, electron microscopic and electron microprobe studies of columbite group minerals, collected during heavy mineral concentrate sampling of alluvial deposits in the Mayoko region (Republic of the Congo). The aim of the study is revealing tantalum niobates ore body in this region. We found that these minerals in loose deposits are represented by two grain-size groups: less than 1.6 mm (fine fraction) and 1.6-15 mm (coarse fraction). The grains of both fractions belong mainly to columbite-(Fe), less often to columbite-(Mn), tantalite-(Mn) and tantalite-(Fe), contain impurities of Sc, Ti, and W. The crystals have micro-scaled zoning (zones varies slightly in the Ta/Nb ratio values) and contains a lot of mineral inclusions and veins represented by zircon, pyrochlore supergroup minerals and others. Columbite-(Fe) and columbite-(Mn) are characterized by an increased content of Ta 2 O 5 up to the transition to tantalite-(Fe) and tantalite-(Mn). This allows us to exclude the formation of subalkaline rare-metal granites, their metasomatites (albitites and greisenes) and carbonatites, from the list of possible columbite ore rocks source in the Mayoko district. Thus, beryl type and complex spodumene subtype rare-element pegmatites of the mixed petrogenetic family LCT-NYF (according to P.Černý) should be considered as a probable root source. The results of the research should be taken into account when developing the methodology for prospecting in this area.
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Date submitted2017-11-09
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Date accepted2017-12-28
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Date published2018-04-24
Chemical weathering of lower paleozoic black shales of south Sweden
- Authors:
- D. O. Voronin
- E. G. Panova
Lower Paleozoic black shales are widespread in Sweden and form part of the Baltic paleobasin, which deposits are also known in Estonia and the Leningrad Oblast of Russia. These rocks are enriched in a carbon substance and characterized by the significant content of uranium, vanadium, molybdenum, copper, nickel, cobalt, zinc, and lead. Black shales contain high levels of Sr – 968; Ba – 337; U – 229; V – 509; Mo – 165; Zn – 411; Ni – 214; Cu – 112 (ppm) in secondary minerals composition formed on their surface. Retrograde diagenetic conditions facilitate the black shales chemical weathering. Elements of the first (U), second (Mo, Sr, Zn), and third (V) hazard classes are washed out of black shales and secondary minerals and can further enter biological cycles.
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Date submitted2017-09-10
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Date accepted2017-11-10
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Date published2018-02-22
Research of heat generation indicators of gas engines
- Authors:
- O. N. Didmanidze
- A. S. Afanasev
- R. T. Khakimov
A comprehensive strategy for reviving the production of mining industry equipment and ensuring its competitiveness includes the wide use of gas engines for various purposes. Experimental studies of the working cycle of a gas engine are one of the main tasks in determining the heat generation characteristics. To this end, indicator charts were recorded in various modes, which were subjected to analysis in order to determine the key parameters characterizing intra-cylinder processes. According to the experimental program, the maximum cycle pressure, the rate of pressure build-up, the heat generation characteristic, the first heat generation phase, the duration of the second combustion phase, and the effect of the ignition advance angle for the ignition period were determined. The results of an experimental study of the influence of gas engine working process with allowance for the change in the ignition advance angle for the ignition period are described and the parameters of the maximum cycle pressure, the rate of pressure build-up, and the heat generation characteristics are determined. In the processing of data, integral charts are constructed, the working cycle parameters are calculated, and the dynamics of the engine heat generation is determined.
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Date submitted2016-11-11
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Date accepted2017-01-21
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Date published2017-04-14
Conducting lithospheric heterogeneities as a criterion of predictive assessment for promising diamond areas (on the example of Siberian kimberlite province)
- Authors:
- E. V. Pospeeva
Results of magnetotelluric tests, carried out in Siberian kimberlite province, are examined from the viewpoint of structural control over location of kimberlite fields and bunches of kimberlite pipes. It is demonstrated that the key factors controlling occurrence of kimberlite magmatism are: deep systems of rift-driven fractures; areas of their intersection within high-ohmic blocks of Earth crust; conducting permeable areas, located at the intersections of deep faults. Various-rank objects of kimberlite magmatism are characterized by a certain combination of geoelectric heterogeneities, differing in resistance, lateral sizes and depth. The province is situated within the boundaries, limited by isolines 180-220 km of current asthenosphere; kimberlite areas – within the contours of high-resistance regional heterogeneities. Fields and bunches of kimberlite pipes are concentrated within boundaries of conducting subvertical zones. These factors can be used as criteria of predictive assessment for promising diamond areas of the ancient platforms.
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Date submitted2016-11-03
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Date accepted2016-12-27
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Date published2017-04-14
Evolution of mineral forms of rare element accumulation in ore-bearing granites and meta-somatites of Verkhneurmiysk ore cluster (Priamur region)
It has been attempted to expand existing understanding of accessory mineralization evolution of rare metal-granite series at post-magmatic stage of their development and formation of associated hydrothermal deposits. Composition and distribution of rare elements of Verkhneurmiysk ore cluster have been examined from the position of mineralogy: the study focused on accessory and ore minerals Sn, W, Nb, Ta, Bi, Y, rare earth elements in rare metal Li-F granites and associated metasomatites. It has been discovered that accessory magmatic and hydrothermal mineral complexes share the same geochemical features, are formed under the leading role of abovementioned elements and consistently follow each other over time. It has been traced how mineral forms of accumulation of Sn, W, Nb, Ta, Y and rare earth elements evolve in the processes of magmatic crystallization and post-magmatic metasomatism in the time series: rare metal granites → zwitters → tourmalinites → chloritites. Mineral rocks of each stage were noted to inherit mineralogical and geochemical distinctions from the rocks of the previous stage. A significant number of minerals, forming in the course of two-three stages, have been discovered, as well as omnipresent magmagene-hydrothermal minerals. For a number of accessory minerals of rare metal granites post-magmatic generations have been identified. Special diversity among accessories of rare metal granites and zwitters was observed in tungsten, tin and bismuth minerals.
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Date submitted2015-12-01
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Date accepted2016-02-29
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Date published2016-12-23
Simulation of diesel engine energy conversion processes
- Authors:
- A. S. Afanasev
- A. A. Tretyakov
In order to keep diesel engines in good working order the troubleshooting methods shall be improved. For their further improvement by parameters of associated processes a need has arisen to develop a diesel engine troubleshooting method based on time parameters of operating cycle. For such method to be developed a computational experiment involving simulation of diesel engine energy conversion processes has been carried out. The simulation was based on the basic mathematical model of reciprocating internal combustion engines, representing a closed system of equations and relationships. The said model has been supplemented with the engine torque dynamics taking into account the current values of in-cylinder processes with different amounts of fuel injected, including zero feed. The torque values obtained by the in-cylinder pressure conversion does not account for mechanical losses, which is why the base simulation program has been supplemented with calculations for the friction and pumping forces. In order to determine the indicator diagram of idle cylinder a transition to zero fuel feed mode and exclusion of the combustion process from calculation have been provisioned.
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Date submitted2010-07-21
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Date accepted2010-09-08
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Date published2011-03-21
Calculation methodology of physical parameters of the artificial pillar barrier
- Authors:
- M. N. Adreev
The article is devoted to the calculation methodology of physical parameters of the artificial barrier pillar needed when developing underquarry deposits of kimberlitic pipes in difficult hydrogeological conditions.
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Date submitted2010-07-27
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Date accepted2010-09-09
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Date published2011-03-21
Utilization of enrichment waste of diamondiferous rock accounting peculiarities of M.V.Lomonosov deposit
- Authors:
- A. Yu. Oblitsov
In given article the questions of enrichment waste utilization of M.V.Lomonosov diamond deposit are considered taking in account some important peculiarities of this deposit and prospective of obtaining building materials on basis of enrichment waste products is stated.
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Date submitted2010-07-15
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Date accepted2010-09-26
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Date published2011-03-21
Development of the stowing material and testing of its mechanical properties
- Authors:
- M. N. Andreev
- E. I. Boguslavskiy
Article is in touch with analysis of backfill materials applied on diamond mines, description of research of its mechanical properties to create the optimal compound in conditions of Yakutian kimberlitic tubes.
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Date submitted2008-10-21
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Date accepted2008-12-10
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Date published2009-12-11
Prediction and prospecting types of reflection of buried kimberlite fields in terrigenous diamond-bearing rocks
- Authors:
- V. N. Ustinov
On the basis of complex of lithologic-stratigraphic, mineralogical, facial-dynamic, paleogeomorphologic and morphogenetic features of post-kimberlitic terrigenous diamond-bearing rocks and reconstructed synchronous relief three prediction and prospecting types of reflection of buried kimberlite fields are distinguished. It is shown that ranging of diamondiferous territories to various types enables to direct exploration works to discovery of diamond deposits of the certain origin and makes possible to select proper prospecting technique. With the use of suggested criteria of research of promising territories the evaluation of diamond presence in the industrial regions of the Siberian, East-European and African-Arabian platforms is carried out.
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Date submitted2008-10-24
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Date accepted2008-12-06
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Date published2009-12-11
Geological structure, characteristics of ores and genesis of ore occurrences in the Halvdanpiggen field (West Spitsbergen island)
- Authors:
- A. N. Sirotkin
- V. V. Khailov
- D. V. Nikitin
A new metallogenic zone was separated out in a central part of the archipelago Spitsbergen by the results of exploration work. It was shown an integral series of ore areas and fields in the limits of this zone, including the ore field Halvdanpiggen. This field integrates several non-uniformly scaled the ore occurrences, which present a great interest in regard to a material composition of the ore. They likewise produce an information for determination of genesis and outlooks of total metallogenic zone. The article contains data on geology, mineralogy and geochemistry of deposits; it is established their genesis, formation membership and time of origination.