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Date submitted2024-04-12
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Date accepted2024-09-05
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Date published2024-11-12
Promising reagents for the extraction of strategic metals from difficult-to-enrich mineral raw materials
The need of the mining and processing industry for new types of directional reagents is due to the deterioration of the material composition of the processed ores. Low Au content (less than 0.5-1.0 g/t), finely dispersed Au inclusions (0.1-10.0 microns) in the ore, similar properties of the separated minerals have an extremely negative effect on flotation performance when using traditional reagents, which leads to significant losses of valuable metal with enrichment tailings. Expanding the range of domestic flotation reagents based on the latest achievements of fundamental research and their targeted application at mining and processing companies will compensate for the negative impact of the mineral composition of raw materials and ensure maximum extraction of strategic metals from difficult-to-enrich ores. The use of modern research methods (scanning electron and laser microscopy, UV spectrophotometry, XRF and chemical analysis) made it possible to visualize the adsorption layer of new reagents-collectors of a number of dithiocarbamates with different structures of a hydrocarbon radical and an organic modifier on the surface of gold-containing sulfides. The amount of adsorbed reagents on the surface of minerals has been experimentally determined. The specific features of the fixation of reagents on minerals of various compositions led to optimal correlations of their consumption in the flotation process. Scientifically based reagent regimes ensured an increase in the gold content in the concentrate and a decrease in the loss of gold with tailings by 5-6 % during flotation enrichment of the refractory ore of the Malinovskoe deposit.
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Date submitted2024-10-29
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Date accepted2024-10-29
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Date published2024-11-12
Study of thermodynamic processes of the Earth from the position of the genesis of hydrocarbons at great depths
In the context of significant depletion of traditional proven oil reserves in the Russian Federation and the inevitability of searching for new directions of study and expansion of the raw material base of hydrocarbon raw materials in hard-to-reach regions and on the Arctic shelf, a scientific search is underway for accumulations in complex geological conditions and in manifestations that differ significantly from traditional ones, which include the processes of oil and gas formation and preservation of oil and gas in low-permeability “shale” strata and in heterogeneous reservoirs at great and super-great depths. Within the oil and gas provinces of the world, drilling of a number of deep and super-deep wells has revealed deposits at great depths, established connections between hydrocarbon deposits and “traces” of hydrocarbon migration left in the core of deep wells, which has made it possible to significantly re-evaluate theoretical ideas on the issue of oil and gas formation conditions and the search for technologies aimed at solving applied problems. Modern geochemical, chromatographic, bituminological, coal petrographic and pyrolytic methods of studying oil and bitumoids extracted from the host rocks of deep well cores give a hope for identifying correlations in the oil-source system, revealing processes that determine the possibility of hydrocarbon formation and accumulation, and defining predictive criteria for oil and gas potential at great depths.
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Date submitted2023-07-05
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Date accepted2024-06-03
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Date published2024-12-25
Complete extraction of conditioned ores from complex-structured blocks due to partial admixture of substandard ores
- Authors:
- Bayan R. Rakishev
The paper presents mining-technological substantiation of complete extraction of conditioned ores from complex-structured blocks of benches by mixing a layer of substandard ores of certain sizes. The relevance of the work consists in the development of innovative methods of establishing the parameters of the substandard layer of ores to be added to the conditioned ores. The main problem is to ensure complete extraction of useful components into concentrate from shipped ore with acceptable deviations from the required ones. A new typification of complex-structured ore blocks of the bench has been carried out. Analytical dependences of mining and geological characteristics of complex-structured ore blocks were obtained. Theoretical dependences for determining the main indicators of mineral processing are derived. Analytical dependences for determination of the content of useful component in shipped ore α' – mixture of conditioned ore with the content of useful component α and admixed layer of substandard ore with the content of useful component α'' are offered. For the first time in mining science, a new approach of complete extraction of conditioned ores from complex-structured blocks of benches by grabbing a certain part of substandard ores during excavation, increasing the volume of extracted ore and expanding the extraction of useful components in the concentrate has been substantiated. The increment of useful components can reach 10-15 % of the total volume of extraction, which allows predicting a significant increase in the completeness of mineral extraction from the Earth's interior.
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Date submitted2022-10-28
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Date accepted2023-03-02
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Date published2023-04-25
Assessment of the possibility of using iron-magnesium production waste for wastewater treatment from heavy metals (Cd2+, Zn2+, Co2+, Cu2+)
Relevant problems associated with treatment of industrial wastewater from heavy metal ions are considered. Due to industrial development, the amount of wastewater increases as well as the risks of heavy metals getting into surface and groundwater, accumulating in water bodies and becoming aggressive environmental pollutants, which affect the animal and human organisms. To assess the possibility of extracting metal ions (Cd 2+ , Zn 2+ , Co 2+ , Cu 2+ ) from industrial wastewater and their further treatment, studies were carried out on redistribution of heavy metals in the “wastewater – waste” system using iron-magnesium production waste. Samples of the investigated waste weighing 0.1; 0.2; 0.5; 1; 1.5; 2 g were taken for wastewater volume of 50 ml per each subsample. Contact time varied from 5 to 180 min, waste fraction was 1 mm. The interaction process showed that the waste efficiently removes metal ions (Cd 2+ , Zn 2+ , Co 2+ , Cu 2+ ) from industrial wastewater. The efficiency of removing a pollutant from the solution depends on the weight of the waste subsample, initial concentration of metal ions, and contact time.
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Date submitted2022-02-22
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Date accepted2022-05-11
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Date published2022-11-03
Scientific substantiation and development of innovative processes for the extraction of zirconium and rare earth elements in the deep and comprehensive treatment of eudialyte concentrate
- Authors:
- Valentin A. Chanturiya
Based on a package of modern analysis methods, the influence of various acids and energy effects on the morphology, elemental composition, structural and chemical transformations of the mineral surface, and the efficiency of eudialyte concentrate leaching was studied. The mechanism and the optimal conditions and specific features of the destruction of eudialyte and rock minerals and the extraction of zirconium and REE under the influence of various acids, powerful nanosecond pulses, dielectric barrier discharge, electrochemical processing, mechanochemical activation and ultrasound were revealed. The mechanism of formation and the optimal conditions for the dispersion of silica gel, depending on the methods and parameters of energy effects, was theoretically and experimentally substantiated. A combined three-stage circuit of nitric acid leaching of eudialyte concentrate with ultrasonic treatment of the suspension, providing 97.1 % extraction of zirconium and 94.5 % REE, were scientifically substantiated and tested. The conditions for the selective deposition of zirconium and REE were theoretically and experimentally substantiated.
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Date submitted2021-06-15
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Date accepted2021-10-18
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Date published2021-12-16
Study on hydrometallurgical recovery of copper and rhenium in processing of substandard copper concentrates
- Authors:
- Denis S. Lutskiy
- Aleksander S. Ignatovich
Over the past decade, there has been a steady growth in demand for rare metals, with rhenium being one of the most highly demanded, but also one of the most expensive and difficult to obtain. The high demand for rhenium is due to its use as a key component of metallurgical alloys or as a component of catalysts used in the oil refining industry. The aggregate of facts causes profitability of processing of the rhenium-containing mineral resources, which also are the copper substandard concentrates obtained at processing of the Zhezkazgan sandstones. The study focuses on the processes of extraction of copper and sorption recovery of rhenium from solutions of ammonia leaching of copper substandard concentrates. Model solutions similar in the elemental composition to solutions of ammonia leaching solutions of copper substandard concentrates obtained during the processing of Zhezkazgan sandstones were used as an object of the study. The paper estimates extraction characteristics of copper recovery using LIX 84-I solution in kerosene, as well as sorption characteristics of the rhenium recovery process using the Purolite PPA100 anion exchanger. Based on the obtained characteristics the possibility of hydrometallurgical processing of ammonia leaching solutions of substandard copper-sulfide concentrates, and recovery of the obtained commercial products is shown.
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Date submitted2020-07-29
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Date accepted2021-03-30
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Date published2021-06-24
Model of baddeleyite recovery from dump products of an apatite-baddeleyite processing plant using a CVD6 concentrator
The paper is devoted to developing a model of baddeleyite recovery from dump products of an apatite-baddeleyite processing plant using centrifugal concentrators. The relevance of the work arises from the acquisition of new knowledge on the optimization of technological parameters of centrifugal concentrators using Knelson CVD (continuous variable discharge) technology – in particular, setting the frequency of valve opening and the duration of valves remaining open. The purpose of the research was to assess the applicability of CVD technology in the treatment of various dump products of the processing plant and to build a model of dependencies between the concentrate and tailings yields and the adjustable parameters, which will allow to perform preliminary calculations of the efficiency of implementing this technology at processing plants. The research objects are middling and main separation tailings of the coarse-grained stream and combined product of main and recleaner separation tailings of the fine-grained stream. The study uses general methods of mathematical statistics: methods of regression analysis, aimed at building statistically significant models, describing dependence of a particular variable on a set of regressors; group method of data handling, the main idea of which is to build a set of models of a given class and choose the optimal one among them. Authors proposed an algorithm for processing experiment results based on classical regression analysis and formulated an original criterion for model selection. Models of dependencies between the concentrate and tailings yields and the adjustable parameters were built, which allowed to establish a relationship between the concentrate yield and the valve opening time, as well as a relationship between the tailings yield and the G-force of the installation.
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Date submitted2019-06-06
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Date accepted2019-08-09
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Date published2020-04-24
Studies of enrichment of sulfide and oxidized ores of gold deposits of the Aldan shield
The paper presents the analysis of studies of the enrichment of sulfide and oxidized ores in Yakutia deposits. The ore of the deposit is a mixture of primary, mixed and oxidized ores. The main useful component of the studied ore samples is gold with a content of 1.5 to 2.8 g/t, the silver content is low – 5-17 g/t. Ore minerals are represented by sulfides, among which pyrite predominates. The total sulfide content does not exceed 3-5 %. The presence in the ore of free and associated gold with a grain size from fractions of a micron to 1.5 mm. Gold is represented by nuggets in intergrowth with sulfides and also forms independent inclusions. Ores are classified as easily cyanidable. It was found that the content of amalgamable gold is 10-49, the share of cyanidable gold ranges from 66.67-91, the share of refractory gold is 9.0-33.33 %, which in absolute amount equals to 0.24-0.8 g/t. The extraction of gold in gravitation concentrate varies depending on the gold content in the ore and the yield of concentrate and for ores with a gold content of 1.5-2.8 g/t from 40 to 60 %. The direct cyanidation of all studied ore samples established the possibility of extracting gold into solution up to 86.7-92.9 %, the gold content in cyanidation cakes is 0.2-0.3 g/t. Investigations of the gravitation concentrate by the method of intensive cyanidation showed that with an initial gold content of ~ 500 g/t, up to 98.9 % is extracted into the solution. The gold content in intensive cyanide cakes will be 6-15 g/t. A set of studies carried out by the authors of the article at various institutes showed that it is advisable to process ore from the deposit using cyanidation technology with preliminary gravitational extraction of gold.
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Date submitted2019-07-11
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Date accepted2019-09-11
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Date published2020-04-24
Research of lithium sorption by KU-2-8 cation exchanger from model solutions simulating geothermal fluids in the dynamic mode
- Authors:
- Tatiana P. Belova
- Tatiana I. Ratchina
The extraction of chemical compounds from hydromineral raw materials is currently a promising objective. The geothermal deposits in the Kamchatka Territory should be considered as possible sources of lithium, boron and other chemical compounds. Their economic efficiency is justified by the complexity of the use of resources of geothermal fluids. The article presents data obtained as a result of experimental studies of lithium sorption by KU-2-8 cation exchanger from model solutions that simulate geothermal fluids in the dynamic mode. It was shown that in the first phase of sorption, ion exchange results in the absorption of lithium and sodium ions by the hydrogen form of cation exchanger up to the degree of cation exchanger saturation by 78 %. After that, the displacement of lithium ions by sodium ions is observed. The intermediate solutions were obtained in which the molar ratio of Li/Na is 80 times higher than in the initial solution. To separate sodium and lithium, it is proposed to use the lithium form of cation exchanger obtained using a portion of lithium chloride concentrate. The separation occurs due to the displacement of lithium ions by sodium ions. The effluent has a molar ratio of Li/Na = 10.4. The regeneration is carried out with 1 n hydrochloric acid, while the concentration coefficient of sodium chloride equals three.
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Date submitted2018-05-14
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Date accepted2018-07-15
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Date published2018-10-24
Experience of Integrated use of gold-bearing raw material in the production of precious metals
- Authors:
- V. V. Zhmurova
- N. V. Nemchinova
With the depletion of rich gold-bearing ores, the processing started to use polymetallic ores, which, in addition to precious metals, contain other elements that could be valuable after recovery. The problem of using such ores is extremely difficult because of the high cost of recovery of associated valuable components. The paper presents the results of studies on the integrated use of extracted gold-bearing raw materials based on the example of the Berezitovoye deposit (Amurskaya oblast), they have low content of precious metals and many heavy non-ferrous metals (copper, lead). Experimental work was carried out to obtain copper by the method of cementation from solutions formed after the leaching of the impurities of gold-containing cathode deposits with hydrochloric acid. The cementing metal was iron turnings (waste products of the turning shop of the enterprise). Next, it was proposed to use cemented copper as a collector during re-melting of slags – wastes of processing of low-grade polymetallic ores containing precious metals. The authors obtained ingots of alloyed gold with gold weight fraction of 16 %, which meets the requirements of TU 117-2-7-75 on the content of non-ferrous metals. During hydrochloric acid treatment of cathodic deposits silver partially passed into the solution, it was recovered together with cemented copper and, in subsequent melting, passed into alloyed gold. Thus, the method proposed by the authors helps to reduce the content of precious metals in the «incomplete production cycle» of the gold recovery factory. The opportunity of selling the cementation copper at the enterprises specializing on manufacturing of jewels is shown; the expected economic effect at the same time amounted to more than 1.8 million rubles.
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Date submitted2017-11-20
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Date accepted2018-01-09
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Date published2018-04-24
Sulfidization of silver-polymetallic ores of «Goltsovoe» deposit for decreasing loss of silver in mill tailings
- Authors:
- L. V. Shumilova
- O. S. Kostikova
The results of laboratory studies of flotation concentration of silver-polymetallic ores of the Goltsovoe deposit at the Omsukchansk concentrator are presented. The results of sieve analysis of mill tailings of the experimental sample of MTP N 101 (N 7577-i) are described. They indicate that a large amount of silver (123 g/t) is lost in the size class – 0.040 mm (yield 50.25 %). According to the results of mineralogical analysis, it is established that the major losses of noble metal are associated with its fine impregnation in oxides, sulfides and silicate rocks. The main silver-bearing minerals are acanthite, polybasite and kustelite (class – 0.040 mm). Experimental studies were carried out in two stages. The purpose of the first stage is to determine the influence of grinding fineness in flotation feed (for a finished class content of 0.074 mm in the range of 60-95 %) for silver recovery at different amounts of butyl potassium xanthate (50, 150, 300 g/t). The purpose of the second stage is to evaluate the effectiveness of sulfidization at different consumption of sodium sulfide Na 2 S·9H 2 O (50, 150, 200, 450, 750 g/t – 1 % aqueous solution) under the conditions of the optimal reagent mode established in the first stage of the study. The results of experiments to determine the optimum grinding fineness and studies on the enrichment of silver-polymetallic ore with the use of sodium sulfide as a sulfidizer are presented. The efficiency of the sulfidization process is estimated. The following experimental dependencies of silver recovery are established: on the degree of grinding and consumption of butyl potassium xanthate; on variations of grinding fineness and the consumption of sodium sulphide (with a consumption of butyl xanthate 150 g/t); and on grinding fineness at optimum consumption of sodium sulfide 150 g/t and butyl potassium xanthate 300 g/t. A comparative evaluation of dependence of silver recovery index from the degree of grinding fineness before and after introduction of sodium sulphide (collecting agent consumption of 150 g/t) is given. T\
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Date submitted2015-10-19
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Date accepted2015-12-20
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Date published2016-08-22
Changes in thermal plasticity of low grade coals during selective extraction of metals
- Authors:
- V. Yu. Bazhin
As the world oil market tends to be highly volatile, the coal becomes a primary source of organic raw materials for chemical and metallurgical industries. Fossil coals can accumulate high amounts of elements and mixtures quite often reaching commercially valuable concentrations. Reserves of scandium and other rare elements in coal deposits in Siberia alone are sufficient to satisfy the expected global demand for several decades. This study is intended to solve complex tasks associated with extraction of metal oxides using the developed enrichment method to ensure the required thermal plasticity determining the quality and properties of metallurgical coke. Laboratory experiments have been conducted for the enrichment of high-ash coals containing the highest concentrations of metals. Thermal plasticity values have been determined with the help of Gieseler plastometer . Using modern technologies and equipment individual deposits can be turned into profitable production of enriched coking coals with concurrent extraction of rare metals. It has been proven that the highest commercial potential lies with the extraction of scandium and some other rare metals in the form of oxides from the coal.
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Date submitted2015-08-27
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Date accepted2015-10-05
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Date published2016-04-22
Processing of alumina production red mud with recovery of scandium concentrate
The chemical and technological principles of scandium recovery from red mud of alumina production with the use of flue gases from sintering furnaces have been developed. The optimal conditions of hydrochemical processes of successive removal of impurities for the production of scandium concentrate with simultaneous obtaining of titanium-containing product have been worked out on a pilot plant.
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Date submitted2014-10-27
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Date accepted2014-12-28
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Date published2015-08-25
Extraction of rare earth metals of di-2-ethylhexyl phosphoric acid from phosphoric solutions
- Authors:
- O. V. Cheremisina
The paper is devoted to solvent extraction of rare earth metals exemplified by Сe, Y from standard test and industrial solutions of wet-process phosphoric acid with di-2-ethylhexyl phosphoric acid used as extractant. The mechanism of rare earth metals extraction with di-2-ethylhexyl phosphoric acid was determined and studied on the basis of calculated thermodynamic characteristics. The paper considers the influence of impurity ions (Fe 3+ , Mg 2+ , ) on extraction of rare earth metals using industrial solutions. It has also been determined that for a stripping process the use of sulfuric acid solutions in concentration of 2 mol/l is the most preferable.
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Date submitted2014-07-09
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Date accepted2014-08-31
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Date published2014-12-22
Properties of electric arc furnace dust and methods of utilizing it
- Authors:
- M. A. Pashkevich
- T. A. Lytaeva
The least utilized recyclable wastes from mining and processing enterprises are dispersed wastes, which are in the form of dust captured by systems of gas purification. This dust is a technogenic raw material for the production of zinc and other metals. Various ways of utilizing the steelmaking dust are presented. For utilization of the steel-making dust, a hydrometallurgical method with the use of autoclave technologies is proposed. The results of experiments in sulfate autoclave leaching are described.
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Date submitted2009-10-16
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Date accepted2009-12-07
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Date published2010-09-22
Geomechanical and geodynamic problems ассompanying the мining of hydrocarbon deposits
Rock mechanics in petroleum industry is used for determination of geomechanical models of rock mass, calculating parameters of rock subsidence, stability of oil and gas wells, problems relevant to geodynamics. The present paper describes the analytical and numerical analyses of compaction in reservoir, following reduction in filter-capacity performance and well productivity.
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Date submitted2009-09-25
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Date accepted2009-11-15
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Date published2010-06-25
Studies of resistance micro-welding modes for dentistry applications
- Authors:
- A. B. Tsyganov
- A. S. Mustafaev
Various modes of resistance welding between steel and Ni-Ti-extracting electrodes and fractures of endodontic files were investigated. It was demonstrated that in close to real clinical situations there is most suitable a sequence of a number of pulses of a steepened welding current. As a result, detachment force limit of 15-50 N is achievable which is sufficient for the fracture extraction in most cases.
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Date submitted1954-07-11
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Date accepted1954-09-11
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Date published1955-11-17
Извлечение молибдена из бедных концентратов и промпродуктов
Первые работы по гидрометаллургии молибдена были начаты Ленинградским горным институтом в 1932 г. и осуществлялись на бедном сырье Тахтарвумчоррского месторождения, чрезвычайно далеком от обычных кондиций. В течение двух последующих лет результаты этих работ были обсуждены и одобрены на проводившихся академиком А. Е. Ферсманом широких совещаниях в г. Кировске и Ленинграде, но практическое использование получили позднее, в связи с проблемой извлечения молибдена, содержащегося в балхашских медных рудах. В октябре 1941 г. на Балхашском заводе был введен в эксплуатацию цех, предназначенный для передела некондиционных молибденовых продуктов методом, разработанным в Ленинградском горном институте.