-
Date submitted2023-10-28
-
Date accepted2024-11-07
-
Date published2025-02-25
Radiation characteristics of coals at different stages of metamorphism
The formation of deposits and subsequent metamorphic processes that affect concentrations of radioactive elements in coal can indicate ongoing geological activities, therefore, analyzing trends in the radiation characteristics of coal throughout the metamorphic series is highly relevant. The aim of this work is to experimentally evaluate the radiation characteristics of different coal ranks (metamorphic stages) using thermoluminescent (TL) dosimetry and beta activity measurements, and to identify correlations between these radiation characteristics and data obtained from technical, elemental, and thermogravimetric analyses, as well as mass spectrometric and electron paramagnetic resonance spectroscopy (EPR) measurements. For dosimetric measurements that indirectly characterize the content of radionuclides in coal, a modified dosimetric complex and original soil-equivalent thermoluminescent detectors based on SiO2 were used. The analysis of the obtained results supports the use of TL studies to determine the ash content of coals at low and medium stages of metamorphism (coal rank B→G), while indicating that this method is not feasible for coals at higher stages of metamorphism. The correlation dependencies in the metamorphism series suggest abrupt change in the conditions of coal formation during the time range corresponding to transformation from high to low volatile bituminous coals (coal rank G→Zh→K). These abrupt changes in regional metamorphism conditions (time, temperature, pressure, oxidation-reduction conditions) are confined to the boundary of the Permian and Triassic periods (~250 million years ago), during which both the transformation of existing coal deposits and the formation of new deposits occurred.
-
Date submitted2024-05-08
-
Date accepted2024-11-07
-
Date published2024-12-12
The effect of mechanical and thermal treatment on the characteristics of saponite-containing material
Solving the problems of modern building materials science is reduced to obtaining high-quality materials, expanding and searching for a rational raw material base, which can be carried out through the use of various industrial wastes. In this paper, the possibility of using waste from the mining industry – saponite-containing material (SCM) obtained during the enrichment of kimberlite ores from the Lomonosov diamond deposit, as an active mineral additive for cement binders and concretes is considered. The influence of mechanical and thermal treatment on a number of properties of the material selected from the tailings dump and in its initial state was studied. The study of the surface activity of SCM samples consisted in determining the sorption capacity, acid-base centers and their distribution. An increase in the activity of the surface of the material particles as a result of mechanical activation and its decrease during temperature treatment were determined. These effects are associated with phase rearrangements and structural changes in the sandy-clay rock, which was confirmed during thermal analysis. The temperature effect has no pronounced effect on the microstructure, the “smoothness” of the particles and the formation of a consolidated surface of the structural elements of the saponite-containing material are noted.
-
Date submitted2022-05-20
-
Date accepted2023-06-20
-
Date published2024-02-29
Increasing the quality of zeolite-bearing rocks from Eastern Transbaikalia by applying directed energy
This paper presents the use of accelerated electrons to treat zeolite-bearing rocks from Eastern Transbaikalia to increase the efficiency of separating zeolites from rock-forming minerals via electromagnetic separation. The effectiveness of the liberation of zeolite minerals using accelerated electrons was analyzed. The results of dry electromagnetic separation of zeolite-bearing rocks are presented. The dependence of the extraction of iron-bearing minerals from zeolite-bearing rocks by electromagnetic separation on the magnetic field intensity for different particle sizes has been established. The main methods of zeolite-bearing rock enrichment and ore preparation were determined. A technological scheme for processing zeolite-bearing rocks, based on the use of accelerated electron treatment at the ore preparation stage, is presented, significantly improving the zeolite production quality.
-
Date submitted2022-05-17
-
Date accepted2023-04-03
-
Date published2024-02-29
Improvement of concentrate quality in flotation of low-rank coal
- Authors:
- Sergei A. Kondratev
- Tatyana A. Khamzina
Percentage of high-rank coal with low content of ash, moisture, and sulfur in total coal production output is low. Most of the produced coal has a low quality (lignite, bituminous coal: long-flame and fiery). Under increasing requirements for ecological cleanness of coal, the efficient use of coal products is only possible after improvement of their processing properties. The authors discuss the enhancement of flotation efficiency of low-rank coal using the mechanism of physisorption of a collecting agent in particle – bubble attachment. It is explained why the yield of concentrate with low ash content increases as a result of combination of collectors having different physical properties. It is shown that the surface activity of a heteropolar agent relative to the gas – liquid interface and the adsorption density of the agent govern its collecting properties. Based on the recovery – surface activity relationship, the correlation is found between the collecting activity of a chemical compound and the structure of its molecules. The combination of the collectors with different surface activity enables adjusting collectability and selectivity of the blend. The physisorption mechanism of collectors can be a framework for developing recommendations on modification of concentrate yield and ash content, and on selection of optimized ratios of surface activities of miscible collectors relative to the gas – liquid interface.
-
Date submitted2022-10-24
-
Date accepted2023-03-03
-
Date published2023-04-25
Use of clay-containing waste as pozzolanic additives
Growing productivity of mining and processing enterprises entails an increase in the volumes of liquid tailings impoundments and upstream impoundments of ore processing waste. Enterprises face the challenge of minimizing the environmental impact of waste and guaranteeing the sanitary and epidemiological safety of population. The article presents a possibility of recycling one type of such waste (clay-containing concentration tailings of apatite-nepheline and sylvinite ores, coal beneficiation tailings) by using them after preliminary thermochemical treatment as pozzolanic additives to cements and concretes, including concrete mixtures used for soil stabilization, development of territories, reclamation of mine workings, as a component of the insulating layer of landfills for the disposal of municipal solid waste. An analysis of the phase changes of kaolinite, one of the main minerals that make up clay-containing waste, in the temperature range of 200-1,000 °С showed that a change in its mineral form during heat treatment is the main factor in changing its pozzolanic activity. The effect of heat treatment of clay minerals at temperature of 700-800 °C on their pozzolanic activity, estimated by the ability to absorb calcium hydroxide (0.7 g Ca(OH) 2 per 1 g of modified kaolinite), is considered. It is shown that the addition of heat-treated samples (20 % by weight) improves the quality of cement increasing its activity by 15 %, in comparison with the use of unmodified clay minerals. It was proved experimentally that partial replacement of Portland cement with thermally modified kaolinite increases the strength of consolidating stowing mixture by up to 15 %. This approach to processing of ores containing layered silicates, which provides for thermochemical modification of run-of-mine ore, intensifies the processes of tailings thickening and filtering.
-
Date submitted2022-03-22
-
Date accepted2022-11-17
-
Date published2023-02-27
Development of composition and study of sorbent properties based on saponite
The development of a comprehensive approach to preventing the pollution of natural objects is necessary due to the high requirements of environmental legislation for the discharge of industrial wastewater. Adsorbents are used in various industries to extract heavy metals from wastewater. In this study the possibility of using saponite clay as a raw material for the production of sorbent for the extraction of copper ions Cu 2+ from industrial wastewater is considered, a recipe and technology of sorbent production are developed, and its chemical composition is established. It has been established that the optimum temperature for heat treatment of the sorbent and corresponds to 550 ºC, since at this temperature saponite extrudates acquire strength (strength 34.1 kg/mm 2 ) and textural properties (specific surface area of pellets 22.803 m 2 /g), allowing them to be used as sorbents. The kinetics of molecular adsorption was studied using model solutions of copper (II) sulfate. The extraction efficiency of copper (II) ions from the model solutions is 93 %. Extraction efficiency of copper (II) ions from copper plating wastewater reaches 94 %. SEM results confirm the presence of metal on the sorbent surface.
-
Date submitted2022-03-17
-
Date accepted2022-06-20
-
Date published2022-11-03
Assessment of collecting activity of physically sorbed reagents on the example of easily floatable coking coal sludge
- Authors:
- Sergey A. Kondratev
- Tatyana A. Khamzina
The article presents one of the new approaches to theoretical assessment of collecting ability of reagents. The efficiency of reagents-collectors with different chemical composition used for flotation of coking coals was studied. A comparative assessment of the flotation activity of kerosene, mineral oil, thermal gas oil, KETGOL and FLOTEK is given. The criteria of collecting activity of the above reagents-collectors for coal sludge flotation were specified. A correlation was established between the indicators of coal sludge flotation by the above reagents and their physical parameters. It is shown that the rate of spreading over water surface can characterize the flotation activity of reagents. Based on dependence of the collecting activity of a reagent on its rate of spreading along the “gas – liquid” interface and surface pressure, the main approaches to determining the structure and composition of molecules of an effective flotation collector can be determined. A new concept of the function performed by a physically sorbed collector in the elementary act of flotation and a criterion for the flotation activity of reagents used in coal sludge beneficiation are proposed. It is shown that the collector used in coal flotation, in addition to hydrophobizing the surface of the extracted particles, should reduce the induction time and remove the kinetic constraint on formation of a flotation aggregate.
-
Date submitted2021-10-08
-
Date accepted2022-01-24
-
Date published2022-04-29
Methodology for thermal desorption treatment of local soil pollution by oil products at the facilities of the mineral resource industry
- Authors:
- Mariya A. Pashkevich
- Marina V. Bykova
The analysis of the main environmental consequences of leaks and local spills of petroleum products at the enterprises of the mineral resource complex is presented. It is established that the problem of soil contamination with petroleum products at the facilities of the mineral resource complex and enterprises of other industries is caused by significant volumes of consumption of the main types of oil products. Based on the results of the author's previous field research, a series of experiments was carried out, consisting in modeling artificial soil pollution with petroleum products such as gasoline, diesel fuel, highly refined oil, motor oil, and transmission oil, followed by their purification by heat treatment at temperatures of 150, 200, and 250 °C. The 250 °C limit of the heating temperature was set due to the need to partially preserve the structure and quality of the soil after heat treatment to preserve its fertility. When the processing temperature rises to 450 °C, all humates are completely burned out and, as a result, productivity is lost. Confirmation is provided by the results of experiments to determine the humus content in uncontaminated soil and soil treated at different temperatures. It was found that at a maximum processing temperature of 250 °C, about 50 % of the initial organic carbon content is preserved. According to the results of the conducted experimental studies, the dependences of the required processing temperature on the concentration of petroleum products to reduce the concentration of petroleum products to an acceptable level have been established. The methodology of thermal desorption cleaning of soils with varying degrees of contamination at enterprises of the mineral resource complex is presented.
-
Date submitted2018-09-07
-
Date accepted2018-11-08
-
Date published2019-02-22
Assessment of refractory gold-bearing ores based on interpretation of thermal analysis data
- Authors:
- T. N. Aleksandrova
- G. Heide
- A. V. Afanasova
The article presents the results of a study on the possibility to assess refractory gold-bearing ores using thermal analysis data. It studies the flotation concentrates obtained during the enrichment of double refractory sulfide gold-bearing ores. This type of ore is complicated by the fine impregnation of gold in sulphide minerals and the presence of sorption-active scattered carbonaceous matter, which is in close association with sulphides. The results of thermogravimetric and mass spectrometric studies of refractory gold-bearing ores are presented. The obtained fragments for kerogen CH (m/z = 15), C 2 H (m/z = 29) and C 3 H (m/z = 43) indicate the presence of various types of carbonaceous matter in the studied samples. It is justified that the degree of sorption activity of carbonaceous matter depends on the presence of kerogen and bitumen in the ore. High sorption activity of scattered carbonaceous material significantly affects the processing technology of ores and concentrates, both flotation and pyro- and hydrometallurgical methods. Thermogravimetric and mass spectroscopic analyzes can be used to determine the degree of preg-robbing of refractory gold-bearing ores. The obtained results predetermine the direction of creating new methods and technologies in the field of decarburization of refractory gold-bearing ores in the integrated development of solid minerals in the mining regions of Russia.
-
Date submitted2014-12-07
-
Date accepted2015-02-23
-
Date published2015-12-25
Bump hazard evaluation of a rock mass area as a result of its seismic acoustic activity registration
- Authors:
- V. V. Nosov
Ore production in deep rock-bump hazardous mines is closely connected with the need to in-crease workers’ safety, which demands heavy costs of taking preventive shockproof actions and applying expensive protection systems against mountain blows. The article considers a resource forecasting technique and a bump hazard evaluation method for a rock mass area, based on a mi-cromechanical model, which registers acoustic emission of heterogeneous materials, and empirical data, obtained as a result of acoustic signals registration with the help of the model, aimed at seis-mic-acoustic activity evaluation at «Taimir» and «Oktyabrsky» rock mass areas, belonging to Norylsk industrial region.
-
Date submitted2014-07-12
-
Date accepted2014-08-24
-
Date published2014-12-22
The study of structural features of outburst coal seams
- Authors:
- V. N. Zakharov
- O. N. Malinnikova
A study of the structural features of outburst-dangerous and non-outburst dangerous coal layers was conducted. It was shown that coal taken from a sudden outburst zone has a significantly greater sorption surface than coal from the same layer which was not part of the sudden outburst. The size of the sorption surface of coal is affected by its history up to that point; thus the heating of the coal sample during its preparation enlarges its sorption surface. An electron microscope study of coal surfaces has shown that for coal from outburst-dangerous layers, a disturbed structure with a large quantity of fissures and partings the size of 1 micrometer is typical. Under the same enlargement, a coal structure from safe coal layers is much more uniform. The study of digital images of coal surfaces, taken with the help of an electron microscope, shows that the structural institution of surface elements may be presented by multifractal analysis, with its spectrum of fractal dimensions, which allows us to state quantitative distinctions in coal microstructures for outburst-dangerous layers. Coal from outburst-dangerous layers has a greater set of structural elements, and therefore a spectrum of fractal dimensions that is 1.5-2 times wider than for nonoutburst dangerous layers.
-
Date submitted2009-10-22
-
Date accepted2009-12-27
-
Date published2010-09-22
Preconditions for prediction of technogenic seismic activity by cycles of objects of the solar system
- Authors:
- B. G. Tarasov
- A. G. Olovianny
- L. V. Bugaenko
The paper contains the statistical rows of rockbursts, sudden outbursts of methane at coal mines and ore mines in Russia for the period from 1954 to 2007, as well as the reflection in them of the eleven-year cycles of the Sun activity. Some results are presented of computer modeling of activation periods of outburst-hazardous state of rock mass at coal mines of the Kuzbass basin. Recommendations are given.
-
Date submitted2009-10-01
-
Date accepted2009-12-02
-
Date published2010-09-22
Specific manifestations of tectonic and seismic activity in Kuzbass
- Authors:
- A. I. Ekimov
- S. V. Tsirel
The conducted observations demonstrated the substantial growth and variation of nature of tectonic and seismic activity in Kuzbas. Growth of geodynamic risks is marked. Methods for study of observable processes are suggested.
-
Date submitted2009-10-17
-
Date accepted2009-12-07
-
Date published2010-09-22
Regularities of progressing of technogenic seismic activity in mining areas
- Authors:
- S. V. Tsirel
Regularities of variation of cumulative graphs of seismic events repetition in process of transferring from natural seismic activity to the technogenic one are studied. Processes of growth of technogenic seismicity in mining regions on examples of the Kola peninsula and Kuzbass are reviewed.
-
Date submitted2009-09-10
-
Date accepted2009-11-11
-
Date published2010-06-25
Stages of training activation methods development
- Authors:
- M. A. Perfilova
The article is dedicated to the problem of developing methods of training activation. Historical and pedagogical background for the development of these methods and distinguishes the stages of training activation methods development from the ancient times till nowadays are analysed. The brief chronological survey is presented tabular. The main features of the methods of active training are pointed out.
-
Date submitted2009-09-19
-
Date accepted2009-11-15
-
Date published2010-06-25
Potassium chloride content in ore and products оf recycling automatic control system
- Authors:
- S. S. Galushkin
- B. A. Vishnyak
- V. N. Smirnov
Potassium chloride percentage in continuous transported ore flows and products of potassium plants recycling automatic control system is offered and described. It differs fundamentally from used before ones at bulk solids containing natural radio-activity elements effective constituents producing and recycling plants. Sensing device is used in this information-measuring system (IMS). It allows to realize automatic control in flows for that instantaneous productivity fluidity in wide limits is resided. Using such IMS gives considerable economic effect by measurements error lowering and their quickness increase.
-
Date submitted2008-10-30
-
Date accepted2008-12-22
-
Date published2009-12-11
Investigations of the mechanism of methane desorption in coal saturation with carbon dioxide
- Authors:
- A. T. Karmansky
The article considers the developed unit for investigations of interaction between coal and gas, and gas outflow from the coal surface by gravimetric method under gas pressure up to 6 MPa. Relationship between the sorption ability and metamorphism stage is explained by the microstructure of coal. The adsorption increment indices of volume V and velocity of changes in pressure P – during adsorption may be used for prediction of outburst-hazard of coal and gas.