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Date submitted2022-11-06
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Date accepted2022-11-29
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Date published2022-12-29
Technological sovereignty of the Russian Federation fuel and energy complex
- Authors:
- Oleg V. Zhdaneev
The review to achieve technological sovereignty of the Russian fuel and energy complex (FEC) in the ongoing geopolitical situation is presented in the article. The main scope has been to identify the key technology development priorities, restrictions and internal resources to overcome these utilizing the developed by the author the innovative methodology that consists of novel approaches to calculate level of local content, digitalization, business continuity andinteractions with military-industrial complex. Some organizational changes have been proposed to intensify the development of hi-tech products for the FEC and related industries, including establishment of the state committee for science and technology and the project office of lead engineers for the critical missing technologies. Two successful examples to utilize the described in the paper methodology is presented: the first domestic hydraulic fracturing fleet and polycrystalline diamond compact cutter bit inserts.
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Date submitted2022-03-03
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Date accepted2022-04-27
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Date published2022-07-26
Peculiarities of rare-metal mineralization and genetic relationship of mineral associations in the eastern rim of Murzinsko-Aduysky anticlinorium (the Ural Emerald Belt)
- Authors:
- Mikhail P. Popov
The paper presents features of the location and composition, as well as a generalization of data on the age of rare-metal mineralization developed at the deposits and occurrences of rare metals and gemstones in the eastern rim of Murzinsko-Aduysky anticlinorium, within the Ural Emerald Belt, which is a classic ore and mineralogical object and has been studied for almost two hundred years. With a significant number and variety of prospecting, research and scientific works devoted mainly to emerald-bearing mica complexes and beryl mineralization, as well as rare-metal pegmatites, scientific literature has so far lacked generalizations on the formation of numerous mineral associations and ore formations that represents a uniform genetic process in this ore district. The aim of the work is a comprehensive geological-mineralogical analysis of mineral associations of the eastern rim of Murzinsko-Aduysky anticlinorium and studying their age, formation conditions and characteristic features to determine the possibility of expanding and using the mineral resource base of the Urals through developing new prognostic and prospecting criteria for rare-metal and gemstone ore formations and creating the new devices for promising objects prospecting
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Date submitted2021-06-10
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Date accepted2021-07-27
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Date published2021-10-21
Defects of diamond crystal structure as an indicator of crystallogenesis
- Authors:
- Evgeny A. Vasilev
Based on the study of a representative collections of diamonds from diamondiferous formations of the Urals and deposits of the Arkhangelsk and Yakutian diamond provinces, we established patterns of zonal and sectoral distribution of crystal structure defects in crystals of different morphological types, identified the specifics of crystals formed at different stages of crystallogenesis and performed a comprehensive analysis of constitutional and population diversity of diamonds in different formations. We identified three stages in the crystallogenesis cycle, which correspond to normal and tangential mechanisms of growth and the stage of changing crystal habit shape. At the stage of changing crystal habit shape, insufficient carbon supersaturation obstructs normal growth mechanism, and the facets develop from existing surfaces. Due to the absent stage of growth layer nucleation, formation of new {111} surfaces occurs much faster compared to tangential growth mechanism. This effect allows to explain the absence of cuboids with highly transformed nitrogen defects at the A-B 1 stage: they have all been refaceted by a regenerative mechanism. Based on the revealed patterns, a model of diamond crystallogenesis was developed, which takes into account the regularities of growth evolution, thermal history and morphological diversity of the crystals. The model implies the possibility of a multiply repetitive crystallization cycle and the existence of an intermediate chamber; it allows to explain the sequence of changes in morphology and defect-impurity composition of crystals, as well as a combination of constitutional and population diversity of diamonds from different geological formations.
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Date submitted2020-10-22
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Date accepted2021-03-02
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Date published2021-04-26
Dynamic simulation of industrial-scale gibbsite crystallization circuit
- Authors:
- Vladimir O. Golubev
- Tatyana E. Litvinova
Population balance model is crucial for improving the method of aluminum hydroxide massive crystallization and enhancing the quality of control over industrial precipitation trains. This paper presents the updated population balance model, which can be used for simulation of industrial-scale precipitation. Processes of birth-and-spread and particle breakage are considered integral parts of the precipitation process along with secondary nucleation, growth and agglomeration of particles. The conceptual difference of the proposed system of equations is its ability to reproduce the oscillatory process that occurs in precipitation circuits as a result of cyclic changes in the quality of the seed surface. It is demonstrated that self-oscillations can occur in the system without any external influence. The updated model is adjusted and verified using historical industrial data. The simulation of seed-recycle precipitation circuit showed an exact correspondence between the calculated dynamic pattern of changes in particle size distribution of aluminum hydroxide and the actual data.
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Date submitted2019-03-05
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Date accepted2019-05-03
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Date published2019-08-23
Efficiency Estimation of the Single- and Multicomponent Anti-hydrate Reagents
- Authors:
- N. A. Shostak
- E. P. Zaporozhets
Different types of technological and technical problems in the oil, gas and chemical industries are connected with the hydrate formation process and with the using of anti-hydrate chemicals. That is why, it is necessary to estimate thermobaric ranges within which reagents does not let hydrate to grow or is their dissociation. Also, to estimate anti-hydrate influence we need to determine the chemicals’ anti-hydrate efficiency and chose the best one. They make the reagents consisting of several chemical components depending on the purpose of their application – for prevention of formation and (or) elimination of hydrates. It demands calculations of the optimum concentration and expenses and also the intensity (speed) of hydrates dissociation causing with the reagents. The analytical method of the anti-hydrate chemical reagents efficiency determination containing one or several components from different classes of chemical compounds – alcohols, salts, acids, compounds of nitrogen and oxygen – is presented in this paper. With its help it is possible to define decrease in temperature of hydrate formation from reagents influence, to count key parameters of reagents anti-hydrate efficiency depending on component compositions of hydrate gas and a phase condition of a hydrate-gas system, to select types of chemical components and their quantity in multicomponent reagents, i.e., to make new compounds. The method can be used for express assessment of anti-hydrate chemical reagents efficiency on criteria sign for practical application in oil, gas and processing industry.
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Date submitted2015-07-25
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Date accepted2015-09-01
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Date published2016-02-24
The phenomenon of isothermal transition of metastable aluminate solutions into the labile area and prospects of its industrial use
- Authors:
- V. N. Brichkin
- A. Kraslawski
The paper presents theoretically based requirements for the activation of synthetic gibbsite for maximum solubility of the activated product. The article describes the methodological foundations of gibbsite thermal activation and its effectiveness evaluation in terms of aluminate solutions decomposition. It is shown that to obtain high-saturation aluminate solutions, activation should provide generation of the reagent with highly-developed surface area, which is not identical to the structure of the deposited gibbsite. As a result of high-gradient thermal activation of synthetic gibbsite, it has been found that the targeted product develops predominantly an amorphous structure with a specific surface area up to 256 m2/ g, preserving its primary particle size. Activation products were investigated using modern methods of physical and chemical analysis. The experimental results confirmed the possibility of the activated product dissolution in the aluminate solution with a metastable compound and their spontaneous decomposition with aluminum hydroxide formation, characterized by high dispersion ability. It is shown, that a significant difference in kinetics and decomposition rates of solutions is connected with the use of a seed material with different particle size composition, which leads to the development of competing mechanisms, resulting in seed recrystallization, homogeneous and heterogeneous nucleation.
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Date submitted2009-09-26
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Date accepted2009-11-21
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Date published2010-06-25
The measurements of emission parameters of tungsten thermo cathodes in plasma energetic equipments
Emission parameters and coefficients of reflection of heat electrons from tungsten thermo cathodes were investigated under nontraditional for emission electronic conditions, when the surface contacts with highly ionized plasma. For measurements plasma diode electron current-magnetic field strength relations were used. Parameter Dj, which characterizes cathode heterogeneity by work function, and coefficient of reflection for policrystallic tungsten and for face 110 tungsten single crystal were measured. Proportion entering in effective reflection coefficient of electrons, reflected immediately from the surface and from potential barrier of spots field was determinate.
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Date submitted2009-08-26
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Date accepted2009-10-27
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Date published2010-02-01
Scheelites of Gavrilovskoe deposit (first find)
- Authors:
- A. E. Melnik
The Gavrilovskoe deposit (deposit of building stone) is situated in Vyborg district, Leningrad region. There was found scheelite (CaWO 4 ) in the «Northern» quarry at the Gavrilovskoe deposit in 2008. This mineral was identified exactly in the Saint Petersburg State Mining Institute (Technical University) with Raman Spectrometer Renishaw InVia Reflex. It was for the first time that scheelite was found at this place. There was researched a form of one scheelite crystal. The simple forms of this scheelite crystal were detected. It is very interesting to compare simple forms of scheelite from the Gavrilovskoe deposit to different crystals of this mineral, described in any science literature.
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Date submitted2008-10-05
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Date accepted2008-12-30
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Date published2009-12-11
Thermobaric granite crystallization conditions of the severniy massif (the Chukotka) in accordance with the feldspars study data
- Authors:
- V. I. Alekseev
The Kamentsev I.E. and Sorokin N.D. method is used to investigate the dependence of Al-Si-ordering and structure of alkaline feldspars decomposition in different granites from the Severny massif (Chukotka) under thermobaric conditions of their crystallization. The temperature and pressure on the granite system in the initial period of feldspars ordering are determined quantitatively for the first time for the region. Progressive pressure change which exceeds lithostatic load by 750 МPа at the late stage of lithium-fluoride granites formation is revealed. It is hypothesized that the deposits similar to explosive ore-bearing breccia can be discovered in the Chukotka. The conclusion on possibility to apply the Sobolev-Dobretsov concept of superpressure to interpret the process of rare-metal magmatism is drawn.
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Date submitted2008-10-17
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Date accepted2008-12-07
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Date published2009-12-11
Morphometry of aggregates and modeling of phase transition kinetics under metamorphism
- Authors:
- Yu. L. Gulbin
The paper discusses some general relations between the structure of metamorphic rocks and mechanisms of phase reactions. Among these relations is the influence of nucleation and growth of kinetics on the crystal size distribution. A brief overview is made of theoretical models which have been proposed to explain granulometric properties of rocks, and kinetic laws and factors on the metamorphic crystallization are considered by the example of metapelitic garnets, including the phenomenon of avalanche nucleation at finite overheating as well as the growth of porphyroblasts under diffusion-limited conditions. As a result, a new approach to modeling of native granulometric curves is presented.
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Date submitted1948-07-20
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Date accepted1948-09-27
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Date published1949-11-04
Genetic relationship of crystal nests with quartz veins and the origin of cavities
- Authors:
- A. E. Karyakin
In the early stages of studying the piezo-optical quartz deposits of the Northern Urals, some geologists believed that crystal nests had no genetic connection with quartz veins. Geologists came to this conclusion because at that time the bulk of piezo-optical quartz was mined not from crystal nests, but from placers, and geologists did not have enough data to correctly resolve this issue. Later, in connection with the transition to exploration of primary deposits, it was established that in most cases quartz veins and crystal nests are located in the same cracks. The asymmetrical arrangement of crystal nests in relation to quartz veins does not give reason to deny the genetic relationship of both, but only indicates a later formation of crystal nests compared to quartz veins. In all likelihood, after the formation of quartz veins, there was a fairly long intermineralization break, after which crack formation and the flow of hydrothermal solutions resumed. The duration of the intermineralization break can be judged by the sharp change in the nature of the hydrothermal solutions - from highly supersaturated with silicic acid (during the formation of quartz veins) to normal (during the formation of quartz crystals). Consequently, quartz veins and crystal nests are derivatives of a single magmatic chamber, but they were only formed in different phases of a single hydrothermal process.
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Date submitted1908-03-02
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Date accepted1908-05-24
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Date published1908-09-01
Crystals of the Mineralogical Museum
- Authors:
- Ye. S. Fedorov
Natural crystals are the most difficult object for the method of crystal-chemical analysis, and I must admit that my attempt to give the correct setting to all minerals turned out to be imperfect in many points. But it was precisely this imperfection that prompted the further development of criteria for correct installation, and pointed to the need to reconsider and individually study the crystals of many minerals.