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Date submitted2024-03-11
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Date accepted2024-09-24
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Date published2025-04-25
Comparative analysis of nitrogen and carbon isotopic fractionation during diamond formation based on β-factor determination
- Authors:
- Dmitrii P. Krylov
First quantitative estimates are presented for nitrogen isotopic fractionation during diamond crystallization with respect to nitrogen-bearing fluid components using quantum-mechanical (DFT) calculations on the defect (with the substitutional nitrogen) diamond lattice. Provided equilibrium isotopic fractionation, 15N/14N ratio decreases within the sequence of compounds NH4+ > N2 > (diamond, NH3) > CH3N > CN− > NH2. At temperatures of 1,100 to 1,200 °C fractionation among diamond and fluid N-compounds are estimated at –2.23, –0.77, 0.01, 0.44, 1.31 and 2.85 ‰ and substantially (over 1 ‰) exceed the already available estimates based on the modeling diamond C-N bonds by analogy with HCN or CN – molecules. Depending on the dominant nitrogen and carbon substance in the mineral-forming fluid, diamond formation can be accompanied by different isotope compositional trends, as expressed either by zoned patterns within individual diamond grains or by isotopic δ15N vs δ13C covariations during successive crystallization. Provided the dominance of NH3 component (the reduced conditions, high pressures and the cold geotherm) nitrogen isotope fractionation between diamond and fluid does not exceed 0.1-0.2 ‰ and the isotope shifts at temperature ca. 1100 °C Δ15N << Δ13C. In nitrogen depleted reduced mantle fluids possible existence of compounds with low heavy isotope affinity at temperature of diamond formation (especially NH2) implies high isotope fractionation between diamond and the fluid and hence, evolved Δ15N/Δ13C ratios. Oxidized fluids dominated by CO2 or CO3 coupled with N2 component are characterized by close to zero Δ15N/Δ13C ratios as inferred by prevailing carbon isotope fractionation with respect to nitrogen isotopes, the latter change considerably with nitrogen distribution coefficient among diamond and the growth media.
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Date submitted2023-07-07
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Date accepted2023-12-27
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Date published2024-08-26
Landslide hazard assessment in Tinh Tuc town, Cao Bang province, Vietnam using Frequency ratio method and the combined Fractal-frequency ratio method
Landslides are one of the most frequent natural disasters that cause significant damage to property in Vietnam, which is characterized by mountainous terrain covering three-quarters of the territory. In 17 northern mountainous provinces of the country, over 500 communes are at a high to very high landslide hazard. The main goal of this study was to establish landslide hazard maps and conduct a comparative evaluation of the efficiency of the methods employed in Tinh Tuc town, Cao Bang province. The landslide hazard assessment was carried out in this study using the combined Fractal-frequency ratio (FFR) and the Frequency ratio (FR) methods. The FR method is based on the actualist principle, which assumes that future landslides may be caused by the same factors that contributed to slope failure in the past and present. The FFR method is based on the determination of the fractal dimension, which serves as a measure of the landslide filling density in the study area. Eight landslide-related factors were considered and presented in cartographic format: elevation, distance to roads, slope, geology, distance to faults, land use, slope aspect, and distance to drainage. Determining the area under the receiver operating characteristic curve (ROC-AUC) and verification index (LRclass) was performed to assess the performance of prediction models and the accuracy of the obtained maps. As a result, five zones were identified for the study area, characterized by very low, low, moderate, high, and very high landslide hazards. The analysis of the reliability of the obtained landslide hazard maps using the AUC and LRclass indices revealed that the FFR model has a higher degree of reliability (AUC = 86 %, LRclass = 86 %) compared to the FR model (AUC = 72 %, LRclass = 73 %); therefore, its use is more effective.
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Date submitted2022-04-03
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Date accepted2023-03-02
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Date published2023-12-25
Specifics of geotechnical risk control in the design of underground structures
The underground space development is associated with the emergence of complex and dangerous situations, often leading to accidents. The condition for their development is the potential geotechnical risks. High-quality execution and analysis of design work at all the stages of design, starting from the early stages, is one of the effective ways to control risks. Clarification of the characteristics and features of the rock mass adjacent to the projected underground structure makes it possible to identify the potential cause of the occurrence of an adverse event with a certain probability during the construction and operation of an underground structure. The purpose of a qualitative risk analysis is to identify risk factors in underground construction. The value of the total geotechnical risk, expressed by the sum of each of the possible risks, should be numerically estimated at the design stage of a specific underground facility. At the same time, it is extremely important to develop a methodology for managing geotechnical risks, which would make it possible to assess their probability of development at an early stage of project preparation and propose measures to reduce or prevent them. This technique is given in the article. The results of the study conducted in accordance with the presented methodology showed that geotechnical risk control proved an effective method in preventing accidents during underground construction.
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Date submitted2021-07-19
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Date accepted2022-05-31
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Date published2022-07-13
Study of a set of factors influencing the error of surveying mine facilities using a geodesic quadcopter
The factors influencing the qualitative and quantitative components of the result of surveying in open-pit mining using a quadcopter were identified and systematized, and the mathematical dependence of the influence of factors on the final error of surveying was determined. After a large number of field observations – numerous flights of a geodesic quadcopter over mining facilities – the subsequent mathematical justification of the results of the aerial photogrammetric surveying was made, which allowed to analyze the degree of participation in the final accuracy of the survey of each of the considered factors. The results of this study demonstrate the source of errors, which provide the surveyor with the opportunity to efficiently and competently carry out pre-flight preparation and planning of fieldwork. The study and subsequent consideration of the factors affecting the accuracy of surveying with the use of an unmanned aerial vehicle are the basis for the subsequent development and formation of a methodology for using a geodesic quadcopter in the conditions of open-pit mining.
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Date submitted2021-06-01
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Date accepted2021-07-27
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Date published2021-10-21
Indicator assessment of the reliability of mine ventilation and degassing systems functioning
- Authors:
- Nina O. Kaledina
- Valentina A. Malashkina
The gas emission control in the mines is operated by ventilation and degassing systems that ensure the aerological safety of the mines or minimize the aerological risks. The ventilation system of the mine and its individual sites includes a significant number of technical devices and equipment, and the air tubes are mainly mining workings, the condition of which determines the quality of the ventilation network (its capacity) and depends on a number of mining factors. Similarly, one of the most important elements of the degassing system, which includes its own chain of technological equipment, are wells, and in some cases, mining workings. Thus, mine ventilation and degassing systems cannot be attributed to purely technical systems, since they include mining elements characterized by high variability of the determining parameters. To assess their reliability, it is necessary to use various combined methods that include additional characteristics in relation to the mining component. At the same time, the reliability of technical devices that ensure the functioning of mine ventilation and degassing systems largely determines the efficiency (stability and reliability) of these systems and, consequently, affects the level of aerological risks. The described approach to assessing the reliability of ventilation and degassing systems of coal mines when analyzing aerological risks is based on the developed system of risk indicators for the methane factor and will allow determining the risk dynamics in automatic mode based on monitoring the parameters of the ventilation and degassing system state.
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Date submitted2020-08-03
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Date accepted2020-12-13
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Date published2021-06-24
Tectonic and magmatic factors of Li-F granites localization of the East of Russia
- Authors:
- Viktor I. Alekseev
We have investigated tectonic and magmatic factors of Li-F granites localization of the East of Russia. The study is based on the ideas of Far Eastern geologists about the deep structures of intraplate activity. A model of a source structure with mantle heat sources and ore-forming magmatic complexes was used. We carried out a special metallogenic analysis of the East of Russia as applied to the rare metal-tin-bearing formation of subalkaline leucogranites, including Li-F ones. Source structures are the main factor in the tectonic and magmatic development of the East of Russia, localization of ore-forming granites and the formation of rare-metal-tin ore regions. On deep layers of source structures there are areas of the mantle and earth's crust decompaction, heat, magmas and fluids sources, as well as granitoid cryptobatholiths. Relatively large massifs of leucogranites, small intrusions of tin monzonitoids and Li-F granites are concentrated near the modern surface. The source structures correspond to the rank of the ore region. The source structures in the South of the region are: Badzhalskaya, Miao-Chanskaya, Ippato-Merekskaya, Hogdu-Lianchlinskaya, Arminskaya, etc.; in the North: Pevekskaya, Kuiviveem-Pyrkakayskaya, Kuekvun-Ekiatapskaya, Iultinskaya, Telekayskaya, Central Polousnaya, Omsukchanskaya, etc. Three types of ore regions have been identified according to the degree of source structures and Li-F granites erosion. We have also outlined the patterns of source structures evolution and their place in the geological history of ore-bearing granites. A classification of source structures and its comparison with the classifications of regional intrusives and metallogenic subdivisions are proposed. It has been established that, despite the diversity of tectonic, geological and petrological settings in the East of Russia, the intrusions of Li-F granites are regulated by the same tectonic and magmatic factors. The tectonic and magmatic factors of Li-F granites localization in the East of Russia are identified and classified as geophysical, orogenic, geoblock, magmatic, metasomatic and disjunctive.
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Date submitted2018-06-28
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Date accepted2018-09-15
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Date published2018-12-21
Causes of fluid entry absence when developing wells of small deposits (on the example of Khadum-Batalpashinsky horizon)
- Authors:
- R. A. Gasumov
A promising direction for the development of the oil and gas industry is the drilling of small hydrocarbon fields, which constitute two thirds of Russia's total hydrocarbon reserves. When choosing an effective method of development and assessing the potential of small fields in Eastern Ciscaucasia, which are characterized by complex mining and geological conditions with abnormally high reservoir pressures and temperatures, it is necessary to determine the optimal amount of oil production taking into account the flow of edge water under elastic water drive. The article discusses the reasons for the lack of inflows of reservoir fluids in wells during their development, which are due to complex unconventional fractured clay reservoirs in the lower Maykop deposit and the presence of loose rocks in the section of the reservoir. The results of studies of the influence of technological and geological factors on the poroperm properties of the Khadum-Batalpashinsky reservoir are described, zones of rock softening are revealed, the intervals with bottom water and their influence on the well development process are specified. It has been established that the state of the hydrodynamic system of the field depends on the introduction of the bottom and edge waters of the sedimentation basin of the East Stavropol Depression. Oil deposits in the Khadum and Batalpashinskaya suites initially work in an elastic and then in an elastic-water drive mode. The main reasons for the lack of inflows of formation fluids into wells are the low reservoir properties of clay fractured reservoir rocks; clogging of the fracture capacity of reservoir rocks at the drilling in as a result of penetration of drilling mud and its filtrate deep into the reservoir; inflow of formation water from an overlying aquifer with abnormally high formation pressure; the closure of cracks in the clay reservoir due to a sharp decrease in pressure caused by the lowering of the slotted filter into the well; secondary dissection of productive layers by perforation during repression on the formation in a liquid medium with the presence of a solid phase and high density.
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Date submitted2017-10-29
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Date accepted2017-12-31
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Date published2018-04-24
Risk assessment of accidents due to natural factors at the Pascuales – Cuenca multiple-use pipeline (Ecuador)
- Authors:
- Dzh. Zambrano
- S. V. Kovshov
- E. A. Lyubin
The natural aspects of the accident risk at the Pascuales – Cuenca multiple-use pipeline (Ecuador) are analysed in the paper. The Russian Methodological recommendations for the quantitative analysis of accident risks at hazardous production plants of oil trunk pipelines and oil product trunk pipelines issued in 2016 are used as a methodological framework due to relatively poorly defined evaluation mechanism for natural factors of accidents at oil trunk pipelines in the most widespread international accident risk assessment methodologies. The methodological recommendations were updated to meet the environmental conditions of oil pipelines of Latin America. It was found that the accidents due to natural factors make up approximately 15 % of cases at oil trunk pipelines in Ecuador. Natural geographical features of the areas surrounding the main Ecuadorian Pascuales–Cuenca oil trunk pipeline and its relatively short length allow defining three zones along the line in terms of the accident risk: lowland coastlines, high plateaus, and foothills. Calculations and analysis revealed that the maximum predicted specific frequency of accidents is characteristic of the lowland seaside area. The evidence showed that physical and chemical properties of soils and significant seismic activity are the root causes of failures.
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Date submitted2015-12-22
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Date accepted2016-02-13
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Date published2016-12-23
Risk of injuries among coal mine workers and its hysteresis
- Authors:
- Yu. Parkhanski
The paper gives an overview of employment in coal mining, levels of extraction and injuries among the coal mine operators in Poland over a span of time from 1954 through to 2010. The injury indicators, such as the incidence rate, severity and the generalized loss index, have been assessed for a period of coal mining sector restructuring from 1993 to 2010. Diverging trends have been revealed, resulting in a need to extend the time span of the analysis. Analysis of records from 1954 to 2010 has shown a multiple cyclicity of trends of change in the values used to derive coefficients. The definition of the Injury Risk has been justified, along with a new way for its representation and its interpretation as a new method with account of the previous studies. Based on this method the injuries at the coal mines of Poland during a period of their restructuring have been investigated with analyzed database expansion to include records from 1954 to 2010.As a result a new dependency, namely the injury risk hysteresis, has been identified.
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Date submitted2013-07-22
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Date accepted2013-09-28
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Date published2014-03-17
Influence of personal factors on neadekvatne of action of officials of mines
In article the method of definition of personal factors of inadequate actions which lead to traumatism cases at the mountain enterprise is opened. For definition of personal factors the data received at poll of experts are used.
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Date submitted2009-10-18
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Date accepted2009-12-09
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Date published2010-09-22
Influence of blocky-hierarchy structure of geological medium on the forming of natural and technogenic geodynamic fields in the North-West part of the Amur geoblock
- Authors:
- I. Yu. Rasskazov
- B. G. Saksin
On the example of the South-Argun uranium ore district of Zabaikalie consideration is given to the interaction of regional and local fields of stresses. The district includes a number of deposits prone to rock bursts. The performed analysis contains data on recent geodynamics of the explored part of the Amur geoblock as well as on geomechanical and geologo-structural materials of Tulukuev caldera and of Antey deposit. It is shown that with the use of the M.A. Sadovsky relationship the indices of local structural forms of a row are subjected to unified laws of deformation and fracturing. Conclusion was made that at the beginning of deposit exploitation the direction of action of stress field within rock mass conformed to regional one, and then it considerably changed under influence of large-scale mining operations.
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Date submitted2009-09-17
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Date accepted2009-11-20
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Date published2010-06-25
Functional and stylistic, national and temporal features of modern scientific english text building
- Authors:
- S. A. Sveshnikova
The paper presents the analysis of the influence of functional and stylistic, national and cultural and time-of-creation factors on the organization of modern scientific texts in English.
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Date submitted2008-11-23
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Date accepted2009-01-05
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Date published2009-12-11
The economic mechanism of project risk management in development of oil and gas resources
- Authors:
- E. A. Krainova
Management decisions efficiency in well construction projects depends on the control of the worked out planning taking into consideration expected risks, rapid reaction on plan vs fact deviations and adjustment to course of works. Economic assessment of well construction risks offers an opportunity to find adequate managerial decisions for prevention of possible design deviations and to submit respective recommendations for construction of new wells to be placed in operation.
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Date submitted2008-10-19
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Date accepted2008-12-21
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Date published2009-12-11
Modern problems in regional monitoring оf underground waters
- Authors:
- V. A. Kiryukhin
- L. P. Norova
The new situation with the carrying out of monitoring of underground waters on regional level was mainly caused by two reasons: 1) new regulations on the preservation of the environment were approved; the present water Regulations are being renewed; 2) studying of regime-forming factors of underground waters (geological, cosmic, climatic, biological, hydrological and technogenic) testify to the urgent necessity of introducing certain amendments into the system and maintainance of monitoring of underground waters.