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Date submitted2023-07-07
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Date accepted2023-12-27
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Date published2024-12-25
A new insight into recording the mineral composition of carbonate reservoirs at well killing: experimental studies
Well killing operation remains an important technological stage before well workover or servicing, during which filtrate penetrates the bottomhole area of the formation. The impact of process fluids and their filtrate on rock has a significant influence on permeability and porosity of carbonate reservoirs, which decrease due to fines migration. There are few known scientific studies of the interaction of killing fluid filtrate with carbonate rock and fines migration. In our experiments, an aqueous phase was used which is the basis for well killing in pure form, for the preparation of blocking agents and is used in reservoir pressure maintenance system. Core samples taken from the pay of the reservoir were used to simulate the well killing process with generation of reservoir thermobaric conditions. Killing fluid filtrate was kept for seven days, which characterizes the average workover time at flowing wells in the fields of the Perm Territory. Using micro-X-ray tomography and scanning electron microscope, images were obtained before and after the experiment, which allowed confirming a decrease in total number of voids due to fines migration and, as a consequence, a decreasing permeability of samples. Measurement of pH and fines concentration in the aqueous phase was performed before and after the experiment and pointed to mineral reactions occurring as a result of rock dissolution. The results of experiments made it possible to record a decrease in permeability of carbonate samples by an average of 50 % due to clogging of void space and migration of fines (clayey and non-clayey).
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Date submitted2023-02-10
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Date accepted2023-09-20
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Date published2024-04-25
Depth distribution of radiation defects in irradiated diamonds by confocal Raman spectroscopy
Five colored diamonds were investigated. According to the results of the study by FTIR, UV-Vis-NIR and Photoluminescence spectroscopy, they are natural type Ia diamonds. The depth distribution of the color intensity was carried out by measuring the intensity of the PL peak at 741 nm (GR1 center) upon excitation by a laser with a wavelength of 633 nm of Raman Confocal microscope. To minimise the perturbation due to geometrical effects, defect distribution profiles were normalised with respect to diamond Raman peak intensity (691 nm) point by point. For two diamonds, the intensity of the GR1 peak (741 nm) sharply decreased to a depth of 10 µm, and then became equal to the background level, which is typical for irradiation with alpha particles from natural sources like uranium. In other diamonds, the profiles vary slightly with depth, and the color intensity is close to uniform, which is for irradiation with accelerated electrons or neutrons. The source of radiation has not been determined. However, long duration radioactivity measurements of the diamonds suggested that neutrons were not used for colour centers production in the diamonds studied.
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Date submitted2023-04-29
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Date accepted2023-10-11
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Date published2023-10-27
Pink-violet diamonds from the Lomonosov mine: morphology, spectroscopy, nature of colour
The article presents the results of the first comprehensive study of mineralogical and spectroscopic (IR, PL, EPR) characteristics of diamonds from the Lomonosov mine (Arkhangelskaya pipe) with a unique pink, pink-violet colour. It is shown that all crystals belong to the IaA type, with a total nitrogen content in the range of 500-1500 ppm, with a low degree of aggregation. The colour is heterogeneous, concentrated in narrow twin layers. It is presumably caused by the previously described M2 centres. The colour shade is affected by the content of P1 paramagnetic centres (C-defect). A positive correlation is observed between the colour saturation and the intensity of W7 paramagnetic centres. A convergent model of the formation of pink diamonds is assumed, according to which the determining factors are the ratio and concentration of structural impurities in the diamond, its thermal history, and conditions of plastic deformation, and not the origin of the diamond and the petrochemical properties of its host rocks.
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Date submitted2021-10-14
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Date accepted2022-04-07
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Date published2022-04-29
The influence of the shape and size of dust fractions on their distribution and accumulation in mine workings when changing the structure of air flow
The results of the analysis of statistical data on accidents at Russian mines caused by explosions in the workings space have shown that explosions of methane-dust-air mixtures at underground coal mines are the most severe accidents in terms of consequences. A detailed analysis of literature sources showed that in the total number of explosions prevails total share of hybrid mixtures, i.e. with the simultaneous participation of gas (methane) and coal dust, as well as explosions with the possible or partial involvement of coal dust. The main causes contributing to the occurrence and development of dust-air mixture explosions, including irregular monitoring of by mine engineers and technicians of the schedule of dust explosion protective measures; unreliable assessment of the dust situation, etc., are given. The main problem in this case was the difficulty of determining the location and volume of dust deposition zones in not extinguished and difficult to access for instrumental control workings. Determination of the class-shape of coal dust particles is a necessary condition for constructing a model of the dust situation reflecting the aerosol distribution in the workings space. The morphological composition of coal mine dust fractions with dispersion less than 0.1 has been studied. Particle studies conducted using an LEICA DM 4000 optical microscope and IMAGE SCOPE M software made it possible to establish the different class-shapes of dust particles found in operating mines. It was found that the coal dust particles presented in the samples correspond to the parallelepiped shape to the greatest extent. The mathematical model based on the specialized ANSYS FLUENT complex, in which this class-form is incorporated, is used for predicting the distribution of explosive and combustible coal dust in the workings space. The use of the obtained model in production conditions will allow to determine the possible places of dust deposition and to develop measures to prevent the transition of coal dust from the aerogel state to the aerosol state and thereby prevent the formation of an explosive dust-air mixture.
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Date submitted2020-06-29
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Date accepted2021-05-21
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Date published2021-09-20
Transformation of grains of technological raw materials in the process of obtaining fine powders
Crushing and grinding of materials are the most common processes of sample preparation for subsequent analysis and industrial application. Recently, grinding has become one of the most popular methods for producing nano-sized powders. This study investigates certain features of grain transformation in the process of grinding ores with finely dispersed valuable components in order to liberate them, as well as specifics of grinding metallurgical raw materials, metals and their mixtures for using them as initial components in metallurgical and other technological processes. We identified and examined structural and morphological changes of various powders after ultrafine grinding using the methods of scanning electron microscopy and X-ray microanalysis. It was proved that in order to take into account sample preparation artifacts during analytic studies of solid samples and development of technological processes, fine grinding of heterogeneous materials, especially if they contain metals, requires monitoring of the ground product by methods of scanning electron microscopy and X-ray microanalysis.
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Date submitted2017-08-30
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Date accepted2017-11-23
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Date published2018-02-22
Basic provisions and problems of ELW technology for the manufacture of aluminum-magnesium alloys constructions
- Authors:
- E. I. Pryakhin
- N. I. Sharonov
Existing problems of electron beam welding of aluminum alloy constructions are considered. For research purposes, the aluminum-magnesium alloy of grade 1561 up to 60 mm thick was used. The thermal field in the heat influence zone is studied experimentally and analytically on the basis of the finite element method (the «Ansys» program). The effect of electron beam movement (scanning) influence on the quality of welded connections and the surface of the welded parts was studied. On the basis of metallographic studies and mechanical tests of welded metal, it is proved that high quality of welded joints is ensured when the beam moves along a curve of the «compressed brackets» shape. A special generator is designed to control the electron beam, which allows to implement a new type of scanning (compressed brackets). The fundamentals of welding technology for alloy 1561 up to 60 mm thick are outlined. Specific recommendations are given, and two new methods are proposed that will allow the successful use of the developed technology in factories in the production of new products and in the repair processes. Examples and analysis of thermal cycles obtained by calculation and experimental method are given. The patterns of heat distribution along the trajectory of the beam movement for different types of scanning are established. The main types of defects in the formation of the welded joints and those formed in the metal during crystallization are considered. Their interrelation with the parameters of the welding mode is shown.