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Date submitted2024-01-31
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Date accepted2024-06-03
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Date published2024-07-04
Rationale for a possibility of using humic preparations production waste for wastewater purification from metals (Cd2+, Zn2+, Mg2+, Cu2+) aimed at developing efficient measures on environmental rehabilitation
Results of studying optimal conditions and parameters for afterpurification of underspoil waters from metal ions using humic acids production waste are presented with a view to develop the efficient measures on environmental rehabilitation of ecosystems disturbed by the development of copper pyrite deposits. The influence of contact time and waste dosage on the purification process was analysed, changes in the pH of wastewater and its impact on the growth and development of plants were studied. The key factors were identified allowing to achieve the efficiency of the purification process – the optimal contact time in the range from 120 to 180 min and waste dosage of 10 g/l. The study showed that the use of waste resulted in a neutral pH value of 7.03 compared to the initial pH value of 5.95. It was ascertained that the use of iron-magnesium production waste in combination with waste from humic preparations production made it possible to achieve the MPC of commercial fishing importance (with the exception of magnesium). Wastewater after the afterpurification process with high magnesium concentrations did not have a stimulating effect on the growth and development of Lepidium sativum L. plants. From biotesting results it can also be stated that there is no negative impact on the growth and development of Lepidium sativum L. The results obtained indicate a potentiality of using afterpurified wastewater for watering plants in the process of initiating the environmental rehabilitation of the disturbed ecosystems.
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Date submitted2022-10-28
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Date accepted2023-03-02
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Date published2023-04-25
Assessment of the possibility of using iron-magnesium production waste for wastewater treatment from heavy metals (Cd2+, Zn2+, Co2+, Cu2+)
Relevant problems associated with treatment of industrial wastewater from heavy metal ions are considered. Due to industrial development, the amount of wastewater increases as well as the risks of heavy metals getting into surface and groundwater, accumulating in water bodies and becoming aggressive environmental pollutants, which affect the animal and human organisms. To assess the possibility of extracting metal ions (Cd 2+ , Zn 2+ , Co 2+ , Cu 2+ ) from industrial wastewater and their further treatment, studies were carried out on redistribution of heavy metals in the “wastewater – waste” system using iron-magnesium production waste. Samples of the investigated waste weighing 0.1; 0.2; 0.5; 1; 1.5; 2 g were taken for wastewater volume of 50 ml per each subsample. Contact time varied from 5 to 180 min, waste fraction was 1 mm. The interaction process showed that the waste efficiently removes metal ions (Cd 2+ , Zn 2+ , Co 2+ , Cu 2+ ) from industrial wastewater. The efficiency of removing a pollutant from the solution depends on the weight of the waste subsample, initial concentration of metal ions, and contact time.
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Date submitted2022-01-24
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Date accepted2022-04-26
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Date published2023-04-25
Forecast of radionuclide migration in groundwater of the zone affected by construction drainage at the Leningrad NPP-2
The distribution of natural (at the level of global background) and technogenic radionuclides in groundwater of the industrial zone in Sosnovy Bor town, where several nuclear power facilities are operating, was analyzed. The main technogenic radionuclides recorded in groundwater samples are cesium ( 137 Cs), strontium ( 90 Sr), and tritium isotopes. The first two aquifers from the surface are subject to contamination: the Quaternary and the upper zone of the Lomonosov aquifer. Based on extensive material on the engineering and geological studies of the work area, a 3D geological model and hydrodynamic and geomigration models of the industrial zone were constructed. By means of modeling, the extent and nature of changes in hydrogeological conditions of area resulting from the construction and operational drainage of the new stage of the Leningrad Nuclear Power Plant (LNPP-2) were determined. The “historical” halo of radioactive contamination of groundwater forming (1970-1990) at the site adjacent to the NPP, where the storage facility of low- and medium-level radioactive waste is located, falls into the zone of influence. Interpretation of monitoring data allowed obtaining the migration parameters for predictive estimates. Modeling has shown that during the time of the LNPP-2 operation there was no intake of contaminated water by the drainage system of the new power plant.
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Date submitted2019-07-09
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Date accepted2019-09-26
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Date published2020-04-24
Development of mathematical models to control the technological properties of cement slurries
Oil and gas producing enterprises are making increasingly high demands on well casing quality, including the actual process of injection and displacement of cement slurry, taking into account requirements for the annular cement level, eliminating possible hydraulic fracturing, with developing a hydraulic cementing program. It is necessary to prevent deep invasion of cement slurry filtrate into the formation to exclude bridging of productive layers. It is impossible to fulfill all these requirements at the same time without application of modifying additives; complex cement compositions are being developed and applied more often. Furthermore, need to adjust cement slurries recipes appears for almost every particular well. In order to select and justify cement slurries recipes and their prompt adjustment, taking into account requirements of well construction project, as well as geological and technical conditions for cementing casing strings, mathematical models of the main technological properties of cement slurries for cementing production casing strings in the Perm Region were developed. Analysis of the effect of polycarboxylic plasticizer (Pl) and a filtration reducer (fluid loss additive) based on hydroxyethyl cellulose (FR) on plastic viscosity (V), spreadability (S) and filtration (F) of cement slurries is conducted. Development of mathematical models is performed according to more than 90 measurements.
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Date submitted2018-11-09
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Date accepted2019-01-22
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Date published2019-04-23
Determining the stability of the borehole walls at drilling intervals of loosely coupled rocks considering zenith angle
- Authors:
- P. A. Blinov
During development of drilling projects, a whole array of data is needed considering the properties of rocks and the conditions of their bedding. Accounting for geomechanical processes occurring in the near-wellbore zone allows avoiding many complications associated with the violation of the wellbore walls stability at all stages of its construction and operation. Technological and technical factors such as vibration and rotation of the drilling string, formation of launders during the descent and ascent of the assembly, pressure pulsation during the start and stop of pumps, hydrostatic and hydrodynamic pressure of the drilling fluid, its composition and properties, have a great influence on the stress-strain state of the medium opened by the well. The washing fluid circulating in the well should provide backpressure to the reservoir, not interact with the rocks chemically, colmatage channels in porous and fractured rocks, preventing penetration of the mud into the medium, by creating an impermeable barrier at drilling clay seams that are prone to swelling, cracking, etc. The article discusses the method for determining the stability of the directed well walls, taking into account the penetration of drilling mud into the pores and fractures of rocks. The technique will allow adjusting the zenith angle of the well during the workout of an unstable interval at the design stage, or selecting a drilling fluid composition to ensure fail-safe drilling.
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Date submitted2018-07-18
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Date accepted2018-08-25
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Date published2018-12-21
Development of vibroacoustic module for fine filtration of drilling muds
- Authors:
- G. B. Fedorov
- O. L. Dudchenko
- D. S. Kurenkov
The issue of drilling mud multiple use is problematic. To reuse, the solution must be efficiently cleaned from solid particles according to the class of 0.04-0.07 mm. An analysis of existing technologies and equipment has shown that drilling mud regeneration schemes are rather difficult to operate and expensive. In world practice there has been a tendency to create universal equipment, which allows most complete cleaning cycle for a drilling mud in fine grades. The paper proposes an innovative vibroacoustic module for cleaning drilling muds from sludge. The creative element of the proposal is the impact of vibroacoustic oscillations on the drilling mud passing through the mesh element. At the same time, specific effects arise around the mesh, which increase the productivity and efficiency of the process. The design of the vibroacoustic apparatus and the principle of its operation are presented. An important element of the proposal is that the oscillation is created by pistons interconnected by rods and located on opposite sides of the mesh. This dipole system provides the excitation of variable pressures of different polarity before the mesh and after it. The results of industrial tests of the vibroacoustic module when servicing the BU-75-BrE drilling rig are presented. The dependence of the installation performance and efficiency on the amplitude of oscillations was found. The optimal dynamic range of exposure (from 5.5 to 6.5 mm) was determined. Analysis showed that in the composition of the cleaned drilling mud, the maximum particle size of the solid phase did not exceed 0.04 mm. The conducted industrial tests confirmed the possibility of using the vibroacoustic module for cleaning the washing fluid and developing a pit-free drilling technology on its basis.
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Date submitted2016-08-30
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Date accepted2016-10-30
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Date published2017-02-22
Gas-dynamic processes affecting coal mine radon hazard
- Authors:
- V. I. Efimov
- A. B. Zhabin
- G. V. Stas
The paper focuses on vertical migration of radon in surrounding rocks described by Fick's first law as well as by the continuity equation for diffusion flow, with allowance for sorption and radioactive decay processes. Taking into account special characteristics of vertical radon diffusion, the process can be considered stable. It is demonstrated that for productive areas it is feasible to consider one-dimensional convective diffusion, as diffusive transport of radon by the air of productive areas occurs at steady-state conditions. Normally the factor of radon emissions prevails if atmospheric pressure is constant. Amount of air, calculated using this factor, by 20-30 % exceeds the one needed to dilute carbon dioxide to maximum allowed concentration (MAC).
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Date submitted2010-07-18
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Date accepted2010-09-16
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Date published2011-03-21
Two genetic types of peristerites in iridescent plagioclases
- Authors:
- M. A. Ivanov
- A. P. Simakov
Physico-mathematical modeling has shown that color of iridescent depends on spacing of peristerite lattice. The more spacing lattice, the color of iridescent is higher. The phenomenon of iridescent in plagioclases has an interferential nature. We can select two genetic types of peristerites: peristerites of decomposition and segregation peristerites. Segregation peristerites are formed from postcrystallizational consolidation of peristerites of decomposition. The form of segregation pertisrerites is one of the reasons of polychromatic iridescent genesis in plagioclases.
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Date submitted2009-08-10
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Date accepted2009-10-15
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Date published2010-02-01
Spacing of lattice in labradorite and interference model of iridescent
- Authors:
- A. P. Simakov
Spacing of lattice for non-iridescent labradorite, blue-iridescent labradorite, green-iridescent labradorite and red-iridescent labradorite were determined with scanning probe electron microscope. Lattice spacing increases the dynamical trend for different kinds of labradorite, line non-iridescent labradorite (107,5 ± 10 nm), blue-iridescent labradorite (150 ± 10 nm), green-iridescent labradorite (196 ± 10 nm), red-iridescent (231 ± 10 nm). This trend let is state iridescent of these samples to be caused by interference of secondary order.