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Date submitted2024-04-25
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Date accepted2024-09-24
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Date published2024-11-12
Specific features of kinetics of thermal transformation of organic matter in Bazhenov and Domanik source rocks based on results of pyrolysis gas chromatography
Pyrolysis of organic matter with subsequent analysis of hydrocarbon composition of the resulting products allows obtaining multicomponent distribution spectra of the generation potential by the activation energies of reactions of kerogen transformation into hydrocarbons. Configuration of the spectra depends on the structure of kerogen and is individual for each type of organic matter. Studies of kerogen kinetics showed that the distribution of activation energies is unique for each oil source rocks. The kinetic model of thermal decomposition of kerogen of the same type, for example, marine planktonic (type II), can differ significantly in different sedimentary basins due to the multivariate relationship of chemical bonds and their reaction energy threshold. The developed method for calculating multicomponent kinetic spectra (four-component models are used) based on results of pyrolysis gas chromatography allows obtaining one of the most important elements of modelling the history of oil and gas generation in geological basins. Kinetic parameters of organic matter of oil and gas source rocks influence the onset time of generation and directly reflect differences in the composition and structure of different types of kerogens. The results of determining the kinetic parameters of two high-carbon source rocks occurring across the territory of three oil and gas basins are shown. Generation and updating of the data of kinetic models of certain oil and gas source rocks will increase the reliability of forecasting oil and gas potential using the basin modelling method.
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Date submitted2022-09-30
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Date accepted2023-04-03
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Date published2024-02-29
Optimization of the location of a multilateral well in a thin oil rim, complicated by the presence of an extensive gas cap
- Authors:
- Кirill О. Тomskii
- Mariya S. Ivanova
The specific share of the reserves of hard-to-recover hydrocarbon raw materials is steadily growing. The search for technologies to increase the hydrocarbon recovery factor is one of the most urgent tasks facing the oil and gas industry. One of the methods to expand the coverage of oil reserves and increase oil recovery is to use the technology of drilling multilateral wells with a fishbone trajectory. In the Russian Federation, the most branched well was drilled in the Republic of Sakha (Yakutia) at the Srednebotuobinskoye oil and gas condensate field. The main object of development is the Botuobinsky horizon (Bt reservoir). About 75 % of the geological reserves of the reservoir are concentrated in a thin oil rim with an average oil-saturated layer thickness of 10 m with an extensive gas cap. This circumstance is one of the main complicating factors in the development of the Srednebotuobinskoye oil and gas condensate field. For such complex wells, one of the most important design stages is to determine the optimal location of the fishbone well in an oil-saturated reservoir. The article shows the results of sector modeling in the conditions of the Srednebotuobinskoye field to determine the optimal location of multilateral wells using Tempest simulator.
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Date submitted2022-10-23
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Date accepted2023-02-13
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Date published2023-12-25
Sorption purification of acid storage facility water from iron and titanium on organic polymeric materials
Obtaining and production of metals from natural raw materials causes a large amount of liquid, solid, and gaseous wastes of various hazard classes that have a negative impact on the environment. In the production of titanium dioxide from ilmenite concentrate, hydrolytic sulphuric acid is formed, which includes various metal cations, their main part is iron (III) and titanium (IV) cations. Hydrolytic acid waste is sent to acid storage facilities, which have a high environmental load. The article describes the technology of ion exchange wastewater treatment of acid storage facility from iron (III) and titanium (IV) cations, which form compounds with sulphate ions and components of organic waste in acidic environments. These compounds are subjected to dispersion and dust loss during the evaporation of a water technogenic facility, especially in summer season. Sorption of complex iron (III) cations [FeSO4]+ and titanyl cations TiO2+ from sulphuric acid solutions on cation exchange resins KU-2-8, Puromet MTS9580, and Puromet MTS9560 was studied. Sorption isotherms were obtained both for individual [FeSO4]+ and TiO2+ cations and in the joint presence. The values of the equilibrium constants at a temperature of 298 K and the changes in the Gibbs energy are estimated. The capacitive characteristics of the sorbent were determined for individual cations and in the joint presence.
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Date submitted2021-03-11
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Date accepted2021-05-21
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Date published2021-09-20
The influence of solar energy on the development of the mining industry in the Republic of Cuba
Cuba is traditionally considered a country with an underdeveloped industry. The share of the mining and metallurgical industries in the gross industrial production of the republic is small – about 3 % of GDP. The development of deposits and the extraction of nickel ores is an important sector of the economy of the Republic of Cuba, since the largest reserves of nickel and cobalt on the North American continent are located on the territory of the country. The development of the country energy system can serve as a growth factor in this sector of the economy. Due to climatic features and impossibility of integrating new capacities into the energy system through the construction of hydroelectric power plants, solar energy is a promising direction. Determining the feasibility of using solar tracking systems to increase the generation of electricity from solar power plants is one of the main challenges faced by engineers and renewable energy specialists. Currently, there are no solar tracking systems in Cuba that can provide information to assess the effectiveness of this technology in the country. The lack of the necessary technologies, as well as the high cost of developing solar power plants with tracking systems, limit the widespread introduction of such complexes. Hence follows the task of creating an inexpensive experimental model that allows assessing the effectiveness of tracking systems in specific weather conditions of the Republic of Cuba. This model will allow in future to increase the efficiency of electrical complexes with solar power plants, which provide power supply to the objects of the mineral resource complex and other regions.
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Date submitted2020-01-27
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Date accepted2020-05-22
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Date published2020-10-08
Sorption of rare earth coordination compounds
Rare earth elements (REEs) are valuable and strategically important in many high-technology areas, such as laser technology, pharmacy and metallurgy. The main methods of REE recovery are precipitation, extraction and sorption, in particular ion exchange using various sorbents, which allow to perform selective recovery and removal of associated components, as well as to separate rare earth metals with similar chemical properties. The paper examines recovery of ytterbium in the form of coordination compounds with Trilon B on weakly basic anion exchange resin D-403 from nitrate solutions. In order to estimate thermodynamic sorption parameters of ytterbium anionic complexes, ion exchange process was carried out from model solutions under constant ionic strength specified by NaNO 3 , optimal liquid to solid ratio, pH level, temperatures 298 and 343 K by variable concentrations method. Description of thermodynamic equilibrium was made using mass action law formulated for ion exchange equation and mathematically converted to linear form. Values of equilibrium constants, Gibbs free energy, enthalpy and entropy of the sorption process have been calculated. Basing on calculated values of Gibbs energy, a sorption series of complex REE ions with Trilon B was obtained over anion exchange resin D-403 from nitrate solutions at temperature 298 K. Sorption characteristics of anion exchange resin have been estimated: total capacity, limiting sorption of complex ions, total dynamic capacity and breakthrough dynamic capacity.
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Date submitted2019-06-29
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Date accepted2019-08-25
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Date published2019-12-24
New technical solutions for ventilation in deep quarries
- Authors:
- S. G. Shakhrai
- G. S. Kurchin
- A. G. Sorokin
The paper discusses the issues of ventilating in deep quarries caused by the intensification of blasting operations at great depths, the increased distance of ore truck transportation to the daylight area, constant change in the geometrical parameters of the quarry, its microrelief and direction of mining, and increased isolation of the mined space from the environment. We provide a brief analysis of the current tools for forced airflow in deep quarries, which showed that the use of forced ventilation is often challenging since it leads to high energy consumption, high level of noise exceeding the permissible parameters, and high speeds of forced air flows may blow the dust off the quarry surfaces. The article presents methods and tools developed at the Siberian Federal University for intensifying the natural airflow in deep quarries by changing the air density at the entrance and exit points of the pit, as well as heating the shady areas using mirrors and solar energy, which do not interfere with mining and blasting operations.
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Date submitted2019-01-13
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Date accepted2019-03-04
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Date published2019-06-25
Thermodynamic model of ion-exchange process as exemplified by cerium sorption from multisalt solutions
A complex heterogeneous process of ion exchange can be defined with an isotherm-isobar equation of the chemical reaction, which describes differential affinity between the process and its effect – the law of mass action. Ion exchange includes processes accompanied by changes in the charge of ions and functional groups caused by the passing of ionic bond into covalent one. Hence isotherm equations of ion exchange for such processes must differ from conventional stoichiometric equations, but they can be obtained by classical study approaches to ion exchange equilibrium. The paper describes a new thermodynamic model, based on linearization of mass action law, modified for the ion exchange equation. The application of this model allows to define stoichiometry of ion exchange and the shape of ions adsorbed by the solid phase of ion-exchange resins, as well as to estimate equilibrium constant and Gibbs free energy of the process. Comparative analysis has been carried out for the thermodynamic model of cerium sorption in the form of anionic complex with Trilon B from a multisalt solution with ionic strength of 1 mol/kg (NaNO 3 ) under рН = 3 and temperature 298 K on a test sample of weak-base anion-exchange resin Cybber EV009. Experimental isotherm of the sorption has been obtained. Calculations of thermodynamic parameters have been performed using Langmuir, Freundlich, Dubinin – Radushkevich, Temkin and Flory – Huggins models, as well as thermodynamic model of linearized mass action law, proposed by the authors. Calculated values of the equilibrium constant and Gibbs energy – K = 9.0±0.5 and ΔrG 0 298 = –5.54±0.27 kJ/mol – characterize the sorption of EDTA cerate ions by ion-exchange resin. The shape of adsorbed ions has been defined in Stern-Helmholtz layer of CeTr, and total capacity of anion resin EV009 for EDTA cerate ions has been estimated as q ∞ = 2.0±0.1 mol/kg.
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Date submitted2018-08-29
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Date accepted2018-10-25
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Date published2019-02-22
The study of the effect of temperature on the ability of metals to accumulate energy during their plastic deformation
The subject of research is the surface layer of highly loaded parts, friction units of mining machines and equipment. The article presents a theoretical analysis of the factors that determine the ability of the material of the surface layer of parts to accumulate energy in the process of plastic deformation. It is suggested that the activation character of the accumulation of energy by metals. Based on the theory of diffusion, it was shown that the mobility of atoms, as well as the accumulated energy, are determined by the ratio of the test temperature to the melting temperature.
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Date submitted2016-11-01
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Date accepted2017-01-20
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Date published2017-04-14
Technology and economics of near-surface geothermal resources exploitation
- Authors:
- E. I. Boguslavskii
- V. V. Fitsak
The paper presents economic justification for applicability of near-surface geothermal installations in Luga region, based on results of techno-economic calculations as well as integrated technical and economic comparison of different prediction scenarios of heat supply, both conventional and using geothermal heat pumps (GHP). Construction costs of a near-surface geothermal system can exceed the costs of central heating by 50-100 %. However, operation and maintenance (O&M) costs of heat production for geothermal systems are 50-70 % lower than for conventional sources of heating. Currently this technology is very important, it is applied in various countries (USA, Germany, Japan, China etc.), and depending on the region both near-surface and deep boreholes are being used. World practice of near-surface geothermal systems application is reviewed in the paper.
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Date submitted2010-07-23
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Date accepted2010-09-28
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Date published2011-03-21
Sistaining mining in whole different rigidity
- Authors:
- L. K. Gorshkov
- S. G. Kokoev
Studies conducted in the mines «Rostovugol», showed that, for assessing the sustainability of preparatory excavations in the management of sewage treatment works is enough to determine the allowable values of convergence of the roof and ground-level workings and potential energy of elastic deformation of the pillars. These indicators can be used in the coal mines of other basins.
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Date submitted2009-09-24
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Date accepted2009-11-05
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Date published2010-06-25
Anthropological crisis: problems and decisions (ontology of hesychasm and humanism prospects)
- Authors:
- A. I. Voronov
The European humanism can have new page of the history, by means of assimilation of philosophical ideas Greek hesychasm. The given concept opens the person not as motionless human «I» based on Aristotel”s idea of substantiality, but as a being (in style of Heraclites philosophy), with eternally mobile energy, forming the human person.
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Date submitted2009-08-01
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Date accepted2009-10-23
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Date published2010-02-01
Influence of detonation parameters of explosives on energy efficiency of explosive destruction of rocks
- Authors:
- M. G. Menzhulin
- P. I. Afanasev
- A. V. Trofimov
About 30 % of the mountain weight extracted on rubble the enterprises, at explode and the subsequent mechanical crushing, the fraction less makes than5 mm(elimination) which practically does not find selling and litters an environment. The output of elimination is influenced essentially with detonation characteristics explosives.
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Date submitted2009-08-25
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Date accepted2009-10-23
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Date published2010-02-01
Mathematical model of impact energy pulse changes in «rock drill – rod – rock» system of rotary-percussion drill rigs
- Authors:
- S. A. Resheten
This article describes the process of passing the impact energy through the connection of drilling composition. Based on the concept of impact energy transfer, created a mathematical model of impact energy pulse changes in the «rock drill-rod-rock» system of rotary-percussion drill rigs.
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Date submitted2009-07-12
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Date accepted2009-09-30
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Date published2010-04-22
Development of geothermal resources – higher efficiency in utilization of the earth’s interior
- Authors:
- E. I. Boguslavsky
Preservation of Russia as the great state, its further development and prosperity, appreciably depends on possibilities to provide its own power needs, and also fuel and electric power export. On this historical period, power resources are the basic trading source of replenishment of the state budget. However, oil resources, at preservation of volumes of its export, are quickly exhausted; natural gas is not boundless too. Coal stocks have essentially decreased with disintegration of the USSR, and the remained demand considerable investments, increase of current expenses and are characterised by decrease in quality of coals. Additional expenses on ecological protection of environment will increase. Search of alternative to the organic fuel, burnt in heating plants, is conducted more than ten years. Use of low-temperature sources of thermal energy of resources is one of general directions in the decision of this problem in the XXI-st century. It proves to be true: certain advantages of geothermal resources, a readiness of scientific bases of their development, world industrial experience and specificity of systems of a heat supply in the country.