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Date submitted2024-03-11
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Date accepted2024-09-24
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Date published2024-12-06
Comparative analysis of nitrogen and carbon isotopic fractionation during diamond formation based on β-factor determination
- Authors:
- Dmitrii P. Krylov
First quantitative estimates are presented for nitrogen isotopic fractionation during diamond crystallization with respect to nitrogen-bearing fluid components using quantum-mechanical (DFT) calculations on the defect (with the substitutional nitrogen) diamond lattice. Provided equilibrium isotopic fractionation, 15N/14N ratio decreases within the sequence of compounds NH4+ > N2 > (diamond, NH3) > CH3N > CN− > NH2. At temperatures of 1,100 to 1,200 °C fractionation among diamond and fluid N-compounds are estimated at –2.23, –0.77, 0.01, 0.44, 1.31 and 2.85 ‰ and substantially (over 1 ‰) exceed the already available estimates based on the modeling diamond C-N bonds by analogy with HCN or CN – molecules. Depending on the dominant nitrogen and carbon substance in the mineral-forming fluid, diamond formation can be accompanied by different isotope compositional trends, as expressed either by zoned patterns within individual diamond grains or by isotopic δ15N vs δ13C covariations during successive crystallization. Provided the dominance of NH3 component (the reduced conditions, high pressures and the cold geotherm) nitrogen isotope fractionation between diamond and fluid does not exceed 0.1-0.2 ‰ and the isotope shifts at temperature ca. 1100 °C Δ15N << Δ13C. In nitrogen depleted reduced mantle fluids possible existence of compounds with low heavy isotope affinity at temperature of diamond formation (especially NH2) implies high isotope fractionation between diamond and the fluid and hence, evolved Δ15N/Δ13C ratios. Oxidized fluids dominated by CO2 or CO3 coupled with N2 component are characterized by close to zero Δ15N/Δ13C ratios as inferred by prevailing carbon isotope fractionation with respect to nitrogen isotopes, the latter change considerably with nitrogen distribution coefficient among diamond and the growth media.
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Date submitted2023-07-07
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Date accepted2023-12-27
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Date published2024-08-26
Landslide hazard assessment in Tinh Tuc town, Cao Bang province, Vietnam using Frequency ratio method and the combined Fractal-frequency ratio method
Landslides are one of the most frequent natural disasters that cause significant damage to property in Vietnam, which is characterized by mountainous terrain covering three-quarters of the territory. In 17 northern mountainous provinces of the country, over 500 communes are at a high to very high landslide hazard. The main goal of this study was to establish landslide hazard maps and conduct a comparative evaluation of the efficiency of the methods employed in Tinh Tuc town, Cao Bang province. The landslide hazard assessment was carried out in this study using the combined Fractal-frequency ratio (FFR) and the Frequency ratio (FR) methods. The FR method is based on the actualist principle, which assumes that future landslides may be caused by the same factors that contributed to slope failure in the past and present. The FFR method is based on the determination of the fractal dimension, which serves as a measure of the landslide filling density in the study area. Eight landslide-related factors were considered and presented in cartographic format: elevation, distance to roads, slope, geology, distance to faults, land use, slope aspect, and distance to drainage. Determining the area under the receiver operating characteristic curve (ROC-AUC) and verification index (LRclass) was performed to assess the performance of prediction models and the accuracy of the obtained maps. As a result, five zones were identified for the study area, characterized by very low, low, moderate, high, and very high landslide hazards. The analysis of the reliability of the obtained landslide hazard maps using the AUC and LRclass indices revealed that the FFR model has a higher degree of reliability (AUC = 86 %, LRclass = 86 %) compared to the FR model (AUC = 72 %, LRclass = 73 %); therefore, its use is more effective.
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Date submitted2022-04-03
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Date accepted2023-03-02
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Date published2023-12-25
Specifics of geotechnical risk control in the design of underground structures
The underground space development is associated with the emergence of complex and dangerous situations, often leading to accidents. The condition for their development is the potential geotechnical risks. High-quality execution and analysis of design work at all the stages of design, starting from the early stages, is one of the effective ways to control risks. Clarification of the characteristics and features of the rock mass adjacent to the projected underground structure makes it possible to identify the potential cause of the occurrence of an adverse event with a certain probability during the construction and operation of an underground structure. The purpose of a qualitative risk analysis is to identify risk factors in underground construction. The value of the total geotechnical risk, expressed by the sum of each of the possible risks, should be numerically estimated at the design stage of a specific underground facility. At the same time, it is extremely important to develop a methodology for managing geotechnical risks, which would make it possible to assess their probability of development at an early stage of project preparation and propose measures to reduce or prevent them. This technique is given in the article. The results of the study conducted in accordance with the presented methodology showed that geotechnical risk control proved an effective method in preventing accidents during underground construction.
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Date submitted2021-07-19
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Date accepted2022-05-31
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Date published2022-07-13
Study of a set of factors influencing the error of surveying mine facilities using a geodesic quadcopter
The factors influencing the qualitative and quantitative components of the result of surveying in open-pit mining using a quadcopter were identified and systematized, and the mathematical dependence of the influence of factors on the final error of surveying was determined. After a large number of field observations – numerous flights of a geodesic quadcopter over mining facilities – the subsequent mathematical justification of the results of the aerial photogrammetric surveying was made, which allowed to analyze the degree of participation in the final accuracy of the survey of each of the considered factors. The results of this study demonstrate the source of errors, which provide the surveyor with the opportunity to efficiently and competently carry out pre-flight preparation and planning of fieldwork. The study and subsequent consideration of the factors affecting the accuracy of surveying with the use of an unmanned aerial vehicle are the basis for the subsequent development and formation of a methodology for using a geodesic quadcopter in the conditions of open-pit mining.
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Date submitted2020-08-03
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Date accepted2020-12-13
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Date published2021-06-24
Tectonic and magmatic factors of Li-F granites localization of the East of Russia
- Authors:
- Viktor I. Alekseev
We have investigated tectonic and magmatic factors of Li-F granites localization of the East of Russia. The study is based on the ideas of Far Eastern geologists about the deep structures of intraplate activity. A model of a source structure with mantle heat sources and ore-forming magmatic complexes was used. We carried out a special metallogenic analysis of the East of Russia as applied to the rare metal-tin-bearing formation of subalkaline leucogranites, including Li-F ones. Source structures are the main factor in the tectonic and magmatic development of the East of Russia, localization of ore-forming granites and the formation of rare-metal-tin ore regions. On deep layers of source structures there are areas of the mantle and earth's crust decompaction, heat, magmas and fluids sources, as well as granitoid cryptobatholiths. Relatively large massifs of leucogranites, small intrusions of tin monzonitoids and Li-F granites are concentrated near the modern surface. The source structures correspond to the rank of the ore region. The source structures in the South of the region are: Badzhalskaya, Miao-Chanskaya, Ippato-Merekskaya, Hogdu-Lianchlinskaya, Arminskaya, etc.; in the North: Pevekskaya, Kuiviveem-Pyrkakayskaya, Kuekvun-Ekiatapskaya, Iultinskaya, Telekayskaya, Central Polousnaya, Omsukchanskaya, etc. Three types of ore regions have been identified according to the degree of source structures and Li-F granites erosion. We have also outlined the patterns of source structures evolution and their place in the geological history of ore-bearing granites. A classification of source structures and its comparison with the classifications of regional intrusives and metallogenic subdivisions are proposed. It has been established that, despite the diversity of tectonic, geological and petrological settings in the East of Russia, the intrusions of Li-F granites are regulated by the same tectonic and magmatic factors. The tectonic and magmatic factors of Li-F granites localization in the East of Russia are identified and classified as geophysical, orogenic, geoblock, magmatic, metasomatic and disjunctive.
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Date submitted2018-06-28
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Date accepted2018-09-15
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Date published2018-12-21
Causes of fluid entry absence when developing wells of small deposits (on the example of Khadum-Batalpashinsky horizon)
- Authors:
- R. A. Gasumov
A promising direction for the development of the oil and gas industry is the drilling of small hydrocarbon fields, which constitute two thirds of Russia's total hydrocarbon reserves. When choosing an effective method of development and assessing the potential of small fields in Eastern Ciscaucasia, which are characterized by complex mining and geological conditions with abnormally high reservoir pressures and temperatures, it is necessary to determine the optimal amount of oil production taking into account the flow of edge water under elastic water drive. The article discusses the reasons for the lack of inflows of reservoir fluids in wells during their development, which are due to complex unconventional fractured clay reservoirs in the lower Maykop deposit and the presence of loose rocks in the section of the reservoir. The results of studies of the influence of technological and geological factors on the poroperm properties of the Khadum-Batalpashinsky reservoir are described, zones of rock softening are revealed, the intervals with bottom water and their influence on the well development process are specified. It has been established that the state of the hydrodynamic system of the field depends on the introduction of the bottom and edge waters of the sedimentation basin of the East Stavropol Depression. Oil deposits in the Khadum and Batalpashinskaya suites initially work in an elastic and then in an elastic-water drive mode. The main reasons for the lack of inflows of formation fluids into wells are the low reservoir properties of clay fractured reservoir rocks; clogging of the fracture capacity of reservoir rocks at the drilling in as a result of penetration of drilling mud and its filtrate deep into the reservoir; inflow of formation water from an overlying aquifer with abnormally high formation pressure; the closure of cracks in the clay reservoir due to a sharp decrease in pressure caused by the lowering of the slotted filter into the well; secondary dissection of productive layers by perforation during repression on the formation in a liquid medium with the presence of a solid phase and high density.
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Date submitted2009-09-17
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Date accepted2009-11-20
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Date published2010-06-25
Functional and stylistic, national and temporal features of modern scientific english text building
- Authors:
- S. A. Sveshnikova
The paper presents the analysis of the influence of functional and stylistic, national and cultural and time-of-creation factors on the organization of modern scientific texts in English.
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Date submitted2008-10-19
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Date accepted2008-12-21
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Date published2009-12-11
Modern problems in regional monitoring оf underground waters
- Authors:
- V. A. Kiryukhin
- L. P. Norova
The new situation with the carrying out of monitoring of underground waters on regional level was mainly caused by two reasons: 1) new regulations on the preservation of the environment were approved; the present water Regulations are being renewed; 2) studying of regime-forming factors of underground waters (geological, cosmic, climatic, biological, hydrological and technogenic) testify to the urgent necessity of introducing certain amendments into the system and maintainance of monitoring of underground waters.