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Date submitted2024-03-22
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Date accepted2024-09-24
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Date published2025-02-25
Behaviour of cerium (III) phosphate in a carbonate-alkaline medium
- Authors:
- Tatyana E. Litvinova
- Stepan A. Gerasev
The article investigates the behaviour of rare earth metals in carbonate-alkaline systems. The results of experimental studies on rare earth element extraction from phosphogypsum, a large-tonnage industrial waste forming in production of phosphoric acid are presented. Using the liquid phase leaching method, it was possible to extract more than 53 % of rare earth elements from old phosphogypsum and more than 69 % from fresh phosphogypsum due to solid phase treatment with a 4 mol/l potassium carbonate solution at temperature 90 °C. The behaviour of model cerium (III) phosphate in a carbonate-alkaline medium is characterized: a solubility isotherm is obtained as well as the dependences of the degree of cerium extraction into solution on temperature, carbonate ion concentration, interphase ratio, stirring intensity, and pH. The ability of soluble rare earth element complexes to precipitate over time was established, which was confirmed using cerium and neodymium as an example. Within 240 h after the end of the experiment, approximately 25 % of cerium and 17 % of neodymium were precipitated from the liquid phase. A similar property was recorded in representatives of the light group and was not noted in elements of the heavy group. The ability to self-precipitate in future can serve as a basis for developing an alternative approach to separating rare earth metals into groups after extraction in a carbonate ion medium. Also, based on the analysis of experimental data, the mechanism of cerium (III) phosphate dissolution in a carbonate-alkaline medium was characterized. An assumption was made that rare earth metal phosphates dissolve sequentially passing into an insoluble carbonate and then into a soluble carbonate complex.
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Date submitted2022-06-20
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Date accepted2022-09-06
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Date published2022-11-03
Adaptive approach formation using machine vision technology to determine the parameters of enrichment products deposition
In this paper, an adaptive approach has been developed for automatic initialization of the thickening curve using machine vision technology, which makes it possible to determine with high accuracy the material parameters necessary for the design of thickening and clarification apparatuses. Software has been developed that made it possible to search for the coordinates of the condensation critical point in automatic mode. Studies on two samples of materials (tailings of apatite-containing ores and gold-bearing concentrate) were carried out and made it possible to statistically prove the reproducibility of the results obtained using the parametric criteria of Fisher and Bartlett. It has been established that the deposition curves are approximated with high accuracy by the Weibull model, which, together with the piecewise linear approximation, makes it possible to formalize the method for determining the critical point coordinates. The empirical coefficients of the Weibull model for two samples are found, and the final liquefaction and settling rates of the studied materials are determined.
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Date submitted2020-06-10
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Date accepted2020-11-19
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Date published2021-04-26
Influence of jarosite precipitation on iron balance in heap bioleaching at Monywa copper mine
Ferric iron is an important oxidant in sulfide ore bioleaching. However, recirculating leach liquors leads to excess iron accumulation, which interferes with leaching kinetics and downstream metal recovery. We developed a method for controlling iron precipitation as jarosite to reduce excess iron in heap bioleaching at Monywa copper mine. Jarosite precipitation was first simulated and then confirmed using batch column tests. From the simulations, the minimum pH values for precipitation of potassium jarosite, hydronium jarosite, and natrojarosite at 25 °C are 1.4, 1.6, and 2.7, respectively; the minimum concentrations of potassium, sulfate, ferric, and sodium ions are 1 mM, 0.54, 1.1, and 3.2 M, respectively, at 25 °C and pH 1.23. Column tests indicate that potassium jarosite precipitation is preferential over natrojarosite. Moreover, decreased acidity (from 12 to 8 g/L), increased temperature (from 30 to 60 °C), and increased potassium ion concentration (from 0 to 5 g/L) increase jarosite precipitation efficiency by 10, 5, and 6 times, respectively. Jarosite precipitation is optimized by increasing the irrigating solution pH to 1.6. This approach is expected to reduce the operating cost of heap bioleaching by minimizing the chemicals needed for neutralization, avoiding the need for tailing pond construction, and increasing copper recovery.
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Date submitted2014-07-08
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Date accepted2014-09-08
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Date published2014-12-22
The development of methods for increasing the efficiency factor of gravitation extraction for fine and ultrafine gold from different genesis placers
- Authors:
- T. N. Aleksandrova
- V. B. Kuskov
The basis for and results of experimental studies for increasing the efficiency factor of gravitation extraction for fine and ultrafine gold from geogenic and man-made mineral formations with high clay content as well as alluvial placers are presented. The clayey gold-bearing placers of the Khabarovsk region in Russia’s Far East were used as the subject of research. These placers contain a substantial amount of fine particle gold and muddy material with hard washability, which are the main reasons for gold losses. One more object of research is a placer located in the Krasnoyarsk region, east Siberia. A special method of interpretation has been created for particle size distribution, using newly developed software which can increase the accu-racy of sedimentation analysis and predict the morphology of gold. It has been proved that one of the most promising ways in which to intensify the gravity processes can be effective preparation, including the chemical dispersion of gold dust before gravitational processing. Exploring the joint effect of sodium hexapolyphosphate and halogen oxidant on the efficiency of processing revealed that the combination of the peptization-coagulation cycles improves gold recovery. Also, the possibility of using concentration tables with various designs for production of rough concentrate is shown. The use of a new round disk concentrated table design enables metallurgi-cal results to be improved in comparison with shaking tables.