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Date submitted2024-04-10
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Date accepted2024-06-03
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Date published2025-04-25
Combined method for processing spent acid etching solution obtained during manufacturing of titanium products
Possessing high strength, low density and significant chemical resistance, titanium has found wide application in various fields of the national economy – the chemical industry, aviation and rocket technology, mechanical engineering, medicine, etc. The production of titanium products is hampered by a fairly strong oxide film covering its surface. Removal of the oxide film from the surface of titanium workpieces is carried out by etching in solutions of mineral acids of various compositions. A spent acid etching solution (SAES) is formed, containing titanium salt and the remainder of unreacted acids. Almost all etching solutions contain HF and one of the strong acids. This is H2SO4, HCl or HNO3. Thus, the SAES includes ions of titanium, fluorine or chlorine, orsulfate, or nitrate. SAES is quite toxic and must be diluted or cleaned several times before being discharged into a reservoir. Most of the methods used to extract impurities contained in SAES lead to a decrease in their content. As a result of such purification, there is a loss of substances contained in SAES in significant quantities and of interest for further use. The work presents experimental results obtained from the combined processing of SAES containing titanium fluoride, hydrofluoric and hydrochloric acids. At the first stage, SAES is treated with sodium hydroxide. The resulting titanium hydroxide precipitate is filtered off. At the second stage, the filtrate containing sodium fluoride and chloride is processed in a membrane electrolyzer. In this case, not only the extraction of sodium salts from the filtrate occurs, but also the production of sodium hydroxide and a mixture of hydrofluoric and hydrochloric acids. Sodium hydroxide can be used for processing SAES, and a mixture of acids for etching titanium workpieces.
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Date submitted2022-10-30
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Date accepted2023-09-20
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Date published2024-02-29
Combined method of phytoremediation and electrical treatment for cleaning contaminated areas of the oil complex
The scale of land pollution with oil waste necessitates the use of economical and effective methods of recultivation. Phytoremediation is one of the simplest methods, but it has a number of limitations, so additional preparation of the territory is often required before it is carried out. Preliminary electrical preparation and subsequent seeding of special phytoremediants are of interest. Passing a constant electric current through the soil volume under a low voltage removes toxicants from deep soil layers even with flooding. In addition, it reduces pollutant content in the upper layer, where the plants root system is located, which creates more favorable conditions for phytoremediants. Adequately selected types of plants will ensure additional soil cleaning, improve its structure and air exchange. The results of two research directions are presented. Experiments on the study of plant resistance to oil-contaminated soil substrate allowed establishing contamination thresholds at which it is advisable to sow a particular species, and to choose optimal phytoremediants. The study of the oil-containing soil cleaning in a monocathodocentric electrochemical installation with the fixation of main characteristics (oil products concentration, soil temperature, volt-ampere characteristics) allows us to develop technical measures to prepare territories for phytoremediation taking into account the relief features.
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Date submitted2022-07-10
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Date accepted2023-06-20
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Date published2024-02-29
Mathematical modeling of the electric field of an in-line diagnostic probe of a cathode-polarized pipeline
A mathematical model of the in-line control of the insulation resistance state for cathodically polarized main pipelines according to electrometry data is considered. The relevance of the work is caused by the opportunity to create in-line internal isolation defects indicators of the main pipelines for transported liquids that are good conductors and expand the functionality of monitoring and controlling cathodic protection systems of the main pipelines. Features of the mathematical model are: consideration of the electric conductivity of transported liquid influence on electric field distribution; consideration of the influence of external and internal insulating coating resistance; use of the electric field of an in-line diagnostic probe for quality control of internal insulation. Practical significance consists in the development of modeling methods for control subsystems of main pipeline protection against corrosion and the development of special mathematical and algorithmic support systems for monitoring and controlling the operating modes of the cathodic protection station of main pipelines.
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Date submitted2022-03-25
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Date accepted2022-09-06
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Date published2022-12-29
Autoclave modeling of corrosion processes occurring in a gas pipeline during transportation of an unprepared multiphase medium containing CO2
The problem of selecting a method for ensuring the reliability of the unprepared fluid transport facilities of an unprepared fluid in the presence of carbon dioxide is considered. Carbon dioxide corrosion is one of the dangerous types of damage to field and main pipelines. It has been shown that dynamic autoclave tests should be carried out during staged laboratory tests in order to determine the intensity of carbon dioxide corrosion and to select the optimal method of protection. A hypothesis about the imperfection of the existing generally accepted approaches to dynamic corrosion testing has been put forward and confirmed. A test procedure based on the use of an autoclave with an overhead stirrer, developed using elements of mathematical modeling, is proposed. The flows created in the autoclave provide corrosive wear of the sample surface similar to the internal surfaces elements wear of the pipelines piping of gas condensate wells. The autoclave makes it possible to simulate the effect of the organic phase on the flow rate and the nature of corrosion damage to the metal surface, as well as the effect of the stirrer rotation speed and, accordingly, the shear stress of the cross section on the corrosion rate in the presence/absence of a corrosion inhibitor. The given results of staged tests make it possible to judge the high efficiency of the developed test procedure.
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Date submitted2021-02-20
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Date accepted2021-10-18
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Date published2021-12-16
Thermal protection implementation of the contact overheadline based on bay controllers of electric transport traction substations in the mining industry
The article presents the principle of thermal protection of the contact overheadlineand substantiates the possibility of practical implementation of this principle for rail electric transport in the mining industry. The algorithm for the implementation of modern digital protection of the contact overhead line as one of the functions of the controller is described. A mathematical model of thermal protection is proposed, which follows from the solution of the heat balance equation. The model takes into account the coefficient of the electrical networktopology, as well as the coefficient of consumption of the current-carrying core of the cable, which determines the reduction in the conducting section from contact erosion and the growth of oxide films. Corrections for air flows are introduced when receiving data from an external anemometer, via telemechanics protocol. The mathematical model was tested by writing a real thermal protection program in the C programming language for the bay controller, based on the circuitry of which is the STM32F407IGT6 microcontroller for the microcontroller unit. Verification tests were carried out on a serial bay controller in 2020. The graphs for comparing the calculated and actual values of temperatures, with different flow rates of the current-carrying conductor of the DC cable, are given. To obtain data, telemechanics protocols IEC 60870-104 and Modbus TCP, PLC Segnetics SMH4 were used.
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Date submitted2020-10-05
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Date accepted2021-03-30
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Date published2021-06-24
Improving the efficiency of relay protection at a mining and processing plant
The paper presents the results of constructing effective relay protection in the power supply system of a mining and processing plant (MPP). A brief description of the MPP is given, the power supply and substitution circuits used to calculate the short-circuit currents are given. A statistical analysis of failures in the electric network of the MPP has been carried out, which makes it possible to draw conclusions about the nature of failures ranges. Analysis of the registered faults shows that a significant part of them are line-to-earth faults, which in most cases turn into multiphase short circuits, which are interrupted by overcurrent protection. In order to improve the efficiency and reliability of the relay protection, the power supply scheme of the MPP was refined and analyzed. The calculation of the short-circuit currents was made, which made it possible to calculate the settings of the relay protection and give recommendations on the place of its installation and adjustment in order to ensure the normal operation of electricity consumers. To reduce the number of failures to the cable insert on the line leaving the administrative and household complex (AHC), and to increase the reliability of power supply to consumers, it is advisable to divide the capacities of the existing 10 kV line into two parallel ones by laying a second line. It is recommended to install a current cut-off on the line outgoing to the AHC, the feasibility of the installation of which was shown by calculations. This will reduce the chance of failures to the cable gland. Data on the setting currents of overcurrent protection and current cut-off are given on the selectivity card.
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Date submitted2015-07-30
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Date accepted2015-09-11
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Date published2016-02-24
Principles of corporate communications management system development for mineral resources companies
- Authors:
- A. B. Makhovikov
The article shows the benefits of using unified communications for the management of mineral resources companies and discusses some principles of a modern corporate communications system providing the guaranteed encryption of all transmitted information (voice, text and files). The system structure, its operations and technologies, necessary for the creation of such a system, are substantiated. The secure corporate communication system developed at the National Mineral Resources University (Mining University) is described, and its comparison with other domestic and foreign systems is provided.
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Date submitted2015-07-07
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Date accepted2015-09-16
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Date published2016-02-24
Activation of heap leaching of low-sulfide ores the invisible gold
- Authors:
- A. G. Sekisov
- Yu. I. Rubtsov
- A. Yu. Lavrov
This article deals with a physical-chemical model of heap leaching processes justifying new technological approaches to recovering dispersed forms of gold from ores, placer sands and deute-rogene mineral raw materials. The key process of this model includes lattice diffusion of high-energy hydrion minerals and hydroxyl-radicals formed as a result of photochemical and electro-chemical processing of initial reagent aqueous solutions. Active components of gas-water emulsions obtained while processing initial reagent solutions provide a structural and material trans-formation of a mineral lattice which concentrates clusters of dispersed gold creating conditions for its interacting with complexing compounds of process solutions. The article also considers the technological processes of activation heap leaching of dispersed gold from the Pogromnoe ore field and the results of the experiments conducted in percolators with their charge ranged from 3 to 100 kg. The results have proved the efficiency of using gas-water suspensions prepared in the pho-toelectrochemical reactor with active ion-radical oxidizing agents.
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Date submitted2014-11-28
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Date accepted2015-01-13
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Date published2015-10-26
Nanobar code as multi-purpose two-dimensional notation with new features
- Authors:
- E. I. Pryakhin
The article gives an analysis of the current standard two-dimensional codes, showing their features and applications. It was concluded that the feasibility of developing a new type of two-dimensional codes, the Nanobar code (NBC), in which information can be open (available) and, if necessary, closed (unavailable) to the user through the use of cryptographic encryption techniques. At the same time the new codes provide a significant increase in the volume of coded information that allows us to recommend using them as a local database, in particular for the issue of electronic technological certificates and product passports, personal dog tags for the military, athletes and others. It is noted as an important characteristic that the Nanobar code is able to encode different types of digital information. Due to its characteristics, the NBC is proposed to use as an identification number and protect legal products against counterfeiting. Two variants of the NBC technology application are proposed – with laser printing and printer. For reading information from the NBC, special software was developed, including mobile applications that allow using a smartphone to read the NBC. The basic scope of the NBC application was suggested.
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Date submitted2013-07-05
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Date accepted2013-09-23
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Date published2014-03-17
Increase of stability of mine workings in the permafrost zone
- Authors:
- A. F. Galkin
Some experimental results of increase of stability of mine workings are presented in this article. The investigated mine workings are located in the permafrost conditions and the increasing of stability is achieved by insulation. Problems of thermal protection of frozen breeds are considered at high temperatures of air in mine workings.
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Date submitted2013-07-13
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Date accepted2013-09-21
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Date published2014-03-17
Modern technology of consumption waste management in the mining agglomeration
- Authors:
- M. Sh. Barkan
- A. B. Makhovikov
- E. I. Kabanov
Any industrial agglomeration is a territory, not only with a high concentration of industrial facilities, but also with high population density. This, in turn, is an essential prerequisite to problems associated with the large volume of waste consumption. To solve these problems it is necessary not only to improve the technology for processing different kinds of waste, but also to establish a system by their rapid collection and transport.
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Date submitted2010-07-07
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Date accepted2010-09-06
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Date published2011-03-21
Improvement of quality of dissimilar welded joints made of pipelines steels by application of vibromechanical treatment in welding
- Authors:
- O. F. Khafizova
The article describes opportunity of improvement of physical-mechanical properties of welded joint made of different strength grade pipeline steels (Steel 20 of K42 strength grade and 16ГС – K52) by applying vibration during the welding cycle. It’s shown that maximal positive effect is achieved by vibration frequency approximating to natural-vibration frequency of welded construction.
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Date submitted2010-07-15
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Date accepted2010-09-13
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Date published2011-03-21
Experimental setup for research Influence of vibromechanical treatment on mechanical properties of welded joints
- Authors:
- O. F. Khafizova
- V. I. Bolobov
The description of developed experimental setup for welding product that made of pipeline steels with application of applying vibration with intended frequency approximating to natural-vibration frequency of welded construction unit of pipelines during the welding cycle is presented.
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Date submitted2008-11-23
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Date accepted2009-01-30
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Date published2009-12-11
The estimate of the utilization’s efficiency of the production waste products, which appeared as a result of the preservation of the environment measures
- Authors:
- E. M. Pronin
Nowadays the problems of the stable growth of mineral and source of raw materials and fuel and energy complex industries are attached great importance to, since it influences the country social-economic condition. In its turn the development of the mining industry requires opening up new lands, which are especially vulnerable to different kinds of anthropogenous and technogenous factors. The changes in the state of economic system have excluded the lowering expenditure by the economy of the production scale. The typical features of a new economy became the progress of free competition and intensive demonopolization. At the same time for the mining industry it is significant that large-scale enterprises should be the foundation of many cities economies of the Russian Federation. For the way out of a system crisis it is necessary to change the strategy – to alter not only the condition of the system, but its management. The formation of the mining complexes permits to use sources of raw materials of the exploited deposits in the proper way, to process waste products of the basic production into the commodity output, to raise the efficiency and cut costs of the preservation of the environment measures from concentration waste products, exhaust solutions, gases, warm water harmful influence on the environment. The practical use of the production waste products of the mining complexes is unprofitable and makes sense only because of its opportunity partially compensating the aggregate investments for the preservation of the environment. The estimate of the utilization s efficiency of the production waste products has made.