Kinetic oxidations of phenol by piroluzit containing minerals
About authors
- 1 — Ph.D., Dr.Sci. associate professor National Mineral Resources University (Mining University)
- 2 — post-graduate student National Mineral Resources University (Mining University)
- 3 — Ph.D., Dr.Sci. professor National Mineral Resources University (Mining University)
Abstract
The kinetics parameters of phenol oxidation by MnO2 on the surface of iron-manganese nodules at pH = 5,5±0,5 at temperature region from 293 till 353 K was described in this paper. The oxidation reaction runs by second order on phenol. At temperature region from 293 till 353 K the limited stage is chemical reaction. The activation energy of oxidation on the surface of iron-manganese nodules is equal 6,65 kJ/mol, and it is less than it’s one for oxidation on MnO2 surface (42,0 kJ/mol). The oxidation products are hydrohinon and less than 10 pier. % p-benzohinon.
Область исследования:
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References
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- Serikov N.F. Water management of ferrous metal-lurgy factories. Мoscow, 1973. 408 p.
- Matocha Ch.J. Role of Mn(III) in Oxidation of Soil Organic Matter / Ch.J.Matocha, D.L.Sparks, J.E.Amonette, R.K.Kukkadapu // Soil Science Soc. of Amer.J. 2001. Vol. 65. N 1. P.58-66.
- Ukrainczyk L. Oxidation of phenol in acidic aque-ous suspensions of manganese oxides / L.Ukrainczyk, M.B.McBride // Clays and Clay Minerals. 1992. Vol. 40. N 2. P.157-166.
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