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M. A. Sulimova
M. A. Sulimova
National Mineral Resources University (Mining University)
National Mineral Resources University (Mining University)

Articles

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  • Date submitted
    2012-09-01
  • Date accepted
    2012-11-08
  • Date published
    2013-03-01

Kinetic oxidations of phenol by piroluzit containing minerals

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The kinetics parameters of phenol oxidation by MnO2 on the surface of iron-manganese nodules  at pH = 5,5±0,5 at temperature region from 293 till 353 K was described in this paper. The oxidation reaction runs by second order on phenol. At temperature region from 293 till 353 K the limited stage is chemical reaction. The activation energy of oxidation on the surface of iron-manganese nodules is equal 6,65 kJ/mol, and it is less than it’s one for oxidation on MnO2 surface (42,0 kJ/mol). The oxidation products are hydrohinon and less than 10 pier. % p-benzohinon.

How to cite: Cheremisina O.V., Sulimova M.A., Chirkst D.E. Kinetic oxidations of phenol by piroluzit containing minerals // Journal of Mining Institute. 2013. Vol. 202. p. 224.