Sustainable cold asphalt concrete from petroleum sludge and endogenous mining wastes: a circular economy approach for road maintenance in Moa, Cuba
Abstract
The accumulation of petroleum sludge in port facilities constitutes a significant environmental liability due to its high viscosity and complex management. This study evaluates the technical feasibility of using this waste as the main binder in the formulation of a cold asphalt concrete, combining it with endogenous aggregates (serpentinites from nickel industry rejects and vitric tuffs) for road maintenance in Moa, Cuba. A physical-chemical characterization of the materials was carried out, and asphalt mixtures with sludge contents of 8.0; 8.5, and 9.0 % were designed. Twenty-four specimens were fabricated using Marshall compaction, and their properties (density, stability, and deformation) were evaluated according to Cuban standards. After applying statistical quality control (rejection of specimens with > 10 % deviation), the experimental results demonstrated that curing time is a determining factor. After 45 days of curing at room temperature, the optimal mixture (8.5 % sludge) developed a Marshall stability of 7.32±0.21 kN and a deformation of 3.38±0.15 mm, satisfactorily complying with the quality indices of Cuban standard NC 54-18:1985 for dense mixtures. Environmental leaching tests confirmed the encapsulation of contaminants. This approach offers a sustainable technical solution for road infrastructure and contributes to the circular economy through the valorisation of industrial waste.
None
References
- Asim N., Badiei M., Torkashvand M. et al. Wastes from the petroleum industries as sustainable resource materials in construction sectors: Opportunities, limitations, and directions. Journal of Cleaner Production. 2021. Vol. 284. N 125459. DOI: 10.1016/j.jclepro.2020.125459
- Litvinova T.E., Suchkov D.V. Lightweight ash-based concrete production as a promising way of technogenic product utilization (on the example of sewage treatment waste). Journal of Mining Institute. 2023. Vol. 264, p. 906-918.
- Pashkevich M.A., Kulikova Yu.A. Lithification of leachate from municipal solid waste landfills with blast furnace slag. Journal of Mining Institute. 2024. Vol. 267, p. 477-487.
- Gorbaev A.V., Gorlenko N.V., Timofeeva S.S. Use of oil sludge as a combustible additive for the production of bricks. IOP Conference Series: Materials Science and Engineering. 2020. Vol. 962. N 042031. DOI: 10.1088/1757-899X/962/4/042031
- Benlamoudi A., Abdul Kadir A., Khodja M., Nuruddin M.F. Analysis of the cement clinker produced with incorporation of petroleum sludge. IOP Conference Series: Journal of Physics. 2018. N 995. N 012070, p. 6. DOI: 10.1088/1742-6596/995/1/012070
- Gerasimov A.M., Ustinov I.D., Zyryanova O.V. Use of clay-containing waste as pozzolanic additives. Journal of Mining Institute. 2023. Vol. 260, p. 313-320. DOI: 10.31897/PMI.2023.33
- Cañete-Pérez C.C., Linares-Cala E., García-Delgado D.E. et al. Caracterización y clasificación de algunos residuales petrolizados para su posible utilización y aprovechamiento económico. X Congreso Cubano de Geología (Geología, 2013). Geología Ambiental., La Habana, 1 al 5 de abril de 2013. URL: http://www.redciencia.cu/geobiblio/paper/2013_Canete_Perez_GEO6-P15.pdf (accessed 18.11.2025).
- Lara Negronis I.A. Evaluación de los residuos sólidos de la Empresa Comandante Pedro Sotto Alba para ser empleadas en la elaboración de mezclas asfálticas: Trabajo de Diploma. Universidad de Moa: Departamento de Minería, 2018, p. 56. URL: https://ninive.ismm.edu.cu/handle/123456789/1993 (accessed 18.11.2025).
- Cala A., Caro S., Lleras M., Rojas-Agramonte Y. Impact of the chemical composition of aggregates on the adhesion quality and durability of asphalt-aggregate systems. Construction and Building Materials. 2019. Vol. 216, p. 661-672. DOI: 10.1016/j.conbuildmat.2019.05.030
- Mohd Pauzi N.N., Ahmad Shah M.S. A Review on the Treatment of Petroleum Sludge and Use as Construction Materials. Civil and Sustainable Urban Engineering. 2022. Vol. 2. Iss. 1, p. 12-20. DOI: 10.53623/csue.v2i1.74
- Strizhenok A.V., Korelskiy D.S., Choi Y. Assessment of the Efficiency of Using Organic Waste from the Brewing Industry for Bioremediation of Oil-Contaminated Soils. Journal of Ecological Engineering. 2021. Vol. 22. Iss. 4, p. 66-77. DOI: 10.12911/22998993/133966
- Khurmamatov A.M., Yusupova N.K., Berdimbetov S.B. et al. Use of oil sludge waste for the production of lightweight granular material – expanded clay (keramzite). Universum: Technical sciences. 2025. N 11-9 (140), p. 26-30 (in Russian). DOI: 10.32743/UniTech.2025.140.11.21137
- Terrero Aguirre I., Leyva Rodríguez C.A., Noa Monjes R.R. Serpentine waste from Moa Nickel S.A. company as stone powder substitute in hot asphalt mixes. Ciencia & Futuro. 2025. Vol. 15. N 4, p. 377-391.
- Pashkevich M.A., Petrova T.A. Technogenic Impact of Sulphide-Containing Wastes Produced by Ore Mining and Processing at the Ozernoe Deposit: Investigation and Forecast. Journal of Ecological Engineering. 2017. Vol. 18. Iss. 6, p. 127-133. DOI: 10.12911/22998993/76700
- Ricardo-Solis D. Perspectiva de empleo de las tobas vítreas como áridos ligeros, localidad de Flores. Municipio de Banes: Trabajo de Diploma. Universidad de Moa, 2019, p. 63. URL: https://ninive.ismm.edu.cu/handle/123456789/3810 (accessed 20.11.2025).
- Hassan F.S., Ismael M.Q. Marshall Properties and Rutting Resistance for Asphaltic Mixtures Modified by Nano-Montmorillonite. Journal of Engineering. 2025. Vol. 31. N 2, p. 19-33. DOI: 10.31026/j.eng.2025.02.02
- Hernández-Acosta L., Domínguez-Rodríguez V.I., Adams R.H., Jiménez-Zapata K.C. Remediation and re-use of weathered hydrocarbon residue for the preparation of dense asphaltic mixtures. International Journal of Environmental Science and Technology. 2023. Vol. 20. Iss. 8, p. 8433-8444. DOI: 10.1007/s13762-022-04515-y
- Petrova T.A., Rudzisha E., Alekseenko A.V. et al. Rehabilitation of Disturbed Lands with Industrial Wastewater Sludge. Minerals. 2022. Vol. 12. Iss. 3. N 376. DOI: 10.3390/min12030376
- Fedorova L.V., Tretyakova Z.O., Voronina M.V. Bitumen-polymer compositions for asphalt concrete. Journal of Physics: Conference Series. 2021. Vol. 1990. N 012009. DOI: 10.1088/1742-6596/1990/1/012009
- Bykova M.V., Alekseenko A.V., Pashkevich M.A., Drebenstedt C. Thermal desorption treatment of petroleum hydrocarbon-contaminated soils of tundra, taiga, and forest steppe landscapes. Environmental Geochemistry and Health. 2021. Vol. 43. Iss. 6, p. 2331-2346. DOI: 10.1007/s10653-020-00802-0
- Yu Song, Jianlin Feng, Shaopeng Wu et al. Effect of Marshall compaction parameters on the performance and internal structure of steel slag asphalt concrete. Journal of Cleaner Production. 2025. Vol. 517. N 145843. DOI: 10.1016/j.jclepro.2025.145843
- Hasan A.M.A., Kamal R.S., Farag R.K., Abdel-raouf M.E. Petroleum sludge formation and its treatment methodologies: a review. Environmental Science and Pollution Research. 2024. Vol. 31. Iss. 6, p. 8369-8386. DOI: 10.1007/s11356-023-31674-3
- Gardete D., Picado-Santos L., Capitão S., Luzia R. Asphalt mix design: Discussion on the bulk specific gravity procedure influence on the results obtained from empirical, volumetric, and performance-based methods. Construction and Building Materials. 2022. Vol. 342. Part B. N 127870. DOI: 10.1016/j.conbuildmat.2022.127870
- Yao Zhang, Hu Chen, Peng Xiao et al. Investigation of average asphalt film thickness of dense graded asphalt mixtures with compaction effects. Construction and Building Materials. 2022. Vol. 326. N 126696. DOI: 10.1016/j.conbuildmat.2022.126696
- Bojorque Iñeguez J., Flores C., V’ásquez M. Marshall parameters for quality control of hot mix asphalt after pavement construction. Journal of Construction. 2019. Vol. 18. N 1, p. 178-185. DOI: 10.7764/RDLC.18.1.178
- Abbas M., Zaumanis M. Methodology for Physics-Informed Neural Networks for materials test result prediction: Case study on the Marshall test for asphalt. Case Studies in Construction Materials. 2026. Vol. 24. N e05829. DOI: 10.1016/j.cscm.2026.e05829
- Kuiry M., Karati S., Roy T.K. Determination of Marshall parameters of bituminous mix by using non-destructive testing method. Materials Today: Proceedings. 2023. DOI: 10.1016/j.matpr.2023.03.575
- Satayeva S.S., Burakhta V.A., Urazova A.F. et al. Asphalt Concrete Production Technology Using Oil Sludge from Zhaik Munay LLP. Journal of Engineering and Technological Sciences. 2024. Vol. 56. N 1, p. 71-80. DOI: 10.5614/j.eng.technol.sci.2024.56.1.6
- Kumar R., Goli A., Gottumukkala B.V. et al. Influence of curing process on the moisture loss, mechanical and performance characteristics of cold recycled asphalt mixes. Road Materials and Pavement Design. 2024. Vol. 25. Iss. 2, p. 259-275. DOI: 10.1080/14680629.2023.2199884
- Bastidas-Martínez J.G., Rondón-Quintana H.A. Assessment of asphalt binder content, temperature and loading rate in indirect tensile strength and resilient modulus tests of a hot-mix asphalt – Comparison with Marshall design method. Construction and Building Materials. 2024. Vol. 426. N 136158. DOI: 10.1016/j.conbuildmat.2024.136158
- Upadhya A., Thakur M.S., Sharma N., Sihag P. Assessment of Soft Computing-Based Techniques for the Prediction of Marshall Stability of Asphalt Concrete Reinforced with Glass Fiber. International Journal of Pavement Research and Technology. 2022. Vol. 15. Iss. 6, p. 1366-1385. DOI: 10.1007/s42947-021-00094-2
- Bin Xu, Jingyun Chen, Changhong Zhou, Weiying Wang. Study on Marshall Design parameters of porous asphalt mixture using limestone as coarse aggregate. Construction and Building Materials. 2016. Vol. 124, p. 846-854. DOI: 10.1016/j.conbuildmat.2016.08.005
- Xueying Zhao, Baofu Ma. Measurement of the Promoting Effect of Complex Conditions on the Adhesion Development in Curing Process of Cold Recycling Mixture with Emulsified Asphalt. Advances in Civil Engineering. 2024. Vol. 2024. N 9683383. DOI: 10.1155/2024/9683383
- Wenting Yang, Jian Ouyang, Yan Meng et al. Effect of curing and compaction on volumetric and mechanical properties of cold-recycled mixture with asphalt emulsion under different cement contents. Construction and Building Materials. 2021. Vol. 297. N 123699. DOI: 10.1016/j.conbuildmat.2021.123699
- Dalhat M.A., Osman S.A., Mu’azu N.D., Alagha O. Utilization of oil sludge as rejuvenator in hot-mix-asphalt containing reclaimed asphalt concrete. Construction and Building Materials. 2022. Vol. 338. N 127483. DOI: 10.1016/j.conbuildmat.2022.127483
- Ferrotti G., Mancinelli E., Passerini G., Canestrari F. Comparison of energy and environmental performance between warm and hot mix asphalt concrete production: A case study. Construction and Building Materials. 2024. Vol. 418. N 135453. DOI: 10.1016/j.conbuildmat.2024.135453
- Abdulrahman S., Yaro N.S.A., Al-Osta M.A. et al. Harnessing Sludge-Derived Materials for Circular and Sustainable Asphalt Pavement Engineering: A Bibliometric, Systematic Review, and Strategic SWOT Analysis. Arabian Journal for Science and Engineering. 2026. Vol. 51. Iss. 1, p. 615-654. DOI: 10.1007/s13369-025-10994-1
- Satayeva S., Nazarova D., Satybayeva N. Development of technology for obtaining asphalt concrete mixture using oil sludge as an additive. E3S Web of Conferences. 2024. Vol. 474. N 01014. DOI: 10.1051/e3sconf/202447401014
- Medina García L., Betancourt S., Rodríguez E. et al. Use of mining wastes in asphalt concretes production. Revista Ingeniería de Construcción. 2023. Vol. 38. N 2. DOI: 10.7764/RIC.00071.21
- Memon A.M., Sutanto M.H., Memon Z.A. et al. Valorization of petroleum sludge as rejuvenator for recycled asphalt binder and mixture. Case Studies in Construction Materials. 2024. Vol. 20. N e03318. DOI: 10.1016/j.cscm.2024.e03318